• Membrane and Water Treatment
• /
• v.1 no.4
• /
• pp.297-316
• /
• 2010

Membrane fouling is one of the major operational concerns of membrane processes which results in loss of productivity. This paper investigates the ultrafiltration (UF) results of synthetic oil-in-water (o/w) emulsion using flat sheets of polysulfone (PSf) membrane synthesized with four different compositions. The aim is to identify the mechanisms responsible for the observed permeate flux reduction with time for different PSf membranes. The experiments were carried out at four transmembrane pressures i.e., 68.9 kPa, 103.4 kPa, 137.9 kPa and 172.4 kPa. Three initial oil concentrations i.e., 75 $mgL^{-1}$, 100 $mgL^{-1}$ and 200 $mgL^{-1}$ were considered. The resistance-in-series (RIS) model was applied to interpret the data and on that basis, the individual resistances were evaluated. The significances of these resistances were studied in relation to parameters, namely, transmembrane pressure and initial oil concentration. The total resistance to permeate flow is found to increase with increase in both transmembrane pressure and initial oil concentration while for higher oil concentration, resistance due to concentration polarization is found to be the prevailing resistance. The applicability of the constant pressure filtration models to the experimental data was also tested to explain the blocking process. The study shows that intermediate pore blocking is the dominant mechanism at the initial period of UF while in the later period, the fouling process is found to approach cake filtration like mechanism. However, the duration of pore blocking mechanism is different for different membranes depending on their morphological and permeation properties.

• Journal of Korean Society of Water and Wastewater
• /
• v.35 no.3
• /
• pp.197-204
• /
• 2021

In MBR, extracellular polymeric substance (EPS) is known as an important factor of fouling; soluble EPS (sEPS) affects internal contamination of membrane, and bound EPS (bEPS) affects the formation of the cake layer. The production of EPS changes according to the composition of influent, which affects fouling characteristics. Therefore, in this study, the effects of the F/M ratio on the sEPS concentration, bEPS content, and fouling were evaluated. The effects of F/M ratio on the amount and composition of EPS were confirmed by setting conditions that were very low or higher than the general F/M ratio of MBR, and the fouling occurrence characteristics were evaluated by filtration resistance distribution. As a result, it was found that the sEPS increased significantly with the increase of the F/M ratio. When the substrate was depleted, bEPS content decreased because bEPS was hydrolyzed into BAP and seemed to be used as a substrate. In contrast, when the substrate is sufficient, UAP (utilization-associated products) was rapidly generated in proportion with the consumption of the substrate. UAP has a relatively higher Protein/Carbohydrate ratio (P/C ratio) than BAP, and this means, it has a higher adhesive force to the membrane surface. As a result, UAP seems like causing fouling rather than BAP (biomass-associated products). Therefore, R_f (Resistance of internal contamination) increased rapidly with the increase of UAP, and R_c (Resistance of cake layer) increased with the accumulation of bEPS in proportion, and as a result, the fouling interval was shortened. According to this study, a high F/M ratio leads to an increment in UAP generation and accumulation of bEPS, and by these UAP and bEPS, membrane fouling is promoted.

• Journal of Korean Society of Water and Wastewater
• /
• v.23 no.1
• /
• pp.121-128
• /
• 2009

Objectives of this study were to investigate influencing factors of detention time, particle size distribution, and filter medium characteristics for waterworks sludge dewatering. The stepped pressure filtration was carried out with lab scale apparatus and the filter press pilot test for dewatering was conducted at the water treatment plant. Effects of filter medium and polymer dose were examined through observing water content and dewatering velocity and cyclic dewatering rate with filter press pilot test. Relationships among detention time, particle size distribution and filtration resistance were analyzed. Prolongation of sludge detention time was found to cause blinding phenomenon in cake and filter medium and to decrease dewatering process efficiency. The average specific resistance increased according to detention time. In pilot test of dewatering for thickened sludge with Nylon Multi-NY840D and Nylon Mono-100% filter media, dewatering velocities were 0.92 and $0.93kg\;DS/m^2{\cdot}hr$ according to 0.1% polymer dose of dried solids weight base. And cyclic dewatering rates were 2.45 and $2.50kg\;DS/m^2{\cdot}cycle$ cycle for the Nylon Multi-NY840D and Nylon Mono-100% media. Dewatering velocity of polymer dosed sludge was observed to be higher than that of non-polymer sludge.

• Journal of Korean Society on Water Environment
• /
• v.20 no.4
• /
• pp.370-375
• /
• 2004

Synthetic organic polyelectrolytes can be used to condition sludges to enhance their dewaterability. When conditioning biological sludges, the charge on the polymer has a significant impact on the effectiveness of the polymer as a conditioner. The objectives of this investigation were to determine the most effective type and dosage of polymer for conditioning digested sludge prior to dewatering, and to investigate the relationship between dewaterability and particle size. 3 types of digested sludge were used under the different digestion processes like anaerobic digestion, aerobic digestion and intermittent aerobic digestion. CST(capillary suction time), TTF(time-to-filter) and SRF(specific resistance to filtration) were tested as a dewaterability index and the number of particle distribution was analyzed using particle size analyzer. The results indicate that cationic polymer appears to be required for effective conditioning of these 3 types digested sludge and the optimal polymer dosage is about 0.6% of SS. CST and TTF are well correlated with mean particle diameter of which the dimension order is 1.7.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.8 no.4
• /
• pp.874-880
• /
• 2007

Capillary Suction Time(CST) and Specific Resistance to Filtration(SRF) were commonly used to evaluate the sludge dewatering behaviors. A coupled equation was developed through the mathematical theory which represented both CST and SRF as the physical filterability of the ultrasonically treated sludge. The model for coupling CST and SRF includes both equipment variables and variables related to sludge characteristics, and verified with the results from experiments. The results of the theoretical and experimental study showed that a good correlation relationship among dewaterability indices.

• Journal of Korean Society of Environmental Engineers
• /
• v.27 no.12
• /
• pp.1305-1310
• /
• 2005

As a way to the optimum design of the collector well lateral in riverbed filtration, experiments were performed using sand tanks which were connected to form a model lateral system. Measured were the residual hydraulic heads along the laterals, the discharge rates at each sand tank and the production rates at the collector well while the model laterals were operated with various scenarios of changing parameters including water level of the collector well, the lateral diameter and length, and the hydraulic conductivity of the sand. Results showed that riverbed filtration could be more efficient when the resistance in the lateral was weak compared with the resistance in the sand, which was indicated by the more flattened distribution of the residual hydraulic heads along the lateral. Results also showed that the discharge rate increased exponentially with the approach to the collector well, and that the exponent increased as the lateral diameter decreased and/or the hydraulic conductivity of the sand increased. It was also seen that the well production increased with the increase in the lateral length and diameter although the marginal productivity decreased. It could be concluded that the axial flow velocity in the lateral was an important factor governing the efficiency of a lateral in riverbed filtration and that the maximum entrance velocity to the collector well, over which the efficiency decreased drastically, was about 1 m/sec under the conditions of this study.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2009.11a
• /
• pp.18.2-18.2
• /
• 2009

Ceramics have some properties that are unmatched by other kind of materials like metals or polymers. The ability of high thermal and chemical resistance and in case of being superior in specific mechanical properties makes the ceramic materials suitable for arange of applications. The microstructure and morphology of a material arguably permit the use of many advanced application otherwise difficult to achieve.Porous structures have some important applications in biomedical and environmental field. For human hard tissue reconstruction and augmentation procedure suitable biomaterials are used with a desirable porosity. A range of porous bioceramics were fabricated with tailored design to meet the demand of specific applications. Channeled and interconnected porosity was introduced in alumina, zirconia, and hydroxyapatite or tri calcium phosphate ceramics by different methods like multi-pass extrusion process, bubble formation in viscous slurry,slurry dripping in immiscible liquid, sponge replica method etc. The detailed microstructural and morphological investigations were carried out to establish the unique features of each method and the developed systems. For environmental filters the porous structures were also very important. We investigated a range of channeled and randomly porous silicon based ceramic composites to enhance the material stability and filtration efficiency by taking advantage of the material chemistry of the element. Detailed microstructural and mechanical characterizations were carried out for the fabricated porous filtration systems.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2008.10a
• /
• pp.498-507
• /
• 2008

The mixture of bentonite powder and water is generally used to maintain the stability of excavation surface during the construction of vertical cutoff walls. The filter cake on the sidewall surface is the result of filtration of slurry into the adjacent soil formation. The filter cake is believed to have a very low hydraulic conductivity compared to that of the cutoff wall. This paper evaluates hydraulic conductivities of bentonite filter cakes set up with three types of bentonites under various pressure levels. A modified fluid loss test was employed in this experiment. Theory of filtration process was reviewed to explain the procedure in the present experiment. Hydraulic conductivity of the filter cakes with consideration of the filter medium resistance was evaluated. The results of the experiment with two calculation methods and discussion are presented to show the efficiency of the modified fluid loss test.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2008.10a
• /
• pp.1502-1511
• /
• 2008

The mixture of bentonite powder and water is generally used to maintain the stability of excavation surface during the construction of vertical cutoff walls. The filter cake on the sidewall surface is the result of filtration of slurry into the adjacent soil formation. The filter cake is believed to have a very low hydraulic conductivity compared to that of the cutoff wall. This paper evaluates hydraulic conductivities of bentonite filter cakes set up with three types of bentonites under various pressure levels. A modified fluid loss test was employed in this experiment. Theory of filtration process was reviewed to explain the procedure in the present experiment. Hydraulic conductivity of the filter cakes with consideration of the filter medium resistance was evaluated. The results of the experiment with two calculation methods and discussion are presented to show the efficiency of the modified fluid loss test.

• The Korean Journal of Malacology
• /
• v.22 no.2
• /
• pp.151-155
• /
• 2006

Proportion of Tegillarca granosa surviving after 2-6 hrs air exposure with 12 hrs interval at $20^{\circ}C$ and $28^{\circ}C$ for 20 days showed 85-100%, 80-100%, respectively. The survival rate was somewhat lower at high temperature but not significant (p < 0.05). Subsequent exposures for 7-9 days showed survival rate of 8.0-24.1% at $20^{\circ}C$ and $28^{\circ}C$. Oxygen consumption rates and filtration rates were significantly higher for 4 to 6 hrs exposures, compared with the preceding exposures. On the other hand, at $28^{\circ}C$, oxygen consumption rates in adult granular ark for 6 hrs exposure during 20 days had significantly decreased. Filtration rates in study groups increased a little over extended period of exposure, compared with those in control groups, and were similar irrelevant to the time of exposure and size of experimental animals. It is concluded, in view of their viability and oxygen consumption rate during air exposure, that ark shells have quite a high resistance to air exposure with their limited range of responses.