• Title/Summary/Keyword: Fine particulate

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Atmospheric Concentration of Polycyclic Aromatic Hydrocarbons and Heavy Metals in Suspended Particulate (大氣浮遊粉塵中 多環芳香族炭火水素 및 重金屬의 濃度)

  • 손동헌;권창호;정원태;허문영
    • Journal of Korean Society for Atmospheric Environment
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    • v.7 no.1
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    • pp.17-22
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    • 1991
  • Total suspended particulates (TSP) in the atmosphere was collected and size-fractionated by Andersen high volume air sampler for one year (Mar. 1987 $\sim$ Feb. 1988) in Seoul. The concentrations of several polycyclic aromatic hydrocarbons and heavy metals were determined to investigate the atmospheric concentrations, seasonal variations and its relationship with the size distribution of suspended particulate matter. The arithmetic mean concentration of total suspended particulates was 200.44 $\mug/m^3$. The concentrations of heavy metals were 2433.80 for Fe, 629.49 for Zn, 600.71 for Pb, 143.87 for Cu, and 107.21 $ng/m^3$ for Mn, respectively. The concentrations of PAHs were 3.83 for benzo(a) pyrene, 2.95 for benzo(k)fluoranthene, and 4.42 $ng/m^3$ for benzo(ghi)perylene, respectively. PAHs, Pb and Zn abounded in particles below 2.0 $\mu$m, while Fe and Mn aboounded in particles above 2.0 $\mu$m. TSP and its chemical compositions showed the seasonal variations. The concentrations of anthrophogenic pollutants like TSP, PAHs and heavy metals in the fine particles were highest in winter and lowest in summer. PAHs and Pb analyzed showed significant correlations between each other and between TSP concentration in fine particles, indicating that the particles in which they are contained have a similar behavior in the atmosphere.

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Measurement of Nitrogen and Sulfur Deposition to Lake Paldang (팔당호로의 질소와 황성분 침적 측정)

  • Ghim Young Sung;Jin Hyoun Cheol
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.1
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    • pp.39-48
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    • 2005
  • Nitrogen and sulfur deposition was measured on Lake Pal dang from March 2002 to October 2003. Wet and dry depositions were separately measured using wet- and dry-only samplers, respectively. In order to measure the dry deposition to the water body, a dry deposition sampler composed of three pans filled with pure water, called the deposition water, was used. Since ammonium was generally in excess in ambient air, more than half of ammonium was present in the gaseous form. Ammonium concentration was also generally higher than the sum of major anion concentrations in the deposition water because gaseous species were much easily deposited than the species in fine particles. Nevertheless, the contribution of gaseous ammonia to the deposition of ammonium was not high as well as that of particulate ammonium while the contribution of gaseous nitric acid was much higher than that of particulate nitrate. Annual wet deposition fluxes of nitrogen and sulfur were five and six times higher than their dry deposition fluxes, respectively. Except for ammonium, the dry deposition flux estimated in the present work was a half of the previous results. This was mainly caused by much smaller dry deposition velocities over the water than over the ground.

Satellite-based Assessment of Ecosystem Services Considering Social Demand for Reduction of Fine Particulate Matter in Seoul

  • Lim, Chul-Hee
    • Korean Journal of Remote Sensing
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    • v.38 no.4
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    • pp.421-434
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    • 2022
  • Fine particulate matter (PM2.5) has been the biggest environmental problem in Korea since the 2010s. The present study considers the value of urban forests and green infrastructure as an ecosystem service (ES) concept for PM2.5 reduction based on satellite and spatial data, with a focus on Seoul, Korea A method for the spatial ES assessment that considers social demand variables such as population and land price is suggested. First, an ES assessment based on natural environment information confirms that, while the vitality of vegetation is relatively low, the ES is high in the city center and residential areas, where the concentration of PM2.5 is high. Then, the ES assessment considering social demand (i.e., the ESS) confirms the existence of higher PM2.5 values in residential areas with high population density, and in main downtown areas. This is because the ESS of urban green infrastructure is high in areas with high land prices, high population density, and above-average PM2.5 concentrations. Further, when a future green infrastructure improvement scenario that considers the urban forest management plan is applied, the area of very high ESS is increased by 74% when the vegetation greenness of the green infrastructure in the residential area is increased by only 20%. This result suggests that green infrastructure and urban forests in the residential area should be continuously expanded and managed in order to maximize the PM2.5 reduction ES.

Atmospheric concentration and mutagenicity of organic pollutants of suspended particulate in Seoul (서울시 대기중 유기오염물질의 농도와 돌연변이원성에 대한 연구)

  • Shin, Dong-Chun;Chung, Yong;Moon, Young-Hahn;Roh, Jae-Hoon
    • Journal of Preventive Medicine and Public Health
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    • v.23 no.1 s.29
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    • pp.43-56
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    • 1990
  • To evaluate the difference of concentration and mutagenicity of organic pollutants between residential and traffic area of Seoul, air samples were collected in Bulkwang (residential) and Shinchon (traffic) area. Samples were analyzed to measure the concentration of extractable organic matters (EOM) and their subfractions and mutagenicities were tested using Salmonella typhimurium TA 98. The concentrations of polycyclic aromatic hydrocarbons (PAHs) were also measured by gas-chromatography and compared between two areas. The results were as follows ; 1. While the concentration of total suspended particulate (TSP) in residential area was below the environmental standard in annual average, the concentration in traffic area was above the standard and was up to its maximum $256{\mu}g/m^3$ in November. The difference of TSP concentrations in both areas of each month was statistically significant (P<0.05). 2. The concentration of fine particle in traffic area was significantly higher compare to that in residential area and showed statistically significant monthly difference in both areas (P<0.05). The proportion of concentration of fine particle to TSP was 55-68%. 3. Mean concentrations of EOM in residential and traffic areas were $4.3{\mu}g/m^3\;and\;5.3{\mu}g/m^3$ respectively. The proportion of amount of EOM from fine particle to EOM from TSP was 70-88%. 4. While the percentage of polar neutral organic compounds (POCN) of fine particle in Bulkwang's sample was higher compare to Shinchon's sample, the percentage of aliphatic compounds of fine particle in Shinchon's sample was higher compare to Bulkwang's sample. The percentages of PAH fraction were as low as 6-10% in both areas. 5. The mutagenic activity of nit concentration of organic matters extracted from fine particle was higher compare to that of coarse particle and was increased when metabolically activated with S9. Mutagenicities with metabolic activation calculated by unit air volume were significantly different between residential and traffic area, $17\;revertants/m^3$\;and\;22\;revertants/m^3$ respectively. 6. The concentrations of benzo(a)pyrene in fine particle of traffic and residential areas were $3.10ng/m^3\;and\;2.02ng/m^3$ respectively. Sixteen PAHs were higher in samples of traffic area compare to residential area and also concentrations of PAHs in fine particle were higher compare to coarse particle.

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Measurements of Polycyclic Aromatic Hydrocarbons(PAHs) Concentration in Air of the Seoul Underground Shopping Stores (서울시 지하상가 공기중 다환방향족 탄화수소의 농도조사에 관한 연구)

  • 전준민;김윤신
    • Journal of Korean Society for Atmospheric Environment
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    • v.9 no.1
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    • pp.81-92
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    • 1993
  • A purpose of this study was carried out to investigate the concentrations of four elements of PAHs(Polycyclic Aromatic Hydrocarbons) in suspended particulate matters of underground shopping stores in Seoul city. The particulate matters were collected at five underground shopping stores(Yongdungpo, Myongdong, Ulchiro, Express Terminal, Chamshil) in the Seoul area during February-October, 1992. Samples were collected using cascade impactor of low volumn air sampler and were analysed using High Performance Liquid Chromatography(HPLC) with fluorescence detector. Calibration on HPLC analyse is nearly accord with retention time between the standard solution and the samples. Analysed results obtained favorable analysing recovery rate of 97.3% and coefficient of variation of 1.60%. Mean concentrations of suspended particulate matters in five underground shopping stores wre 216.3 g/$m^3$ and observed higher at fine particles(117.2 g/$m^3$) which is respirable particulates than coarse particles(99.2 g/$m^3$). Concentrations of four species PAH were determined with anthracene of 16.8ng/$m^3$, fluoranthene of 72.3ng/$m^3$, benzo(a)pyrene of 0.54ng/$m^3$, and benzo(k)fluoranthene of 0.29ng/$m^3$, respectively. Fluoranthene levels were significantly higher than those levels in other components. PAHs concen-tration at shopping areas showed 21.3ng/$m^3$ in Yongdungpo, 35.1ng/$m^3$ in Myongdong, 23.4ng/$m^3$ in Ulchiro, 11.1ng/$m^3$ in Express Terminal, and 21.4ng/$m^3$ in Chamshil, respectively. Particularly, benzo(a)pyrene and benzo(k)-fluoranthene were detected over 83 percentage in fine particles, while fluoranthene wre highly detected in coarse particles. Also, higher concentrations of benzo(a)pyrene, benzo(k)fluoranthene were found in winter while levels of anthracene and fluoranthene were found higher in summer than other seasons.

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Study on Airborne Particulate Matter ($PM_{10}$) Monitoring in Urban and Rural Area by Using Gent SFU Sampler and Instrumental Neutron Activation Analysis (중성자 방사화분석법과 Gent SFU 샘플러를 이용한 도시의 농촌지역의 대기분지($PM_{10}$)관측 연구)

  • 정용삼;문종화;김선하;박광원;강상훈
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.5
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    • pp.453-467
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    • 2000
  • The aim of this research is to collect and characterize fine particles (FPM:$\leq$2.5${\mu}{\textrm}{m}$) and coarse particles (CPM: 2.5~10${\mu}{\textrm}{m}$) using a low volume air sampler provided by the IAEA, at urban (Taejon) and rural area(Wonju) for a period of about two years(April 1996 to May 1998) and to promote a use of nuclear analytical techniques for air pollution studies. For the collection of airborne particulate matter (PM(sub)10), the Gent stacked filter unit sampler and polycarbonate membrane filters were employed. The concentration of trace elements in collected APM samples were determined byu instrumental Neutron Activation Analysis. For validation of the analytical data, internal quality control were implemented by using both the comparison of the analytical results of standard reference materials(NIST SRM 1648) and interlaboratory comparison for proficiency test (NAT-3). The standard uncertainty was less than 15% and Z-score of two samples were within $\pm$1. The monitoring of (PM(sub)10) mass concentration and elemental concentrations were carried out weekly. The average mass concentration of (PM(sub)10) in urban and rural areas were 59.2$\pm$36.5$\mu\textrm{g}$/㎥ and 41.4$\pm$23.7$\mu\textrm{g}$/㎥, respectively. To investigate the emission source, the enrichment factors were calculated for the fine and coarse particle fractions at two sites, respectively and these values were classified for anthropogenic and soil origin elements.

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Analysis of Aerosol Optical Properties for High Particulate Matters and Light Asian Dust in Seoul Using GOCI (GOCI 자료를 이용한 서울 지역 고농도 미세먼지와 옅은 황사 시 에어로졸 광학적 특성 분석)

  • Kim, Deok-Rae;Choi, Won-Jun;Choi, Myungje;Kim, Jiyoung;Cho, Ara;Kim, Sang-Kyun;Kim, Jhoon;Moon, Kyung-Jung
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.3
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    • pp.233-240
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    • 2017
  • To distinguish between high particulate matter (HPM) and light Asian dust (LAD) events, aerosol optical properties from GOCI were investigated in Seoul from 2014 to 2016. The poor air quality case caused by fine atmospheric particulate matter (i.e., 80<$PM_{10}$<$400{\mu}g/m^3$) is clearly separated from the case of heavy Asian dust that generally shows the $PM_{10}$ concentration more than $400{\mu}g/m^3$. In this study, we have found eight cases for the poor air quality and divided them into the two events(i.e., HPM and LAD). In case of aerosol optical depth (AOD), there was no big difference between two events. However, Angstrom exponent (AE) for HPM events was greater than 1, while that for LAD events less than 1. As a result of comparing aerosol type, non-absorbing fine mode aerosols were dominant for HPM events, but coarse and absorbing coarse mode aerosols for LAD events. Therefore, AE and aerosol type from GOCI can be used to distinguish between two events effectively.

HEPA Filter Tests Using PLS and Composite Nanospheres (PLS 및 복합 나노구체를 이용한 HEPA 필터 시험)

  • Hwang, Min-Jin;Sung, Dong Chan;Moon, Hee
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.357-362
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    • 2013
  • Monodispersed polystyrene latex spheres (PLS) and PS-MPS/silica composite nanospheres were used to test high efficiency particulate air (HEPA) filters. Prior to filter tests, all nanospheres used in this work were characterized by measuring their average particle diameters and coefficients of variation (CV) for assessing them as artificial dusts. The average particle sizes of PLS and composite nanospheres could be well controlled in the range of 100~300 nm well by changing reaction temperature and the amount of a stabilizer during emulsion polymerization. The CV of all nanospheres were also in the range of 3~7%, lower than 15% that is the criterion for monodispersed particle distributions. Furthermore the results of HEPA filter tests show that all nanospheres used were quite proper as artificial dusts for testing air filters.

Theoretical Analysis and Experimental Evaluation of Small Cyclone Separator to Remove Fine Particulate Matter (미립 물질 제거를 위한 소형 사이클론 분리기의 이론적 연구 및 실험적 검증)

  • Ko, Han Gyul;Kim, Hong Seok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.1
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    • pp.77-82
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    • 2013
  • A cyclone separator has been widely used in various industrial processes for removing fine particulate matter because it is easy to fabricate, cost effective, and adaptable to extremely harsh conditions. However, owing to the complex flow field in cyclones, a complete understanding of the detailed mechanisms of particulate removal has not yet been gained. In this study, a theoretical analysis was performed for calculating the collection efficiency and cut-off size in cyclones by taking into account the effects of geometrical and flow parameters. The collection efficiency and cut-off size values predicted by the theoretical model showed good agreement with experimental measurements for particles with a diameter of $0.5-30{\mu}m$. It was also revealed that the surface friction, along with the flow and geometrical parameters, has a significant effect on the cyclone performance.

Analysis of Infiltration of Outdoor Particulate Matter into Apartment Buildings (외기 중 미세먼지의 공동주택 실내 유입에 관한 연구)

  • Bang, Jong-Il;Jo, Seong-Min;Sung, Min-Ki
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.34 no.1
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    • pp.61-68
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    • 2018
  • Recently, concentration of fine and ultra-fine particulate matter(PM) has been increased in KOREA. The increase of PM in KOREA is due to increase of domestic industries and yellow dust from china. PM is known to cause diseases such as dyspnoea, asthma, arrhythmia. Since PM is harmful to human, KOREA Ministry of Environment(ME) warns people to stay indoors when the outdoor PM concentration is high. However, prior studies has shown that indoor PM concentration can be relatively high when outdoor PM concentration is high due to infiltration of PM into buildings though leakage areas. In this study, airtightness, indoor and outdoor pressure difference and PM 2.5 & 10 concentration were measured in an apartment complex to observe PM infiltrating into building. Field measurement was conducted in newly-built apartment buildings to avoid the influence of indoor PM which can be generated by residents. The airtightness test was conducted to identify the leakage areas of the apartment, such as electric outlets and supply/exhaust diffusers. The airtightness test result showed that the air leakage area of the building was dominant in buildings envelop. According to indoor and outdoor pressure difference measurement result and PM concentration measurement result, it can be concluded that outdoor PM can infiltrate into indoor by leakage areas when wind is blown toward the apartment. As a result, pressure difference formed by the external weather condition and architectural characteristics such as the airtightness in building can influence PM to infiltrate into buildings. In further studies, I/O ratio, stack-effect, infiltration and penetration factor will be considered.