• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.85-92
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• 1997

Flammability of non-flame-retardant and flame-retardant materials was studied by using cone calorimeter Also, relations between the results obtained by using cone calorimeter and those obtained by the flammability test of japanese fire Service Law were examined. The results are as follows: 1) The ignition time of the molten specimens is relatively long, whereas the ignition time of the non-molten specimens is short. None of remarkable difference of the ignition time has been found between non-flame-retardant and flame-retardant materials specimens. 2) The peak heat release rates of flame-retardant materials are smaller than those of non-flame- retardant materials. 3) The carbon monoxide and smoke evolved from flame-retardant materials generate much more than those evolved from non-flame-retardant materials. 4) Even if flame-retardant materials are passed by the flammability test of Japanese Fire Service Law, they burn easily under external radiative heating condition.

• 한국연소학회:학술대회논문집
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• 2006.10a
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• pp.196-201
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• 2006

Silica(SiO2) nanoparticles are used as additives in plastics and rubbers to improve mechanical, electrical, magnetic properties and optical material. Silica nanoparticles were synthesized by the gas phase thermal oxidation of several kinds of precursors in many types of reactor. Diffusion flame reactor has some advantages compared with other types of reactors. In this study, we investigated the generation of silica nanoparticles on the effect of residence time by tetraethylothosilicate(TEOS) in a turbulent diffusion flame reactor controlled by providing reactant flowrate and reactor geometry affect particle morphology, particle size and particle size distribution. To determine the flame residence time, flame length should be determined which was examined by ICCD image. Particle size, distribution and morphology were performed with TEM.

• Journal of the Korean Wood Science and Technology
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• v.14 no.4
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• pp.21-28
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• 1986

Plywood used for construction as a decorative inner material is inflammable and can fire accident, causing destruction of human life and property. In this study, 3.5mm Kapur plywoods were soaked in the 23% monoammonium phosphate solutions by cold soaking method 3, 6, 9hrs and hot-cold bath method for 3/3hrs, and redrying was carried out by press-drying at the platen temperature of 110, 130, 160, 180$^{\circ}C$, and then fire test was carried out to investigate burning point, flame exhausted length, frame spread length, back side carbonized area and weight loss. The results are as follows; 1. In cold soaking method for 3, 6, 9hrs. retentions of monoammonium phosphate were 0.377, 0.448, 0.498kg/(30cm)$^3$ respectively, and in hot-cold bath method for 3/3hrs, the retention was 1.331kg(30cm)$^3$ that exceeded the minimum retention 1.124kg/(30cm)$^3$. 2. Correlation coefficients among the variable were shown in table 2. From the table, it could be recognized that there were close negative correlations between the treatment and burning point, flame spread length, back side carbonized area, flame exhausted time and weight loss, and there was negative correlation between treating time and back side carbonized area, but there was positive correlation between platen temperature and burning point. 3. From table 3, it can be observed that there were highly significant differences for burning point, flame spread length, flame exhausted time, back side carhonized area, weight loss between treatments. And in 2-way interactions, there were also highly significant for burning point, flame spread length, flame exhausted time, weight loss between time x treatment. 4. It was observed that burning point, flame exhausted time, flame spread length, back side carbonized area, and weight loss in fire-retardant treated plywood were the best effects in fire-retardant treated plywood, water treated plywood and nontreated plywood. In conclusion, I can estimate that absorbed chemical contents by hot-cold bath method for 3/3hrs, have a lot of effects on fire-retardant factors such as burning point, flame spread length, flame exhausted time, backside carbonized area and weight loss, but platen temperatures have a little effects on the fire factors.

• Journal of the Korean Wood Science and Technology
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• v.49 no.6
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• pp.667-678
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• 2021

The flame retardancy of plywood should be improved as much as possible while minimizing the impact on the bonding strength of plywood. Six commercial flame retardants and three laboratory synthesized phosphorous nitrogen flame retardants were selected. E₀, E₁ and E₂ grade commercial formaldehyde resins (UF) were applied in this study to evaluate the effect of different flame retardants on the curing time of resin, bonding strength, flame retardant performance, and formaldehyde emission of plywood. The results show that the effect of the addition of different flame retardants on the bonding strength of plywood gradually decreased with the increase of the formaldehyde molar ratio of the resin. The effect of flame retardants on the curing time of UF gradually decreased as the mole ratio of formaldehyde increasing, while the amount of formaldehyde emission varied according to the content of formaldehyde in the flame retardant. Compared with plywood without flame retardant, flame retardant of plywood added with phosphorous nitrogen flame retardant was improved.

• Journal of the Korean Society of Industry Convergence
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• v.2 no.1
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• pp.121-130
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• 1999

It is necessary to measure pressure, temperature, chemical equilibrium and the shape of flame in order to understand the combustion process in a combustion chamber. In particular, the flame formulation and combustion process of divided combustion chamber are different from those of a single chamber, And the variable diameter of a jet hole can effect not only physical properties like ejection velocity, temperature and time of combustion but also a chemical property like the reaction mechanism. Accordingly temperature is one of the most important factors which influence the combustion mechanism. This paper observed shape of flame by using the schlieren photographs and measured the pressure in a combustion chamber and the reaching time of the flame by ion probe By doing these, we investigation the formulation of the flame and the process of propagation. These measurement methods can be advanced in understanding the combustion process and process and propagation of flame.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.2
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• pp.116-123
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• 2009

Carbon black, activated carbon and carbon nanotube have been used as supporting materials for precious metal catalysts used in fuel cell electrodes. One-step flame synthesis method is used to coat 2-5nm Pt dots on flame-generated carbon particles. By adjusting flame temperature, gas flow rates and resident time of particles in flame, we can obtain Pt/C nano catalyst-support composite particles. Additional injection of hydrogen gas facilitates pyrolysis of Pt precursor in flame. The size of as-incepted Pt dots increases along the flame due to longer resident time and sintering in high temperature flame. Surface coverage and dispersion of the Pt dots is varied at different sampling heights and confirmed by Transmission electron microscopy (TEM), Energy-dispersive spectra (EDS) and X-ray diffraction (XRD). Crystalinity and surface bonding groups of carbon are investigated through X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.154-161
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• 1997

Several studies have developed upward flame spread models which use somewhat different features. However, the models have not considered the transient effects of the igniter and the burning rate. Thus, the objective of this study is to examine a generalized upward flame spread model which includes these effects. We shall compare the results with results from simpler models used in the past in order to examine the importance of the simplifying assumptions. We compare these results using PMMA, and we also include experimental results for comparison. The results of the comparison indicate that flame velocity depends on the thermal properties of a material, the specific model for flame length and transient burning rate, as well as other variables including the heat flux by igniter and flame itself. The results from the generalized upward flame spread model can provide a prediction of flame velocity, flame and pyrolysis height, burnout time and position, and rate of energy output as a function of time.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.1
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• pp.140-148
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• 1999

Experiments on flame spread in an one-dimensional droplet array up to supercritical pressures of fuel droplet have been conducted In normal gravity and microgravity. Evaporating process around unburnt droplet is observed through high-speed Schlieren and direct visualizations in detail, and flame spread rate is measured using high speed chemiluminescence images of OH radical. Flame spread behaviors are categorized into three: flame spread is continuous at low pressures and is regularly intermittent up to the critical pressure of fuel. flame spread is irregularly intermittent and zig-zag at supercritical pressures of fuel. At atmospheric pressure, the limit droplet spacing and the droplet spacing of maximum flame spread rate in microgravity are larger than those in normal gravity. In microgravity, the flame spread rate with the increase of ambient pressure decreases initially, takes a minimum, and then decreases after taking maximum. This is so because the flame spread time is determined by competing effects between the increased transfer time of thermal boundary layer due to reduced flame diameter and the reduced ignition delay time in terms of the increase of ambient pressure. Consequently, it is found that flame spread behaviors in microgravity are considerably different from those in normal gravity due to the absence of natural convection.

• 한국연소학회:학술대회논문집
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• 2000.12a
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• pp.47-58
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• 2000

The relationship among the flame radiation, NOx emissions, residence time, and global strain rate are examined for turbulent non-premixed jet flames with wide variations in coaxial air conditions. Measurements of NOx emission, flame geometry and flame radiation were made to explain the NOx emission scaling based on global parameters such as flame residence time, global strain rate, and radiant fraction. The overall 1/2-power scaling is observed in coaxial air flames, irrespective of coaxial air conditions, but the degree of deviation from the l/2-slope curve in each case differs from one another. From the comparison between the results of pure hydrogen flames and those of helium diluted hydrogen flames, it is observed that flame radiation plays a significant role in pure hydrogen flames with coaxial air and the deviation from 1/2-power scaling may be explained in two reasons: the difference in the flame radiation and the difference in jet similarity in coaxial air flames. From the radiation measurements, more detailed explanations on these deviations were suggested.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.29-30
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• 2012

The objectives of this study are to examine the variation of flame chemiluminescence on flame condition and to evaluate the possibility to apply the optical sensor for air/fuel ratio control. Flame chemiluminescence is one of the most important factor to judge the real time flame condition like a air/fuel ratio. In this paper, it is experimentally found that a strong relationship between the air/fuel ratio and optical element output (i.e., photo diode) should be existed. This is verified through the flame spectral analysis for various PD output signal.