• Title/Summary/Keyword: Fe-Co alloys

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A Study on Development of High Strength Al-Zn Based Alloy for Die Casting II: Evaluation of Fluidity and Gravity Casting (고강도 Al-Zn기 다이캐스팅 합금개발에 관한 연구 II: 중력주조, 유동성평가)

  • Shin, Sang-Soo;Lim, Young-Hoon;Kim, Eok-Soo;Lim, Kyung-Mook
    • Korean Journal of Metals and Materials
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    • v.50 no.7
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    • pp.531-538
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    • 2012
  • In this study, we evaluated the fluidity of the Al-Zn based alloys which exhibit excellent mechanical properties. We conducted computer simulations of fluid flow using the results of DSC, DTA analysis and Java-based Materials Properties software (J. Mat. Pro). Such computer simulations were then compared with the results obtained from experimental observations. The computer simulation results and the experimental results were very similar in fluidity length. It was found that the fluidity length of Al-Zn alloys is improved by increasing the Zn content while decreasing the solidus temperature of an alloy. In addition, we elucidate the effect of Zn addition on variations in different mechanical properties and the microstructure characteristics of (Al-xZn3Cu0.4Si0.3Fe) x=20, 30, 40, and 45 wt% alloys fabricated by gravity casting.

The study of characteristics and properties of electrodeposited Ni-Co alloys (니켈-코발트 합금도금의 물성 및 특성 연구)

  • Jeong, Sang-Il;Im, Seong-Bong;Lee, Ju-Yeol;Jang, Do-Yeon;Jeong, Yong-Su
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2011.05a
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    • pp.156-157
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    • 2011
  • 고경도 Ni-Co 합금 도금액 개발을 위하여 Ni과 Co의 함량 조성비와 전류밀도에 따라 전기도금을 실시하였다. Ni과 Co의 함량비는 Ni의 농도를 일정하게 유지시키고 Co의 농도를 10~30g/${\ell}$로 하여 실험을 하였다. Ni과 Co의 함량 조성비에 따른 합금 도금층의 성분을 EDS를 이용하여 분석하였고 전류밀도별 표면형상을 FE-SEM을 이용하여 분석하였다. 그리고 도금층의 성분에 따른 경도값을 비커스 경도계를 이용하여 분석하였다.

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Analysis on the Fuel Cell Performance by the Impedance Method (임피던스법을 적용한 연료전지의 성능평가)

  • Kim, Gwi-Yeol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.10
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    • pp.918-923
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    • 2007
  • Fuel cell is a modular, high efficient and environmentally energy conversion device, it has become a promising option to replace the conventional fossil fuel based electric power plants. The high temperature fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. Corrosions in molten electrolytes and the electric conductivity across the oxide scale have crucial characteristics. When molten salts are involved, high temperature corrosions become severe. In this sense, corrosions of alloys with molten carbonates have the most severe material problems. Systematic investigation on corrosion behavior of Fe/21Cr/Ti or Al alloy has been done in (62+38)mol% (Li+K)$CO_3$ melt at $650^{\circ}C$ using the electrochemical impedance spectroscopy method. It was found that the corrosion current of these Fe-based alloys decreased with increasing Al or Ti. And Al addition improved the corrosion resistance of this type of specimen and more improvement of corrosion resistance was observed at the specimen added with Al.

Thermal Behaviors of Nd2Fe14B/Fe3B Based Nanocomposite Magnets

  • Yang, Choong-Jin;Park, Eon-Byung;Choi, Seung-Duck
    • Journal of Magnetics
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    • v.3 no.1
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    • pp.4-8
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    • 1998
  • Two different compositions of melt spun magnetic alloys, $ Nd_4Fe_{80}B_{16} and Nd_4Fe_{76}Co}\_3Hf_{0.5}Ga_{0.5}B_{16},$ were characterized in terms of magnetic properties and thermal behaviors. It was found that the addition of Hf and Ga effectively slow down the crystallization rate of the nanocomposite $ Nd_2Fe_{14}B/Fe_3B$ magnet. Coercivity(iHc) changes only slightly with varying the post annealing conditions confirming that iHc is not a sensitive magnetic quantity as a function of grain size and exchange coupled interaction. The experimentally observed behaviors of Mr and Hc do not vary monotonously with in-creasing grain size which is not in agreement with the numerically calculated result near the critical grain size (dc). The plot of the grain size dependence for the remanence and coercivity in isotrop!c nanocomposite magnets has been revised in this study. The maxium energy product, $(B, H)_{max}$ =15.34 MGOe, and a reduced remanence, Mr/Ms=0.84 were obtained, respectively.

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Effect of Magnetic Properties on the Zr contents of Sm(CO.688-xFe.242Cu.07Zr x)7.404 Sintered Magnets (Sm(CO.688-xFe.242Cu.07Zr x)7.404소결자석의 자기적 특성에 미치는 Zr의 영향)

  • Jung, Woo-Sang;Kim, Yoon-Bae;Jeung, Won-Young
    • Journal of the Korean Magnetics Society
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    • v.12 no.5
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    • pp.189-194
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    • 2002
  • Microstructure and magnetic properties of Sm-Co sintered magnet were investigated with the variation of Zr content and their solution treatment and aging temperatures. The fraction of eutectic structure and the size of eutectic area decreased with increasing x value of cast Sm(C $O_{.688-x}$F $e_{.242}$C $u_{.07}$Z $r_{x}$)$_{7.404}$ alloys. On the other hand, x=0.022 ingot had finer dendritic structure compared to the other alloys. The sintered magnet of Sm(C $O_{.688-x}$F $e_{.242}$C $u_{.07}$Z $r_{x}$)$_{7.404}$ had well defined cell structure which is composed of cell boundary Sm $Co_{5}$ and cell interior S $m_2$Co/ssub 17/ phase. Cell boundary Sm $Co_{5}$ phase has 20nm thickness and its relative angle was 120$^{\circ}$ in x=0.018 and 0.022 alloys. Cell size was decreased with increasing Zr contents. But, x=0.026 alloy has diffuse cell boundary and irregular shape compared to x=0.022 and 0.018 alloys. Maximum value of coercive force and maximum energy Product were obtained from x=0.022 alloys. Optimum solution treatment temperature of Sm(C $O_{.688-x}$F $e_{.242}$C $u_{.07}$Z $r_{x}$)$_{7.404}$ alloy was 1170 $^{\circ}C$ and 1st aging temperature of two step aging process for higher coercivity was 850 $^{\circ}C$.

Magnetic Properties and Thermomagnetic Analysis of Cast and Hot-Pressed Pr, Nd-Fe-B Magnets (주조 및 열간압축된 Pr, Nd-Fe-B계 영구자석의 열자기 분석과 자기적 특성)

  • 김동엽;이동구;정원용
    • Journal of the Korean Magnetics Society
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    • v.2 no.1
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    • pp.37-43
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    • 1992
  • Minor phases in cast and hot-pressed R(R=Pr, Nd)-Fe-B magnet were investigated through thermomagnetic analysis. The relationship between minor phases and coercivities of R-Fe-B magnets was studied. ${\alpha}-Fe$ and $Nd_{2}Fe_{17}$ were precipitated in as-cast Pr-Fe-B and Nd-Fe-B alloys respectively. These phases were considered to deteriorate the magnetic properties of R-Fe-B magnets. During the heat treatment, ${\alpha}-Fe$ and $Nd_{2}Fe_{17}$ were annihilated and the magnetic properties of cast R-Fe-B magnet were improved. Hot-pressed Nd-Fe-B magnet showed better thermal stability than sintered magnet.

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IMPROVEMENT EFFECTS OF ELECTROCHEMICAL STABILITY OF MAGNETIC MATERIALS FOR PROSTHETIC DENTISTRY (치과보철용 자석재료의 전기화학적 안정성 개선효과)

  • Kwack, Jong-Ha;Oh, Sang-Ho;Choe, Han-Cheol;Chung, Chae-Heon
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.5
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    • pp.628-641
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    • 2006
  • Statement of problem: Dental magnetic materials have been applied to removable prosthetic appliances, maxillofacial prostheses, obturator and dental implant but they still have some problems such as low corrosion resistance in oral environments. Purpose: To increase the corrosion resistance of dental magnetic materials, surfaces of Sm-Co and Nd-Fe-B based magnetic materials were plated with TiN and sealed with stainless steels. Materials and methods : Surfaces of Sm-Co and Nd-Fe-B based magnetic materials were plated with TiN and sealed with stainless steels, and then three kinds of electrochemical corrosion test were performed in 0.9% NaCl solution; potentiodynamic, potentiostatic, and electrochemical impedance test. From this study, corrosion behavior, amount of elements released, mean average surface roughness values, the changing of retention force, and magnetic force values were measured comparing with control group of non-coated magnetic materials. Results: The values of surface roughness of TiN coated Sm-Co and TiN coated Nd-Fe-B based magnetic materials were lower than those of non coated Sm-Co and Nd-Fe-B alloy. From results of potentiodynamic test, the passive current density of TiN coated Sm-Co alloy were smaller than those of TiN coated Nd-Fe-B alloy and non coated alloys in 0.9% NaCl solution. From results of potentiostatic and electrochemical impedance test, the surface stability of the TiN coated Sm-Co alloy was more drastically increased than that of the TiN coated Nd-Fe-B alloy and non-coated alloy. The retention and magnetic force after and before corrosion test did not change in the case of TiN coated magnetic alloy sealed with stainless steel. Conclusion: It is considered that the corrosion problem and improvement for surface stability of dental magnetic materials could be solved by ion plating with TiN on the surface of dental magnetic materials and by sealing with stainless steels.

Heat Treatment of Superalloys for High Temperature Applications (고온구조용 초내열합금 열처리)

  • Park, Nho-Kwang
    • Journal of the Korean Society for Heat Treatment
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    • v.16 no.6
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    • pp.341-348
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    • 2003
  • Superalloys which can be devided into three categohes, i.e. Ni-base, Co-base, and Fe-base alloys are widely used for high temperature applications. Since superalloys contain many alloying elements and precipitates, its chemistry and processing parameters need to be carefully designed. In this review, current state-of-the art in the superalloy technologies is described with special attention to the heat-treatment for the control of the microstructures and mechanical properties.

Corrosion behavior of separator materials for MCFC (MCFC 분리판 재료의 부식거동)

  • 김귀열;엄승욱;문성인
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.346-348
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    • 1996
  • The MCFC has conspicuous features and high potential in being used as an energy converter of various fuels to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650[$^{\circ}C$] have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)㏖ % (Li+K)CO$_3$ melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method.

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