• Korean Chemical Engineering Research
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• v.57 no.6
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• pp.868-873
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• 2019

In this study, the evaluation of performance of AORFB using methyl viologen and TEMPOL as organic active materials in neutral supporting electrolyte (NaCl) with various membrane types was performed. Using methyl viologen and TEMPOL as active materials in neutral electrolyte solution, the cell voltage is 1.37V which is relatively high value for AORFB. Two types of membranes were examined for performance comparison. First, when using Nafion 117 membrane which is commercial cation exchange membrane, only the charge process occurred in the first cycle and the single cell couldn't work because of its high resistance. However, when using Fumasep anion exchange membrane (FAA-3-50) instead of Nafion 117 membrane, the result was obtained as the totally different charge-discharge graphs. When current density was $40mA{\cdot}cm^{-2}$ and cut off voltage range was from 0.55 V to 1.7 V, the charge efficiency (CE) was 97% and voltage efficiency (VE) was 78%. In addition, the discharge capacity was $1.44Ah{\cdot}L^{-1}$ which was 54% of theoretical capacity ($2.68Ah{\cdot}L^{-1}$) at $10^{th}$ cycle and the capacity loss rate was $0.0015Ah{\cdot}L^{-1}$ per cycle during 50 cycles. Through cyclic voltammetry test, it seems that this difference in the performance between the full cell using Nafion 117 membrane and Fumasep anion exchange membrane came from increasing resistance due to chemical reaction between membrane and active material, not the capacity loss due to cross-over of active material through membrane.

• Korean Chemical Engineering Research
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• v.51 no.1
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• pp.47-52
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• 2013

In this study, the catalytic performance and characterization of $Ni/Ce_xZr_{1-x}O_2$ were investigated using an autothermal reforming (ATR) process for hydrogen production. The $Ni/Ce_xZr_{1-x}O_2$ catalysts were prepared using the following methods: the water method (CZ-W), urea water method (CZ-UW) and urea, water and ethanol method (CZ-UWA). The performance of $Ni/Ce_xZr_{1-x}O_2$ catalysts in autothermal reforming of propane for hydrogen production was studied in a fixed-bed flow reactor. Reaction tests were conducted by using a feed of $H_2O/C_3H_8/O_2$=3/1/0.37 and $300{\sim}700^{\circ}C$. The CZ-UW and CZ-UWA catalysts showed higher propane conversion and hydrogen yield than the CZ-W catalyst. The activity test confirmed that the improvement in the water-ethanol catalyst was due to the low level of carbon deposition. SEM showed that the surface carbon consisted of clusters on the used CZ-UW catalyst, which is incontrast to the nano-fiber morphology observed on the used CZ-UWA catalyst. It was found that the amount of carbon deposition depends on the preparation method. Especially the $Ni/Ce_{0.75}Zr_{0.25}O_2$ was showed higher propane conversion and hydrogen yield than the other catalysts. Also TGA showed that the resistance of carbon deposition increase to Co addition.

• Proceedings of the Korean Geotechical Society Conference
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• 2009.09a
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• pp.133-144
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• 2009

Incheon Bridge, 18.4 km long sea-crossing bridge, will be opened to the traffic in October 2009 and this will be the new landmark of the gearing up north-east Asia as well as the largest & longest bridge of Korea. Incheon Bridge is the integrated set of several special featured bridges including a magnificent cable-stayed girder bridge which has a main span of 800 m width to cross the navigation channel in and out of the Port of Incheon. Incheon Bridge is making an epoch of long-span bridge designs thanks to the fully application of the AASHTO LRFD (load & resistance factor design) to both the superstructures and the substructures. A state-of-the-art of the geotechnologies which were applied to the Incheon Bridge construction project is introduced. The most Large-diameter drilled shafts were penetrated into the bedrock to support the colossal superstructures. The bearing capacity and deformational characteristics of the foundations were verified through the world's largest static pile load test. 8 full-scale pilot piles were tested in both offshore site and onshore area prior to the commencement of constructions. Compressible load beyond 30,000 tonf pressed a single 3 m diameter foundation pile by means of bi-directional loading method including the Osterberg cell techniques. Detailed site investigation to characterize the subsurface properties had been carried out. Geotextile tubes, tied sheet pile walls, and trestles were utilized to overcome the very large tidal difference between ebb and flow at the foreshore site. 44 circular-cell type dolphins surround the piers near the navigation channel to protect the bridge against the collision with aberrant vessels. Each dolphin structure consists of the flat sheet piled wall and infilled aggregates to absorb the collision impact. Geo-centrifugal tests were performed to evaluate the behavior of the dolphin in the seabed and to verify the numerical model for the design. Rip-rap embankments on the seabed are expected to prevent the scouring of the foundation. Prefabricated vertical drains, sand compaction piles, deep cement mixings, horizontal natural-fiber drains, and other subsidiary methods were used to improve the soft ground for the site of abutments, toll plazas, and access roads. Light-weight backfill using EPS blocks helps to reduce the earth pressure behind the abutment on the soft ground. Some kinds of reinforced earth like as MSE using geosynthetics were utilized for the ring wall of the abutment. Soil steel bridges made of corrugated steel plates and engineered backfills were constructed for the open-cut tunnel and the culvert. Diverse experiences of advanced designs and constructions from the Incheon Bridge project have been propagated by relevant engineers and it is strongly expected that significant achievements in geotechnical engineering through this project will contribute to the national development of the longspan bridge technologies remarkably.

• Journal of the Korea Institute of Building Construction
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• v.20 no.5
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• pp.399-407
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• 2020

The aim of the research is to provide the boundary conditions for segregation of normal strength grade and high fluidity concrete mixture (so called mid-fluidity concrete) with rheology parameters. Since the normal strength grade concrete mixture has a relatively high water-to-cement ratio and no SCMs, it is easy to be segregated when superplasticizer is added. Hence, to achieve the mid-fluidity concrete of normal strength grade and high fluidity, preventing segregation of the mixture is inevitable. In this research, using two superplasticizers with different solid concentrations, the flow behaviors and rheological behaviors were assessed by increasing fluidity until the segregation happened. According to the experiment in this research, an unusual behavior in rheology parameters was observed when the concrete mixture started to be segregated. From this results and report, it is expected to contribute on the definition of segregation with rheological test methods.

• Journal of the Korea Institute of Building Construction
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• v.13 no.4
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• pp.391-399
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• 2013

For high strength concrete of 40~60 MPa, the effects on the early strength and concrete dry shrinkage properties replacing 60~80% of Ordinary Portland Cement with Blast Furnace Slag Powder and using the Alkali Activator (Modified Alkali Sulfate type) are considered in this study. 1% Alkali Activator to the binder, cumulative heat of hydration for 72 hours was increased approximately 45%, indicating that heat of hydration contributes to the early strength of concrete, and the slump flow of concrete decreased slightly by 3.7~6.6%, and the 3- and 7- strength was increased by 8~12%, which that the Alkali Activator (Modified Alkali Sulfate type) is effective for ensuring the early strength when manufacturing High Strength Concrete (60%) of Blast Furnace Slag Powder. Furthermore, the dry shrinkage test, both 40 MPa and 60 MPa specimens had level of length changes in order of BS40 > BS60 > BS60A > BS80A, and the use of the Alkali Activator somewhat improved resistance to dry shrinkage.

• Journal of the Korea institute for structural maintenance and inspection
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• v.17 no.5
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• pp.94-104
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• 2013

Experiments were divided into two parts; one part is to understand the basic properties of high flowable VA/VeoVa-modified cement mortar with different polymer cement ratio (P/C) and the weight ratio of fine aggregate to cement (C:F) and the other part is to investigate the effect of surface water spread on the concrete substrate on adhesion in tension. To understand the basic performance, the specimens were prepared with proportionally mixing VA/VeoVa redispersible powder, ordinary portland cement, silica sand, superplasticizer and viscosity enhancing agent. Here, P/C were 10, 20, 30, 50 and 75% and C:F were 1:1 and 1:3. As the change of P/C and C:F unit weight, flow test, crack resistance and adhesion in tension were measured. Three specimens with good adhesion properties were selected among specimens with different P/C and C:F. The effect of surface water evenly sprayed on concrete substrate on adhesive strength is investigated. The results show that surface water on concrete substrate increases the adhesion in tension of high flowable VA/VeoVa-modified cement mortar and additionally improves the flowability compared to the non-sprayed case.

• Journal of the Korean institute of surface engineering
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• v.39 no.4
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• pp.179-189
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• 2006

High velocity oxygen fuel(HVOF) thermal spray coating of WC-Co powder is one of the most promising candidate for the replacement of the traditional hard chrome plating and ceramics coating because of the environmental problem of the very toxic $Cr^{6+}$ known as carcinogen and the brittleness of ceramics coating. WC-Co micron and nano powder were coated by HVOF thermal spraying method for the study of durability improvement of the high speed spindle. Coatings were planned by Taguchi program for the four spray parameters of spray distance, flow rates of hydrogen, oxygen and powder feed rate. Optimal coating process was obtained by the studies of coating properties such as porosity, surface roughness, micro hardness, and micro structure. WC-Co micron and nano powder were coated on the Inconel 718 substrate by the optimal coating process obtained in this study. The wear behaviors were studied by the sliding wear tester at room temperature and at an elevated temperature of $500^{\circ}C$ for the application to high speed spindle. Sliding wear test was carried out for four most promising hard coatings of chrome coating, ceramics coatings such as $A1_2O_3,\;Cr_2O_3$ and HVOF Co-alloy T800 for the comparison of their wear behaviors. HVOF WC-Co coating was better than other coatings showing highest micro hardness of 1400 Hv and comparable friction coefficients with others. HVOF WC-Co coating is a strong candidate for the replacement of the traditional hard chrome plating for the high speed spindle.

• The Journal of Internal Korean Medicine
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• v.22 no.2
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• pp.199-205
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• 2001

Background and Purpose : Transcranial doppler ultrasonography(TCD) is a noninvasive and nonradioactive technique for evaluation of the hemodynamics in large cerebral vessels. Sahyangsohap-won(SS) has been considered to be effective for the treatment of various disease, especially cerebrovascular, cardiovascular, and psychosomatoform disorders. But, there is no study about the effect of SS on the cerebral hemodynamics in humans. The aim of this study was to assess the effect of SS on the changes in cerebral hemodynamics and the dose-dependant effect by using TCD. Subjects and Methods : 30 healthy subjects were randomly divided into three group: group 1 took no drug, group 2 took SS one pill, and group 3 took SS 2 pills. Changes in the mean blood flow velocity(MBFV) and pulsatility index(PI) in the middle cerebral artery were evaluated by means of TCD. We obtained hypercapnia with breath-holding and evaluated cerebrovascular reactivity with the breath-holding index(BHI). Systolic blood pressure(SBP), diastolic blood pressure(DBP), and heart rate(HR) were measured by means of ambulatory blood pressure monitoring. In group 2 and group 3, the evaluations were performed during the baseline and were repeated at 20, 40, and 60 minutes after SS administration. In group 1, the evaluation was performed at corresponding time intervals. Results : In mean values of MSFV, PI, SSP, DBP, and HR, no stastically significant differences were found between the 3 groups. However, BHI values were significantly lower in groups 2 and 3 than in group 1 at 40 minutes after SS administration(P<0.05, group 1 vs group 2, group 1 vs group 3 by post-hoc analysis: Scheffe's test) but in dose-dependant effect, there was no difference between group 2 and group 3. Conclusion : These results suggest that SS can decrease vascular resistance in cerebral small arteries or arterioles and enhance their distensibility. Further studies on larger numbers of subjects are needed to confirm these effects and the dose-dependant effects.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.8
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• pp.3704-3712
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• 2012

Recently, antiwashout underwater concrete has been increasingly used for marine foundations of long span bridges. However, to shorten the construction period of antiwashout underwater concrete used in marine foundations, high fluidity antiwashout underwater concrete should be manufactured largely improving fluidity than the previous one. Thus, the objective of this experimental research is to suggest optimum mix proportions of high fluidity antiwashout underwater concrete. For this purpose, concrete specimens containing ground granulated blast furnace slag were manufactured according to the dosage of antiwashout admixture for unit binder contents of 550 and 600kg/$m^3$, respectively. And then, their quality performances such as slump flow, setting time, underwater segregation resistance, and ratio of compressive strength were evaluated according to the related specification of Korea Concrete Institute. It was observed from the test results that the minimum dosage of antiwashout admixture was necessary to satisfy the related specification.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.4
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• pp.154-159
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• 2019

The glass-ceramic of $Li_2O-Al_2O_3-SiO_2$ system was fabricated by using yttrium oxide and iron oxide that it can reduce the melting temperature and affect the homogenization. Zirconium sulfate was used as a nucleation agent. Calcium phosphate was used to improve the flow the glass so as reduce the viscosity of the glass. The glass-ceramics met a thermal shock test of more than $750^{\circ}C$ and the temperature at which the coefficient of thermal expansion rapidly increased at over $800^{\circ}C$ was shifted by about the above $30^{\circ}C$. Therefore, it is concluded that the glass-ceramic of $Li_2O-Al_2O_3-SiO_2$ system with yttrium oxide and iron oxide was founded to have good melting conditions and excellent thermal expansion resistance at high temperature such as special field for kitchen utensils.