• Korean Journal of Materials Research
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• v.20 no.1
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• pp.31-36
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• 2010

Methylene blue (MB) was degraded by $TiO_2$ and ZnO deposited on an activated carbon fiber (ACF) surface under UV light. The ACF/$TiO_2$ and ACF/ZnO composites were characterized by BET, SEM, XRD, and EDX. The BET surface area was related to the adsorption capacity for composites. The SEM results showed that titanium dioxide and zinc oxide are distributed on the ACF surface. The XRD results showed that the ACF/$TiO_2$ and ACF/ZnO composites contained a unique anatase structure for $TiO_2$ and a typical hexagonal phase for ZnO respectively. These EDX spectra showed the presence of peaks of Ti element on ACF/$TiO_2$ composite and peaks of Zn element on the ACF/ZnO composite. The blank experiments for either illuminating the MB solution or the suspension containing ACF/$TiO_2$ or ACF/ZnO in the dark showed that both illumination and the catalyst were necessary for the mineralization of organic dye. Additionally, the ACF/$TiO_2$ composites proved to be efficient photocatalysts due to degradation of MB at higher reaction rates. The addition of an oxidant $([NH_4]_2S_2O_8)$ led to an increase of the degradation rate of MB for ACF/$TiO_2$ and ACF/ZnO composites.

• Macromolecular Research
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• v.12 no.1
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• pp.119-126
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• 2004

In this study, the influence of silane coupling agents, featuring different organo-functional groups on the interlaminar and thermal properties of woven glass fabric-reinforced nylon 6 composites, has been by means of short-beam shear tests, dynamic mechanical analysis, scanning electron microscopy, and thermogravimetric analysis. The results indicate that the fiber-matrix interfacial characteristics obtained using the different analytical methods agree well with each other. The interlaminar shear strengths (ILSS) of glass fabric/nylon 6 composites sized with various silane coupling agents are significantly improved in comparison with that of the composite sized commercially. ILSS of the composites increases in the order: Z-6076 with chloropropyl groups in the silanes > Z-6030 with methacrylate groups> Z-6020 with diamine groups; this trend is similar to that of results found in an earlier study of interfacial shear strength. The dynamic mechanical properties, the fracture surface observations, and the thermal stability also support the interfacial results. The improvement of the interfacial properties may be ascribed to the different chemical reactivities of the reactive amino end groups of nylon 6 and the organo-functional groups located at the ends of the silane chains, which results from the increased chemical reactivity in order chloropropyl > methacrylate > diamine.

• Korean Journal of Materials Research
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• v.3 no.2
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• pp.197-204
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• 1993

Abstract The effects of the hole size and the specimen width on the fracture behavior of several fabric composite plates are experimentally investigated in tension. Tests are performed on plain woven glass/ epoxy, plain woven carbon/epoxy and satin woven glass/polyester specimens with a circular hole. It is shown in this paper that the characteristic length according to the point stress criterion depends on the hole size and the specimen width. An excellent agreement is found between the experimental results and the analytical predictions of the modified failure criterion. The notched strength increase with an increase in the damage ratio, which is explained by a stress relaxation due to the formation of damage zone. When the unstable fracture occurred, the critical crack length equivalent for the damage zone is about twice the characteristic length. The critical energy release rate $G_c$ is independent of hole size for the same specimen width. The variation of $G_c$ according to the material system, fiber volume fraction and specimen width relates to the notch sensitivity factor. $G_c$ increases with a decrease in the notch sensitivity factor, which can be explained by a stress relaxation due to the increase of damage zone.

• Carbon letters
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• v.18
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• pp.18-23
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• 2016

Polyacrylonitrile (PAN)-based carbon fibers have high specific strength, elastic modulus, thermal resistance, and thermal conductivity. Due to these properties, they have been increasingly widely used in various spheres including leisure, aviation, aerospace, military, and energy applications. However, if exposed to air at high temperatures, they are oxidized, thus weakening the properties of carbon fibers and carbon composite materials. As such, it is important to understand the oxidation reactions of carbon fibers, which are often used as a reinforcement for composite materials. PAN-based carbon fibers T300 and T700 were isothermally oxidized in air, and microstructural changes caused by oxidation reactions were examined. The results showed a decrease in the rate of oxidation with increasing burn-off for both T300 and T700 fibers. The rate of oxidation of T300 fibers was two times faster than that of T700 fibers. The diameter of T700 fibers decreased linearly with increasing burn-off. The diameter of T300 also decreased with increasing burn-off but at slower rates over time. Cross-sectional observations after oxidation reactions revealed hollow cores in the longitudinal direction for both T300 and T700 fibers. The formation of hollow cores after oxidation can be traced to differences in the fabrication process such as the starting material and final heat treatment temperature.

• Journal of Korean Society of Steel Construction
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• v.18 no.2
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• pp.161-171
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• 2006

paper presents the results of a three-dimensional study of the natural vibration of laminated composite rectangular plates with various combinations of clamped and free boundaries. The Ritz method was used to obtain the stationary values of the associated Lagrangian, with displacements approximated using mathematicaly complete, characteristic orthogonal polynomials. The correctness of the three-dimensional model was established through a convergence study of the non-dimensional frequencies, followed by a comparison of the analytical findings in the existing literature. The wide scope of additional three-dimensional frequency results explains the influence of a number of geometrical and material parameters for angle-ply and cross-ply laminated plates, namely aspect ratio (${\mathcal{a/b}}$), thickness ratio (${\mathcal{a/h}}$), orthotropy of material, number of plies (${\mathcal{N}}$), fiber orientation angle (${\theta}$), and stacking sequence.

• Korean Journal of Materials Research
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• v.8 no.4
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• pp.299-303
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• 1998

We examined, using thermoanalytical methods, the effects of $2000^{\circ}C$ heat-treated graphite powders and heating rate of cure after impregnation on the thermal stability and carbon yield of furfuryl alcohol, which is frequently used not only as an impregnant but also as a matrix precursor for carbon fiber-reinforced carbon composites. It was founded that the addition of 30wt% graphite powders to furfuryl alcohol and the heating rate of $35^{\circ}C$/min showed the highest thermal stability of furfuryl alcohol/graphite powder mixture. The carbon yield above $1000^{\circ}C$ was enhanced more than 10% in comparison with the absence of graphite powders. It would be expected that this result can contribute to some extent to reduce the repeating number of processing cycle (carbonization-impregnation-cure-re-carbonization) required to densify a carbonaceous composite.

• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.2
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• pp.95-103
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• 2012

In order to improve the dimensional stability and mechanical performance of cement-based composites, the effect of an expansive admixture based on calcium sulphoaluminate (CSA) on the shrinkage and mechanical properties of strain-hardening cement-based composite (SHCC), which exhibits multiple cracks and pseudo strain-hardening behavior in the direct tension, is investigated. Polyethylene fibers reinforced SHCC mixtures with three levels (30, 70, and 100MPa) of compressive strength were compared through free shrinkage, compressive strength, flexural strength, and direct tensile strength measurements. The SHCC mixtures were cast with and without replacing 10% of Portland cement content with CSA admixture. According to test results, CSA admixture is effective in reducing shrinkage of SHCC material. SHCC mixture with CSA admixture exhibited a little higher strength than companion mixture without CSA admixture.

• Journal of Aerospace System Engineering
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• v.13 no.5
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• pp.94-101
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• 2019

The dynamic characteristics of the composite reflector panels are numerically and experimentally investigated. A dynamics model of the panel is analytically developed based on a deployment mechanism of the antenna. The deployment is passively activated using elastic energy of a spring with two rotational degrees of freedom. Using the flexible multi-body dynamic analysis ADAMS, dynamic behavior of the panels such as velocities, deformations, as well as reaction forces during the deployment, are investigated in the gravity and zero-gravity cases. The reflector panel is manufactured using carbon fiber reinforced plastics (CFRPs) and its deployment characteristics are experimentally observed using a zero-gravity deployment test. The impact response and vibration problems that occur during deployment of the antenna panel have been identified and reliably deployed using dampers.

• Journal of the Korean Wood Science and Technology
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• v.47 no.5
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• pp.655-662
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• 2019

This study evaluated the multi-bonding performances of timbers as well as those of reinforcement and timber to obtain data for preparing guidelines regarding the use of timbers as large structural members. For the multi-bonding performances of timbers, four types of bonding surfaces were prepared according to the pith position. For the bonding performances of FRP (fiber-reinforced plastic)/steel plate and timber, a total of 11 types of specimens were produced for the selection of the appropriate adhesive. The bonding performances of the produced specimens were evaluated through a water soaking delamination test, a water boiling delamination test, and a block shear strength test. The test results showed that the bonding strength of the bonding surface according to the pith position was highest in the specimen for which the two sections with the pith at the center of the cross-section on timber and between the bonding surfaces (the tangential and radial sections were mixed) were bonded. Furthermore, the specimens for which the section (radial section) with the pith on the bonding surface of the timber was bonded showed a high delamination percentage. The results of the block shear strength test showed that the bonding section did not have a significant effect on the shear strength, and that the measured wood failure percentage was higher than the KS standard value. The PVAc adhesive showed the highest bonding strength between larix timber and GFRP (glass FRP). Furthermore, the epoxy and polyurethane adhesives showed good bonding strength for CFRP (carbon FRP) and structure steel, respectively.

• Journal of Advanced Navigation Technology
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• v.23 no.4
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• pp.273-280
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• 2019

There are many studies that use structure health monitoring to reduce maintenance costs for aircraft and to increase aircraft utilization. Many studies on FBG sensors are also being conducted. However, if the FBG sensor is installed inside the composite, voids will occur between the layers of the composite, resulting in signal split problem. In addition, the FBG sensor is not affected by electromagnetic waves, but will produce electromagnetic noise caused by electronic equipment during post-processing. In this paper, to reduce the error caused by these noises, the stationary wavelet transform, which has the characteristics of movement immutability and is efficient in nonlinear signal analysis, is presented. And in the above situation, we found that noise rejection performance of stationary wavelet transform was better compared with the wavelet packet transform.