• Title/Summary/Keyword: Fick's law

Search Result 93, Processing Time 0.032 seconds

Influence of Carbonation for Chloride Diffusion in Concrete (탄산화 복합환경시 염소이온 확산에 관한 연구)

  • Oh Byung-Hwan;Lee Sung-Kyu;Lee Myung-Kue;Jung Sang-Hwa
    • Journal of the Korea Concrete Institute
    • /
    • v.17 no.2 s.86
    • /
    • pp.179-189
    • /
    • 2005
  • Corrosion of steel due to chloride attack is a major concern in reinforced concrete structures which are located in the marine environments. In this case, Fick's 2nd law has been used for the prediction of chloride diffusion related with service life of concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the influences of carbonation to chloride attack in concrete structures and to investigate the validity of Fick's law to chloride attack combined carbonation. The test results indicate that the chloride ion profiles from Fick's law using the diffusion coefficient of immersion tests is not reflected the effect of separation of chloride ions in carbonation region but valid in sound region in case of combined action. On the other hand, the chloride ion profiles from Fick's law using the diffusion coefficient of Tang and Nilsson's method coincide with test results under dry-wet condition but not under combined condition. The results of present study may Imply that the new method for the measurement of diffusion coefficient is required to predict the chloride ion profiles in case of combined action at early.

A new approach for predicting sulfate ion concentration in concrete

  • Mohammad Ghanooni-Bagha;Mohsen Ali Shayanfar;Sajad Momen
    • Computers and Concrete
    • /
    • v.33 no.1
    • /
    • pp.1-11
    • /
    • 2024
  • Aggressive environmental conditions, and especially the acidic effects of sulfate ion penetration, have reduced the lifetime of concrete structures in some areas, especially coastal and marine areas. In this research, at first, samples made of type II and V cement were kept in a solution of magnesium sulfate (MgSO4) for a period of 90 and 180 days, the change of appearance. Field Emission Scanning Electron Microscopy (FE-SEM) and X-Ray Diffraction (XRD), were used to analyze the microstructure and the complex mineral composition of the concrete after exposure to corrosive environments. Then solving the differential equation governing the sulfate ion penetration, which is based on the second Fick law, it has been tried to determine the concentration of sulfate ions inside the concrete. In the following, an attempt has been made to improve the prediction of sulfate ion concentration in concrete by using Crank's penetration equation. At the same time, the coefficient in the Crank's solution have been optimized by using the Particle Swarm Optimization (PSO algorithm). The comparison between the results shows that the values obtained from Crank's relation are closer to the experimental results than the equation obtained from Fick's second law and shows a more accurate prediction.

Health prognostics of stator Windings in Water-Cooled Generator using Fick's second law (Fick's second law 를 이용한 수냉식 발전기 고정자 권선의 건전성 예지)

  • Youn, Byeng D.;Jang, Beom-Chan;Kim, Hee-Soo;Bae, Yong-Chae
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
    • /
    • 2014.10a
    • /
    • pp.533-538
    • /
    • 2014
  • Power generator is one of the most important component of electricity generation system to convert mechanical energy to electrical energy. I t designed robustly to maintain high system reliability during operation time. But unexpected failure of the power generator could happen and it cause huge amount of economic and social loss. To keep it from unexpected failure, health prognostics should be carried out In this research, We developed a health prognostic method of stator windings in power generator with statistical data analysis and degradation modeling against water absorption. We divided whole 42 windings into two groups, absorption suspected group and normal group. We built a degradation model of absorption suspected winding using Fick's second law to predict upcoming absorption data. Through the analysis of data of normal group, we could figure out the distribution of data of normal windings. After that, we can properly predict absorption data of normal windings. With data prediction of two groups, we derived upcoming Directional Mahalanobis Distance (DMD) of absorption suspected winding and time vs DMD curve. Finally we drew the probability distribution of Remaining Useful Life of absorption suspected windings.

  • PDF

Diffusion of Cr(VI) in Porous Media (심층 지하에서의 육가 크롬 확산)

  • 현재혁
    • The Journal of Engineering Geology
    • /
    • v.3 no.2
    • /
    • pp.203-214
    • /
    • 1993
  • Underground Injection Control regulations for Class I injection wells require that the vertical dufusion be considered as a mechanism for transport of contaninants in evaluating containment Due to the low permeability in the confining aquitard, the movement of contaminants over the long term is controlled by the molecular diffusion. The movement can be predicted, using the Fick' S second law of diffusion. The diffusion coefficient in Fick' s law has been determined experimentally in this study. Instantaneous injection of $^{51}Cr$ was used to trace the distribution of Cr(VI) in soil plugs and an analytical solution was applied to calculate the diffusion coefficients. This study shows the effect of environmental factors, such as temperature, chloride concentration, applied amount of $^{51}Cr$, and bulk density of injection formations on diffusion of Cr(VI)

  • PDF

Determination of Required Cover Depth of Concrete Exposed to Simultaneous Attack of Carbonation and Chloride Ion (중성화와 염소이온의 동시 복합환경에 노출된 콘크리트의 적정 피복두께의 결정)

  • 이창수;윤인석;이규동
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2003.11a
    • /
    • pp.90-93
    • /
    • 2003
  • The most common deteriorating processes of concrete structures in the world-wide are carbonation and chloride ion. In this paper, chloride profiles of carbonated concrete is predicted to considering two layer composite model, which is based on Fick's 2nd law. From the experimental result on combined deterioration of chloride and carbonation, it was examined that high chloride concentration was built up to 3-5㎜ over depth from carbonation depth. The analytical modeling of chloride diffusion, which was based on the Fick's 2nd law of diffusion, was suggested to depict the relative influence of the carbonation depth.

  • PDF

2D random walk와 세포 확산 비교 연구

  • Gwon, Tae-Jin
    • Proceeding of EDISON Challenge
    • /
    • 2015.03a
    • /
    • pp.53-60
    • /
    • 2015
  • 본 연구에서는 random walk하는 입자와 암세포 확산을 비교하여 Fick's law를 따르는 확산 모형과 암세포 확산의 차이를 밝힌다. 암세포 확산은 암 전이 메커니즘을 이해하는데 매우 중요하다. 하지만 아직까지 암세포 확산은 정확하게 이해되지 않고 있다. 따라서 이번 연구에서는 가장 간단한 2차원 random walk와 암세포 확산을 비교하고, 동역학적인 차이를 규명해 암세포 확산을 이해하고자 한다. Random walk하는 입자는 EDISON 전산화학 전문센터의 프로그램 중 dynamic Monte Carlo(dynamic MC) 전산 모사 소프트웨어를 이용하여 2차원에서 움직이는 레나드-존스 입자의 운동을 통해 살펴보았다. 암세포 확산은 실제 암세포의 시간에 따른 위치 변화 정보 (세포의 궤적)를 직접 구하여 분석하였다. Dynamic MC 결과는 Fickian 확산 모형을 잘 따르는 것을 평균 제곱 거리와 밀도 함수를 통해 확인할 수 있었다. 암세포 확산의 경우 평균 제곱 거리는 시간에 대해서 선형적으로 비례하지만 밀도 함수는 가우시안 형태로 나오지 않으며 Fick's law를 따르는 확산 모형과 다른 확산 형태를 보인다. 이러한 확산 형태는 암세포의 동역학적인 다양성 때문에 나타나며 각각의 암세포가 다른 운동성을 가지는 것에 기인하는 것으로 보인다.

  • PDF

Analysis of Concentration Distribution and Diffusion Depth in Tinted Lenses Using the Law of Diffusion (확산법칙을 이용한 착색렌즈에서의 농도분포와 확산깊이의 분석)

  • Choi, Eun Jung;Lee, Sin Ui
    • Journal of Korean Ophthalmic Optics Society
    • /
    • v.16 no.4
    • /
    • pp.403-408
    • /
    • 2011
  • Purpose: To study the concentration distribution and diffusion depth in tinted lenses using the law of diffusion. Methods: The measured values taken from experiments were fitted with the theoretical fitting curve induced on the basis of Fick's second law of diffusion. Results: The fitting curves were in very good agreement with the measured values. As the results, we found the quantitative relationship between mass of dye solution diffused into the tinted lens per unit area and dyeing time, and evaluated concentration distribution of dye in tinted lens, diffusion depth, etc. Conclusions: The dyeing mechanism of tinted lenses can be well described by diffusion theory.

SiC composite formed by Si vapor diffusion into porous graphite (다공질 그래파이트내부로 Si 증발입자 확산에 의해 형성되는 SiC 복합재료)

  • Park, Jang-Sick
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2015.11a
    • /
    • pp.167-167
    • /
    • 2015
  • SiC thin films made by vapor silicon infiltration into porous graphite can be obtained for shorter time than liquid silicon. Si diffusion coefficient is estimated by comparing experiment results with quadratic equation obtained by Fick's second law.

  • PDF

Kinetic Modeling of Dewatering of Potato Slice When Soaked in Concentrated Solution (고농도 용액에 침지시 감자 절편의 동력학적 탈수 모델링에 관한 연구)

  • 최동원;신해헌
    • The Korean Journal of Food And Nutrition
    • /
    • v.13 no.5
    • /
    • pp.477-482
    • /
    • 2000
  • For the purpose of explaining the dewatering phenomena of potato slice soaked in concentrated solution three models were proposed. Earlier model cannot explain the dewatering phenomena of potato slice in concentrated solution because of limiting its condition which is necessary to build a model. Therefore other three models were suggested and a model based on Fick\`s second law of mass transport at infinite plate conditions and numerical analysis was test model for explaining dewatering phenomena of potato soaked in concentrated solution. Apparent diffusion coefficient of water could be readily estimated from model III, and it could explain adequately the difference of the dewatering phenomena of various soaking conditions.

  • PDF

A Diffusion-based Model Theory of Passive-Targeted Drug Delivery in Solid Tumors (단단한 종양 안에 수동 조준된 약물의 전달에 관한 확산에 기초한 모델 이론)

  • Choi, Joon-Hyuck;Kang, Nam-Lyong;Choi, Sang-Don
    • Progress in Medical Physics
    • /
    • v.18 no.3
    • /
    • pp.161-166
    • /
    • 2007
  • A model theory of passive-targeted drug delivery in sphere-shaped solid tumors is introduced on the basis of Fick's law of diffusion, with appropriate boundary and initial conditions. For a uniform initial concentration inside the tumor, the concentration is obtained as a function of time and radial position. The concentration is shown to approach the equilibrium distribution as the time elapses, as is expected by the Gedanken Experiment. The time-evolution rate is found to be determined by the diffusion coefficient of the drug in the tissue, the size of the tumor, the volume of the drug-injected region, and the concentration gradient at the boundary.

  • PDF