• 제목/요약/키워드: Fe-base alloys

검색결과 69건 처리시간 0.023초

CIS 박막태양전지용 철계 연성 기판재의 열팽창 특성 연구 (Study on the thermal expansion properties of Fe alloys for the flexible substrate of CIS thin film solar cell)

  • 한윤호;이민수;송영식;조용기;임태홍
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
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    • pp.44.2-44.2
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    • 2010
  • 차세대 태양전지로써 플렉서블 태양전지에 대한 연구가 활발하다. CIS 박막태양전지의 경우도 Glass base 태양전지 시스템 연구와 더불어 금속과 플라스틱 등 연성 기판재를 이용한 전지 시스템에 관한 연구가 진행 되고 있다. 그러나 태양전지의 핵심 부자재라고 할 수 있는 기판재에 대한 체계적인 연구는 미흡한 실정이다. 특히 플렉서블 박막태양전지용 기판재와 그 위에 적층되어 태양전지를 구성하는 박막 소재의 열팽창 거동들 사이에 차이가 있어 태양전지 시스템에 결함을 야기할 수 있다. 본 연구에서는 플렉서블 태양전지용으로 적용되거나 연구되고 있는 SUS 300 계열과 SUS 400번 계열을 중심으로 철계 연성 기판재의 열팽창 거동을 비교 분석하였다. 그리고 CIS 박막태양전지 제조 공정인 고온 박막 생성 공정의 열분석을 통해 기판재의 성능을 평가 하였다.

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Fe-29%Ni-17%Co 저열팽창 합금의 피로 특성에 미치는 알파상의 영향 (Effects of Alpha Phase on the Fatigue Properties of Fe-29%Ni-17%Co Low Thermal Expansion Alloy)

  • 김민종;권진한;조규상;이기안
    • 한국재료학회지
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    • 제24권9호
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    • pp.481-487
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    • 2014
  • The effect of alpha phase on the fatigue properties of Fe-29%Ni-17%Co low thermal expansion alloy was investigated. Two kinds of alloys (Base alloy and Alpha alloy) were prepared by controlling the minimal alloy composition. Microstructure observation, tensile, high-cycle fatigue, and low-cycle fatigue results were measured in this study. The Base alloy microstructure showed typical austenite ${\gamma}$ phase. Alpha alloy represented the dispersed phase in the austenite ${\gamma}$ matrix. As a result of tensile testing, Alpha alloy was found to have higher strengths (Y.S. & T.S.) and lower elongation compared to those of the Base alloy. High cycle fatigue results showed that Alpha alloy had a higher fatigue limit (360MPa) than that (330MPa) of the Base alloy. The Alpha alloy exhibited the superior high cycle fatigue property in all of the fatigue stress conditions. SEM fractography results showed that the alpha phase could act to effectively retard both fatigue crack initiation and crack propagation. In the case of low-cycle fatigue, the Base alloy had longer fatigue life in the high plastic strain amplitude region and the Alpha alloy showed better fatigue property only in the low plastic strain amplitude region. The fatigue deformation behavior of the Fe-29%Ni-17%Co alloy was also discussed as related with its microstructure.

Fe-20Cr-1.7C-1Si-xV 경면처리 합금의 미세조직과 고온 Sliding 마모저항성에 미치는 Vanadium의 영향 (The Effect of Vandium on the microstructure and Elevated Temperature Sliding Wear Resistance of Fe-20Cr-1.7C-1Si-xV Hardfacing Alloy)

  • 김준기;김근모;이덕현;장세기;강성군;김선진
    • 한국재료학회지
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    • 제8권10호
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    • pp.969-974
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    • 1998
  • Fe 계 합금의 적층결함에너지를 감소시키는 거승로 알려진 vanadium이 Fe-20Cr-1.7C-1Si합금의 미세조직과 고온 마모저항성에 미치는 영향에 대하여 조사하였다. Fe-20Cr-1.7C-1Si-xV (x=0, 1, 3, 6, 10wt.%)조성에서 오스테나이트 기지상을 유지하면서 첨기될 수 있는 V의 최대 첨가량은 약 3wt.%이었으며 오스테나이트 기지상을 갖는 합금은 상온에서 낮은 적층결함에너지와 $\gamma->\alpha$ 변형유기 상변태에 의해 페라이트 합금보다 높은 마모저항성을 보인 것으로 생각된다.$225^{\circ}C$에서 $\alpha$ 생성량도 많은 것으로 보다 V은 Fe-20Cr-1.7C-1Si 합금의 온도에 따른 적층결함에너지 증가율를 억제하고 Md온도도 증가시킴으로써 고온 마모저항성을 증가시키는 것으로 생각된다.

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Fe-Al 합금의 제진특성에 미치는 열처리의 영향 (Effects of Heat Treatment on Damping Characteristics of Fe-Al Alloys)

  • 이진형;김기주;김동관;이규환;신명철
    • 분석과학
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    • 제9권3호
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    • pp.302-309
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    • 1996
  • Fe-5.7%Al-1.1%Cr-0.5%Si 및 여기에 0.12wt.%C가 함유된 합금의 최종 열처리를 $800^{\circ}C$에서 가열 후 수냉 또는 노냉함으로써 냉각방법에 의한 제진특성의 변화를 조사한 결과, 수냉은 이 합금의 제진특성을 현저히 악화시켰다. 그 원인을 미세조직 및 우선방위 특성과 관련시켜 조사하여 다음과 같은 결과를 얻었다. 열처리 후의 냉각방법에 의해 결정립 크기 및 잔류응력은 거의 무시할 정도로 변화가 없었으며, 이로부터 이들은 제진특성과 직접적인 상관이 없다고 판단되었다. 그러나 이 합금의 집합조직 형성은 수냉의 경우(200) 및 노냉의 경우(110)가 우세하게 형성되어, 이 현상을 이 합금의 자화용이축 <100>과 관련시켜 수냉시의 제진특성 악화를 해석할 수가 있었다. 즉 수냉에 의해 $180^{\circ}$ 자구벽이 $90^{\circ}$ 자구벽에 비해 많이 형성되어 제진에 결정적 역할을 하는 $90^{\circ}$ 자구벽이 적어져 그 제진특성이 악화된 것이다.

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알루미늄 합금의 용접특성 - part I : 균열 및 기공 (Weldability of Al Alloys,Part I ;Cfacking and Porosity)

  • 이창희;장래웅
    • Journal of Welding and Joining
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    • 제10권3호
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    • pp.1-12
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    • 1992
  • A literature review was conducted to survey informations available on the welding metallurgy of aluminum alloys and its effect on fusion weldability, especially on solidification cracking and pore formation. Solidification cracking behavior of Al weld is a complicate matter as compared to other high alloys, where a relatively simple Fe-X(most detrimental elements S, P, B, Si, etc) binary diagram can be successfully applicable. Both additive and synergistic effects of elements should be considered together. A same element play a different role from system to system. Porosity, caused by hydrogen contamination of the weld is one of the most troublesome welding problems. The primary sources of hydrogen are believed to be an absorbed moisture on the filler metal or base metal and in the shielding gas. It is extremely important that reliable quality-control procedures be employed to eliminate all possible sources of hydrogen contamination. Selection of proper process and parameters is sometimes more important than controlling of alloying elements in order to make a defect-free weld.

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Novel process of rare-earth free magnet and thermochemical route for the fabrication of permanent magnet

  • Choi, Chul-Jin
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2013년도 자성 및 자성재료 국제학술대회
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    • pp.89-89
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    • 2013
  • Rare earth (RE) - transition metal based high energy density magnets are of immense significance in various engineering applications. $Nd_2Fe_{14}B$ magnets possess the highest energy product and are widely used in whole industries. Simultaneously, composite alloys that are cheap, cost effective and strong commercially available have drawn great attention, because rare-earth metals are costly, less abundant and strategic shortage. We designed rare-earth free alloys and fabrication process and developed novel route to prepare $Nd_2Fe_{14}B$ powders by wet process employing spray drying and reduction-diffusion (R-D) without the use of high purity metals as raw material. MnAl-base permanent magnetic powders are potentially important material for rare-earth free magnets. We have prepared the nano-sized MnAl powders by plasma arc discharge and micron-sized MnAl powders by gas atomization. They showed good magnetic property, compared with that from conventional processes. $Nd_2Fe_{14}B$ powders with high coercivity of more than 10 kOe were successfully synthesized by adjusting R-D step, followed by precise washing system. It is considered that this process can be applied for the recycling of RE-elements extracted from ewaste including motors.

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Fe-5.7% Al 합금의 제진특성에 미치는 탄소의 거동 (The Behavior of Carbon on the Damping Characteristics of Fe-5.7% Al Alloy)

  • 이진형;이문종;이규환;신명철
    • 분석과학
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    • 제8권2호
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    • pp.195-203
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    • 1995
  • Fe-5.7% Al 합금에 탄소 및 미량 합금원소를 첨가하고 그 제진특성 변화를 결정립 크기 및 자기적 특성과 관련하여 관찰하였으며, 탄소의 거동을 XRD 및 EDS로 조사하였다. 이 합금은 강자성형 제진 양상을 나타냈고, 제3원소 첨가는 그 SDC를 악화시키며 특히 탄소는 현저하였다. 제진 특성은 결정립 크기와는 직접적인 상관관계가 없었고, 자기이력곡선 면적은 상관관계가 있었다. 탄소가 이 합금의 제진특성을 악화시키는 원인은 고용탄소에 의한 $90^{\circ}$ 자구벽의 고착이 주원인이었으며, 탄화물도 자구벽의 이동을 방해할 것이므로 제진특성에 악영향을 미치는 것으로 해석되었다.

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Effects of Sr Additions on the Interfacial Reaction Layers Formed between Liquid Al-Si-Cu Alloy and Cast Iron

  • Kyoung-Min Min;Je-Sik Shin;Jeong-Min Kim
    • 한국재료학회지
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    • 제33권9호
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    • pp.353-359
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    • 2023
  • This study investigated the growth behavior and characteristics of compounds formed at the interface between a liquid Al-Si-Cu alloy and solid cast iron. Through microstructural analyses, it was observed that various AlFe and AlFeSi phases are formed at the interface, and the relative proportion of each phase changes when small amounts of strontium are added to the Al alloy. The results of the microstructural analysis indicate that the primary phases of the interfacial compounds in the Al-Si-Cu base alloy are Al8Fe2Si and Al4.5FeSi. However, in the Sr-added alloys, significant amounts of binary AlFe intermetallic compounds such as Al5Fe2 and Al13Fe4 formed, in addition to the AlFeSi phases. The inclusion of Sr has a slight diminishing effect on the rate at which the interfacial compounds layer thickens during the time the liquid Al alloy is in contact with the cast iron. The study also discusses the nano-indentation hardness and micro-hardness of the interfacial phases.

DCSP-GTAW에 의한 고력 Al합금의 고온균열감수성에 대한 연구 (Hot Cracking Susceptibility in Welds of High Strength Al Alloys by Using DCSP-GTAW)

  • 하려선;정병호;박화순
    • Journal of Welding and Joining
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    • 제22권5호
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    • pp.65-72
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    • 2004
  • The tendency and degree of hot cracking of high strength 5083, 6N01 and 7N01 Al alloy welds by using DCSP-GTAW through modified Varestraint test and autogenous butt welding were investigated. In hot cracking test, 6N01 alloy showed the highest susceptibility to hot cracking in the weld metal and HAZ. Cracking susceptibilities generally increased with increase of solidification temperature range of the base metal and bead penetration-to-width ratio of the weld metal. The cracks in welds of the alloys vertically formed to solid-liquid interface and propagated along with columnar grain boundaries. The fracture facets of cracks showed the typical morphology of solidification crack observed as dendritic structures. Especially, in 6N01 alloy, liquation cracks which were due to elements of Si, Fe and Mg also observed in HAZ near fusion boundary. In butt welding of different Al alloys, the bead crack was mainly occurred in the welds of 6N01, 7N01 and other Al alloys together with 6N01 or 7N01. In the butt welds of 7N01, it was found that the component of Cu had an effect on the higher susceptibility to the hot cracking.

Al-Mg합금의 압연변수에 다른 미세구조의 변화와 고온인장특성 (The effects of rolling process on microstructures and high temperature tensile properties of Al-Mg alloy)

  • 김태규;전채홍;권숙인;박종우
    • 열처리공학회지
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    • 제10권2호
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    • pp.81-92
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    • 1997
  • The effect of alloying elements, precipitate size, its distribution, and dislocation substructure resulted from warm rolling or cold rolling in the superplastic Al-Mg alloy system was investigated. One of the major requirements for fine structure superplasticity is that the grain size should be very small. Fine grain structure is controlled by the dislocation substructure and the dynamic recrystallization during hot or warm working. The recovery of Al-Mg base alloys was constrained resulting in relatively high dislocation density when the alloys were warm rolled. In particular, Al-Mg-Zr alloy exhibited the smallest sub-grain size among Al-Mg alloys containing Mn, Cu, Zr as a third element. The Al-Mg-Mn alloy cold rolled 80% after hot rolling showed the maximun strain rate sensitivity exponent, m, of 0.75 under strain rate of $7.1{\times}10^{-4}/s$ at $500^{\circ}C$. The elongation of the alloys was limited in spite of high m values due to large dispersoids containing appreciable amount of Fe impurities.

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