• Bulletin of the Korean Chemical Society
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• 제35권12호
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• pp.3590-3594
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• 2014

Blue phosphorescent $(dfpypy)_2Ir(mppy)$, where dfpypy = 2',6'-difluoro-2,3'-bipyridine and mppy = 5-methyl-2-phenylpyridine, has been synthesized by newly developed effective method and its solid state structure and photoluminescent properties are investigated. The glass-transition and decomposition temperature of the compound appear at $160^{\circ}C$ and $360^{\circ}C$, respectively. In a crystal packing structure, there are two kinds of intermolecular interactions such as hydrogen bonding ($C-H{\cdots}F$) and edge-to-face $C-H{\cdots}{\pi}(py)$ interaction. This compound emits bright blue phosphorescence with ${\lambda}_{max}=472nm$ and quantum efficiencies of 0.23 and 0.32 in fluid and the solid state. The emission band of the compound is red-shifted by 40 nm relative to homoleptic congener, $Ir(dfpypy)_3$. The ancillary ligand in $(dfpypy)_2Ir(mppy)$ has been found to significantly destabilize HOMO energy, compared to $Ir(dfpypy)_3$, $(dfpypy)_2Ir(acac)$ and $(dfpypy)_2Ir(dpm)$, without significantly changing LUMO energy.

• Structural Engineering and Mechanics
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• 제66권4호
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• pp.505-513
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• 2018

Steam flooding is widely used in heavy oil reservoir with coupling effects among the formation temperature change, fluid flow and solid deformation. The effective stress, porosity and permeability in this process can be affected by the multi-physical coupling of thermal, hydraulic and mechanical processes (THM), resulting in a complex interaction of geomechanical effects and multiphase flow in the porous media. Quantification of the state of deformation and stress in the reservoir is therefore essential for the correct prediction of reservoir efficiency and productivity. This paper presents a coupled fluid flow, thermal and geomechanical model employing a program (MATLAB interface code), which was developed to couple conventional reservoir (ECLIPSE) and geomechanical (ABAQUS) simulators for coupled THM processes in multiphase reservoir modeling. In each simulation cycle, time dependent reservoir pressure and temperature fields obtained from three dimensional compositional reservoir models were transferred into finite element reservoir geomechanical models in ABAQUS as multi-phase flow in deforming reservoirs cannot be performed within ABAQUS and new porosity and permeability are obtained using volumetric strains for the next analysis step. Finally, the proposed approach is illustrated on a complex coupled problem related to steam flooding in an oil reservoir. The reservoir coupled study showed that permeability and porosity increase during the injection scenario and increasing rate around injection wells exceed those of other similar comparable cases. Also, during injection, the uplift occurred very fast just above the injection wells resulting in plastic deformation.

• Journal of Advanced Marine Engineering and Technology
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• 제35권4호
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• pp.414-420
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• 2011

평균전류밀도 0~2000 $A/m^2$ 의 운전범위에 대한 음극 지지형 고체산화물 연료전지의 단위셀에 대한 열응력해석을 수행하였다. 평균전류밀도가 2000 $A/m^2$ 운전에서, 단위전지 열유동에 대한 수치해석적 방법으로 얻어진 온도분포를 토대로 구조해석을 수행하였다. 온도 편차가 매우 미미한 상태 에서 이러한 유체-구조 연성 해석 방법을 통하여 완전 결합된 조건에서 최대등가응력이 전해질은 262.58MPa, 캐소드는 28.55MPa, 애노드는 15.1MPa로 계산되어 전해질에서 가장 높은 응력이 발생함 을 알 수 있었다. 또한, 마찰접합조건인 경우 마찰계수가 증가함에 따라 응력이 증가함을 알 수 있었으며, 이는 셀 내부 물질간의 결합력에 의한 응력이 지배적임을 알 수 있었다.

• 대한기계학회논문집B
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• 제40권6호
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• pp.347-355
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• 2016

본 연구에서는 격자볼츠만 방법을 기반으로 유체-입자 상호작용에 대한 수치계산을 수행하였다. 유체 유동은 격자볼츠만 방법을 이용하였으며, 유동장 내에서의 고체입자 운동은 계산점(node) 기반의 가상영역으로 간주하여 해석하였다. 유체-입자의 상호작용은 격자볼츠만 방법의 지배방정식에 국부적으로 운동량 교환량을 추가하여 해석하며, 가상영역 내에 위치한 고체입자의 병진 및 회전 운동은 뉴턴 운동 방정식과 오일러(Euler) 방정식을 이용한다. 구성된 상호작용 모델의 유효성을 검증하기 위하여 중립상태에서의 부유 입자운동 및 단 입자의 침강에 대한 수치계산을 수행하였으며, 기존 연구들과의 비교를 통하여 본 연구의 유체-입자 상호작용 모델이 갖는 신뢰성과 효용성을 평가하였다.

• 한국자동차공학회논문집
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• 제19권5호
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• pp.134-142
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• 2011

Although combustion is essential in most energy generation processes, it is one of the major causes of air pollution. Exhaust pipes with circular fin were designed to study the effect of cooling the recirculated exhaust gases (EGR) of Diesel engines on the chemical composition of the exhaust gases and the reduction in the percentages of pollutant emissions. The gases examined in this study were oxides of nitrogen (NOx), carbon dioxide ($CO_2$) and carbon monoxide (CO). In addition, $O_2$ concentration in the exhaust was measured. The designs adopted in this study were about exhaust pipes with solid and hollow fins around them direct surface force measurement in water using a nano size colloidal probe technique. The direct force measurement between colloidal surfaces has been an essential topic in both theories and applications of surface chemistry. As particle size is decreased from micron size down to true Carbon nano Colloid size (<10 nm), surface forces are increasingly important. Nano particles at close proximity or high solids loading are expected to show a different behavior than what can be estimated from continuum and mean field theories. The current tools for directly measuring interaction forces such as a surface force apparatus or atomic force microscopy (AFM) are limited to particles much larger than nano size. This paper use Water and CNC fluid at normal cooling system of EGR. Experimental result showed all good agreement at Re=$2.54{\times}10^4$ by free convection and Re=$3.36{\times}10^4$ by forced air furnace.

• Nuclear Engineering and Technology
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• 제47권1호
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• pp.11-25
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• 2015

The accident at Japan's Fukushima Daiichi nuclear power plant in March 2011, caused by an earthquake and a subsequent tsunami, resulted in a failure of the power systems that are needed to cool the reactors at the plant. The accident progression in the absence of heat removal systems caused Units 1-3 to undergo fuel melting. Containment pressurization and hydrogen explosions ultimately resulted in the escape of radioactivity from reactor containments into the atmosphere and ocean. Problems in containment venting operation, leakage from primary containment boundary to the reactor building, improper functioning of standby gas treatment system (SGTS), unmitigated hydrogen accumulation in the reactor building were identified as some of the reasons those added-up in the severity of the accident. The Fukushima accident not only initiated worldwide demand for installation of adequate control and mitigation measures to minimize the potential source term to the environment but also advocated assessment of the existing mitigation systems performance behavior under a wide range of postulated accident scenarios. The uncertainty in estimating the released fraction of the radionuclides due to the Fukushima accident also underlined the need for comprehensive understanding of fission product behavior as a function of the thermal hydraulic conditions and the type of gaseous, aqueous, and solid materials available for interaction, e.g., gas components, decontamination paint, aerosols, and water pools. In the light of the Fukushima accident, additional experimental needs identified for hydrogen and fission product issues need to be investigated in an integrated and optimized way. Additionally, as more and more passive safety systems, such as passive autocatalytic recombiners and filtered containment venting systems are being retrofitted in current reactors and also planned for future reactors, identified hydrogen and fission product issues will need to be coupled with the operation of passive safety systems in phenomena oriented and coupled effects experiments. In the present paper, potential hydrogen and fission product issues raised by the Fukushima accident are discussed. The discussion focuses on hydrogen and fission product behavior inside nuclear power plant containments under severe accident conditions. The relevant experimental investigations conducted in the technical scale containment THAI (thermal hydraulics, hydrogen, aerosols, and iodine) test facility (9.2 m high, 3.2 m in diameter, and $60m^3$ volume) are discussed in the light of the Fukushima accident.

• 터널과지하공간
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• 제28권5호
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• pp.400-425
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• 2018

본 논문에서는 국제공동연구인 DECOVALEX-2019 프로젝트 Task B의 연구결과와 현황을 소개하였다. Task B의 주제는 'Fault slip modelling'으로 유체의 주입으로 인해 발생하는 단층의 재활성(미끄러짐, 전단파괴)과 수리역학적 거동을 예측할 수 있는 해석기법을 개발하는 데에 그 목적이 있다. 1단계 연구는 참가팀들이 연구주제에 대해 숙지하고, 벤치마크 모델을 대상으로 단층의 투수특성과 역학적 거동의 상호작용을 모사할 수 있는 해석코드를 개발할 수 있도록 하는 준비 단계의 연구이다. 본 연구에서는 TOUGH-FLAC 연동해석 기법을 사용하여 물 주입으로 인한 단층의 수리역학적 연계거동을 모사하였다. TOUGH2 해석에서는 단층을 Darcy의 법칙과 삼승법칙을 따르는 연속체 요소로 모델링하였으며, FLAC3D 해석에서는 미끄러짐과 개폐가 허용되는 불연속 인터페이스 요소를 통해 모사하였다. 두 가지 수리간극모델에 대하여 수리역학적 커플링 관계식을 수치화하였으며, 연속체 요소(수리모델)와 인터페이스 요소(역학모델)의 거동을 연계할 수 있는 해석기법을 제시하였다. 또한, 단층의 역학적 변형(간극의 변화)으로 인한 수리물성 변화와 기하학적 변화(해석 메쉬의 변형)를 수리해석에 반영할 수 있는 해석기법을 개발하였다. 다양한 압력의 물을 단계적으로 주입하고 이로 인해 유도되는 단층의 탄성거동 및 전단파괴(미끄러짐)에 대해 살펴보았으며, 수리간극의 변화 양상과 원인, 압력 분포와 주입율의 관계 등을 면밀히 검토하였다. 해석 결과, 본 연구에서 개발한 해석기법이 물 주입으로 인한 단층의 미끄러짐 거동을 합리적인 수준에서 재현할 수 있는 것으로 판단할 수 있었다. 본 연구의 해석모델은 Task B에 참여하는 국외 연구팀들과의 의견 교류와 워크숍을 통해 지속적으로 개선하는 한편, 향후 연구의 현장시험에 적용하여 타당성을 검증할 예정이다.