• Journal of Magnetics
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• 제19권4호
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• pp.327-332
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• 2014

The effect of minor element additions (Ca, Al) on microstructural change and magnetic properties of Fe-Nb-Cu-Si-B alloy has been investigated, in this paper. The Fe-Si-B-Nb-Cu(-Ca-Al) alloys were prepared by arc melting in argon gas atmosphere. The alloy ribbons were fabricated by melt-spinning, and heat-treated under a nitrogen atmosphere at $520-570^{\circ}C$ for 1 h. The soft magnetic properties of the ribbon core were analyzed using the AC B-H meter. A differential scanning calorimetry (DSC) was used to examine the crystallization behavior of the amorphous alloy ribbon. The microstructure was observed by X-ray diffraction (XRD), transmission electron microscope (TEM) and scanning electron microscope (SEM). The addition of Ca increased the electrical resistivity to reduce the eddy current loss. And the addition of Al decreased the intrinsic magnetocrystalline anisotropy $K_1$ resulting in the increased permeability. The reduction in the size of the ${\alpha}$-Fe precipitates was observed in the alloys containing of Ca and Al. Based on the results, it can be concluded that the additions of Ca and Al notably improved the soft magnetic properties such as permeability, coercivity and core loss in the Fe-Nb-Cu-Si-B base nanocrystalline alloys.

• 대한치과보철학회지
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• 제44권5호
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• pp.628-641
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• 2006

Statement of problem: Dental magnetic materials have been applied to removable prosthetic appliances, maxillofacial prostheses, obturator and dental implant but they still have some problems such as low corrosion resistance in oral environments. Purpose: To increase the corrosion resistance of dental magnetic materials, surfaces of Sm-Co and Nd-Fe-B based magnetic materials were plated with TiN and sealed with stainless steels. Materials and methods : Surfaces of Sm-Co and Nd-Fe-B based magnetic materials were plated with TiN and sealed with stainless steels, and then three kinds of electrochemical corrosion test were performed in 0.9% NaCl solution; potentiodynamic, potentiostatic, and electrochemical impedance test. From this study, corrosion behavior, amount of elements released, mean average surface roughness values, the changing of retention force, and magnetic force values were measured comparing with control group of non-coated magnetic materials. Results: The values of surface roughness of TiN coated Sm-Co and TiN coated Nd-Fe-B based magnetic materials were lower than those of non coated Sm-Co and Nd-Fe-B alloy. From results of potentiodynamic test, the passive current density of TiN coated Sm-Co alloy were smaller than those of TiN coated Nd-Fe-B alloy and non coated alloys in 0.9% NaCl solution. From results of potentiostatic and electrochemical impedance test, the surface stability of the TiN coated Sm-Co alloy was more drastically increased than that of the TiN coated Nd-Fe-B alloy and non-coated alloy. The retention and magnetic force after and before corrosion test did not change in the case of TiN coated magnetic alloy sealed with stainless steel. Conclusion: It is considered that the corrosion problem and improvement for surface stability of dental magnetic materials could be solved by ion plating with TiN on the surface of dental magnetic materials and by sealing with stainless steels.

• 한국분말재료학회지
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• 제9권3호
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• pp.161-166
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• 2002

Processing and properties of $Al_2O_3$ composites with Ni-Fe content of 10 and 15 wt% were investigated. Homogeneous powder mixtures of $Al_2O_3$/Ni-Fe alloy were prepared by the solution-chemistry route using $Al_2O_3$, $Ni(NO_3)_2{\cdot}6H_2O$ and $Fe(NO_3)_3{\cdot}9H_2O$ powders. Microstructural observation of composite powder revealed that Ni-Fe alloy particles with a size of 20nm were homogeneously dispersed on $Al_2O_3$ powder surfaces. Hot-pressed composites showed enhanced fracture toughness and magnetic response. The properties are discussed based on the observed microstructural characteristics.

• 한국전산구조공학회논문집
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• 제35권5호
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• pp.287-297
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• 2022

본 논문에서는 철계형상기억합금(Fe SMA) 스트립으로 능동구속된 콘크리트 기둥의 실험적, 해석적 연구결과를 제시한다. Fe SMA과 탄소섬유보강시트(CFRP)로 각각 구속된 콘크리트 공시체의 압축실험을 통해 형상기억합금 기반 능동구속기법의 효과성을 평가하였다. 실험결과, Fe SMA 스트립으로 구속된 콘크리트 공시체가 낮은 구속력에도 불구하고 CFRP 시트로 구속된 공시체에 비해 더 우수한 변형능력을 가지는 것으로 밝혀졌다. 실험을 통해 얻은 구속된 콘크리트의 압축거동 결과를 이용해 소성힌지 영역이 각각 Fe SMA 스트립과 CFRP 시트로 보강된 콘크리트 기둥의 유한요소모델을 구축하였다. 기존 수행된 콘크리트 기둥의 수평반복가력 실험결과를 바탕으로 구축된 기둥 모델을 검증하였고, 각각의 기둥 모델에 대한 수평반복가력 해석을 수행하였다. 해석결과, Fe SMA 스트립으로 보강된 콘크리트 기둥이 CFRP 시트로 보강된 기둥모델에 비해 변형, 에너지 소산능력 향상에 효과적임을 확인하였다.

• 한국재료학회지
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• 제13권9호
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• pp.619-624
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• 2003

This paper describes a method to control Mn and Fe contents in recycled AZ91D ingots, based on the mutual solubility of Mn and Fe in AZ91 alloy melts. For this purpose, Fe solubility with the change of Mn content and temperature was investigated in the homogenized and re-precipitated liquid AZ91 alloy. The increase of the amount of Mn added to the melt resulted in the decrease of Fe content. The data obtained in this study was adopted to the pilot plant for recycling of the scrap. As a result, Mn and Fe contents measured in the recycled ingot were in good agreement with ASTM B93 standard.

• Applied Microscopy
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• 제48권4호
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• pp.117-121
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• 2018

The multiple length scale analysis of previously designed Fe-Mn-Al-C based low-density model alloys reveals the difference in ordered ${\kappa}-carbide$, $(Fe,Mn)_3AlC_x$, between Fe-25Mn-16Al-5.2C (at%) alloy and Fe-3Mn-10Al-1.2C (at%) alloy. For the former alloy composition consisting of fully austenite grains, ${\kappa}-carbide$ showed majorly cuboidal and minorly pancake morphology and its chemical composition was not changed through aging for 24 h and 168 h at $600^{\circ}C$. Meanwhile, for the isothermally annealed ferritic alloy system for 1 hr at 500 and $600^{\circ}C$, the dramatic change in the chemical composition of needle-shape ${\kappa}-carbide$, $(Fe,Mn)_3(Fe,Al)C_x$, was found. Here we address that the compositional fluctuations in the vicinity of the carbides are significantly controlled by abutting phase, either austenite or ferrite. Namely, the cooperative ordering of carbon and Al is an important factor contributing to carbide formation in the high-Mn and high-Al alloyed austenitic steel, while the carbon and Mn for the low-Mn and high Al alloyed ferritic steel.

• 한국자기학회지
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• 제5권1호
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• pp.38-41
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• 1995

$\alpha$-Fe를 주상으로 하는 새로운 Nd-Fe-B계 합금을 개발하기 위하여 Nd 함유량을 4at.%로 고정시킨 Nd-Fe-B 초미세결정립합금의 제조 및 자기특성이 조사되었다. 급속응고법으로 제조된 $Nd_{4}Fe_{85.5}B_{10.5}$ 비정질합금은 결정화하여 $\alpha$-Fe 기지상에 $Nd_{2}Fe_{14}B$이 형성되나 자기특성${_{i}H_{c}=95.5kA/m(1.2kOe),\;Br=1.2T}$은 열화된다. Nb 및 Cu를 첨가한 $Nd_{4}Fe_{82}B_{10}Nb_{3}Cu_{1}$ 합금은 $\alpha$-Fe 결정립미세화(<30nm)로 보자력이 207kA/m(2.6 kOe)로 증가하나 잔류자화는 개선되지 않았다. 이 합금조성에 8at.% Co 첨가는 결정립을 더욱 미세화시키며 자기특성을 개선 시킨다. 최적열처리조건에서 $Nd_{4}Fe_{74}Co_{8}B_{10}Nb_{3}Cu_{1}$ 합금의 잔류자화, 보자력 및 최대에너지적이 각각 1.34 T, 219 kA/m (2.75kOe) 및 $95.5kJ/m^{3}$(12MGOe) 이다.

• 한국자기학회지
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• 제7권1호
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• pp.44-48
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• 1997

약 30 nm의 미세결정립으로 구성된 ( .alpha. -Fe)-(Nd$_{2}$Fe$_{14}$B$_{1}$)형 저 Nd함유 Nd-Fe-B계 합금이 급속응고법으로 제조된 비정질상으로 부터 결정화하여 제조되었다. Nd$_{4}$Fe$_{82}$B$_{10}$Mo$_{3}$Cu$_{1}$ 조성에 Ga의 첨가는 각형성 개선효과와 함께 잔류자화를 1.29 T까지 증가시킨다. Nd의 함유량을 증가시킨 초미세결정립 Nd$_{5}$Fe$_{81}$B$_{9}$Mo$_{3}$Cu$_{1}$Ga$_{1}$ 합금의 Nd$_{2}$Fe$_{81}$B$_{9}$Mo$_{3}$Cu$_{1}$Ga$_{1}$ 합금의 잔류자화, 보자력 및 최대자기에너지적은 각각 1.24 T, 257.4 kA/m(3.23 kOe), and 100.3 kJ/m$^{3}$(12.6 MGOe)이다.다.

• 한국분말재료학회지
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• 제18권2호
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• pp.105-111
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• 2011

This study investigated the effect of wire diameter and applied voltage on the fabrication of Ni-free Fe-based alloy nano powders by employing the PWE (pulsed wire evaporation) in liquid, for high temperature oxidation-resistant metallic porous body for high temperature particulate matter (or soot) filter system. Three different diameter (0.1, 0.2, and 0.3 mm) of alloy wire and various applied voltages from 0.5 to 3.0 kV were main variables in PWE process, while X-ray diffraction (XRD), field emission scanning microscope (FE-SEM), and transmission electron microscope (TEM) were used to investigate the characteristics of the Fe-Cr-Al nano powders. It was controlled the number of explosion events, since evaporated and condensed nano-particles were coalesced to micron-sized secondary particles, when exceeded to the specific number of explosion events, which were not suitable for metallic porous body preparation. As the diameter of alloy wire increased, the voltage for electrical explosion increased and the size of primary particle decreased.

• 한국재료학회지
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• 제20권1호
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• pp.37-41
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• 2010

Creep tests were conducted under a condition of constant stress on two aluminum-based alloys containing particles: Al-5% Mg-0.25% Fe and Al-5% Zn-0.22% Fe. The role of grain boundary sliding was examined in the plane of the surface using a square grid printed on the surface by carbon deposition and perpendicular to the surface using two-beam interferometry. Estimates of the contribution of grain boundary sliding to the total strain, $\varepsilon_{gbs}/\varepsilon_t$ reveal two trends; (i) the sliding contribution is consistently higher in the Al-Mg-Fe alloy, and (ii) the sliding contribution is essentially independent of strain in the Al-Mg-Fe alloy, but it shows a significant decrease with increasing strain in the Al-Zn-Fe alloy. Sliding is inhibited by the presence of particles and its contributions to the total strain are low. This inhibition is attributed to the interaction between the grain boundary dislocations responsible for sliding and particles in the boundaries.