• Title/Summary/Keyword: Fe-Cr alloy

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Microstructural Evaluation and High Temperature Mechanical Properties of Ni-22Cr-18Fe-9Mo ODS Alloy (Ni-22Cr-18Fe-9Mo계 ODS 합금의 미세조직 및 고온인장 특성 평가)

  • Jeong, Seok-Hoan;Kang, Suk-Hoon;Han, Chang-Hee;Kim, Tae-Kyu;Kim, Do-Hyang;Jang, Jin-Sung
    • Journal of Powder Materials
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    • v.18 no.5
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    • pp.456-462
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    • 2011
  • Yttrium oxide is one of the most thermo-dynamically stable materials, so that it is generally used as a dispersoid in many kinds of dispersion strengthed alloys. In this study, a nickel-base superalloy is strengthened by dispersion of yttrium oxide particles. Elemental powders with the composition of Ni-22Cr-18Fe-9Mo were mechanically alloyed(M.A.) with 0.6 wt% $Y_2O_3$. The MA powders were then HIP(hot isotactic press)ed and hot rolled. Most oxide particles in Ni-22Cr-18Fe-9Mo base ODS alloy were found to be Y-Ti-O type. The oxide particles were uniformly dispersed in the matrix and also on the grain boundaries. Tensile test results show that the yield strength and ultimate tensile strength of ODS alloy specimens were 1.2~1.7 times higher than those of the conventional $Hastelloy^{TM}$ X(R), which has the same chemical compositions with ODS alloy specimens except the oxide particles.

Gd effect on microstructure and properties of the Modified-690 alloy for function structure integrated thermal neutron shielding

  • Cheng Zhang;Jie Pan;Zixie Wang;Zhaoyu Wu;Qiliang Mei;Qianxue Ding;Jing Gao;Xueshan Xiao
    • Nuclear Engineering and Technology
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    • v.55 no.5
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    • pp.1541-1558
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    • 2023
  • The new Modified-690Gd alloy, namely as Ni-30Cr-(10-x) Fe-xGd (x = 0.5, 1.0, 1.5,2.0, 3.0 wt%) for function structure integrated thermal neutron shielding has been prepared and characterized. The Modified-690Gd alloy was mainly composed of γ austenite matrix and (Ni, Cr, Fe)5Gd precipitated along grain boundaries. The new Modified-690Gd alloy had great mechanical properties, which had the tensile strength exceeding 620 MPa and the elongation being above 50%. Meanwhile, this alloy had excellent weldability and good corrosion resistance in boric acid. The new Modified-690Gd alloy is expected to be a kind of high efficiency thermal neutron shielding materials.

Corrosion Behavior and Surface Coating of Muffler Materials by Using EB-PVD (전자빔 진공증착기를 이용한 muffler재료의 표면코팅과 내식특성)

  • 최한철
    • Journal of the Korean institute of surface engineering
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    • v.34 no.1
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    • pp.39-48
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    • 2001
  • Fe-Cr-Al alloy has been studied for application in automobile muffler materials due to good corrosion and oxidation resistance. In order to develop the automobile muffler materials, corrosion behaviors of electron beam physical vapor deposition (EB-PVD) coated surface of muffler matericls of muffler materials were investigated using potentiostat. For 0.1M NaCl solution, corrosion potential and pitting potential of Fe-20Cr-10Al was higher than that of Fe-5Cr- 10Al samples. Especially, in the case of Ti and Nb coated samples, pitting potential increased remarkably compared with non-coated samples. For 0.1M $CaCl_2$ solution, Ti-coated Fe-20Cr-10Al showed remarkably improved pitting corrosion resistance in comparison with non-coated Fe-20Cr-10Al and Fe-5Cr-10Al. The number and size of pits were decreased in the case of Ti coated samples in the 0.1M NaCl and 0.1M $CaCl_2$ solution.

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The Effect of Additional Elements and Grain Size Distribution on the Magnetic Properties of the Nd-Fe-B Sintered Magnets (Nd-Fe-B계 소결자석의 자기적 특성에 미치는 첨가원소와 결정립 분포의 영향)

  • Hong, Yeon-Gi;Kim, Jong-O
    • Korean Journal of Materials Research
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    • v.8 no.9
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    • pp.819-824
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    • 1998
  • The influence of casting cooling rate during the preparation of ingots on the grain size distribution and the magnetizing ability of $\textrm{Nd}_{16}\textrm{Fe}_{72}\textrm{V}_{4}\textrm{B}_{8}$ sintered magnets were investigated. Sintered magnets prepared from copper mold which allow a higher cooling rate, show a smaller grain size distribution and god magnetizing ability. The effects of adding bride forming elements, such as Cr, Mn, Nb, and W on the magnetic properties of Nd-Fe-B sintered magnets were also investigated. Both Cr and W addition increase coercivity and the resultant $\textrm{Nd}_{16}\textrm{Fe}_{72}\textrm{Cr}_{4}\textrm{B}_{9}$ alloy exhibits a similar magnetizing ability in comparison with $\textrm{Nd}_{16}\textrm{Fe}_{72}\textrm{V}_{4}\textrm{B}_{8}$ alloy.

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Mechanical Properties of Fe-P-(Mo,Mn) Sintered Alloy Related with Si Contents (Fe-P-(Mo,Mn)계 소결분말 합금에서 Si 첨가에 따른 기계적 특성 변화에 대한 연구)

  • Jung, Woo-Young;Park, Dong-Kyu;Ko, Byung-Hyun;Park, Jin-Woo;Ahn, In-Shup
    • Journal of Powder Materials
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    • v.23 no.5
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    • pp.397-401
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    • 2016
  • A lean alloy is defined as a low alloy steel with a minimum amount of the alloying element that maintains the characteristics of the sintered alloy. It is well known that the addition of elements such as Cr, P, Si, or Mn improves the mechanical characteristics of the alloy, but decreases the sinterability. The mother alloy is used to avoid an oxidation reaction with the alloying elements of Cr, P, Si or Mn. The purpose of this study is to determine the change in the mechanical properties of Fe-P-Mo and Fe-P-Mn alloys as a result of the addition of Si. In this article, the Fe-P-Mo and Fe-P-Mn alloys to which Si is added are compacted at $7.0g/cm^3$ and then sintered in $H_2-N_2$ at $1120^{\circ}C$. The P around the macropores and large grains reduces due to the formation of $SiO_2$ as the Si content increases. This is caused by the increase in strength owing to reducing intergranular fracture by suppressing the reaction with oxygen.

A Study on the low temperature magnetic properties of Fe-Cr-Ni alloys (Fe-Cr-Ni 합금의 저온에서의 자기적 성질에 관한 연구)

  • 안병덕;김진옥;장경호;송기영
    • Journal of the Korean Magnetics Society
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    • v.3 no.4
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    • pp.277-283
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    • 1993
  • The temperature dependence of DC magnetic susceptibilities of three austenitic Fe-Cr-Ni stainless alloys were measured in the temperature range of 4.2 and 300 K. Two alloys support a general magnetic description of austen-itic stsinless steels in terms of a two-magnetic-phase (spin glass + superparamagnetic cluster) model and one alloy shows magnetic double transition phenomena. Also this study shows that incressing the Ni/Cr ratio in Fe-Cr-Ni alloys causes a increase of the DC susceptibility peak value and a decrease of the magnetic transition temperature.

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As-Cast and Solidification Structures of Fe-3%C-x%Cr-y%V-w%Mo-z%W Multi- Component White Cast Irons (Fe-3%C-x%Cr-y%V-w%Mo-z%W 다합금계백주철의 주방상태 및 급냉조직)

  • Yu, sung-Kon;Shin, Sang-Woo
    • Korean Journal of Materials Research
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    • v.12 no.5
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    • pp.414-422
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    • 2002
  • Three different multi-component white cast irons alloyed with Cr, V, Mo and W were prepared in order to study their as-cast and solidification structures. Three combinations of the alloying elements were selected so as to obtain the different types of carbides and matrix structures : 3%C-10%Cr-5%Mo-5%W(alloy No.1), 3%C-10%V-5% Mo-5%W(alloy No. 2) and 3%C-17%Cr-3% V(alloy No.3). The as-cast microstructures were investigated with optical and scanning electron microscopes. There existed two different types of carbides, $M_7C_3$ carbide with rod-like morphology and $M_6C$ carbide with fishbone-like one, and matrix in the alloy No. 1. The alloy No. 2 consisted of MC carbide with chunky and flaky type and needle-like $M_2C$ carbide, and matrix. The chunky type referred to primary MC carbide and the flaky one to eutectic MC carbide. The morphology of the alloy No. 3 represented a typical hypo-eutectic high chromium white cast iron composed of rod-like $M_7C_3$ carbide which is very sensitive to heat flow direction and matrix. To clarify the solidification sequence, each iron(50g) was remelted at 1723K in an alumina crucible using a silicon carbide resistance furnace under argon atmosphere. The molten iron was cooled at the rate of 10K/min and quenched into water at several temperatures during thermal analysis. The solidification structures of the specimen were found to consist of austenite dendrite(${\gamma}$), $ ({\gamma}+ M_7C_3)$ eutectic and $({\gamma}+ M_6C)$ eutectic in the alloy No. 1, proeutectic MC, austenite dendrite(${\gamma}$), (${\gamma}$+MC) eutectic and $({\gamma}+ M_2C)$ eutectic in the alloy No. 2, and proeutectic $M_7C_3$ and $ ({\gamma}+ M_7C_3)$ eutectic in the alloy No 3. respectively.

고온의 염기성 수용액에서 Ni기 합금의 응력부식파괴

  • 김홍표;황성식;국일현;김정수
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.84-89
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    • 1998
  • Alloy 600 및 alloy 690과 Ni-8Cr-lOFe 합금 등의 응력부식(stress corrosion cracking, SCC) 거동을 고온의 염기성 분위기에서 C-ring 시편을 사용하여 연구하였다. Alloy 600과 alloy 690을 여러 조건에서 열처리하여 etching한 후 탄화물의 분포와 입계 주변의 Cr고갈 정도 등의 미세조직을 광학현미경과 주사 전자현미경(SEM)으로 관찰하였다. 이들 재료에 대한 SCC 시험을 315$^{\circ}C$의 40% NaOH 수용액에서 일정한 부하전위(부식전위 + 200㎷)를 가하면서 수행하였으며, 동일 조건에서의 분극거동도 측정하였다. Alloy 600 MA(mill anneal) 및 TT(thermal treatment)의 SCC 저항성은 alloy 690 TT와 Ni-8Cr-10Fe SA(solution anneal)보다 낮았다. Alloy 600 TT 재료는 alloy 600 MA 및 SA 재료에 비해 SCC 저항성이 더 컸다. 고용 탄소농도는 alloy 600의 SCC 저항성에 큰 영향을 주지 못했다. 대부분의 Alloy 600은 균열전파 입계균열을 보였으나, 일부에서는 입계 및 입내 혼합양상(mixed mode cracking)을 보였다. 염기성 분위기에서 Ni기 합금의 SCC 거동을 미세조직, 분극거동의 관점에서 고찰하였다.

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Effect of gadolinium and boron addition on the texture development and magnetic properties of 23Cr-10NiCu duplex stainless steels

  • Baik, Youl;Kang, Bo Kyeong;Choi, Yong;Woo, Wan Chuck
    • Nuclear Engineering and Technology
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    • v.53 no.6
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    • pp.1887-1892
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    • 2021
  • The effect of gadolinium and boron on the texture development and magnetic properties of the texture controlled 23Cr-10NiCu duplex stainless steels were studied to develop a high performance neutron and electromagnetic shielding material. The 23Cr-10NiCu base alloy is composed of 60% of austenite and 40% of ferrite, whereas, the 23Cr-10NiCu-0.5Gd-0.8B modified alloy is composed of 66% of austenite, 27% of ferrite and 7% of CrFeB intermetallic compounds. The gadolinium and boron addition to the 23Cr-10NiCu base alloy increased mechanical properties. Microstructure observation showed that the small addition of 0.5 wt% gadolinium and 0.8 wt% boron to the alloy retarded to form texture at the same hot rolling conditions, and improved the maximum magnetism, residual magnetism and coercive force about 3%, 122% and 120%, respectively.