• 한국화재소방학회논문지
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• 제24권3호
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• pp.66-71
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• 2010

화학공정에서의 안전하고 최적화된 조작과 내재되어 있는 화재 및 폭발 위험성 평가를 위해서 연소 특성치를 알아야 한다. 폭발한계는 가연성물질의 화재 및 폭발위험성을 결정하는데 주요한 특성치 가운데 하나이다. 본 연구에서, 에스테르류의 폭발하한계와 상한계에 대해 연소열을 이용하여 예측하였다. 제시된 예측식에 의한 예측값은 문헌값과 적은 오차범위에서 일치하였다. 제시된 방법론을 사용하여 다른 가연성 에스테르류의 폭발한계 예측이 가능해졌다.

• 한국안전학회지
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• 제17권4호
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• pp.126-132
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• 2002

By using the reference data, the empirical equations which describe the interrelationships of explosion properties and physical properties of n-chlorinated hydrocarbons have been derived. The properties which have been correlated are the lower and upper explosive limits, the stoichiometric coefficients, the heats of combustion, the carbon numbers. Also, the new equations using the mathematical and statistical methods for predicting the temperature dependence of lower explosive limits(LEL) of chlorinated hydrocarbons on the basis of the literature data are proposed. The fire and explosion properties calculated by the proposed equations in this research were a good agrement with literature data within a few A.A.P.E.(Average Absolute Percent Error) and A.A.D.(Average Absolute Deviation.) From a given explosive properties, by using the proposed equations, it is possible to predict to the fire and explosion characteristics for the other chlorinated hydrocarbons.

• 한국화재소방학회논문지
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• 제19권4호
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• pp.26-31
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• 2005

화학공정에서의 안전하고 최적화된 조작과 내재되어 있는 화재 및 폭발 위험성 평가를 위해서 연소 특성치를 알아야 한다. 폭발한계는 가연성물질의 화재 및 폭발위험성을 결정하는데 주요한 특성치 가운데 하나이다 본 연구에서, 알코올류의 폭발한계에 대해 용액론을 근거로 표준끓는점과 인화점을 이용하여 예측하였다. 제시된 예측식에 의한 예측값은 문헌값과 적은 오차범위에서 일치하였다. 제시된 방법론을 사용하여 다른 가연성 물질의 폭발한계 예측이 가능해졌다.

• 한국위험물학회지
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• 제6권2호
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• pp.23-29
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• 2018

The fire and explosion properties necessary for waste, safe storage, transport, process design and operation of handling flammable substances are lower explosion limits(LEL), upper explosion limits(UEL), flash point, AIT( minimum autoignition temperature or spontaneous ignition temperature), fire point etc., An accurate knowledge of the combustion properties is important in developing appropriate prevention and control measures fire and explosion protection in chemical plants. In order to know the accuracy of data in MSDSs(material safety data sheets), the flash point of phenol was measured by Setaflash, Pensky-Martens, Tag, and Cleveland testers. And the AIT of phenol was measured by ASTM 659E apparatus. The explosion limits of phenol was investigated in the reference data. The flash point of phenol by using Setaflash and Pensky-Martens closed-cup testers were experimented at $75^{\circ}C$ and $81^{\circ}C$, respectively. The flash points of phenol by Tag and Cleveland open cup testers were experimented at $82^{\circ}C$ and $89^{\circ}C$, respectively. The AIT of phenol was experimented at $589^{\circ}C$. The LEL and UEL calculated by using Setaflash lower and upper flash point value were calculated as 1.36vol% and 8.67vol%, respectively. By using the relationship between the spontaneous ignition temperature and the ignition delay time proposed, it is possible to predict the ignition delay time at different temperatures in the handling process of phenol.

• 한국화재소방학회논문지
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• 제26권4호
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• pp.63-69
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• 2012

폭발한계는 가연성물질의 폭발위험성을 결정하는데 중요한 특성치 가운데 하나이다. 본 연구에서는 연소열과 화학양론계수를 이용하여 유기할로겐화탄화수소의 폭발하한계와 상한계를 예측하였다. 제시된 예측식에 의한 폭발한계 값은 문헌값과 적은 오차범위에서 일치하였다. 제시된 방법론을 사용하여 다른 가연성 유기할로겐화탄화수소류의 폭발한계 예측이 가능할 것으로 판단된다.

• 한국안전학회지
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• 제32권5호
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• pp.25-31
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• 2017

The flash point, explosion limits, autoignition temperature(AIT) are important combustible properties which need special concern in the chemical safety process that handle hazardous substances. For the evaluation of the flammable properties of n-butylacetate, this study was investigated the explosion limits of n-butylacetate in the reference data. The flash points, fire points and AIT by the ignition delay time of n-butylacetate were experimented. The lower flash points of n-butylacetate by using the Setaflash and Pensky-Martens closed-cup testers were $24^{\circ}C$ and $26^{\circ}C$, respectively. The flash points of n-butylacetate using the Tag and Cleveland open cup testers are measured $31^{\circ}C$ and $40^{\circ}C$, respectively. And the fire points of n-butylacetate by the Tag and Cleveland open cup testers were measured $32^{\circ}C$ and $41^{\circ}C$. The AIT of n-butylacetate measured by the ASTM 659E tester was measured as $411^{\circ}C$. The lower explosion limit of lower flash point $24^{\circ}C$, which was measured by the Setaflash tester, was calculated to be 1.40 vol%. Also, the upper explosion limit of upper flash point $67^{\circ}C$ the Setaflash tester was calculated to be 12.5 vol%.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2007년도 춘계학술논문 발표대회
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• pp.9-12
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• 2007

Recently, research and development related to high strength concrete for the high rise and large scale reinforced concrete building has been actively promoted in worldwide by national and private research project. But, it is reported that violent explosive explosion would be happened when it was exposed in fire. In the existed study, a explosion in a reinforced concrete structure looses the organism by the different contraction and expansion of hardened cement paste and aggregate, and causes crack by thermal stress. In case of the Europe, Japan and America, they have studied the explosion for a long time. However it would hardly study the explosion in domestic, So it is needed base on mechanical properties of fire deterioration in high strength concrete. Therefore, this study is intend as an mechanical properties of specimen to high heating by heating and load test machine and $700^{\circ}C$. As a result, it is willing to propose fundamental data for quick and accurate diagnosis of deteriorated concrete structure by fire damage with experiment according to the design high strength concrete.

• 한국화재소방학회논문지
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• 제23권5호
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• pp.50-56
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• 2009

폭발한계와 최소자연발화온도는 가연성 물질의 화재 및 폭발 위험성을 결정하는데 중요한 특성으로 이용된다. 에틸렌의 안전한 취급을 위해 에틸렌의 폭발한계와 최소자연발화온도를 고찰하였다. 에틸렌의 폭발하한계와 상한계는 공기 중에서 각 각 2.6vol%와 36vol%를 추천하며, 최소자연발화온도는 전면 가열인 경우는 $420^{\circ}C$, 국소 고온표면인 경우는 약 $800^{\circ}C$를 추천한다. 또한 에틸렌의 폭발한계의 온도 및 압력의 존성에 대한 새로운 예측식을 제시하였으며, 제시된 식에 의한 예측값은 문헌값과 일치하였다.

• 한국가스학회지
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• 제11권4호
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• pp.7-11
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• 2007

축열식 소각로에서 화재폭발 사고보고서가 있었다. 본 논문은 수지 재처리공정에서 축열식 소각로의 사고원인을 조사하였다. 실험은 인화점 시험기, 폭발한계장치, 자동발화 시험기, 가스크로마토그래프를 사용한 물리화학적 특성과 열안정성시험기 활용한 열안정성을 분석하였다. 축열식 소각로를 가동하는 공정의 사고예방을 위해 화재폭발 사고원인을 규명하였다.

• 한국안전학회지
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• 제31권5호
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• pp.42-48
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• 2016

The usage of the correct combustion properties of the treated substance for the safety of the process is critical. For the safe handling of n-nonane being used in various ways in the chemical industry, the flash point and the autoignition temperature(AIT) of n-nonane was experimented. And, the explosion limit of n-nonane was calculated by using the flash point obtained in the experiment. The flash points of n-nonane by using the Setaflash and Pensky-Martens closed-cup testers measured $31^{\circ}C$ and $34^{\circ}C$, respectively. The flash points of n-nonane by using the Tag and Cleveland open cup testers are measured $37^{\circ}C$ and $42^{\circ}C$. The AIT of n-nonane by ASTM 659E tester was measured as $210^{\circ}C$. The lower explosion limit by the measured flash point $31^{\circ}C$ was calculated as 0.87 vol%. And the upper explosion limit by the measured upper flash point $53^{\circ}C$ was calculated as 2.78 vol%. It was possible to predict lower explosion limit by using the experimental flash point or flash point in the literature.