• 한국표면공학회지
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• 제49권3호
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• pp.260-264
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• 2016

In this study, fractured surface morphology and mechanical properties of Ni-Cr-Mo alloys with various contents of Mo for dental material use have been evaluated by mechanical test. The alloys used were Ni-13Cr-xMo alloys with Mo contents of 4, 6, 8, and 10 wt.%, prepared by using a vacuum arc-melting furnace. Ni-13Cr-xMo alloys were used for mechanical test without heat treatment. The phase and microstructure of alloys using an X-ray diffraction (XRD) and optical microscopy (OM) were evaluated. To examine the mechanical properties of alloys according to microstructure changes, the tensile test and the hardness test were carried out using tensile tester. To understand the mechanism of Mo addition to Ni-Cr alloy on mechanical property, the morphology and fractured surfaces of alloys were investigated by field-emission scanning electron microscope (FE-SEM). As a result, 79Ni-13Cr-8Mo alloy was verified that the tensile strength and the hardness were better than others. Varying Mo content, the changes of microstructures of alloys were identified by OM and SEM and that of 79Ni-13Cr-8Mo alloy was proved fabricated well. Microstructures of alloys were changed depending on Mo content ratio. It has been observed that 8% alloy had the most suitable mechanical property for dental alloy.

• 한국재료학회지
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• 제10권6호
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• pp.409-414
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• 2000

3%C-10%Cr-5%Mo-5%W, 3%C-10%V-5%Mo-5%W 및 3%C-17%Cr-3%V의 3종류 고합금백주철에 있어서 열처리후의 기지조직의 변태거동을 연구하였다. 15kg 용량의 고주파 유도용해로에 선철, 고철, Fe-Cr, Fe-V, Fe-Mo 및 Fe-W 등을 장입시켜 용해시킨 후 슬래그를 제거시키고 $1550^{\circ}C$에서 Y-block의 펩 주형에 주입시켰다. 적당한 크기로 절단한 시편을 진공분위기하에$950^{\circ}C$에서 5시간동안 우선 균질화처리를 실시하였다. 그 후 다시 이 시편을 $1050^{\circ}C$에서 2시간동안 오스테나이징시킨 후 강제공냉을 행하였다. 강제공냉된 시편을 $300^{\circ}C$에서 3시간 유지시킨 후 템퍼링을 실시하였다. 주방상태에서의 기지조직은 3합금 공히 퍼얼라이트이었으며 강제공냉후에는 마르텐사이트 및 오스테나이트로 변태하였다. 또한 기지조직내에 무수히 많은 이차탄화물 입자들의 석출되었다. 템프링 후 일부 오스테나이트 및 마르텐사이트는 템퍼드마르텐사이트로 변태하였다. 변태하였다.

• 열처리공학회지
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• 제31권4호
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• pp.180-186
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• 2018

High temperature flow behaviors of Fe-Cr-Mo-V-W-C tool steel were investigated using isothermal compression tests on a Gleeble simulator. The compressive test temperature was varied from 850 to $1,150^{\circ}C$ with the strain rate ranges of 0.05 and $10s^{-1}$. The maximum height reduction was 45%. The dynamic softening related to the dynamic recrystallization was observed during hot deformation. The constitutive model based on Arrhenius-typed equation with the Zener-Hollomon parameter was proposed to simulate the hot deformation behavior of Fe-Cr-Mo-V-W-C steel. An artificial neural network (ANN) model was also developed to compare with the constitutive model. It was concluded that the ANN model showed more accurate prediction compared with the constitutive model for describing the hot compressive behavior of Fe-Cr-Mo-V-W-C steel.

• 한국표면공학회지
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• 제35권6호
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• pp.371-376
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• 2002

Steam turbine components of power generators are subjected to severe damages from the particle erosion by iron oxides (mainly $Fe_3$$O_4$) which are formed due to the oxidation of boiler tubes, causing high costs for maintaining and repairing. One of the practical ways to minimize the particle erosion is to apply the erosion resistant boride coating on the turbine components which is composed of boride apply. But the evaluation of its performance has not been carried out. A particle erosion tester, which can offer the erosion condition of steam turbine components, was developed to evaluate the performances of the boronized Cr/Mo alloy. The result showed that the boronized Cr/Mo alloy showed superior resistance to particle erosion to the bare Cr/Mo alloy in all test conditions.

• 한국해양공학회지
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• 제1권2호
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• pp.101-112
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• 1987

Fracture toughness characterization in the transition region is examined for heat-treated and ionnitrided Ni-Cr-Mo steel. After heat treatment for the specimens of Ni-Cr-Mo steel, organizations of specimens-specimens which are heat-treated and ion-nitrided for 4 hours at 500 .deg. C and 5 torr in 25%N/dub 2/-75%H/sub 2/mixed gas-, hardness variety, and X-ray diffraction pattern of the ion-nitriding compound layer are observed. Fracture toughenss test of unloading compliance method were conducted over the regions from room trmperature to -70.deg. C. The compound layer was consisted of r'=Fe/sub 4/N phase and ion-nitrided layer's depth was 200mm from surface. The transition regions of heat-treated and ion-nitrided specimens were about -30.deg. C and -50.deg. C, respectively. The transition region of ion-nitrided specimens is estimated less than that of heat-treated one, and this is the effect of ion-nitriding.

• 한국분말재료학회지
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• 제23권5호
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• pp.397-401
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• 2016

A lean alloy is defined as a low alloy steel with a minimum amount of the alloying element that maintains the characteristics of the sintered alloy. It is well known that the addition of elements such as Cr, P, Si, or Mn improves the mechanical characteristics of the alloy, but decreases the sinterability. The mother alloy is used to avoid an oxidation reaction with the alloying elements of Cr, P, Si or Mn. The purpose of this study is to determine the change in the mechanical properties of Fe-P-Mo and Fe-P-Mn alloys as a result of the addition of Si. In this article, the Fe-P-Mo and Fe-P-Mn alloys to which Si is added are compacted at $7.0g/cm^3$ and then sintered in $H_2-N_2$ at $1120^{\circ}C$. The P around the macropores and large grains reduces due to the formation of $SiO_2$ as the Si content increases. This is caused by the increase in strength owing to reducing intergranular fracture by suppressing the reaction with oxygen.

• 한국환경생태학회지
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• 제12권3호
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• pp.271-278
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• 1998

충남 홍성에 위치한 백동 사문암지역에서 암석 및 토양에 함유되어 있는 중금속 함량과 이 지역에서 생육하고있는 소나무 및 리기다소나무에 의해 식물체의 부위별로 흡수된 중금속 농도를 다른 모암지역(각섬석 편암 및 편마암)과 비교하여 측정하였다. 암석의 경우 사문암의 Ni, Cr, Co, Fe 농도가 각섬석 편암 및 편마암에 비해 더 높았다. 상부토양도 암석과 매우 유사한 결과를 나타내고 있어서, 특히 Ni, Cr, Co, Fe는 사문암토양이 가장 높았고, Zn과 Sc는 각섬석 편암이 더 높았다. 소나무의 평균 중금속 함량은 사문암지역에서 Ni, Cr, Co, Au, As, Sb. W농도가 가장 높았으며, 이 중 Ni, Cr, Co는 암석 및 토양내 높은 함량 변화와도 일치하였다. 그외에 Zn, Sc는 각섬석 편암지역이 높았으며, Fe, Mo는 편마암이 각각 높았다. 같은 사문암지역에 분포하는 두 수종을 비교하면 대부분의 원소에서 소나무보다 리기다소나무내 함량이 더 높았으며(Ni 및 W은 예외), 이로 보아 식물체로의 중금속 흡수량이 리기다소나무가 더 크다는 것을 알 수 있다. 식물체의 부위별로 비교해 보면 두 수종 모두 모암의 구별없이 대부분 원소에서 뿌리부분이 지상부보다 흡수량이 높았다. 사문암지역에서 대부분 원소(Ni, Cr, Co, Zn, Sc, Fe)의 상대적인 비(평균 식물체 함량/토양 함량)는 모두 사문암보다 각섬석 편암이나 편마암지역에서 더 높았다. 특히 편마암지역은 Zn을 제외하고 전 원소에서 가장 높게 나타났다.

• Journal of Welding and Joining
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• 제15권5호
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• pp.46-55
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• 1997

This study has evaluated the liquation cracking behavior in the heat affected zone of several Ni base superalloys (Incoloy 825, Inconel 718 and Inconel 600). 304 and 310S austenitic stainless steels were also included for comparison. In addition, the mechanism of liquation cracking in the HAZ was postulated based on the extensive microstructural examinations with SEM, EDAX and TEM. The liquation cracking resistance of Ni base alloys was found to be far inferior to that of austenitic stainless steels. The liquation cracking of Incoloy 825 and Inconel 718 was believed to be closely related with the Laves-austenite(Ti rich in 825 and Nb rich in 718) and MC-austenitic eutectic phases formed along the grain boundaries by constitutional liquation and incipient melting under rapid welding thermal contraction. Further, liquation cracking resistance of the HAZ was dependent not only upon the type and amount of low melting phases but also on the grain size.

• 설비공학논문집
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• 제24권3호
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• pp.281-287
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• 2012

The internal oxide scale of twelve superheater and reheater tubes were tested which were serviced for 30,000~120,000 hours in thermal power plants. The oxide scale was formed in three layers. The Cr-rich area was observed beneath the original metal surface. The hematite ($Fe_2O_3$) phase was formed on the outer surface. The intermediate layer was magnetite ($Fe_3O_4$). The thickness of Cr-rich layer was about half of the total scale. All layers grew during the operation hour of the plant. The thickness of thickest scale was 0.2mm in superheater tubes. This can increase the tube metal temperature about $7^{\circ}C$ more than initial state. $7^{\circ}C$ tube metal temperature can reduce tube life about 30%, but the boiler tube's design margin is big enough therefore it has been analyzed that it would not effect on the life span.

• 대한금속재료학회지
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• 제48권8호
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• pp.741-748
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• 2010

We studied the corrosion and oxidation properties of Fe-18Cr-0.4Nb-(0.1~0.6)Ti-(1~3)Si-(0.5~2)Mo stainless steel. The resistance to general and pitting corrosion was evaluated and the results were analyzed by Response Surface Methodology (RSM) as a function of alloy composition. The effects of alloy composition and heat treatment on the oxidation resistance were also examined. Mo increased both general corrosion resistance and pitting corrosion resistance. Si improved the resistance of the alloys to pitting corrosion. Si was also beneficial for general corrosion resistance of the alloys containing Mo at more than 1 wt.%. However, Mo was detrimental when its content was lower. Effects of Ti on general corrosion properties appeared to be weak and a high concentration of Ti appeared to deteriorate pitting resistance. The thickness of the oxidation scale increased and adhesion of the scale worsened as the temperature increased from $800^{\circ}C$ to $900^{\circ}C$. Weight gain of the alloys due to oxidation at $900^{\circ}C$ clearly showed that the resistance to oxidation is improved by annealing at $860^{\circ}C$ and an increase of Si content.