• Title/Summary/Keyword: Fe-As-S system

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Application of Fe-Mn High Damping Alloys for Reduction of Noise and Vibration in Power Plants (Fe-Mn 방진합금을 적용한 발전소 격납용기 살수펌프의 소음$\cdot$진동 저감효과에 관한 연구)

  • 백승한
    • Journal of KSNVE
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    • v.9 no.4
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    • pp.720-729
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    • 1999
  • Coventional methods for reducing vibration in engineering designs (i.e. by stifferning or detuning) may be undesirable in conditions where size or weight must be minimized, or where complex vibration spectra exist. Some alloys with a combination of high damping capacity and good mechanical properties can provide attractive techanical and economical solutions to problems involving seismic, shock and vibration isolation. Although several non ferrous damping alloys have been developed, none of those materials are applied in any industrial factor due largely to high production cost. To meet these requirement, we have developed a new Fe-Mn high damping alloy. In previous studies, we have reported that an Fe-17%Mn alloy exhibits the highest damping capacity(Specific Damping Capacity:SDC, 30%) among Fe-Mn binary system, and proposed that the boundaries of various types such as $\varepsilon$-martensite variant boundaries, stacking faults in $\varepsilon$-martensite, stacking faults in austenitic and ${\gamma}$$\gamma /\varepsilon$ interfaces give rise to a high damping capacity. The Fe-17%Mn alloy also has advantages of good mechanical properties(T.S. 70 kg/nm$^2$ and low cost over other damping alloys(1/4 times the cost of non-ferrous damping alloy). Thus, the Fe-17%Mn high damping alloy can be widely applied to household appliances, automobiles, industrial facilities and power plant components. In this paper, the overall properties of the Fe-17%Mn high damping alloy is introduced, and its applicability to containment spray pump in the power plant is discussed.

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A Semi-graphical Analysis on the Sublattice Anisotropy of a Two Sublattice System with Uniaxial Anisotropy: Application to Pr2Fe14B

  • Kim, Y.B.;Jin-Han-Min
    • Journal of Magnetics
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    • v.3 no.3
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    • pp.74-77
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    • 1998
  • A method to analyze the anisotropy constants of a two sublattice system with uniaxial anisotropy has been investigated by extending the Sucksmith and Thompson's method to higher order anisotropy terms. Using the method, a set of anisotropy constants for Pr-sublattice of $Pr_2Fe_{14}B at 4.2K has been obtained as K_{1Pr}=5210 J/kg, K_{2Pr}=-7200 J/kg, K_{3Pr}=-770 J/kg, K_{4Pr}=4940 J/kg and K_{SPr}=700 J/kg for N_{PrFe}=2.2 T/Am^2kg^{-1}.$ The magnetization calculated by an energy minimum method by using the sublattice anisotropy constants well reproduced the experimental results and satisfied the simulation assumptions.

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Mode of Occurrences and Depositional Conditions of Arsenopyrite from the Yeonhwa 1 Mine, Korea (연화 제1광산에서의 유비철석의 산상과 배태 조건)

  • Lee, Young-Up;Chung, Jae-Il
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.1
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    • pp.1-17
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    • 2003
  • The chemical composition of the arsenopyrite Ib adjoining“triple mutual contact”arsenopyrite + pyrite + hexagonal pyrrhotite may serve as a useful geothermometer in Stage II. In this study it corresponds to temperature T=33$0^{\circ}C$ and f( $S_2$)=10$^{-9.5}$ atm. And the pyrite-hexagonal pyrrhotite buffer curve indicates the probable range of the two variables; T= 315∼345$^{\circ}C$, and f( $S_2$)=10$^{-1}$0.5/∼10$^{-9}$ atm. The present antimony-bearing arsenopyrite (arsenopyrite Ic) is characterized by relatively high content of antimony, ranging from 4.95 to 8.91 percent Sb by weight and excess of iron and deficiency of anions are evident. Such a high antimonian arsenopyrite has never been known within single grain. But being the high content of antimony as in the arsenopyrite Ic, it does not serve as a geothermometer. The results of microprobe analyses for four pairs of asenopyrite and sphalerite in Stage III indicate the temperature range from 310 to 34$0^{\circ}C$, and sulphur fugacity range from 10$^{-10}$ ∼10$^{-9}$ atm. These values seem to correspond with those inferred from the Fe-As-S system.m..

The Magnetoresistance Properties of Spin Valves with CoFe/Ru/CoFe/FeMn Synthetic Antiferromagnet (Synthetic antiferromagnet CoFe/Ru/CoFe/FeMn을 이용한 스핀 밸브 구조의 자기저항 특성)

  • Jang, S.H.;Kang, T.;Kim, M.J.;Kim, H.J.;Kim, K.Y.
    • Journal of the Korean Magnetics Society
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    • v.10 no.5
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    • pp.196-202
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    • 2000
  • Top synthetic spin valves with structure Ta/NiFe/CoFe/Cu/CoFe(P1)/Ru/CoFe(P2)/FeMn/Ta on Si(100) substrate with natural oxide were prepared by dc magnetron sputtering system, and investigated on the magnetoresistance properties and effective exchange bias field. As the thickness of FeMn increased above 150 $\AA$, MR ratio was decreased due to the current shunting effect. As the thickness of free layer decreased below 40$\AA$, MR ratio was reduced rapidly. In case of 40 $\AA$ thick of free layer, spin valve film with a structure Si(100)/Ta(50 $\AA$)/NiFe(27 $\AA$)/CoFe(13 $\AA$)/Cu(26 $\AA$)/CoFe(30 $\AA$)/Ru(7 $\AA$)/CoFe(15 $\AA$)/FeMn(100 $\AA$)/Ta(50 $\AA$) exhibited maximum MR ratio of 7.5 % and an effective exchange bias field of 600 Oe, respectively. Thickness difference dependence in this synthetic spin valve structure on effective exchange field was investigated and interpreted by the analytical method. It should be noted that thickness increase of CoFe(P 1) and decrease of CoFe(P2) in synthetic antiferromagnet leaded to the decrease in effective exchange bias field by experimentally and analytically.

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The role of heliospheric current sheet on solar energetic particles with enhanced Fe/O

  • Park, Jinhye;Bucik, R.;Moon, Yong-Jae;Kahler, S.W.
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.1
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    • pp.52.1-52.1
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    • 2018
  • We investigate initial Fe/O enhancements for 44 large gradual solar energetic particles events from 2010 to 2014 and examine the associations of the Fe/O enhancements with the structures of the heliospheric current sheet (HCS). For this study, we use STEREO SIT Fe and O data in 0.32-0.45 MeV channel as well as ACE ULEIS Fe and O data in 0.32-0.64 MeV channel. We determine 1) the magnetic polarities of the SEP source regions using the potential field source surface (PFSS) model of the coronal field and 2) the spacecraft magnetic footpoints with Parker spiral approximation of interplanetary magnetic field using the in-situ measurements of STEREO and ACE. We find that 29 out of 44 events have initial Fe/O enhanced more than 5 times of the typical gradual event values. In the 6 events, the enhancements are simultaneously observed by two spacecraft. There is a tendency that the high Fe/O enhancements are observed near SEP source regions. It is also noted that the Fe/O enhancements are associated with the polarity of the magnetic footpoints. The high Fe/O enhancements are usually observed where their footpoints lie in the same polarity regions of SEP sources rather than the opposite polarity regions. Although Fe/O enhancements could be due to a transport effect and/or a flare contribution, our result implies that the structure of HCS is likely to affect particle propagations in the interplanetary space.

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The Effects of Heat Treatment Temperature on Mechanical Property of 93W-6.3Ni-0.7Fe Heavy Alloy (93W-6.3Ni-0.7Fe 중합금에서 열처리온도에 따른 기계적 성질변화)

  • 김은표
    • Journal of Powder Materials
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    • v.5 no.1
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    • pp.42-49
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    • 1998
  • A study on the improvement of the impact energy in 93W heavy alloy with a Ni/Fe ratio of 9/1 has been carried out as a function of heat treatment temperature. The obtained results were compared to that of the traditional alloy system in which the Ni/Fe ratio is 7/3 or 8/2. With increasing heat treatment temperature from 1150 to 125$0^{\circ}C$, the impact energy of the alloy with the Ni/Fe ratio of 9/1 is remarkably increased from 42 to 72 J, which is higher than that of traditional alloy, up to 118$0^{\circ}C$ and then saturated. Fracture mode was also changed from brittle W/W boundary failure to W cleavage. The temperature showing the dramatic shrinkage by dilatometric anaysis of the heavy alloy with Ni/Fe ratio of 9/1 was found to be 1483 $^{\circ}C$, which is higher than that (146$0^{\circ}C$) of the heavy alloy with Ni/Fe ratio of 7/3. Auger Electron Spectroscopy showed that the segregation of impurities, such as S, P, and C in W/W grain boundary was considerably decreased with increasing heat treatment temperature from 1150 to l18$0^{\circ}C$. From the above results, it was found that the impurity segregation in W/W grain boundary played an important role on the decrease of impact properties, and the heat treatment temperature should be appropriately chosen, as considering the Ni/Fe ratio of the alloy, in order to get good impact properties.

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Temperature and Concentration Dependencies of Chemical Equilibrium for Reductive Dissolution of Magnetite Using Oxalic Acid

  • Lee, Byung-Chul;Oh, Wonzin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.2
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    • pp.187-196
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    • 2021
  • Chemical equilibrium calculations for multicomponent aqueous systems involving the reductive dissolution of magnetite (Fe3O4) with oxalic acid (H2C2O4) were performed using the HSC Chemistry® version 9. They were conducted with an aqueous solution model based on the Pitzer's approach of one molality aqueous solution. The change in the amounts and activity coefficients of species and ions involved in the reactions as well as the solution pH at equilibrium was calculated while changing the amounts of raw materials (Fe3O4 and H2C2O4) and the system temperature from 25℃ to 125℃. In particular, the conditions under which Fe3O4 is completely dissolved at high temperatures were determined by varying the raw amount of H2C2O4 and the temperature for a given raw amount of Fe3O4 fed into the aqueous solution. When the raw amount of H2C2O4 added was small for a given raw amount of Fe3O4, no undissolved Fe3O4 was present in the solution and the pH of the solution increased significantly. The formation of ferrous oxalate complex (FeC2O4) was observed. The equilibrium amount of FeC2O4 decreased as the raw amount of H2C2O4 increased.

Comparison of Uptake of Ionic and Tf-bound Fe-59 and Ga-67 in Transformed and Untransformed Cells (변형세포와 비변형세포에서 이온형과 Transferrin 결합형 Fe-59와 Ga-67 섭취율의 비교)

  • Sohn, Myung-Hee;Lee, Young-Hwan;Lee, Sang-Yong;Chung, Gyung-Ho;Han, Young-Min;Kim, Jong-Soo;Choi, Ki-Chul;Yim, Chang-Yeol
    • The Korean Journal of Nuclear Medicine
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    • v.30 no.1
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    • pp.145-151
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    • 1996
  • Pathways both mediated by and independent of transferrin(Tf) and the TfR have been described for the accumulation of iron. Although it is not clear whether the same systems take up iron and gallium, these pathways may suggest the contention that uptake of Ga-67 can, in fact, occur by both Tf-independent and Tf-dependent systems and may share with Fe-59 in part the same mechanism for uptake. The predominant system by which uptake of both radiometals occurs may be different in the degree of the transformation of tumor. Transformed(MMSV/3T3) and untransformed(BALB/3T3) cells were incubated with luM of Ga-67-citrate of Fe-59-chloride for 15 min. at $37^{\circ}C$ in either the presence or absence of Tf. After then, the monolayers were washed with HBSS or PBS, and the cells were solubilized in 1% SDS for gamma well counting and protein determinations. There were similarities, as well as differences, in the pattern of uptake of Fe-59 and Ga-67 presented both in ionic from and as bound to Tf. Both radiometals appeared gain to cells in either ionic or Tf-bound forms. Transformed cells appeared to accumulate more radiometal, either Ga-67 or Fe-59 in the presence of Tf than do the their untransforemd counterparts. Conversly the presentation of either radiometal in ionic form resulted in significantly greater accumulation of metal by the untransformed cells than those transformed. The efficiency for uptake of Ga-67 or Fe-59 in the absence of Tf was greater than for uptake of the Ga-Tf or Fe-Tf. However, the magnitude of difference in efficiency of uptake was greater for Fe-59(10-fold) than for Ga-67 (3-fold). Our results Supports the theory that both Tf-independent and Tf-dependent systems for the uptake of Ga-67 both systems operate oppositely between transformed cells and those untransformed, with uptake by the predominating in transformed cells by the Tf-mediated system and in untransformed cells by the Tf-independent. The uptake of Ga-67 by tumor may share with Fe-59 in part the same mechanism.

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Time-dependent and inelastic behaviors of fiber- and particle hybrid composites

  • Kim, Jeong-Sik;Muliana, Anastasia
    • Structural Engineering and Mechanics
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    • v.34 no.4
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    • pp.525-539
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    • 2010
  • Polymer matrix composites are widely used in many engineering applications as they can be customized to meet a desired performance while not only maintaining low cost but also reducing weight. Polymers can experience viscoelastic-viscoplastic response when subjected to external loadings. Various reinforcements and fillers are added to polymers which bring out more complexity in analyzing the timedependent response. This study formulates an integrated micromechanical model and finite element (FE) analysis for predicting effective viscoelastic-viscoplastic response of polymer based hybrid composites. The studied hybrid system consists of unidirectional short-fiber reinforcements and a matrix system which is composed of solid spherical particle fillers dispersed in a homogeneous polymer constituent. The goal is to predict effective performance of hybrid systems having different compositions and properties of the fiber, particle, and matrix constituents. A combined Schapery's viscoelastic integral model and Valanis's endochronic viscoplastic model is used for the polymer constituent. The particle and fiber constituents are assumed linear elastic. A previously developed micromechanical model of particle reinforced composite is first used to obtain effective mechanical properties of the matrix systems. The effective properties of the matrix are then integrated to a unit-cell model of short-fiber reinforced composites, which is generated using the FE. The effective properties of the matrix are implemented using a user material subroutine in the FE framework. Limited experimental data and analytical solutions available in the literatures are used for comparisons.

The development and application of on-line model for the prediction of roll force in hot strip rolling (얼간 사상 압연중 압하력 예측 모델 개발 및 적용)

  • Lee J. H.;Choi J. W.;Kwak W. J.;Hwang S. M.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.08a
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    • pp.175-183
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    • 2004
  • In hot strip rolling, a capability for precisely predicting roll force is crucial for sound process control. In the past, on-line prediction models have been developed mostly on the basis of Orowan's theory and its variation. However, the range of process conditions in which desired prediction accuracy could be achieved was rather limited, mainly due to many simplifying assumptions inherent to Orowan's theory. As far as the prediction accuracy is concerned, a rigorously formulated finite element(FE) process model is perhaps the best choice. However, a FE process model in general requires a large CPU time, rendering itself inadequate for on-line purpose. In this report, we present a FE-based on-line prediction model applicable to precision process control in a finishing mill(FM). Described was an integrated FE process model capable of revealing the detailed aspects of the thermo-mechanical behavior of the roll-strip system. Using the FE process model, a series of process simulation was conducted to investigate the effect of diverse process variables on some selected non-dimensional parameters characterizing the thermo-mechanical behavior of the strip. Then, it was shown that an on-line model for the prediction of roll force could be derived on the basis of these parameters. The prediction accuracy of the proposed model was examined through comparison with measurements from the hot strip mill.

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