• 제목/요약/키워드: Film formation

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광변색 회절 이미지 형성을 위한 트라이아진계 메타아크릴레이트 모노머를 포함한 광고분자 필름의 특성평가 (Characterization of Photopolymers films containing triazine methacrylate monomer for photochromic diffractive image formation)

  • 오현진;이지예;김은경
    • 정보저장시스템학회논문집
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    • 제3권4호
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    • pp.173-177
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    • 2007
  • A photo-reactive methacrylate monomer having triazine as a core component was examined for photochromic diffractive image formation. Photochromic photopolymer films as a recording media contained a monomer mixture of triazine difunctional metharylate (DT) and ethylene glycol phenyl ether acrylate, binder polymer, photo initiator, and a photochromic spiro-oxazine dye. The content of photochromic dye was changed to examine the effect of photochromophore on diffraction efficiency and real holographic image formation. Holographic recording was performed on the photopolymer film by the combination of reference and probe beam. The diffraction efficiency of the photopolymer film in real-time measurement reached a maximum of $\sim90%$ within 30s. It was highly dependent on the photochromophore contents. After holographic recording, the color of the recorded area was changed under UV light (365 nm) and reversibly bleached to original color upon exposure to a visible light source. Films containing only photochromophore without monomer mixture were not reactive under the recording beam (491nm). Diffractive image formation and mechanism of the holographic recording in the presence of photochromophore will be presented.

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Effects of Edta on the Electronic Properties of Passive Film Formed on Fe-20Cr In pH 8.5 Buffer Solution

  • Cho, EunAe;Kwon, HyukSang;Bernard, Frederic
    • Corrosion Science and Technology
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    • 제2권4호
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    • pp.171-177
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    • 2003
  • The electronic properties of the passive film formed on Fe-20Cr ferritic stainless steel in pH 8.5 buffer solution containing 0.05 M EDTA (ethylene diammine tetraacetic acid) were examined by the photocurrent measurements and Mott-Schottky analysis for the film. XPS depth profile for the film demonstrated that Cr content in the outermost layer of the passive film was higher in the solution with EDTA than that in the solution without EDTA, due to selective dissolution of Fe by EDTA. In the solution with EDTA, the passive film showed characteristics of an amorphous or highly disordered n-type semiconductor. The band gap energies of the passive film are estimated to be ~ 3.0 eV, irrespective of film formation potential from 0 to 700 $mV_SCE$ and of presence of EDTA. However, the donor density of the passive film formed in the solution with EDTA is much higher than that formed in the solution without EDTA, due to an increase in oxygen vacancy resulted from the dissolution of Fe-oxide in the outermost layer of the passive film. These results support the proposed model that the passive film formed on Fe-20Cr in pH 8.5 buffer solution mainly consists of Cr-substituted $\gamma$-$Fe_2O_3$.

충돌 액막 분석을 위한 전기전도 액막 두께 측정장치 최적설계 (Optimum Design of a Liquid Film Thickness Measurement Device Using Electric Conductance for Impingement Liquid Film)

  • 이형원;이현창;김태성;안규복;윤영빈
    • 센서학회지
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    • 제27권6호
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    • pp.386-391
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    • 2018
  • To analyze the film cooling in a liquid rocket engine, it is necessary to understand the characteristics of the wall-impingement liquid film. We designed an optimal two-dimensional device for measuring the thickness of the liquid film thickness. This device quantitatively measures the liquid-film thickness distribution. In previous liquid-film thickness measuring devices, the liquid film was formed over the entire area of the sensor. However, its formation depended on injection conditions. To compensate for this, optimal resistors are selected. Additionally, saturation variations with partial saturation are analyzed. Furthermore, calibration using the enhanced plate method is conducted with improvements in spatial resolution. The device designed here can be used to analyze the properties of an impingement liquid film with a slit injector. This study can be used for film-cooling analysis in liquid rocket engines.

View cell에 의한 가스 하이드레이트 생성 관찰 (Observation of Gas Hydrate Formation by View Cell)

  • 조병학;이영철;모용기;백영순
    • 한국가스학회지
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    • 제8권3호
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    • pp.24-30
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    • 2004
  • 본 연구에서는 개선된 view cell 실험 장치를 통하여 가스 하이드레이트 생성 과정을 관찰하고 이의 동특성을 고찰하였다. 순수한 물과 촉진제로 음이온계 계면활성제를 미량 첨가한 물에 천연가스를 넣어 가스 하이드레이트를 생성 과정을 관찰하였다. 본 실험에서 사용한 276.65 K, 6 MPa 조건 상태에서는 충분한 지체 지연 시간이후 물에 순간 교반을 줌으로써 형성자 생성을 쉽게 유도할 수 있었다. 가스 하이드레이트 필름의 생성은 정적상태에서 가스와 접촉된 물의 표면에 생성되었다. 이는 육안으로 구분하기 어려운 매우 얇은 막이 수초 안에 물의 표면 전체를 덮는 선행과정과 이후 다시 육안관찰이 쉬운 필름층이 재생성되었다. 순수한 물에는 짧고 굵은 섬유 다발의 형태로 끝 부분이 둥글게 말려서 결정이 형성된 모습인 반면 촉진제를 넣은 경우 작은 섬유 다발 형태로 길게 생성되었고 다른 다발과 접촉되어 엉킨 결정 상상을 보였다.

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