• Title/Summary/Keyword: Flame Response

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Determination of Sulfur-containing Drugs by Gas Chromatography with Flame Photometric Detector

  • Kim, Kyoung-Ho;Cho, Yung-Hyun;Park, Man-Ki;Lee, Wang-Kyu
    • Archives of Pharmacal Research
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    • v.6 no.2
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    • pp.103-108
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    • 1983
  • Such sulfur-containing drugs as chlorpromazine, sulfonamides and thiazides were determined by gas chromatography with flame photometric detector (FPD) and flame ionization detector (FID). 0.6% QF-1 or 3% SE-30 on Chromosorb WAWDMCS were found suitable for drugs listed above. In the experimental conditions given maximum response the FPD response and the response ratio of FPD increased with the number of sulfur atom per molecule. It was possible to obtain a linear calibration curve from $10^{-9}$ / mole to $2{\times}10^{-8}$ / mole and to analyze variety of sulfur drugs by the calibration curve of one sulfur standard.

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Simulation of a Diffusion Flame in Turbulent Mixing Layer by the Flame Hole Dynamics Model with Level-Set Method (Level-Set 방법이 적용된 Flame Hole Dynamics 모델을 통한 난류 혼합층 확산화염 모사)

  • Kim, Jun-Hong;Chung, S.H.;Ahn, K.Y.;Kim, J.S.
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.102-111
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    • 2004
  • Partial quenching structure of turbulent diffusion flames in a turbulent mixing layer is investigated by the method of flame hole dynamics to develope a prediction model for the turbulent lift off. The present study is specifically aimed to remedy the problem of the stiff transition of the conditioned partial burning probability across the crossover condition by adopting level-set method which describes propagating or retreating flame front with specified propagation speed. In light of the level-set simulations with two model problems for the propagation speed, the stabilizing conditions for a turbulent lifted flame are suggested. The flame hole dynamics combined with level-set method yields a temporally evolving turbulent extinction process and its partial quenching characteristics is compared with the results of the previous model employing the flame-hole random walk mapping. The probability to encounter reacting' state, conditioned with scalar dissipation rate, demonstrated that the conditional probability has a rather gradual transition across the crossover scalar dissipation rate in contrast to the stiff transition of resulted from the flame-hole random walk mapping and could be attributed to the finite response of the flame edge propagation.

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Simulation of a Diffusion Flame in Turbulent Mixing Layer by the Flame Hole Dynamics Model with Level-Set Method (Level-Set 방법이 적용된 Flame Hole Dynamics 모델을 통한 난류 혼합층 확산화염의 모사)

  • Kim, Jun-Hong;Chung, S.H.;Ahn, K.Y.;Kim, J.S.
    • Journal of the Korean Society of Combustion
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    • v.9 no.2
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    • pp.18-29
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    • 2004
  • Partial quenching structure of diffusion flames in a turbulent mixing layer has been investigated by the method of flame hole dynamics in oder to develope a prediction model for the phenomenon of turbulent flame lift off. The present study is specifically aimed to remedy the shortcoming of the stiff transition of the conditioned partial burning probability across the crossover condition by employing the level-set method which enables us to include the effect of finite flame edge propagation speed. In light of the level-set simulation results with two models for the edge propagation speed, the stabilizing conditions for turbulent lifted flame are suggested. The flame hole dynamics combined with the level-set method yields a temporally evolving turbulent extinction process and its partial quenching characteristics is compared with the results of the previous model employing the flame-hole random walk mapping based on three critical scalar dissipation rates. The probability to encounter reacting state, conditioned with scalar dissipation rate, demonstrated that the conditional probability has a rather gradual transition across the crossover scalar dissipation rate. Such a smooth transition is attributed to the finite response of the flame edge propagation.

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Numerical study on extinction and acoustic response of diluted hydrogen-air diffusion flames with detailed and reduced chemistry (상세 및 축소 반응 메커니즘을 이용한 희석된 수소-공기 확산화염의 소염과 음향파 응답 특성에 관한 수치해석)

  • Son, Chae-Hun;Jeong, Seok-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.11
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    • pp.1527-1537
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    • 1997
  • Extinction characteristics and acoustic response of hydrogen-air diffusion flames at various pressures are numerically studied by employing counterflow diffusion flame as a model flamelet in turbulent flames in combustion chambers. The numerical results show that extinction strain rate increases linearly with pressure and then decreases, and increases again at high pressures. Thus, flames are classified into three pressure regimes. Such nonmonotonic behavior is caused by the change in chemical kinetic behavior as pressure rises. The investigation of acoustic-pressure response in each regime, for better understanding of combustion instability, shows different characteristics depending on pressure. At low pressures, pressure-rise causes the increase in flame temperature and chain branching/recombination reaction rates, resulting in increased heat release. Therefore, amplification in pressure oscillation is predicted. Similar phenomena are predicted at high pressures. At moderate pressures, weak amplification is predicted since flame temperature and chain branching reaction rate decreases as pressure rises. This acoustic response can be predicted properly only with detailed chemistry or proper reduced chemistry.

Experimental study on flame behavior within a porous ceramic burner (다공 세라믹 버너 내부의 화염 거동에 관한 실험)

  • Im, In-Gwon;Jeong, Seok-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.4
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    • pp.518-524
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    • 1997
  • Experimental studies on combustion phenomena within a porous ceramic burner are reported. Main interest of the present work is to investigate fundamental flame behaviors and their effects on the burner operation. Due to high thermal capacity of the porous ceramic materials, the response of flame to burning condition changes is slow and thus to have a stabilized flame is quite difficult and takes much time. It is found that the temperature profile obtained at downstream of the flame zone is not much sensitive to the movement of flame and the speed of flame movement is less than 0.1 mm/sec for the conditions tested. With the premixed LPG/air flame imbedded within the porous ceramic burner, stable combustion regions and unstable combustion regions leading to blowoff or flashback phenomena are observed and mapped on flow velocity versus equivalence ratio diagram. For the development of burner operation technique which is more practical and safe, intermittent burning technique, where the fuel or/and air is supplied to the burner intermittently, is proposed as one of the flame control methods for the porous ceramic burner and tested in this study. Through the experiment, it is realized that the proposed method is acceptable in respect to burner performance and give much flexibility in the operation of porous ceramic burner.

Study on the Disaster Prevention System for Wooden Cultural Assets Using USN -Focusing on the System Checking the Malfunction of Flame Detector- (USN을 이용한 목조문화재 방재시스템에 관한 연구 -불꽃감지기 오작동 확인시스템을 중심으로-)

  • Back, Min-Ho;Kim, Jeong-Ho
    • Journal of the Korean Society of Hazard Mitigation
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    • v.10 no.5
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    • pp.49-54
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    • 2010
  • The wooden cultural assets have the characteristics such as the fast spread of flame and leading to total destruction. Therefore, there is a need for a system for early countermeasure of recognized problem, along with the technological response for accurately recognizing the situation, for the prevention and early suppression of fire. To utilize such technology for detecting the situation through the latest ubiquitous technology and for a quick response to suppress fire, the ubiquitous sensor network (USN) technology, flame detector, image sensor, USN-based cultural asset disaster prevention management application case and malfunction identification system realization were examined in this study and the study result was presented focusing on the flame detector malfunction identification system for the ubiquitous-type cultural asset disaster prevention system.

Current Research Status on Flame Response Characteristics to Flow Disturbances (유동섭동에 대한 화염응답 특성의 실험적 연구동향)

  • Seo, Seonghyeon;Park, Yongjin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.18 no.5
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    • pp.87-94
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    • 2014
  • It becomes critical to understand an energy coupling mechanism between flow perturbations and combustion heat release rate fluctuations for the understanding of high-frequency combustion instabilities occurring in high-performance combustion/propulsion systems. A significant amount of experimental researches have been carried out to understand flame dynamic characteristics by use of flame transfer functions with artificial flow disturbances. Among them, there exist substantial studies on flame response by the excitation of inlet flow. Recently, experimental studies simulating transversal modes excited in actual combustion systems are under way.

Flame Response Modeling for Lean Premixed Combustors Using CFD (CFD를 이용한 희박 예혼합 연소기에서의 연소 응답 모델링)

  • Kim, Daesik;Lee, Jeongwon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.9
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    • pp.773-779
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    • 2014
  • A qualitative and quantitative analysis on flame dynamics is required to model combustion instability characteristics in gas turbine lean premixed combustors. The current paper shows the flame transfer function modeling results using CFD(Computational Fluid Dynamics) techniques for the flame dynamics study. It is generally known that flame shapes determine the basic characteristics of the flame transfer function. The comparisons of the modeled flame shapes with the measured ones were made using the optimized heat transfer conditions. Modeling results of the flame transfer function show the close behaviors to the measured data with a reasonable accuracy if the flame geometry can be exactly captured.

Behavior of Non-premixed Flame Front in an Acoustically-Driven Dump Combustor (가진된 덤프 연소기 내에서의 비예혼합 화염 거동)

  • Park, Jung-Kyu;Shin, Hyun-Dong
    • 한국연소학회:학술대회논문집
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    • 2000.05a
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    • pp.142-151
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    • 2000
  • Dump combustor is a combustor having a dump plane to make coherent structures. A non-premixed flame dump combustor of simple geometry was constructed. We conducted basic experiments such as frequency response on the combustor to confirm the characteristics of the phenomena as a typical dump combustion and unsteady combustion. Furthermore we visualized the flame front behavior by CH chemiluminescence and high speed motion analysis. In spite of the lack of another data such as velocity, species concentration and temperature, the results showed not only the periodic motion of flame front but the ignition process of vortex ring flame. Also we could check out Rayleigh criterion by combining the visualization data with the pressure data.

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Nonlinear Acoustic-Pressure Responses of H2/Air Counterflow Diffusion Flames (수소/공기 대향류 확산화염의 비선형 음향파 응답특성에 관한 연구)

  • Kim, Hong-Jip;Chung, Suk-Ho;Sohn, Chae-Hoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.8
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    • pp.1158-1164
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    • 2003
  • Steady-state structure and acoustic-pressure responses of $H_2$/Air counterflow diffusion flames are studied numerically with a detailed chemistry in view of acoustic instability. The Rayleigh criterion is adopted to judge acoustic amplification or attenuation from flame responses. Steady-state flame structures are first investigated and flame responses to various acoustic-pressure oscillations are numerically calculated in near-equilibrium and near-extinction regimes. The acoustic responses of $H_2$/Air flame show that the responses in near-extinction regime always contribute to acoustic amplification regardless of acoustic-oscillation frequency Flames near extinction condition are sensitive to pressure perturbation and thereby peculiar nonlinear responses occur, which could be a possible mechanism in generating the threshold phenomena observed in combustion chamber of propulsion systems.