• Title/Summary/Keyword: Fine powder

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Effect of Calcium Sulfate Dihydrate (Gypsum) on the Fundamental Properties of Slag-based Mortar (이수석고가 고로슬래그 미분말 베이스 무시멘트 모르타르의 기초물성에 미치는 영향)

  • Baek, Byung Hoon;Han, Cheon Goo
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.3
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    • pp.252-258
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    • 2014
  • With the vision of 'a low carbon green develop' various industrial by-products were used as replacement of cement, in order to reduce $CO_2$ emissions from the manufacturing process of cement. Blast furnace slag is one of the industrial by-products. Due to the similar chemical compositions to ordinary Portland cement, blast furnace slag have been widely used in concrete with minimum side effects. Hence, in recent years, alkali activated slag-based composites are extensively studied by many researchers. However, the alkali activator can cause a number of problems in practice. Therefore, in this study, an alternative way of activating the slag was investigated. To activate the slag without using an alkali activator, calcium sulfate dihydrate was chosen and mixed with natural recycled fine aggregate. Fundamental properties of the slag-based mortar were tested to evaluate the effect of calcium sulfate dihydrate.

Crystallographic and Mossbauer Studies of Magnetic Garnet $Y_{3-x}Bi_xFe_5O_{12}$ by a Sol-Gel Method (Sol-gel 합성에 의한 자성 garnet $Y_{3-x}Bi_xFe_5O_{12}$의 결정학적 및 Mossbauer 분광학 연구)

  • 엄영란;김철성;이재광
    • Journal of the Korean Magnetics Society
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    • v.8 no.4
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    • pp.203-209
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    • 1998
  • Crystallographic and magnetic properties of single phase garnet $Y_{3-x}Bi_xFe_5O_{12}$ (x=0.0, 0.25, 0.5, 0.75, 1.0) were studied by using x-ray diffraction, Mossbauer spectroscopy and vibrating sample magnetometer (VSM). Ultra-fine polycrystalline cubic samples have been prepared by sol-gel method. The lattice constant increase linearly with increasing an amount of Bi. Annealing temperature was larger than 800 $^{\circ}C$ for the growth of a single-phase garnet powder. The second phase of garnet, $(BiFeO_3)$, was at 1000 $^{\circ}C$ for x=0.75, and 950 $^{\circ}C$ for x=1.00. From Mossbauer spectroscopy and VSM measurements, the magnetization and the coercivity were decreased and the Curie temperature $Y_{3-x}Bi_xFe_5O_{12}$(x=0.0, 0.25, 0.5, 0.75, 1.0) was slightly increased as increasing the Bi content.

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Anticarcinogenic Effect of Ginseng Extracts Depending on the Types and Ages Using Yun's Anticarcinogenicity Test(II) (벤조피렌으로 유도된 마우스 폐선종에 대한 인삼분말의 연근별 항발암효과(II))

  • Yun, Taik-Koo;Lee, Yun-Sil
    • Journal of Ginseng Research
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    • v.18 no.3
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    • pp.160-164
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    • 1994
  • In this study, we investigeated the anticarcinogenicity of various types and ages of ginseng extracts as an extended study using Yun's anticarcinogenicity test. Fresh ginseng at 1.5, 3, 4, 5 and 6 years was dried and powdered. And white ginseng was processed in the same way that of fresh ginseng after removal fo the ginseng cortex and fine root. For red ginsneg, fresh ginseng was steamed and dried. Each ginseng powder was extracted and extracts was freeze dried. Newborn N:GP(S) mice were given a single subcutaneous injection of 0.5 mg of benzo(a)pyrene(BP). Various types and ages of ginseng extracts at 2.5mg/ml were orally administered. All the mice were sacrificed at the 9th week. The following results were obtained. In the dried fresh ginseng extract treated group, the incidence of lung adenoma induced by BP was 63.9% and its incidence was reduced to 48.3%, 52.5%, 51.8%, 47.5% and 44.1% after co-treatment with 1.5, 3, 4, 5 and 6 year-dried fresh ginseng, respectively. The incidence of lung adenoma induced by BP on the white ginseng extract treated group was 41.3% and decreased to 31.0%, 46.0%, 44.0% and 26.5% after co-treatment with 3, 4, 5 and 6 year-white ginseng, respectively. In the red ginseng extract treated group, the incidence of lung adenoma induced by BP was 47.5% and its incidence diminished to 40.7%, 35.0%, 30.1%, 30.0% and 26.3% after co-treatment with 1.5, 3, 4, 5 and 6 year-red ginseng, respectively. From the above results, we concluded that a statistically significant anticarcinogenic effect was observed in extracts of 6 year-dried fresh ginseng, 6 year-white ginseng, and 4, 5 and 6 year-red ginseng and it is suggested that the anticarcinogenicity of ginseng varies according to the types and ages Key words Ginseng extract, types and ages. anticarcinogenic, newborn mice, lung tumor.

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Advanced Water Treatment by Hybrid Process of Multi-channel Ceramic MF and Photocatalyst: Effect of Organic Materials (광촉매 및 다채널 세라믹 정밀여과 혼성공정에 의한 고탁도 원수의 고도정수처리: 유기물의 영향)

  • Amarsanaa, Bolor;Park, Jin-Yong
    • Membrane Journal
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    • v.21 no.4
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    • pp.351-359
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    • 2011
  • For advanced drinking water treatment of high turbidity water, we used the hybrid process that was composed of photocatalyst packing in space of between outside of multi-channel ceramic microfiltration membrane and membrane module inside. Photocatalyst was polypropylene (PP) beads coated $TiO_2$ powder by CVD (chemical vapor deposition) process. Instead of natural organic matters (NOM) and fine inorganic particles in natural water source, standard NOM solution was prepared with humic acid and kaolin. Water-back-flushing of 10 sec was performed per every period of 10 min to minimize membrane fouling. Resistance of membrane fouling ($R_f$) increased and J decreased as concentration of humic acid changed from 2 mg/L to 10 mg/L, and finally the highest total permeate volume ($V_T$) could be obtained at 2 mg/L. Then, treatment efficiency of turbidity and $UV_{254}$ absorbance were above 96.4% and 78.9%, respectively. As results of treatment portions by membrane filtration, photocatalyst adsorption, and photo-oxidation in (MF), (MF + $TiO_2$), (MF + $TiO_2$ + UV) processes, turbidity was treated little by photocatalyst adsorption, and photo-oxidation. However, treatment portions of $UV_{254}$ absorbance by adsorption (MF + $TiO_2$) and photo-oxidation (MF + $TiO_2$ + UV) at humic acid of 4 mg/L and 6 mg/L were above 9.0, 9.5 and 8.1, 10.9%, respectively.

Characterization of LaCrO$_3$ Powders Synthesized by Combustion Process with Different Heating Methods (가열방법에 따른 LaCrO$_3$ 연소합성분말의 특성)

  • 정층환;박홍규;오석진;박지연
    • Journal of the Korean Ceramic Society
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    • v.35 no.10
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    • pp.1078-1084
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    • 1998
  • lanthanum chromite(LaCrO3) powder was synthesized by the combustion of a solution of metal nitrates La(NO3).6H2O and Cr(NO3)3.9H2O and urea. The pH of solution affected a yield of the combustion products but did not influence the morphology of the products. When the pH of the solution was in the range of 0.7-4, the yield of the combustion products was more than 90% The morphology of the combustion products was af-fected by heating methods for the solution. The hot-plate induced heating of the solution yielded powders hav-ing two-dimensionally interconnected agglomerates whereas microwave-induced heating produced a fine and non-agglomerated powders. The specific surface area(BET) of the combustion products using microwave-in-non-agglomerated powders. The specific surface area(BET) of the combustion products using microwave-in-duced heating method were larger(25~32m2/g) than that of hot plate heating method(10-14m2/g)

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Synthesis and Crystallization of Fine SiC-${Si_3}{N_4}$Composite Powders by the Vapor Phase Reaction (기상반응에 의한 SiC-${Si_3}{N_4}$복합 분말의 제조 및 결정화)

  • Kim, Hyoung-In;Choi, Jae-Moon;Kim, Suk;So, Myoung-Gi
    • Journal of the Korean Ceramic Society
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    • v.37 no.11
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    • pp.1091-1096
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    • 2000
  • 본 연구에서는 기상 반응법을 이용하여 TMS(Tetramethylsilane:Si($CH_3$)$_4$)와 NH$_3$그리고 H$_2$의 혼합기체로부터 반응 온도 1000~120$0^{\circ}C$ 및 입력비(NH$_3$/Si($CH_3$)$_4$) 1~3의 조건에서 초미분의 SiC-Si$_3$N$_4$복합 분말을 합성하였다. 합성되어진 복합 분말들의 결정상의 변화와 평균 입경을 알아보기 위해 XRD와 TEM 분석을 행한 결과, 구형의 비정질 분말이 형성되었으며, 입자의 크기는 약 70~130nm이었다. 입자의 크기는 입력비에 관계없이 거의 일정하였으나 반응 온도가 증가함에 따라서 감소하였다. FT-IR과 EA 분석 결과, 합성되어진 분말은 Si, N, C, 그리고 H로 이루어진 화합물임을 확인할 수 있었다. 또한 입력비가 다른 조건에서 합성되어진 분말을 $N_2$분위기 하에서 155$0^{\circ}C$로 2시간 열처리를 행한 결과, 낮은 입력비인 경우 $\beta$-SiC, $\alpha$-Si$_3$N$_4$$\beta$-Si$_3$N$_4$의 결정상들이 혼재하였으나, 높은 입력비인 경우는 결정화 후 $\alpha$-Si$_3$N$_4$상만이 존재하였다.

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Sintering Behavior and Mechanical Property of B4C Ceramics Fabricated by Spark Plasma Sintering (방전플라즈마 소결법에 의한 탄화 붕소 세라믹스의 소결 거동 및 기계적 특성)

  • Kim, Kyoung-Hun;Chae, Jae-Hong;Park, Joo-Seok;Kim, Dae-Keun;Shim, Kwang-Bo;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.45 no.1
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    • pp.60-64
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    • 2008
  • [ $B_4C$ ] ceramics were fabricated by spark plasma sintering process and their sintering behavior, microstructure and mechanical properties were evaluated. Relative density of $B_4C$ ceramics could be achieved by spark plasma sintering method reached as high as 99% at lower temperature than conventional sintering method, in addition, without any sintering additives. The mechanical properties of $B_4C$ ceramics could be improved by the heat treatment at $1300^{\circ}C$ during sintering process which can be removed $B_2O_3$ phase from a $B_4C$ powder surface. This improvement results from the formation of a fine and homogeneous microstructure because the grain coarsening was suppressed by the elimination of $B_2O_3$ phase. Particularly, mechanical properties of the specimen experienced the $B_2O_3$ removing process improved over 30% compared with the specimen without that process.

An Experimental Study On the Properties blended with industrial by products Using Mineral Admixture (산업부산물의 혼입에 따른 콘크리트 특성의 실험적 연구)

  • Kim, Dongbaek;Jun, Kyeongbae
    • Journal of the Society of Disaster Information
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    • v.10 no.2
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    • pp.238-243
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    • 2014
  • Recently environmental pollution is serious and therefore, This study aims at reviewing individual mixing ratio and engineering characteristics of concrete due to mixture and mixing using fine powder and fly ash of blast furnace slag having effect on aspects of environmental preservation and resources recycling and performance increase of the concrete, and verifying possibility of application in the field. Test results are as follows: 1)As mixing quantity of the admixture has increased, performance of the slump has been improved, 2)As mixing quantity of the admixture has increased, there is a trend of delayed ending time, 3)As mixing quantity of admixture has increased, it has showed lower strength at short time age, however, as the age has elapsed and mixing quantity has increased, strength improvement has increased and the admixture has effect on the long term age. In this study, the characteristics and critical value of concrete contained blast furnace slag and fly ash are defined, and will be examined about the field applications.

Failure Behavior of Laser Cladding Layer used by Fe-based Bulk Metallic Glass (Fe계 벌크 비정질 합금을 이용한 레이저 용접층의 파손 거동)

  • Lim, Byung-Chul;Kim, Dae-Hwan;Park, Sang-Heup
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.9
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    • pp.5743-5747
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    • 2015
  • In this study, Fe-based bulk amorphous alloy powder manufactured using gas atomization fabrication was used for laser welding. the fracture behavior of welding layer were analyzed. Tensile test results show that the destruction occurred immediately after the elastic deformation, After plastic deformation of the substrate, the destruction occurred. The actual maximum tensile strength of the welding layer and the substrate are 959.9MPa and 220.4MPa. welding layer were each $485.5{\pm}21$ and $197.4{\pm}14$ to the substrate and the actual microhardness, The welding layer has very high hardness. The welding layer showed a very weak fine acicular structure. The base material was shown in the micro structure appear a coarse grain. SEM observations of the fracture after the tensile test. Fracture morphology of the base metal and the welding layer showed ductile fracture and brittle fracture, respectively.

Sheet fabrication of Ni-WC anode for Molten Carbonate Fuel Cell by Tape Casting Method (테이프 캐스팅법에 의한 MCFC Anode용 Ni-WC 박판 제조)

  • Choe, Jin-Yeong;Jeong, Seong-Hoe;Jang, Geon-Ik
    • Korean Journal of Materials Research
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    • v.10 no.10
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    • pp.715-720
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    • 2000
  • By the mechanical alloying method. Ni-WC composite materials were prepared to improve the deformation-resistance for creep and sintering of Ni-anode at the operating temperature of $650^{\circ}C$. Mechanically alloyed powder w was initially fabricated by ball milling for 80hr, and then amorphization was occurred by the destruction of ordered crystals based on XRD analysis. In order to investigate the electrochemical performance and sheet characteristics of Ni-WC anode, tape casting process was adopted. Finally, the obtained sheet thickness of Ni- we after sintering at $1180^{\circ}C$ for 60 minutes in $H_2$ atmosphere was O.9mm and the average pore size was $3~5{\mu\textrm{m}}$ with porosities of 55%. The second phase was not observed in Ni- W matrix while W particles were finely and uniformly distributed in Ni matrix. This fine and uniform distributed W particles in Ni matrix are expected to enhance the mechanical properties of Ni anode through the dispersion and solid solution hardening mechanisms.

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