• Title/Summary/Keyword: Fine material

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Methane gas sensing effect of SnO$_{2}$ fine particle mixed with inhibitor to crystal growth (결정성장 억제재를 첨가한 SnO$_{2}$ 미세입자의 메탄가스 감지효과)

  • 홍영호;강봉휘;이덕동
    • Electrical & Electronic Materials
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    • v.9 no.1
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    • pp.38-43
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    • 1996
  • A coprecipitation method was used for preparing Ca and Pt doped $SnO_2$ fine powder. Components of the powder were investigated by XPS and SIMS. Crystallite size and specific surface area were investigated by TEM, XRD, and BET analysis. $SnO_2$(Ca)/Pt based thick film devices were prepared by a screen printing technique for methane gas detection. Then sensing characteristics of the devices were investigated. As Ca and Pt added, the crystal growth of $SnO_2$ was suppressed during calcining and sintering, and the sensitivity of $SnO_2$(Ca)/Pt thick film to methane gas was enhanced. For the Pt doped $SnO_2$ fine particle, the thick film device shows sensitivity of about 83% to 2000 ppm methane gas at an operating temperature of >$400^{\circ}C$.

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The Synthesis of New Leuco Squarylium Dyes

  • Park, Soo-Youl;Jun, Kun;Shin, Seung-Rim;Shin, Jong-Il
    • Textile Coloration and Finishing
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    • v.19 no.5
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    • pp.24-29
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    • 2007
  • It is well known that certain classes of dye are reducible to stable colorless leuco compounds, which can be oxidized in air back to the colored species. We now reported that bis(4-dialkylaminophenyl)squaraine dyes are readily reduced in solution by borohydride to give alkali soluble leuco compound, which exists in the 3-hydroxy 2,4-bis(4-dialkylaminophenyl)cyclobuten-one. New alkylamine leuco compounds were synthesized by the reaction of leuco chloro-squaraine with alkylamine derivatives. The leuco compounds are easily isolated and can be air oxidized back to the squaraine dyes. These dyes have many technical application. e.g. in xerography, solar cell, optical recording material, redox indicators, and enzyme assays.

Improvement of Powder Feeding Characteristics of Fine$5\mu\textrm{m}$ $Al_2O_3$ Powder by Modification of the Powder Feeding Systems and Characterization of the Coating Layer depending on Plasma Spraying Conditions (분말송급장치의 개조에 의한 미세$5\mu\textrm{m}$ $Al_2O_3$분말의 송급 특성개선 및 플라즈마 용사조건에 따른 코팅층의 특성분석)

  • 설동욱;김병희;정민석;임영우;서동수
    • Journal of Welding and Joining
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    • v.15 no.1
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    • pp.116-124
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    • 1997
  • A scope of this study is to establish the optimum plasma spray conditions for fine ($5\mu\textrm{m}$) $Al_2O_3$ powder. However, the flowability of the $Al_2O_3$ powder is not so good because of irregular particle shape and fine particle size. Therefore, powder feeding system was modified by 1) change of powder feeding line material from polymer to copper 2) shorten the powder feeding tube length 3) heating the powder feeding system to $80^{\circ}C$4) vibrating the powder feeding line continuously, in order to feed the fine powder homogeneously. The homogeneous powder feeding conditions were obtained with the modified powder feeding system by controlling the powder carrier gas flow and the powder flow rate indicator. The best plasma spraying conditions for the fine $Al_2O_3$ powder were found out as 40kw gun power, 80 g/min. powder feed rate and 50 mm working distance after characterizing the microstructure, hardness and wear loss of the $Al_2O_3$ coating layer.

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A Study on the Engineering Properties of Micro Fine Hybrid Silicate Based Grout (마이크로 복합실리카 그라우트의 공학적 특성에 관한 연구)

  • 천병식;김진춘;최영철;정종주;신상재;이홍재
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.11a
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    • pp.63-70
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    • 2000
  • In 1925, H.J. Joosten was the first in the world to use chemical injection grouts composed of sodium silicate and calcium chloride. This unique development prompted the introduction of other chemical grouting techniques. Among these chemical grouting techniques, sodium silicate based grout has been the most widely used in the world, but it has not been generally considered to be a permanent material. Therefore, studies to improve the weak points of sodium silicate based grout have been conducted, and new applications of grout were recently developed. We also developed the micro fine hybrid silicate grout of suspention type which properties are sepecialized as the high strength and durability, according to the reactant of special sodium silicate grout and the high strength hardener. As the results of this study we could derive the 2 times over high strength of Micro fine hybrid Silicate grouting method(MS method) more than that of the ordinary sodium silicate grout. And also we could confirm that the alkali leakage of micro fine hybrid silicate grout is less than that of ordinary sodium silicate grout. So we could get the high strength and durability of hybrid silicate grout are superior to those of ordinary sodium silicate grout.

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The Strength Properties of Latex-Modified Mortar using Recycled Fine Aggregate (순환잔골재를 사용한 라텍스 개질 모르타르의 강도 특성)

  • Lee, Won-Young;Lee, Dae-Gun;Han, Sang-Il;Kwak, Eun-Gu;Kim, Jae-won;Kim, Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.179-182
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    • 2009
  • Concrete containing styrene-butadiene latex is widely used, nowadays, as a protective system for bridge. Latex modification mortar have taken advantage of latex modification concrete advantage that is used in existing, Also, when repair, protection and sticking performance of concrete overlay waterproof agent were known as that are good. Replace and experimented from fine aggregate to recycled aggregate to secure economic performance than existing latex modification concrete. Recycled fine aggregate has low quality because it contains large amount of old mortar. So, its usage is limited to a lower value-add, such as the roadbed material etc. This study is purposed to improve the performance of mortar made of recycled fine aggregate. For this, recycled aggregate mortar was produced with latex, and fluidity, strength were examined. Test result indicate that mortar using recycled fine aggregate is higher compressive and flexural strength than mortar using river sand.

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Fine Dust Adsorption of Cement Matrix Using Sepiolite (세피올라이트를 활용한 시멘트 경화체의 미세먼지 흡착 특성 )

  • Jeon, Eun-Yeong;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.71-72
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    • 2023
  • As industrialization and urbanization accelerate, environmental issues have moved from local concerns to global issues. Among them, air pollution is the most important issue. Modern people spend more than 88% of their day indoors, but the concentration of fine dust and pollutants flowing indoors is increasing. The indoor environment has its own complexity, and various substances used indoors, such as building materials, furniture, electronics, and cleaning agents, emit chemical substances and cause various diseases. Therefore, when selecting building materials and interior finishing materials, the pollutant emission and adsorption capacity must be greatly considered. These considerations will ensure the construction of a sustainable future environment and a healthy life within that environment. Therefore, in order to reduce the generation of indoor air pollutants, this study aims to examine the fine dust adsorption properties of cement hardening materials using sepiolite, which has a porous structure and high absorption power among clay minerals. As a result of the experiment, it was found that the concentration of fine dust decreased as the addition rate of sepiolite increased. It is believed that the fine dust concentration was reduced due to the high porosity due to the microfibrous structure and large specific surface area of sepiolite, which has a porous structure among clay minerals. It is believed that these experimental results can be used as basic research for future use of sepiolite as a construction material.

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A study on the settlement of earth dam by the changes of the density (흙댐의 밀도변화에 의한 압밀침하에 대한 연구)

  • 윤충섭
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.28 no.3
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    • pp.89-98
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    • 1986
  • This study was carried out for the settlement and camber of earth dam by the changes of the density. The testing material was taken five kinds of Soil used as banking material and it was compacted by 100, 95, 90, 85 and 80% compaction degree. The results of the settlement of earth dam whose height ranges from 10m to 50m are as follows. 1.The more the fine particle (n) increases, the higher the liquid limit (WL) and the lower the dry density (rd) becomes as follows; rd=2. 22-0. 0052n (gr/cm$_3$) rd=2. 394-0. 0164WL rd=2. 185-(5. 8n-2. 5WL)X10-$_3$ 2. The higher the optimum moisture content (Wo) becomes, the lower the density becomes as follows; rt,=2. 68-0. 028Wo rd=2. 578-0. 04Wo 3. 3.Most of the consolidation occurs immediately by loading and the more the fine particle increases, the lower the coefficient of consolidation becomes. 4.The more the fine particle increases and lower the compaction degree (D) becomes,the lower the pre-consolidation load (Pc) becomes but on the contrary the compression index (Cc) becomes higher. Those equation is as follows. Pc=3. 32-(4. 3n-3. 0D) X10-2 (kg/cm$^2$) Cc=0. 41+(1. 33n-4. 44D) X10-$^3$ 5.The more the consolidation load (P) increases, the lower the coefficient of volume change (mv) becomes with mv=ap-b, the higher the consolidation ratio (u) becomes with U= (0. 6~1. 35)PO.4 6.The more the fine particle (n) increases, the more the settlement of dam occurs with U=anb and 60-80% of the settlement occurs under construction. 7.The camber of dam has higher value in condition that has more fine particle, poorer compaction and higher height of dam. In the dam construction about twice value of table 7 is required for dam safety.

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Design of shearing process to reduce die roll in the curved shape part of fine blanking process (파인블랭킹 공정에서의 곡률부 다이롤 감소를 위한 전단 공정 설계)

  • Yong-Jun Jeon
    • Design & Manufacturing
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    • v.17 no.3
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    • pp.15-20
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    • 2023
  • In the fine blanking process, which is a press operation known for producing parts with narrow clearances and high precision through the application of high pressure, die roll often occurs during the shearing process when the punch penetrates the material. This die roll phenomenon can significantly reduce the functional surface of the parts, leading to decreased product performance, strength, and fatigue life. In this research, we conducted an in-depth analysis of the factors influencing die roll in the curvature area of the fine blanking process and identified its root causes. Subsequently, we designed and experimentally verified a die roll reduction process specifically tailored for the door latch manufacturing process. Our findings indicate that die roll tends to increase as the curvature radius decreases, primarily due to the heightened bending moment resulting from reduced shape width-length. Additionally, die roll is triggered by the absorption of initial punch energy by scrap material during the early shearing phase, resulting in lower speed compared to the product area. To mitigate the occurrence of die roll, we strategically selected the Shaving process and carefully determined the shaving direction and clearance area length. Our experiments demonstrated a promising trend of up to 75% reduction in die roll when applying the Shaving process in the opposite direction of pre-cutting, with the minimum die roll observed at a clearance area length of 0.2 mm. Furthermore, we successfully implemented this approach in the production of door latch products, confirming a significant reduction in die roll. This research contributes valuable insights and practical solutions for addressing die roll issues in fine blanking processes.

A Study on the Properties of Mortar with Recycled Fine Aggregate (순환잔골재를 사용한 모르타르의 제물성에 관한 실험적 연구)

  • Moon, Dae-Joong;Choi, Jae Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.1
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    • pp.96-100
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    • 2009
  • The properties of recycled fine aggregates which had different source concrete were examined by mortar test. With higher strength of source concrete, specific gravity of recycled fine aggregate was higher and absorption of recycled fine aggregate was lower due to reduction of the volume of adhered cement paste. The compressive strength and flexible strength of mortar with recycled fine aggregate were affected by the interface boundary of new mortar and the strength of adhered mortar. Strength development of mortar with recycled fine aggregate reduced because recycled fine aggregate become a porous material with the smaller strength of source concrete. The drying shrinkage of mortar was about$800{\sim}2000{\mu}m/m$. It was about 1.5 times than that of mortar with natural fine aggregate. Relative dynamic modulus of elasticity was a similar level with that of mortar with natural fine aggregate.

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Synthesis and Electrochemical Properties of LiFePO4 Cathode Material obtained by Electrospinning Method (전기방사법을 이용한 LiFePO4 양극 활물질의 합성 및 전기화학적 특성)

  • Lee, Seung-Byung;Cho, Seung-Hyun;Park, Sun-Il;Lee, Wan-Jin;Lee, Yun-Sung
    • Journal of the Korean Electrochemical Society
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    • v.11 no.4
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    • pp.268-272
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    • 2008
  • $LiFePO_4$ material was synthesized by electrospinning method to obtain optimal particle size($50{\sim}100\;nm$) without carbon coating or ball milling. This material showed an orthorthombic structure with Pnma space group without any impurities, such as FeP or $Fe_2P$, in the XRD pattern. The particle morphology and particle shape were observed by SEM analysis. Li/$LiFePO_4$ cell showed a high initial discharge capacity of 135 mAh/g, at current density of $0.1\;mA/cm^2$ with a cut-off voltage of 2.8 to 4.0V. This cell exhibited a perfect cycle performance over 99.9% cycle retention rate up to 50 cycles.