• Title/Summary/Keyword: Flash Point

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Engineering Cellulose Fibers for High-Value Added Products for Pulp & Paper Industry

  • Ko, Young Chan;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.6
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    • pp.22-40
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    • 2015
  • Cellulose fibers is one of the most abundant in nature. It has many distinctive features: abundant in nature, biodegradable, non-toxic, eco-friendly, sustainable, easy to fabricate, hydrophilic, and cost-effective. Cellulose fibers, known as pulp, is produced from cellulose-containing materials by the pulping process. As the raw material, wood has been most commonly used while recycled pulp has been also used to some degree. Thus, pulp usually refers to wood pulp. Generally, the pulp and paper industry is regarded as the commodity market where the cost should be much more important than the quality. It also belongs to a mature market where the growth is slow, or even in decline. Accordingly, technological development has been rather stagnant for the industry. Recently, however, the pulp and paper industry has faced very serious challenges. First, due to digital technology, there has been a steady decline in the need for pulp and paper products. The digital industry has continuously replaced printed products such as books, newspapers, and magazines. Second, there has been a trend initiated by developed countries to limit the use of wood as the raw material for the sake of environmental protection. This forces the industry to find a more efficient use of wood pulp as well as finding alternative, non-wood sources. Third, as an individual becomes wealthier and more conscious of health-care, the quality of a product becomes more important than the cost. Thus, a paradigm shift is needed from the cost-conscientious to the quality conscientious. The objective of this article is to review the technologies aimed at engineering cellulose fibers for producing high-value added paper products.

Risk Assessment of Fire and Explosion of Methane (메탄의 화재 및 폭발 위험성 평가)

  • Ha Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.9 no.2 s.27
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    • pp.1-7
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    • 2005
  • The thermochemical parameters for safe handling, storage, transport, operation and process design of flammable substances are explosive limit, flash point, autoignition temperature, minimum oxygen concentration, heat of combustion etc.. Explosive limit and autoignition temperature are the major physical properties used to determine the fire and explosion hazards of the flammable substances. Explosive limit and autoignition temperature of methane fur LNG process safety were investigated. By using the literatures data, the lower and upper explosive limits of methane recommended 4.8 vol$\%$ and 16 vol$\%$, respectively. Also autoignition temperatures of methane with ignition sources recommended $540^{\circ}C$ at the electrically heated cruicible furnace (the whole surface heating) and recommended about $1000^{\circ}C$ in the local hot surface. The new equations for predicting the temperature dependence and the pressure dependence of the lower explosive limits for methane are proposed. The values calculated by the proposed equations were a good agreement with the literature data.

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Flammability and Thermal Stabilities of Heat Transfer Oils (열매체유의 인화성과 열안정성)

  • Lee, Keun-Won;Lee, Jung-Suk;Choi, Yi-Rac
    • Journal of the Korean Institute of Gas
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    • v.15 no.2
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    • pp.82-87
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    • 2011
  • Heat transfer oils are used in applications such as heating systems of chemical plant, refinery heat exchange systems, gas plant process, injection molding systems, and pulp and paper processing. These oils are extremely stable and resistance to thermal and oxidative degradation. In the event of a spill or accidental release of heat transfer oils, it can be ignite easily when there is an ignition source. This paper discusses the flammability and thermal stabilities of new and used oils. The flammability of the oils are assessed by measuring changes in flash point and auto ignition temperature. The thermal stability of oils are evaluated by the thermal screening unit ($TS^u$) and the differential scanning calorimeter (DSC). From the experimental results, it is suggested to give fire hazard characteristics to safe precautions for the proper use and treatment of heat transfer oils.

Thermo-Chemical Treatment Characteristics of Recycling Oil Obtained from Pyrolysis of Refused Plastics (폐플라스틱 열분해(熱分解) 재생연료유(再生燃料油)의 열화학적(熱化學的) 처리(處理) 특성(特性))

  • Lee, In-Gu;Kim, Jae-Ho
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2006.09a
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    • pp.39-54
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    • 2006
  • An experimental study on the hydro-cracking of recycling oil obtained from refused plastics was performed for up-grading of its fuel characteristics. Major experimental parameters were reaction temperature ($300^{\circ}C{\sim}700^{\circ}C$) and presence of catalysts (Al-Si, activated carbon, zeolite). The effect of the experimental parameters on the liquid product characteristics such as flash point, kinetic viscosity, and solid content was investigated. The hydro-cracking reactions of the recycling oil at $300^{\circ}C{\sim}400^{\circ}C$ improved the oil characteristics of the liquid products. Activated carbon was revealed as a stable and active catalyst in the hydro-cracking reaction at a temperature range investigated.

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The Development of Authoring Tool for Distance Education of Ubiquitous Environment (유비쿼터스 환경의 원격교육을 위한 저작도구의 개발)

  • Kim, Chi-Su;Yim, Jae-Hyeon
    • Journal of The Korean Association of Information Education
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    • v.8 no.3
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    • pp.365-372
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    • 2004
  • The purpose of this study is to develop FVU, which enables teachers effectively to construct self-page on the screen, to reduce the size of file for teaching, and to correct many different kinds of event which was already made in the previous. The instrument used in the development of this Editor is UML(Unified Modeling Language), which is object-oriented methodology. The Authoring tool developed in this study is named FVU. The first page which is needed in class can be constructed by using VUEditor in FVU. Using VUEditor can get Instructional Syllabus exported into VUAuthor through Vector-transformation. Through this procedure, the size of image file comes to be reduced into forming low band width, which results in solving the problem of network traffic. Also, Instructor can create image, shape and text, and delete and correct errors or mistakes which make in the course of constructing materials for teaching. In conclusion, this VUEditor enables program designer to construct the first page, even without using such applied program as Image Tool and Power Point. This VUEditor makes instructor to make some contents for teaching easily.

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Investigation of Combustion Properties for Using Safe Hydrogen (안전한 수소 이용을 위한 연소특성치 고찰)

  • Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.12 no.2
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    • pp.1-6
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    • 2008
  • For the safety design and operation of many gas process, it is necessary to know certain explosion limit, flash point, autoignition temperature (AIT) and minimum oxygen concentration of handling substances. Also it is necessary to know explosion limit at high temperature and pressure. In this study for the safe handling of hydrogen, explosion limit and AIT of combustion properties for hydrogen were investigated. By using the literatures data, the lower and upper explosion limits of hydrogen recommended 4.0 vol% and 77.0 vol%. Also the AIT of hydrogen with ignition sources recommended $400^{\circ}C$ at the electrically heated crucible furnace (the whole surface heating) and recommended $640^{\circ}C$ at the local hot surface. The new equations for predicting the temperature and the pressure dependence of the explosion limits of hydrogen are proposed. The values calculated by the proposed equations were a good agreement with the literature data.

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Analysis of Development Trends on Bio-based Environmental Transformers Oils in Power Sector (전력분야의 바이오 기반 친환경 전기 절연유 적용에 관한 개발 동향 분석)

  • Kim, Jae-Kon;Min, YoungJe;Kim, Mock-Yeon;Kwark, ByeongSub;Park, Hyunjoo
    • Tribology and Lubricants
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    • v.38 no.2
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    • pp.41-52
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    • 2022
  • Mineral electrical insulating oil, which is widely used in transformers, exhibits excellent cooling performance and transformer efficiency. However, given that it is composed of petroleum-based components, it is weak in terms of biodegradability. This causes environmental problems in case of leakage and a low flash point, which is a factor that would cause great damage in the event of a fire in a substation. In this context, the use of eco-friendly electric insulating oil composed of bio-based vegetable oil and synthetic ester, which has excellent biodegradability and flame retardancy performance, has recently been expanded to the field of electric power, and various research and development (R&D) studies are in progress. According to different research results, vegetable oil and synthetic ester manufacturing technology, thermal stability, oxidation stability, property change, and quality control, which are characteristics of eco-friendly electrical insulating oils, are major factors affecting the maintenance of insulating oil properties. In addition, power companies have established and operated quality control standards according to the use of eco-friendly electrical insulating oil as they expand the exploitatoin of renewable energy in electricity production. In particular, deterioration and oxidation characteristics were jointly identified in R&D as an important influencing factor according to the content of saturated and unsaturated fatty acids present in vegetable oils and synthetic esters in power transformer applications.

Pillared Bentonite Materials as Potential Solid Acid Catalyst for Diethyl Ether Synthesis: A Brief Review

  • Puji Wahyuningsih;Karna Wijaya;Aulia Sukma Hutama;Aldino Javier Saviola;Indra Purnama;Won-Chun Oh;Muhammad Aziz
    • Korean Journal of Materials Research
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    • v.34 no.5
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    • pp.223-234
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    • 2024
  • This review explores the potential of pillared bentonite materials as solid acid catalysts for synthesizing diethyl ether, a promising renewable energy source. Diethyl ether offers numerous environmental benefits over fossil fuels, such as lower emissions of nitrogen oxides (NOx) and carbon oxides (COx) gases and enhanced fuel properties, like high volatility and low flash point. Generally, the synthesis of diethyl ether employs homogeneous acid catalysts, which pose environmental impacts and operational challenges. This review discusses bentonite, a naturally occurring alumina silicate, as a heterogeneous acid catalyst due to its significant cation exchange capacity, porosity, and ability to undergo modifications such as pillarization. Pillarization involves intercalating polyhydroxy cations into the bentonite structure, enhancing surface area, acidity, and thermal stability. Despite the potential advantages, challenges remain in optimizing the yield and selectivity of diethyl ether production using pillared bentonite. The review highlights the need for further research using various metal oxides in the pillarization process to enhance surface properties and acidity characteristics, thereby improving the catalytic performance of bentonite for the synthesis of diethyl ether. This development could lead to more efficient, environmentally friendly synthesis processes, aligning with sustainable energy goals.

The study on performance of characteristics in engine oil by vehicle driving (차량 운행에 따른 엔진오일의 성능특성 평가 연구)

  • Lee, Joung-Min;Lim, Young-Kwan;Jung, Choong-Sub;Kim, Ye-Eun;Han, Kwan-Wook;Na, Byung-Ki
    • Journal of Energy Engineering
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    • v.22 no.2
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    • pp.237-244
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    • 2013
  • The engine oil is used for lubrication of various internal combustion engines. Recently, the vehicle and engine oil manufacture usually guarantee for oil change over 15000~20000 km mileage, but the most of driver usually change engine oil every 5000 km driving in korea. It can cause to raise environmental contamination by used engine oil and increase the cost of driving by frequently oil change. In this study, we investigate the various physical properties such as flash point, pour point, kinematic viscosity, cold cranking simulator characteristics, total acid number, four-ball test and concentration of metal component for fresh engine oil and used engine oil after real vehicle driving (5000 km, 10000 km). The result showed that the total acid number, wear scar diameter by four-ball test, Fe and Cu had increased than fresh engine oil, but 2 kind of used oil (5000 km and 10000km) had similar physical values and concentration of metal component.

The Monitoring Study of Exchange Cycle of Automatic Transmission Fluid (자동변속기유(ATF) 교환주기 모니터링 연구)

  • Lim, Young-Kwan;Jung, Choong-Sub;Lee, Jeong-Min;Han, Kwan-Wook;Na, Byung-Ki
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.274-278
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    • 2013
  • Automatic transmission fluid (ATF) is used as an automatic transmission in the vehicle or as a characterized fluid for automatic transmission. Recently, vehicle manufacturers usually guarantee for changing fluids over 80000~100000 km mileage or no exchange. However, most drivers usually change ATF below every 50000 km driving distance when driving in Republic of Korea according to a survey from the Korea Institute of Petroleum Management which can cause both a serious environmental contamination by the used ATF and an increase in the cost of driving. In this study, various physical properties such as flash point, pour point, kinematic viscosity, dynamic viscosity at low temperature, total acid number and four-ball test were investigated for both fresh ATF and used ATF after the actual vehicle driving distance of 50000 km and 100000 km. It was shown that most physical properties were suitable for the specification of ATF, but the foam characteristics of the used oil after running 100000 km was unsuitable for the specification of fresh ATF. Therefore, the exchange cycle of ATF every 80000~100000 km driving distance is recommended considering great positive contributions to preventing environmental pollution and reducing driving cost.