• Title/Summary/Keyword: Fe-As-S system

Search Result 405, Processing Time 0.032 seconds

Thermal Stress Calculations Using Enhanced Green's Function Considering Temperature-dependent Material Properties (온도 의존적 재료물성치를 고려한 개선된 그린함수 기반 열응력 계산)

  • Han, Tae-Song;Huh, Nam-Su;Jeon, Hyun-Ik;Ha, Seung-Woo;Cho, Sun-Young
    • Journal of the Korean Society of Manufacturing Technology Engineers
    • /
    • v.24 no.5
    • /
    • pp.535-540
    • /
    • 2015
  • We propose an enhanced Green's function approach to predict thermal stresses by considering temperature-dependent material properties. We introduce three correction factors for the maximum stress, the time taken to reach maximum stress, and the time required to attain steady state based on the Green's function results for each temperature. The proposed approach considers temperature-dependent material properties using correction factors, which are defined as polynomial expressions with respect to temperatures based on Green's functions, that we obtain from finite-element (FE) analyses at each temperature. We verify the proposed approach by performing detailed FE analyses on thermal transients. The Green's functions predicted by the proposed approach are in good agreement with those obtained from FE analyses for all temperatures. Moreover, the thermal stresses predicted using the proposed approach are also in good agreement with the FE results, and the proposed approach provides better predictions than the conventional Green's function approach using constant, time-independent material properties.

Fundamental Study on the Formation of Nanostructured Coating Layer (나노구조 용사코팅층의 형성에 관한 기초적 연구)

  • Kim, Y.S.
    • Journal of Power System Engineering
    • /
    • v.9 no.4
    • /
    • pp.90-95
    • /
    • 2005
  • The wire-arc process is a low-cost thermal spray method simply utilizes electrical energy to melt the feedstock wire. It is more userful for field applications, especially to coat large surface area. In this paper, a special Fe-based alloy coatings by using the wire-arc process were developed. Nanoscale composite coatings were achieved either during spraying or through a post heat treatment. As-sprayed Fe-based alloy coatings had been an amorphous matrix structure, after heating to $700^{\circ}C$ for 10 minutes a solid state transformation occurred in the some fraction of amorphous matrix which resulted in the formation of nanostructured recrystallized phase. Scanning electron microscopy (SEM) and field emotional scanning electron microscope(FE-SEM) were applied to analyze the microstructure of the coatings. Additionally hardness and bend resistance of the Fe-based alloy coatings were examined, and these results were compared with those of partially stabilized zirconia(PSZ) coatings by using the plasma spray process.

  • PDF

Surface Relaxation Effect on the Magnetism of Fe Overlayer on Cr (001)

  • Kim, I.G.;Lee, J.I.;Jang, Y.R.;Hong, C.S
    • Journal of Magnetics
    • /
    • v.1 no.1
    • /
    • pp.9-13
    • /
    • 1996
  • The effects of surface relaxation on surface and interface magnetism in Fe/Cr (001) are investigated using the highly precise all-electron total-energy full-potential linearized augmented plane wave method. The Fe-Cr interlayer spacing is deter-mined by total-energy calculation and it is found to be relaxed downward by 18%. For the relaxed system, the magnetic moment of surface Fe is highly suppressed to be $1.72\mu_B$compared to the unrelaxed case ($2.39\mu_B$). This reduction of magnetic moment is considered as a result of the enhanced hybridization between Fe-d and Cr-d states, which can be seen from the calculated density of states. This work suggests the importance of effect of relaxation to the surface and interface magnetism in Fe/Cr system.

  • PDF

LEED I/V Curve Analysis of O/Fe(100) and MgO/Fe(100) System (O/Fe(100) and MgO/Fe(100) 계의 LEED I/V curve 분석)

  • Seo, J.K.;Kim, S.H.
    • Journal of the Korean Vacuum Society
    • /
    • v.16 no.1
    • /
    • pp.1-6
    • /
    • 2007
  • We have analyzed the atomic structure of O/Fe(100) and interface atomic structure of MgO deposited on Fe(100) surface using LEED I/V curve analysis. As the O adsorption on the Fe(100) surface, the first substrate interlayer distance is expanded by up to 16%. For 1ML MgO deposited on Fe(100) surface, the oxygen ions of MgO are located on-top of the Fe atoms, the interlayer distance at the MgO/Fe interface are expanded. From the AIA(average intensity mixing approximation) calculation, we find the interface structure of monolayer MgO on Fe(100) system has the two interface structure with MgO/FeO/Fe(100) and MgO/Fe(100). This supports the results of EELS experiment that shown existence of stretched FeO layer and coexistance of MgO/FeO/Fe(100) and MgO/Fe(100) structure.

The Effect of Alloy Elements on the Damping Capacity and Plasma Ion Nitriding Characteristic of Fe-Cr-Mn-X Alloys. [II Plasma Ion Nitriding Characteristic] (Fe-Cr-Mn-X계 합금의 감쇠능 및 플라즈마 이온 질화특성에 미치는 합금원소의 영향 [II플라즈마 이온 질화특성])

  • Son, D.U.;Lee, H.H.;Seong, J.H.;Park, K.S.;Kim, C.K.;Kang, C.Y.
    • Journal of Power System Engineering
    • /
    • v.9 no.1
    • /
    • pp.76-81
    • /
    • 2005
  • The effect of micro-pulse plasma nitriding temperature and time on the case thickness, hardness and nitride formation in the surface of Fe-12Cr-22Mn-X alloy with 3% Co and 1% Ti alloys elements investigated. External compound layer and internal diffusion layer was constituted in plasma nitride case of Fe-12Cr-22Mn-X alloys and formed nitride phase such as ${\gamma}'-Fe4N\;and\;{\varepsilon}-Fe2-3N$. Case depth increased with increasing the plasma nitriding temperature and time. Surface hardness of nitrided Fe-12Cr-22Mn-X alloys obtained the above value of Hv 1,600 and case depth obtained the above value of $45{\mu}m$ in Fe-12Cr-22Mn-3Co alloy and $60{\mu}m$ in Fe-12Cr-22Mn-1Ti alloy. Wear-resistance increased with increasing plasma nitriding time and showing the higher value in Fe-12Cr-22Mn-1Ti alloy than Fe-12Cr-22Mn-3Co alloy.

  • PDF

MnCo2S4/CoS2 Electrode for Ultrahigh Areal Capacitance

  • Pujari, Rahul B.;Lokhande, C.D.;Lee, Dong-Weon
    • Journal of Sensor Science and Technology
    • /
    • v.29 no.4
    • /
    • pp.215-219
    • /
    • 2020
  • MnCo2S4/CoS2 electrode with highly accessible electroactive sites is prepared using the hydrothermal method. The electrode exhibits an areal capacitance of 0.75 Fcm-2 at 6 mAcm-2 in 1 M KOH. The capacitance is further increased to 2.06 Fcm-2 by adding K3Fe(CN)6 and K4Fe(CN)6 (a redox couple) to KOH. This increment is associated with the redox-active properties of cobalt and manganese transition metals, as well as the ion pair of [Fe(CN)6]-3/[Fe(CN)6]-4. The capacitance retention of the MnCo2S4/CoS2 electrode is 87.5% for successive 4000 charge-discharge cycles at 10 mAcm-2 in a composite electrolyte system of KOH and ferri/ferrocyanide. The capacitance enhancement is supported by the lowest equivalent series resistance (0.62 Ωcm-2) of MnCo2S4/CoS2 in the presence of redox additive couple compared with the bare KOH electrolyte.

Experimental and numerical study on the PSSDB system as two-way floor units

  • Al-Shaikhli, Marwan S.;Badaruzzaman, Wan Hamidon Wan;Al Zand, Ahmed W.
    • Steel and Composite Structures
    • /
    • v.42 no.1
    • /
    • pp.33-48
    • /
    • 2022
  • This paper researches a lightweight composite structure referred to as the Profiled Steel Sheeting Dry Board (PSSDB). It is fundamentally produced by connecting a Profiled Steel Sheeting to Dry Board using mechanical screws. It is mainly employed as floor panels. However, almost all studies have focused on researching the one-way structural performance. Therefore, this study focuses on the bending behaviour of the two-way PSSDB floor system using both of Finite Element (FE) and Experimental analysis. Four panels were used in the experimental tests, and a mild steel plate has been applied at the bottom for two panels. For the FE process, models were created using ABAQUS software. 4 parametric studies have been utilized to understand the system's influential elements. From the experimental tests, it was found that using Steel Plate shall optimize the two-way action of the system and depending on the type of dry board the improvement in stiffness may reach up to 38%. It was shown from the FE analysis that the dry board, profiled steel sheeting and steel plat can affect the system by up to 10 %, 17% and 3% respectively, while applying a uniform load demonstrate a better two-way action.

Chemical Composition and Thermal Changes of Natural Pyrrhotite

  • Moon-Young Kim;Hong-Ja Shin
    • Journal of the Mineralogical Society of Korea
    • /
    • v.3 no.2
    • /
    • pp.65-71
    • /
    • 1990
  • Compositions and thermal changes of pyrrhotites from Ohtani and Uljin mines were examined by Arnold's method and DTA analysis. The results are as follow: 1) The compositions of hexagonal type pyrrhotite are in some range from 47.23-47.42 atom.% Fe in the Ohtani mine, and 47.40-47.64 atom.% Fe in the Uljin mine. 2) The compositions of hexagonal pyrrhotite with exsoluted lamellae of monoclinic pyrrhotite are in 47.35-47.50 atom.% Fe in the Ohtani mine, and 47.15-47.40 atom.% Fe in the Uljin mine. This fact does not agree with phase diagrams of Fe-S system shown by Nakazawa and Morimoto(1970) and Sugaki and Shima(1977). 3) DTA data show two endothermic peak corresponding to ${\gamma}$ and $\beta$ transformation. Sturctural conversions from order(intermediate) to disorder(high) forms occur at about $300^{\circ}C$ for hexagonal type and further lower temperature with increasing Fe-content.

  • PDF

Development of a Framework for Improving Efficiency of Ship Vibration Analysis (선박 전선 진동해석 효율성 향상을 위한 프레임워크 개발)

  • Cho, Dae-Seung;Kim, Jin-Hyeong;Choi, Tae-Muk;Kim, Kyung-Soo;Choi, Sung-Won;Jung, Tae-Seok;Lee, Do-Kyung;Seok, Ho-Il
    • Transactions of the Korean Society for Noise and Vibration Engineering
    • /
    • v.21 no.8
    • /
    • pp.761-767
    • /
    • 2011
  • Free and forced vibration analysis of the global ship structure using the 3-dimensional finite element(FE) method requires not only the specialized knowledge such as ship structure interacted with fluid, damping and various excitations due to propulsion system but also time-consuming manual tasks in FE modeling, analysis and response evaluation. As a result, the quality of the vibration analysis highly depends on engineer's expertise and experience. In this study, a framework system to improve the efficiency of global ship vibration analysis is introduced. The system promising the utilization of MSC/Patran and MSC/Nastran consists of various modules to support data management, FE modeling of ship structure and loading, input deck generation for free and forced vibration analysis, data extraction and evaluation of analysis results, and databases for FE models of marine diesel engines and vibration criteria. The system may be useful for pursuing standardization of uncertain analysis factors as well as reducing time, cost and human dependency in ship vibration analysis.

Development of a Framework for Improving Efficiency of Ship Vibration Analysis (선박 전선 진동해석 효율성 향상을 위한 프레임워크 개발)

  • Cho, Dae-Seung;Kim, Jin-Hyeong;Choi, Tae-Muk;Kim, Kyung-Soo;Choi, Sung-Won;Jung, Tae-Seok;Lee, Do-Kyung;Seok, Ho-Il
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
    • /
    • 2011.04a
    • /
    • pp.779-784
    • /
    • 2011
  • Free and forced vibration analysis of the global ship structure using the 3-dimensional finite element(FE) method requires not only the specialized knowledge such as ship structure interacted with fluid, damping and various excitations due to propulsion system but also time-consuming manual tasks in FE modeling, analysis and response evaluation. As a result, the quality of the vibration analysis highly depends on engineer's expertise and experience. In this study, a framework system to improve the efficiency of global ship vibration analysis is introduced. The system promising the utilization of MSC/Patran and MSC/Nastran consists of various modules to support data management, FE modeling of ship structure and loading, input deck generation for free and forced vibration analysis, data extraction and evaluation of analysis results, and databases for FE models of marine diesel engines and vibration criteria. The system may be useful for pursuing standardization of uncertain analysis factors as well as reducing time, cost and human dependency in ship vibration analysis.

  • PDF