• Title/Summary/Keyword: Fe-As-S system

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Development of Green's Functions for Fatigue Damage Evaluation of CANDU Reactor Coolant System Components (CANDU형 원전 주요기기의 피로손상 평가를 위한 그린함수 개발)

  • Kim, Se Chang;Sung, Hee Dong;Choi, Jae Boong;Kim, Hong Key;Song, Myung Ho;Nho, Seung Hwan
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.7 no.4
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    • pp.38-43
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    • 2011
  • For the efficient and safe operation of nuclear power plant, evaluating quantitatively aging phenomenon of major components is necessary. Especially, typical aging parameters such as stresses and cumulative usage factors should be determined accurately to manage the lifetime of the plant facility. The 3-D finite element(FE) model is generated to calculate the aging parameters. Mechanical and thermal transfer functions called Green's functions are developed for the FE model with standard step input. The stress results estimated from transfer functions are verified by comparing with 3-D FE analyses results. Lastly, we suggest an effective fatigue evaluation methodology by using the transfer functions. The usefulness of the proposed fatigue evaluation methodology can be maximized by combining it with an on-line monitoring system.

Development of Modeling Support System for Lower Arm in Automobile Suspension Module (자동차 서스펜션 로워암의 모델링 보조시스템 개발)

  • Lee T.H.;Shin S.Y.;Suh C.H.;Kwon T.W.;Han S.H.
    • Korean Journal of Computational Design and Engineering
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    • v.11 no.1
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    • pp.49-56
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    • 2006
  • In this study, the modeling support system was developed which can make easy and fast FE-modeling and verify the results of static and durability analysis for the lower arm, one of the important parts in automobile suspension module. It took into account of the whole complicated design processes verifying the durability coefficients evaluated by fatigue analysis, which should be used to satisfy a design criteria. To guide the FE-modeling the drive page was constructed by using HTML and XML, which was based on expert's know-hows. It is able to integrate the processes to design the lower arm in practice, so that the standardization of its FE-Modeling is achieved, consequently. The 3 dimensional CAD's geometrical data were changed automatically into pre-defined shell elements under the concept of mesh-offset technique, and then welding elements were treated to connect between target and basic surfaces constructed by the shell elements. This system has also a user interface to control boundary and load ing conditions applied in performing of the static and durability analysis, in which many load cases can be applied simply with the MPCs driven by just few mouse clicks. These were implemented on the platform of MSC.Patran and utilized ANSYS, MSC.Nastran and MSC.Fatigue as the solver of the analysis performed. The developed system brings not only significant decreasing of man-hours required in FE-modeling process, but also obtaining of satisfied qualities in analyzed results. It will be integrated in a part of virtual prototyping module of the developing e-engineering framework.

Degradative Solidification/Stabilization of Liquid Waste Containing Chloroform and Methylene Chloride by Cement/Slag/Fe(II) Systems (Cement/Slag/Fe(II) 시스템에 의한 클로로포름과 메틸렌클로라이드 함유 액상폐기물의 분해성 고형화/안정화)

  • Seong, Joseph;An, Cheol-Hong;Choi, Won-Ho;Park, Joo-Yang
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.10
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    • pp.1034-1038
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    • 2008
  • Degradative Solidification/Stabilization(DS/S) is a modification of conventional Solidification/Stabilization(S/S) that incorporates degradative processes for organic contaminant destruction with the low cost of conventional S/S. Inorganic contaminants are immobilized and chlorinated organic contaminants are destroyed by DS/S treatment. In this study, a DS/S using cement/slag/Fe(II) systems as binder was investigated to assess its effectiveness in degrading chloroform(CF) and methylene chloride(MC) contained in hazardous liquid wastes. The initial concentration of CF was 0.26 mM, 1.0 mM, 8.4 mM, 25 mM and 42 mM and Fe(II) was 200 mM. The result showed that degradation of CF in various concentration was in one kind reaction as pseudo-first-order and 95% of 0.26 mM initial concentration of CF was removed in five days. 50 mg/L of heavy metal was added in order to accelerate the rate of degradation of MC and initial concentration of MC was 3.50 mM however, degradation did not occur in system. Thus additional studies needed for degradation of MC and more studies on other reaction pathways products will help elucidate reaction mechanisms and pathways for chlorinated methanes in cement/slag/Fe(II) systems.

Nonlinear analysis of reinforced concrete beams strengthened with polymer composites

  • Pendhari, S.S.;Kant, T.;Desai, Y.M.
    • Structural Engineering and Mechanics
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    • v.24 no.1
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    • pp.1-18
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    • 2006
  • Strengthening of existing old structures has traditionally been accomplished by using conventional materials and techniques, viz., externally bonded steel plates, steel or concrete jackets, etc. Alternatively, fibre reinforced polymer composite (FRPC) products started being used to overcome problems associated with conventional materials in the mid 1950s because of their favourable engineering properties. Effectiveness of FRPC materials has been demonstrated through extensive experimental research throughout the world in the last two decades. However there is a need to use refined analytical tools to simulate response of strengthened system. In this paper, an attempt has been made to develop a numerical model of strengthened reinforced concrete (RC) beams with FRPC laminates. Material models for RC beams strengthened with FRPC laminates are described and verified through a nonlinear finite element (FE) commercial code, with the help of available experimental data. Three dimensional (3D) FE analysis has been performed by assuming perfect bonding between concrete and FRPC laminate. A parametric study has also been performed to examine effects of various parameters like fibre type, stirrup's spacing, etc. on the strengthening system. Through numerical simulation, it has been shown that it is possible to predict accurately the flexural response of RC beams strengthened with FRPC laminates by selecting an appropriate material constitutive model. Comparisons are made between the available experimental results in literature and FE analysis results obtained by the present investigators using load-deflection and load-strain plots as well as ultimate load of the strengthened beams. Furthermore, evaluation of crack patterns from FE analysis and experimental failure modes are discussed at the end.

MICROSTRUCTURAL STUDY OF $Fe_{1-x}Ti_x$ ALLOYS FORMED BY ION BEAM MIXING

  • Jeon, Y.;Lee, Y.S.;Choi, B.S.;Woo, J.J.;Whang, C.N.
    • Journal of the Korean Vacuum Society
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    • v.6 no.S1
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    • pp.127-132
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    • 1997
  • Microstructure of the Fe-Ti system by ion beam mixing of multilayers at 300 K and 77 K has been studied in a wide composition range. The ion bombardment was carried out using $Ar^+$ ions at 80 keV. Using grazing angle x-ray diffraction we find that the lattice parameters of these bcc solid solutions are very close to that of $\alpha$-Fe. Extended x-ray absorption fine-structure spectroscopy have been performed to investgate the short-range order in the ion-beam-mixed state. The structure parameters, such as the interatomic distance and the coordination number are estmated from the Fe K-edge Fourier filtered EXAFS spectra. The interatomic distance is independent of the alloy concentration and it is almost constant. The study of x-ray absorption near-edge structure gives information on the individual $\rho$components of the partial densityof states of the conduction band of the Fe and Ti We also find that a charge transfer from Ti to Fe atoms takes place.

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Removal of Heavy Metal and Phenol from Aqueous Solution Using Fe(III) loaded Adsorbent (3가철 함유 흡착제를 이용한 수용액상의 중금속 및 페놀제거연구)

  • Kim, Seok-Jun;Kim, Won-Gee;Lee, Seung-Mok;Yang, Jae-Kyu;Lee, Nam-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.7
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    • pp.541-548
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    • 2009
  • Iron coated media (activated carbon, sand and starfish) were prepared at pH 4 and applied for the treatment of landfill leachate containing organic compounds and soluble metal ions such as $Zn^{2+},\;Cu^{2+},\;Mn^{2+}$ in batch and column experiment. The amount of iron coated in media was analyzed with EPA 3050B method. The removal efficiency of metal ions and phenol was compared with iron coated media. The amount of iron coated in Fe-AC and ICS(iron coated sand) were 1,612 mg/kg and 1,609 mg/kg, respectively, while it was higher with 1,768 mg/kg in ICSF(iron coated starfish). The result of batch study represent the highest removal efficiency in the treatment of wastewater using iron coated starfish. In column study, the removal efficiency of phenol and metal ions was higher in multi-layered system of ICS, Fe-AC and ICSF compared to single layered system. Breakthrough time in the effluent was relatively enhanced for $Cu^{2+}$ and $Zn^{2+}$ in multi-layered system while the removal efficiency of $Mn^{2+}$ were not varied much. Therefore, multi-layered system was identified as the better system for the treatment of wastewater containing of metal ions and organic compound.

FATIGUE LIFE ASSESSMENT OF REACTOR COOLANT SYSTEM COMPONENTS BY USING TRANSFER FUNCTIONS OF INTEGRATED FE MODEL

  • Choi, Shin-Beom;Chang, Yoon-Suk;Choi, Jae-Boong;Kim, Young-Jin;Jhung, Myung-Jo;Choi, Young-Hwan
    • Nuclear Engineering and Technology
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    • v.42 no.5
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    • pp.590-599
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    • 2010
  • Recently, efficient operation and practical management of power plants have become important issues in the nuclear industry. In particular, typical aging parameters such as stress and cumulative usage factor should be determined accurately for continued operation of a nuclear power plant beyond design life. However, most of the major components have been designed via conservative codes based on a 2-D concept, which do not take into account exact boundary conditions and asymmetric geometries. The present paper aims to suggest an effective fatigue evaluation methodology that uses a prototype of the integrated model and its transfer functions. The validity of the integrated 3-D Finite Element (FE) model was proven by comparing the analysis results of individual FE models. Also, mechanical and thermal transfer functions, known as Green's functions, were developed for the integrated model with the standard step input. Finally, the stresses estimated from the transfer functions were compared with those obtained from detailed 3-D FE analyses results at critical locations of the major components. The usefulness of the proposed fatigue evaluation methodology can be maximized by combining it with an on-line monitoring system, and this combination, will enhance the continued operations of old nuclear power plants.

Mössbauer Study of Two Discernable Fe Sites in CaFe2O4

  • Yoon, Sung-Hyun
    • Journal of Magnetics
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    • v.14 no.2
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    • pp.86-89
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    • 2009
  • Structural and magnetic properties of polycrystalline $CaFe_2O_4$ prepared by the solid state reaction method were studied using powder X-ray diffraction (XRD) and $M{\ddot{o}}ssbauer$ spectroscopy. The structure of $CaFe_2O_4$ belongs to an orthorhombic system (space group: Pnma) with the lattice parameters $a=9.2373\;{\AA}$, $b=3.0237\;{\AA}$, and $c=10.7124\;{\AA}$. Results of structural refinement indicate, however, that there are two slightly different iron sites in the sample. The $M{\ddot{o}}ssbauer$ spectrum at 4.2 K shows a hyperfine sextet with a hyperfine magnetic field and an isomer shift of 47.3 T and 0.36 mm/s, respectively. An examination of the spectrum revealed that the line widths of the spectral lines were not uniform. The degree of asymmetric line broadening decreases with increasing temperature, suggesting that the difference in the degree of crystalline distortions between two $FeO_6$ octahedra is eliminated as the temperature rises.

Kinetics and Mechanism for Redox Reaction of cis-$[Co(en)_2(N_3)_2]^+$ with Fe(II) in Acidic Solution (산 촉매하에서 cis-$[Co(en)_2(N_3)_2]^+$ 와 Fe(II) 와의 산화-환원반응에 대한 반응속도와 메카니즘)

  • Byung-Kak Park;Kwang-Jin Kim;Joo-Sang Lim
    • Journal of the Korean Chemical Society
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    • v.33 no.3
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    • pp.309-314
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    • 1989
  • A kinetic study was carried out for the redox reaction of cis-$[Co(en)_2(N_3)_2]^+$ with Fe(II) in acidic solution by spectrophotometric methods. This redox reaction system have been found to show a third order for overall reaction as the respective first order with respect to reactant cis-$[Co(en)_2(N_3)_2]^+$, Fe(II), and $H^+$ catalyst. The activation parameters, ${\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$, were obtained as 14.2Kcal/mol and -16.7 e.u., respectively. On the basis of the kinetic data, we suggest that the redox reaction system proceeds via inner sphere mechanism. The rate equation derived from the proposed mechanism is in agreement with the observed rate equation.

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Sliding Wear Behavior of Pure Metal, Fe and Cu Having a Cubic Crystal System (입방정계 순 금속 Fe, Cu의 미끄럼 마멸 거동)

  • Yi, S.K.;Kim, Y.S.
    • Transactions of Materials Processing
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    • v.19 no.6
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    • pp.357-362
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    • 2010
  • Dry sliding wear behavior of pure Fe and Cu which have BCC and FCC crystal structure, respectively, was investigated. The wear characteristics of the pure metals with different crystal structure were compared. Dry sliding wear tests were carried out using a pin-on-disk wear tester at various loads under the constant sliding speed condition of 0.15 m/s against a silica ball at room temperature. Sliding distance was fixed as 600 m for all wear tests. Wear rate of a specimen was calculated by dividing the weight loss of the specimen after the test by the specific gravity and sliding distance. Worn surfaces and wear debris were analyzed by SEM. The wear of both pure Fe and Cu proceeded with surface deformation, resulting in similar wear rates despite of their structure difference under the current test conditions. Wear rates of both metals were low if the surface deformation due to wear forms thick surface-deformation layer that is strain hardened beneath the wearing surface. The pure Cu specimens showed a lot of oxides on the worn surface when tested at low loads less than 5 N, which resulted in very low wear rate.