• KCI Concrete Journal
• /
• v.14 no.2
• /
• pp.76-80
• /
• 2002

The role of high volume Class F fly ash in reducing expansion due to Alkali-Silica Reaction (ASR) was investigated. A series of modified ASTM C 1260 tests were performed under three different levels of NaOH normality, extending the test period to 28 days, using high- or low alkali cement, and Class F fly ash up to 58 ％ by mass of cement. A reactive siliceous fine aggregate was used. The test results confirm that HVFA replacement in a cementitious system significantly helps in controlling expansion caused by ASR.

• KEPCO Journal on Electric Power and Energy
• /
• v.4 no.1
• /
• pp.39-45
• /
• 2018

Ammonia Adsorbed Fly Ash (AAFA) samples produced from coal fired plants equipped with SNCR (Selective Non-Catalytic Reduction) of nitrogen oxides with urea have been chemically analyzed, and their physical and dissolution properties have been investigated. XRD results for the ammonia component in AAFA ascertained that ABS (ammonium bisulfate) and AS (ammonium sulfate) were deposited on fly ash as $SO_3$ reacted with unreacted ammonia at SNCR. SEM and EDS images showed that fine ashes on large fly ash surface of sphere type were agglomerated, due to adhesive role of ammonium salts attached fly ashes. Dissolution test results of ammonium salts absorbed on AAFA in distilled water or sea water showed that the proportion of un-ionized $NH_3$ to $NH_4{^+}$ were primarily a function of pH and temperature. Increasing pH and temperature causes an increase in the fraction of un-ionized $NH_3$. At pHs of 9.6 and 10.7, un-ionized $NH_3$ and $NH_4{^+}$ ions are present in equal amounts at distilled water and sea water, respectively.

• Journal of Energy Engineering
• /
• v.7 no.1
• /
• pp.146-156
• /
• 1998

Fly ash produced in coal combustion is a fine-grained material consisting mostly of spherical, glassy, and porous particles. A physical, morphological, and chemical characteristic of fly ash has been analyzed. This study may contribute to the data base of domestic fly ash, the improvement of combustion efficiency, ash recycling and ash collection in the electrostatic precipitator. The physical property of fly ash is determined using a particle counter for the measurement of ash size distribution and gravimeter. Morphological characteristic of fly ash is performed using a scanning electron micrograph and an optical microscope. The chemical components of fly ash are determined using an inductively coupled plasma emission spectrometry (ICP). The distribution of fly ash size was ranged from 15 to 25 $\mu$m in mass median diameter. Exposure conditions of flue gas temperature and duration within the combustion zone of the boiler played an important role on the morphological properties of the fly ash such as shape, relative opacity, coloration, cenosphere and plerosphere. The spherical fly ash might be generated at the condition of complete combustion. The size of fly ash was found to be increased the with particle-particle interaction of agglomeration and coagulation. Fly ash consisted of $SiO_2\;Al_2O_3\;and\;Fe_2O_3$ with 85% and carbon with 3~10% of total mass.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2005.05b
• /
• pp.381-384
• /
• 2005

The purpose of this study reutilization of waste fine tailing (FT) as admixture for cement and concrete. Various admixtures were made of Fine tailings and 2 Types of OPC, fly-ash and blast furnace slag. Cement mortars and concrete with FT are tested for fluidity and compressive strength. Also, the hydration reactivity of cement mortar with FT was examined by XRD and SEM morphology analysis. This work showed that the waste fine tailing could be effectively utilized as replacement materials of cement without any decrease in the strength if we can control the blaine of materials like cement, blast furnace slag and fly ash.

• Computers and Concrete
• /
• v.22 no.4
• /
• pp.419-437
• /
• 2018

The compressive strength of self-compacting concrete (SCC) containing fly ash (FA) is highly related to its constituents. The principal purpose of this paper is to investigate the efficiency of hybrid fuzzy radial basis function neural network with biogeography-based optimization (FRBFNN-BBO) for predicting the compressive strength of SCC containing FA based on its mix design i.e., cement, fly ash, water, fine aggregate, coarse aggregate, superplasticizer, and age. In this regard, biogeography-based optimization (BBO) is applied for the optimal design of fuzzy radial basis function neural network (FRBFNN) and the proposed model, implemented in a MATLAB environment, is constructed, trained and tested using 338 available sets of data obtained from 24 different published literature sources. Moreover, the artificial neural network and three types of radial basis function neural network models are applied to compare the efficiency of the proposed model. The statistical analysis results strongly showed that the proposed FRBFNN-BBO model has good performance in desirable accuracy for predicting the compressive strength of SCC with fly ash.

• Journal of the Korean Ceramic Society
• /
• v.37 no.8
• /
• pp.751-759
• /
• 2000

Effects of the dosage change, from 0 to 2.0 wt% based on cement weight, of naphthalenic (NSF) and polycarboxylic(NT-2) superplasticizers, on the fluidity of cement paste substituted by 10 wt% II-anhydrite and fly ash respectively as well as II-anhydrite and fly ash itself were investigated. Dispersion properties between particles in suspension were investigated by zeta potential test. Initial fluidity and slump loss in the paste system were observed through mini-slump and apparent viscosity changes with elapsed time. Zeta potential on the particle surface was a tendency to increase according to increasing of NSF dosage. Especially, zeta potential of fly ash has the highest value among all particles equivalent to NSF dosage. In the fluidity of cement paste substituted by inorganic particles, the specimen with substitution of 10 wt% II-anhydrite and fly ash for cement was more effective than cement itself to improve initial fluidity and retain stable fluidity of cement paste. In addition, effect of NT-2 and NSF to improve the fluidity of cement paste, addition of 1.0 wt% NT-2 was more effective than 1.5wt% NSF.

• International Journal of Concrete Structures and Materials
• /
• v.7 no.3
• /
• pp.193-202
• /
• 2013

Geopolymer mortar compressed blocks were prepared using fly ash, ground granulated blast furnace slag, silica fume and metakaolin as binders and sand/quarry dust/pond ash as fine aggregate. Alkaline solution was used to activate the source materials for synthesizing the geopolymer mortar. Fresh mortar was used to obtain the compressed blocks. The strength development with reference to different parameters was studied. The different parameters considered were fineness of fly ash, binder components, type of fine aggregate, molarity of alkaline solution, age of specimen, fluid-to-binder ratio, binder-to-aggregate ratio, degree of saturation, etc. The compressed blocks were tested for compression at different ages. It was observed that some of the blocks attained considerable strength within 24 h under ambient conditions. The cardinal aim was to analyze the experimental data generated to formulate a phenomenological model to arrive at the combinations of the ingredients to produce geopolymer blocks to meet the strength development desired at the specified age. The strength data was analyzed within the framework of generalized Abrams' law. It was interesting to note that the law was applicable to the analysis of strength development of partially saturated compressed blocks when the degree of saturation was maintained constant. The validity of phenomenological model was examined with an independent set of experimental data. The blocks can replace the traditional masonry blocks with many advantages.

• Resources Recycling
• /
• v.15 no.6 s.74
• /
• pp.16-24
• /
• 2006

In this study, the neutralization and dechlorination process of MWI(Municipal Waste Incinerator) fly ash with $H_2SO_4$ are investigated to recover HCI, which is delivered from the reaction of chloride in the ash and sulfuric acid. The coarse crystalline gypsum and fine impurity containing heavy metal are also separated by 500# wet screening followed by recrystallization of the dechlorinated ash mainly made of $CaSO_4$. As a results, Using 100g MWI fly ash and 85g cone. sulfuric acid as raw material, 52.6g hydrochloric acid with 35% assay and 116.9g crystalline gypsum with 98% or more assay are recovered. In this process, 7.85g fine impurity containing heavy metal and 2.65g coarse impurity are also separated.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2003.11a
• /
• pp.326-329
• /
• 2003

In practice, recycled aggregate is not used for a structural member due to its high absorbability and abrasion. It is, however, highly expected that the usage of recycled aggregate increases as the processing technique of the recycled aggregate progresses. In this study herein, the compressive strength of the recycled aggregate concrete was investigated. Coarse aggregate was replaced with 100% of the recycled aggregate, and cement and fine aggregate was replaced with various amount. The specimen was steam-cured at $80^{\circ}C$. It was shown that the concrete can obtain desirable strength when fine aggregate was replaced with up to 60% of recycled fine aggregate, and when cement was replaced with up to 15% of fly ash.

• Proceedings of the Korean Society of Agricultural Engineers Conference
• /
• 2001.10a
• /
• pp.142-146
• /
• 2001

This research was undertaken on the use of bottom ash as a fine aggregate in Controlled. Low-strength Material(CLSM). The mixtures contained constant fly ash. And four different level of bottom ash with fly ash contents, 25%, 50%, 75%, 100% are investigated. Mixture proportions were developed for producing CLSM at three 28-day strength levels: removal with tools (less than $7kgf/cm^{2}$), removal by mechanical means (less than $200kgf/cm^{2}$), and removal with power equipment (less than $83kgf/cm^{2}$). To obtain these strengths, cement contents of 30, 60, and $120kg/cm^{3}$ were utilized. The compressive strength properties support the concept that by-product bottom ash can be successfully used in CLSM.