• Title/Summary/Keyword: First order decay rate

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Kinetic examination on synergistic effect of co-use of ultrasonic wave and ultraviolet radiation on bacterial disinfection in a household humidifier (초음파와 자외선(UV) 동시 적용이 가정용 가습기 내 살균에 미치는 시너지 효과에 대한 반응속도론적 연구)

  • Kim, Seunga;Kim, Jihyun;Lee, Minjoo;Kim, Jayun;Jung, Woosik;Park, Joonhong
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.3
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    • pp.227-235
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    • 2021
  • This study examined the effect of ultraviolet (UV) application on bacterial disinfection in a commercialized humidifier using ultrasonic wave (UW). To accurately examine disinfection kinetics in tap-water condition, tap-water was sterilized using a filter, and then inoculated with pure cultures of E. coli and P. putida with known viable counts. The disinfection kinetic characteristics were experimentally compared when UV alone, UW alone, and UW+UV together were applied in disinfecting the added bacteria in the commercialized humidifier. When UV alone was applied, bacterial disinfection kinetics followed a first-order decay reaction, and showed an approximately 10-time weaker disinfection compared to the typical UV disinfection in water treatment or wastewater treatment. When UW alone was applied, bacterial disinfection kinetics followed a second-order decay reaction with a low disinfection rate constant of 0.0002 min-1(CFU/mL)-1. When UV and UW were applied together, however and interestingly, the disinfection rate constant (0.0211 min-1(CFU/mL)-1) was approximately 100 times increased than that for the UW alone case. These results revealed that the co-use of UV and UW can provide synergistic effect on bacterial disinfection in a tap-water condition in household humidifiers.

Time Resolved Electron Spin Resonance Spectroscopy of Anthrasemiquinone Radical Produced by Pulse Laser Photolysis. A Study on Chemically Induced Dynamic Electron Polarization (광화학 반응에서 생성된 Anthrasemiquinone Radical의 시간분해 ESR ; CIDEP에 관한 연구)

  • Hong Daeil;Kuwata Keiji
    • Journal of the Korean Chemical Society
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    • v.34 no.5
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    • pp.404-412
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    • 1990
  • The time resolved electron spin resonance spectroscopy are used to two measurement methods of chemically induced dynamic electron polarization (CIDEP) and absorption ESR. The spectra of the semiquinone radical anion were successively detected in the laser flash photolysis of anthraquinone in the mixtures of 2-propanol and triethylamine. The semiquinone radical anion was fairly stable and its cw ESR could be observed. The rate constant (T1$^{-1}$) of the spin-depolarization of polarized semiquinone radical anion was 2.6 ${\times}\;1-^5$ sec$^{-1}$ and the decay of the radical anion was the first order with the rate constant (K$_1}$) of 300.0 sec$^{-1}$. The intensity of CIDEP spectra increased with the increasing the microwave power, but the Torrey wiggles appeared following with decay curves.

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Optimal Remediation Design Considering Effects of Degradation Processes : Pumping strategy with Enhanced Natural Attenuation

  • Park Dong-Kyu;Lee Kang-Kun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.371-374
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    • 2005
  • We accomplished optimization for pump and treat (P&T) designs in consideration of degradation processes such as retardation and biodegradation, which are significant for contaminant fate in hydrogeology. For more desirable remediation, optimal pumping duration and minimum pumping rate constraint problems are studied. After a specific P&T duration, it replaces the P&T with the enhanced natural attenuation (ENA), which induces aerobic biodegradation by maintaining oxygen concentration. The design in this strategy carries out the optimization for the number and locations of oxygen injection wells.

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Development of RETRAN-03/MOV Code for Thermal-Hydraulic Analysis of Nuclear Reactor Under Mowing Conditions

  • Kim, Jae-Hak;Park, Good-Cherl
    • Nuclear Engineering and Technology
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    • v.28 no.6
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    • pp.542-550
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    • 1996
  • Nuclear ship reactors have several features different from land-based PWR's. Especially, effects of ship motions on reactor thermal-hydraulics and good load following capability for abrupt load changes are essential characteristics of nuclear ship reactors. This study modified the RETRAN-03 to analyze the thermal-hydraulic transients under three-dimensional ship motions, named RETRAN-03/MOV in order to apply to future marine reactors. First Japanese nuclear ship MUTSU reactor have been analyzed under various ship motions to verify this code. Calculations have been peformed under rolling, heaving and stationary inclination conditions during normal operation. Also, the natural circulation has been analyzed, which can provide the decay heat removal to ensure the passive safety of marine reactors. As results, typical thermal-hydraulic characteristics of marine reactors such as flow rate oscillations and S/G water level oscillations have been successfully simulated at various conditions.

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Determining chlorine injection intensity in water distribution networks: a comparison of backtracking and water age approaches

  • Flavia D. Frederick;Malvin S. Marlim;Doosun Kang
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.170-170
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    • 2023
  • Providing safe and readily available water is vital to maintain public health. One of the most prevalent methods to prevent the spread of waterborne diseases is applying chlorine injection to the treated water before distribution. During the water transmission and distribution, the chlorine will experience a reduction, which can imply potential risks for human health if it falls below the minimum threshold. The ability to determine the appropriate initial intensity of chlorine at the source would be significant to prevent such problems. This study proposes two methods that integrate hydraulic and water quality modeling to determine the suitable intensity of chlorine to be injected into the source water to maintain the minimum chlorine concentration (e.g., 0.2 mg/l) at each demand node. The water quality modeling employs the first-order decay to estimate the rate of chlorine reduction in the water. The first method utilizes a backtracking algorithm to trace the path of water from the demand node to the source during each time step, which helps to accurately determine the travel time through each pipe and node and facilitate the computation of time-dependent chlorine decay in the water delivery process. However, as a backtracking algorithm is computationally intensive, this study also explores an alternative approach using a water age. This approach estimates the elapsed time of water delivery from the source to the demand node and calculate the time-dependent reduction of chlorine in the water. Finally, this study compares the outcomes of two approaches and determines the suitable and effective method for calculating the chlorine intensity at the source to maintain the minimum chlorine level at demand nodes.

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Rheological Properties of Rehydrated Freeze Dried Instant Rice (동결건조 즉석미반의 리올로지적 성질)

  • Kim, Kwan-Yu;Lee, Shin-Young;Joo, Hyun-Kyu
    • Applied Biological Chemistry
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    • v.32 no.4
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    • pp.332-337
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    • 1989
  • Rheological properties of rehydrated freeze dried instant rice were investigated in comparison with that of cooked rice. The time changes in reciprocal hardness of instant rice grains at various rehydration temperatures$(60{\sim}90^{\circ}C)$ could be expressed by the first order reaction rate equation regardless of rehydration temperature and reaction rate constant increased as the rehydration temperature increased. Activation energy for rehydrating instant rice was 6.1 kcal/g-mol. Analysis of compressive stress relaxation test showed that the viscoelastic properties of both rehydrated instant rice and cooked rice grains could be expressed by 6-elements generalized Maxwell model. Rehydrated instant rice revealed higher relaxation decay than that of cooked rice and showed the elastic property increased by increasing the rehydration temperature.

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Estimation of the methane generation rate constant using a large-scale respirometer at a landfill site

  • Park, Jin-Kyu;Tameda, Kazuo;Higuchi, Sotaro;Lee, Nam-Hoon
    • Environmental Engineering Research
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    • v.22 no.4
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    • pp.339-346
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    • 2017
  • The objective of this study is the evaluation of the performance of a large-scale respirometer (LSR) of 17.7 L in the determination of the methane generation rate constant (k) values. To achieve this objective, a comparison between anaerobic (GB21) and LSR tests was conducted. The data were modeled using a linear function, and the resulting correlation coefficient ($R^2$) of the linear regression is 0.91. This result shows that despite the aerobic conditions, the biodegradability values that were obtained from the LSR test produced results that are similar to those from the GB21 test. In this respect, the LSR test can be an indicator of the anaerobic biodegradability for landfill waste. In addition, the results show the high repeatability of the tests with an average coefficient of variance (CV) that is lower than 10%; furthermore, the CV for the LSR is lower than that of the GB21, which indicates that the LSR-test method could provide a better representation of waste samples. Therefore, the LSR method allows for both the prediction of the long-term biodegradation potential in a shorter length of time and the reduction of the sampling errors that are caused by the heterogeneity of waste samples. The k values are $0.156y^{-1}$ and $0.127y^{-1}$ for the cumulative biogas production (GB21) and the cumulative oxygen uptake for the LSR, respectively.

Degradation of Aromatic Pollutants by UV Irradiation (UV조사에 의한 방향족오염물의 분해)

  • Min, Byoung-Chul;Kim, Jong-Hyang;Kim, Byung-Kwan
    • Applied Chemistry for Engineering
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    • v.8 no.3
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    • pp.502-509
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    • 1997
  • Aromatic pollutants(benzene, toluene, ethylbenzene and xylenes) were photodegraded by using a UV oxidation and the rates of degradation were investigated under various reaction conditions. Each of the solution containing 50 ppm benzene, 150 ppm ethylbenzene and 250 ppm xylenes was found UV-photodegraded over 90% in 1 hour of reaction time, wheras the only was 43 % degradation was obtained with 350 ppm toluene solution. A single component solution was more degradable than a mixed component solution and benzene was almost photodegraded at a pH 4.0, 6.4 and 10.0 after reaction time is 1 hr, ehtylbenzene was photodegraded about 92%(pH 4.0), 90%(pH 6.4) and 91%(pH 10.0), xylenes was photodegraded about 95%(pH 4.0), 90%(pH 6.4) and 92%(pH 10.0), but toluene was photodegraded about 80%(pH 4.0), 43%(pH 6.4) and 70%(pH 10.0), respectively. Kinetics studies show that the rate of decay in TOC(total organic carbon) were pseudo first-order rate except ethylbenzene, and then we could evaluate mineralization rate constants(k) of aromatics.

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Oxygen Sensitivity of Carbon Monoxide-Dependent Hydrogen Production Activity in Citrobacter sp.

  • Kim, Jung-Rae;Oh, You-Kwan;Yoon, Yeo-Joon;Lee, Eun-Yeol;Park, Sung-Hoon
    • Journal of Microbiology and Biotechnology
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    • v.13 no.5
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    • pp.717-724
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    • 2003
  • A newly isolated Citrobacter sp. Y19 catalyzes the CO-dependent $H_2$ production (biological water-gas shift reaction) by the actions of CO dehydrogenase (CODH) and hydrogenase. Y 19 requires $O_2$ for fast growth, but its $H_2$ production activity is significantly inhibited by $O_2$. In the present study, the effect of $O_2$ on the activities of CODH ard hydrogenase was investigated quantitatively in both whole cells and broken cells, based on CO-dependent or methyl viologen (MV)-dependent $H_2$ production in addition to CO-dependent MV reduction. In crude cell extracts, CODH activity was mostly found in the soluble fraction. Inactivation of CODH and hydrogenase activities by $O_2$ followed the first-order decay kinetics, and the dependence of the rate constants on $O_2$ partial pressure could be expressed by the Michaelis-Menten equation. In whole cells, the maximum deactivation rate constants ($k_{d,max}$ of hydrogenase and CODH were quite similar: $0.07{\pm}0.03 min^{-1}\;and\;0.10{\pm}0.04 min^{-1}$, respectively. However, the first-order rate constant ($k_{d,max}/K_s$) of CODH ($0.25\;min^{-1}\;atm^{-1}$) at low $O_2$ partial pressures was about 3-fold higher than that of the hydrogenase, since the half-saturation constant ($K_s$) of CODH was about half of that of hydrogenase. In broken cells, both enzymes became significantly more sensitive to $O_2$ compared to the unbroken cells, while $k_{d,max}/K_s$ increased 37-fold for hydrogenase and 6.7-fold for CODH. When whole cells were incubated under anaerobic conditions after being exposed to air for 1 h, hydrogenase activity was recovered more than 90% in 2 h suggesting that the deactivation of hydrogenase by $O_2$ was reversible. On the contrary, CODH activity was not recovered once deactivated by $O_2$ and the only way to recover the activity was to synthesize new CODH. This study indicates that $O_2$ sensitivity of $H_2$ production activity of Citrobacter sp. Y19 is an important drawback as in other $H_2-producing$ bactria.

Affecting factors to oral scaling experience of the part worker (일부 직장인의 구강건강상식 및 스케일링에 대한 인식도)

  • Cheon, Seok-Yeon;Won, Bok-Yeon
    • Journal of Korean society of Dental Hygiene
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    • v.11 no.1
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    • pp.1-12
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    • 2011
  • Objectives : This study was to investigate into company workers' oral scaling related factors and enhance a rate of oral scaling. Methods : From August 2010, self-administered questionnaires of the about general question items, oral health relation factors, knowledge of periodontal disease for oral scaling performed, in 267 people worker objects. Results : The followings are the findingd of this research. First, Oral scaling experiences were responded by 205 people(76.8%). Among those prevention the case which enforces with a goal periodically 6 month period 7.3% and the period of 1 years is 28.8%, be most inconvenient is cold(50.7%), with motive is dentistry visits inducement for tooth therapy which 51.2%, Non experience in oral scaling was responded by 62 people(23.2%), 45.2% of whom answered they had no necessity for such treatment. Second, Knowledge of periodontal disease is 'dental calculus and stain loses toothbrush quality did eagerly' incorrect one right answer ratio is highest with 86.5%, 'Becoming the adult being made to draw out tooth is periodontitis than decay' was incorrect one right answer rate was lowest with 62.9%. Third, The workers' sex, service field, one month average income, Currently the oral inconvenient presence, oral health Interest degree, tooth brushing method, knowledge of periodontitis have a significant effect on their oral scaling experience. Conclusions : When seeing with result of above, it is necessary of the oral scaling widely with the method which is various includes a mass communication by causing the changes in the perception of oral scaling. The dental hygienist is inconvenience from oral scaling experience have interest when is possible the patient comfortably, in order could be operated, endeavors demanded.