• Title/Summary/Keyword: Flash Point

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Contraction of Alpha-nickel Hydroxide Layers by Excess Coulombic Attraction of Anions (전기화학적으로 형성된 알파 상 니켈 수산화물의 층간 거리에 미치는 음이온의 영향 연구)

  • Kim, Gwang-Beom;Ganesh Kumar, V.;Bae, Sang-Won;Lee, Jae-Seong
    • Journal of the Korean Chemical Society
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    • v.50 no.2
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    • pp.141-152
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    • 2006
  • In this study computer assisted instruction materials for the ‘Solution' chapter in high school chemistry II textbook were developed based on a view of particle and analyze the effect of the materials on 10th and 11th high school students. The contents of developed materials are dissolution, vapor pressure, the change of boiling point and freezing point, osmosis, and so on which are the major contents of Solution chapter in high school chemistry II textbook. Materials were developed with using animation and simulation for students understanding of the phenomena with a particle view point. Many phenomena in a solution were not simplified by colligative property of solution, but tried to explain by the concept of attraction between solute and solvent molecules. This computer assisted learning materials were developed using Flash 5.0 and Flash 6.0 Action Script. Educational effects of the materials on 10th and 11th grade students represented statistically meaningful increase of concept understanding. Especially the materials were effective to the transition stage or formal stage students in 10th grade and formal stage or the natural science major students in 11th grade.

Permanent Deformation Properties of Asphalt Binder Modified by Pyrolysis Carbon Black of Waste Tires (열분해 카본블랙을 이용한 아스팔트 바인더의 소성변형 특성)

  • Lee, Dong-Hang;Kim, Jung-Ku;Lee, Kwan-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.8
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    • pp.4028-4032
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    • 2013
  • Recycling method for pyrolyzed carbon black from pyrolysis process of waste tires is needed. Carbon black from pyrolysis of waste tires was used to modify and improve the permanent deformation properties of asphalt binder. 0%, 5%, 10%, 15% and 20% of pyrolyzed carbon black was mixed. Couple of laboratory tests, such as softening point, flash point test, rotational viscometer test and dynamic shear rheometer test, were carried out. The use of pyrolyzed carbon black incresed the softening point, rotational viscosity at 135oC, and resistance of permanent deformation.

EMISSION CHARACTERISTICS IN ULTRA LOW SULFUR DIESEL

  • Oh, S.-K.;Baik, D.-S.;Han, Y.C.
    • International Journal of Automotive Technology
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    • v.4 no.2
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    • pp.95-100
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    • 2003
  • Automobile industry has been developed rapidly as a key manufacturing industry in Korea. Meanwhile, air pollution is getting worse noticeably than ever. In the diesel emission, PM (Particulate Matter) and NOx (Nitrogen Oxides) have been exhausted with a great amount and the corresponding emission regulations are getting stringent. In order to develop low emission engines, it is necessary to research on better qualified fuels. Sulfur contained in fuel is transformed to sulfur compound by DOC (Diesel Oxidation Catalyst) and then it causes to the increase of sulfate-laden PM on the surface of catalyst. In this research, ULSD (Ultra Low Sulfur Diesel) is used as a fuel and some experimental results are investigated. ULSD can reduce not only PM but also gas materials because cetane value, flash point, distillation 90%, pour point and viscosity are improved in the process of desulfurization. However, excessively reduced sulfur may cause to decease lubricity of fuel and engine performance in fuel injection system. Therefore, it requires only modest adjusted amount of sulfur can improve engine performance and DOC, as well as decrease of emission.

Production of Biodiesel from Yellow Oleander (Thevetia peruvian) Oil and its Biodegradability

  • Yarkasuwa, Chindo Istifanus;Wilson, Danbature;Michael, Emmanuel
    • Journal of the Korean Chemical Society
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    • v.57 no.3
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    • pp.377-381
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    • 2013
  • Thevetia peruviana (Yellow Oleander) seed oil was extracted with n-hexane in a soxhlet extractor. The ethanolysis and methanolysis of the oil were carried out with 50% of potassium hydroxide in ethanol and methanol respectively by weight of oil, as catalyst. The biodiesel was tested for biodegradability using E. coli. The percentage yield of the FAEE and FAME were 84.8% and 91.6% respectively. The biodegradability values of 81.4% and 86.2% were obtained for FAEE and FAME respectively after a period of 28 days. Other fuel quality parameters determined are the cetane index of 47.19 (FAEE) and 58.97 (FAME), flash point of $198^{\circ}C$ (FAEE) and $175^{\circ}C$ (FAME), kinematic viscosity at $40^{\circ}C$ of 5.21 $mm^2s^{-1}$ (FAEE) and 5.10 $mm^2s^{-1}$(FAME), pour point of $4^{\circ}C$ (FAEE) and $-2^{\circ}C$ (FAME) and a cloud point of $6^{\circ}C$ (FAEE) and $3^{\circ}C$ (FAME). Thus, Thevetia peruviana oil has a high potential for use in production of environmentally friendly biodiesel.

Analysis of non-point and point source pollution load in DongPieHong Ditch

  • Shan, Yu;Chen, Jun;Jin, Jie;Song, YongLian;Liu, Jun;Wu, DongBiao;Wu, Ke
    • Journal of Urban Science
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    • v.8 no.2
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    • pp.7-12
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    • 2019
  • In this study, the DongPieHong Ditch were taken as the research object, five sampling points were set to measure the COD, NH3-N,TNandTPindexes. The correlation and principal component analysis were used to judge the main pollution sources and calculate pollution contribution rate. According to the population in the basin, the load of point source pollution into the river was estimated. As a result, the load of COD, NH3-N and TP into the river was 323.04t/a, 43.8t/a and 3.9t/a, respectively. According to the statistics of the rainfall in the basin, the concentrations of COD, TP and NH3-N in the initial rainwater were measured and calculated for non-point source pollution, and the results shown that the inflow loads of COD, NH3-N and TP into the river were 34.59t/a, 0.12t/a and 0.71t/a, respectively. It was found that the main cause of the pollution in the east flash flood gully was point source pollution, and the proportions of COD, NH3-N and TP into the river were 90.33%, 99.72% and 84.61%, respectively.

A Study on the Change of Physical Properties of Engine Oil after Vehicle Driving (차량 운행에 따른 엔진오일 물성변화 연구)

  • Lim, Young-Kwan;Ham, Song-Yi;Lee, Joung-Min;Jeong, Choong-Sub
    • Tribology and Lubricants
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    • v.28 no.2
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    • pp.93-98
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    • 2012
  • The engine oil is an oil used for lubrication of various internal combustion engines. Recently, the vehicle and engine oil manufacture usually guarantee for oil change over 15000~20000 km mileage, but the most of driver usually change engine oil every 5000 km driving in Korea. In this case, it is possible to cause environmental contamination by used engine oil and increase the cost of driving by frequently oil change. In this study, we investigate the various physical properties such as flash point, pour point, kinematic viscosity, cold cranking simulator, total acid number, and four-ball test for fresh engine oil and used engine oil after vehicle driving (5000 km, 10000 km). The test result showed that the total acid number and wear scar by four-ball test of used engine oil had increased than fresh engine oil, but 2 kind of used oil (5000 km and 10000 km) had similar physical properties.

Characterisation of the pyrolysis oil derived from bael shell (aegle marmelos)

  • Bardalai, Monoj;Mahanta, Dimbendra Kumar
    • Environmental Engineering Research
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    • v.21 no.2
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    • pp.180-187
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    • 2016
  • In the present work, bael shell (aegle marmelos) is used as the feedstock for pyrolysis, using a fixed bed reactor to investigate the characteristics of the pyrolysis oil. The product yields, e.g., liquid, char and gases are produced from the biomass at different temperatures with the particle size of 0.5-1.0 mm, at the heating rate of $150^{\circ}C/min$. The maximum liquid yield, i.e., 36.23 wt.%, was found at $5500^{\circ}C$. Some physical properties of the pyrolysis oil such as calorific value, viscosity, density, pH, flash point and fire point are evaluated. The calorific value of the bael shell pyrolysis oil was 20.4 MJ/kg, which is slightly higher than the biomass, i.e., 18.24 MJ/kg. The H/C and O/C ratios of the bio-oil were found as 2.3 and 0.56 respectively, which are quite higher than some other bio-oils. Gas Chromatography and Mass Spectroscopy (GC-MS) and Fourier Transform Infra-red (FTIR) analyses showed that the pyrolysis oil of bael shell is mostly composed by phenolic and acidic compounds. The results of the properties of the bael shell pyrolysis oil reveal the potential of the oil as an alternate fuel with the essential upgradation of some properties.

Hot Flashes and Hypogonadism Symptoms in Patients with Prostate Cancer Receiving Hormone Replacement Therapy (호르몬요법을 받는 전립선암 환자의 안면홍조와 남성호르몬 저하 증상)

  • Park, Hyun Hye;Park, Jeong Sook
    • Korean Journal of Adult Nursing
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    • v.26 no.2
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    • pp.159-170
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    • 2014
  • Purpose: This research investigated the degree and predictors of hot flashes and hypogonadism symptoms in patients with prostate cancer receiving hormone replacement therapy. Methods: The subjects were 111 patients with prostate cancer receiving hormone replacement therapy in two university hospitals located in D city. The measurement tools included Hot Flash Diary and AMS (Aging Male's Symptoms rating scales). The data were analyzed using t-test, ANOVA, and binary logistic regression analysis. Results: The percentage of patients who experienced hot flashes among the participants was 14.4%. The predictors for hot flashes were eating irregularly, having coffee frequently and the types of hormone. The average score of hypogonadism symptom was 2.16 out of five-point scale and the highest score of hypogonadism symptom was the sexual symptoms (2.77 out of five-point scale). The predictors for hypogonadism symptom were eating habits and years of having the illness. Conclusion: These findings provide the information that irregularly eating habit was an important factor in hot flashes and hypogonadism symptoms of the participants. Therefore the development of a nutritional education encouraging regular meals is necessary for the given population.

Structures and Properties of Semi-blown Petroleum Asphalt (세미-브로잉 공정에서 석유 아스팔트의 구조, 물성 변화)

  • Min, Kyung Eui;Jeong, Han Mo
    • Applied Chemistry for Engineering
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    • v.22 no.6
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    • pp.664-671
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    • 2011
  • The vacuum residue of petroleum refinery, i.e. asphalt, was modified through a non-catalytic air blowing process to prepare the semi-blown asphalt. Changes in composition, chemical structure, and physical properties of asphalt were examined. The result from the thin layer chromatography showed that the asphaltene content in asphalt was increased by the air blowing on account of the aromatization of aliphatic hydrocarbon and condensation. These changes in molecular structure were also confirmed by $^1H-NMR$, differential scanning calorimetry, and thermogravimetry. Because of the molecular structure changes, the penetration of asphalt was decreased and the softening point and the flash point of asphalt were increased.

Real-Time Spacer Etch-End Point Detection (SE-EPD) for Self-aligned Double Patterning (SADP) Process

  • Han, Ah-Reum;Lee, Ho-Jae;Lee, Jun-Yong;Hong, Sang-Jeen
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.436-437
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    • 2012
  • Double patterning technology (DPT) has been suggested as a promising candidates of the next generation lithography technology in FLASH and DRAM manufacturing in sub-40nm technology node. DPT enables to overcome the physical limitation of optical lithography, and it is expected to be continued as long as e-beam lithography takes place in manufacturing. Several different processes for DPT are currently available in practice, and they are litho-litho-etch (LLE), litho-etch-litho-etch (LELE), litho-freeze-litho-etch (LFLE), and self-aligned double patterning (SADP) [1]. The self-aligned approach is regarded as more suitable for mass production, but it requires precise control of sidewall space etch profile for the exact definition of hard mask layer. In this paper, we propose etch end point detection (EPD) in spacer etching to precisely control sidewall profile in SADP. Conventional etch EPD notify the end point after or on-set of a layer being etched is removed, but the EPD in spacer etch should land-off exactly after surface removal while the spacer is still remained. Precise control of real-time in-situ EPD may help to control the size of spacer to realize desired pattern geometry. To demonstrate the capability of spacer-etch EPD, we fabricated metal line structure on silicon dioxide layer and spacer deposition layer with silicon nitride. While blanket etch of the spacer layer takes place in inductively coupled plasma-reactive ion etching (ICP-RIE), in-situ monitoring of plasma chemistry is performed using optical emission spectroscopy (OES), and the acquired data is stored in a local computer. Through offline analysis of the acquired OES data with respect to etch gas and by-product chemistry, a representative EPD time traces signal is derived. We found that the SE-EPD is useful for precise control of spacer etching in DPT, and we are continuously developing real-time SE-EPD methodology employing cumulative sum (CUSUM) control chart [2].

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