• 제목/요약/키워드: Fe-As-S system

검색결과 406건 처리시간 0.025초

CANDU형 원전 주요기기의 피로손상 평가를 위한 그린함수 개발 (Development of Green's Functions for Fatigue Damage Evaluation of CANDU Reactor Coolant System Components)

  • 김세창;성희동;최재붕;김홍기;송명호;노승환
    • 한국압력기기공학회 논문집
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    • 제7권4호
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    • pp.38-43
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    • 2011
  • For the efficient and safe operation of nuclear power plant, evaluating quantitatively aging phenomenon of major components is necessary. Especially, typical aging parameters such as stresses and cumulative usage factors should be determined accurately to manage the lifetime of the plant facility. The 3-D finite element(FE) model is generated to calculate the aging parameters. Mechanical and thermal transfer functions called Green's functions are developed for the FE model with standard step input. The stress results estimated from transfer functions are verified by comparing with 3-D FE analyses results. Lastly, we suggest an effective fatigue evaluation methodology by using the transfer functions. The usefulness of the proposed fatigue evaluation methodology can be maximized by combining it with an on-line monitoring system.

자동차 서스펜션 로워암의 모델링 보조시스템 개발 (Development of Modeling Support System for Lower Arm in Automobile Suspension Module)

  • 이태희;신소영;서창희;권태우;한승호
    • 한국CDE학회논문집
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    • 제11권1호
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    • pp.49-56
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    • 2006
  • In this study, the modeling support system was developed which can make easy and fast FE-modeling and verify the results of static and durability analysis for the lower arm, one of the important parts in automobile suspension module. It took into account of the whole complicated design processes verifying the durability coefficients evaluated by fatigue analysis, which should be used to satisfy a design criteria. To guide the FE-modeling the drive page was constructed by using HTML and XML, which was based on expert's know-hows. It is able to integrate the processes to design the lower arm in practice, so that the standardization of its FE-Modeling is achieved, consequently. The 3 dimensional CAD's geometrical data were changed automatically into pre-defined shell elements under the concept of mesh-offset technique, and then welding elements were treated to connect between target and basic surfaces constructed by the shell elements. This system has also a user interface to control boundary and load ing conditions applied in performing of the static and durability analysis, in which many load cases can be applied simply with the MPCs driven by just few mouse clicks. These were implemented on the platform of MSC.Patran and utilized ANSYS, MSC.Nastran and MSC.Fatigue as the solver of the analysis performed. The developed system brings not only significant decreasing of man-hours required in FE-modeling process, but also obtaining of satisfied qualities in analyzed results. It will be integrated in a part of virtual prototyping module of the developing e-engineering framework.

Nonlinear analysis of reinforced concrete beams strengthened with polymer composites

  • Pendhari, S.S.;Kant, T.;Desai, Y.M.
    • Structural Engineering and Mechanics
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    • 제24권1호
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    • pp.1-18
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    • 2006
  • Strengthening of existing old structures has traditionally been accomplished by using conventional materials and techniques, viz., externally bonded steel plates, steel or concrete jackets, etc. Alternatively, fibre reinforced polymer composite (FRPC) products started being used to overcome problems associated with conventional materials in the mid 1950s because of their favourable engineering properties. Effectiveness of FRPC materials has been demonstrated through extensive experimental research throughout the world in the last two decades. However there is a need to use refined analytical tools to simulate response of strengthened system. In this paper, an attempt has been made to develop a numerical model of strengthened reinforced concrete (RC) beams with FRPC laminates. Material models for RC beams strengthened with FRPC laminates are described and verified through a nonlinear finite element (FE) commercial code, with the help of available experimental data. Three dimensional (3D) FE analysis has been performed by assuming perfect bonding between concrete and FRPC laminate. A parametric study has also been performed to examine effects of various parameters like fibre type, stirrup's spacing, etc. on the strengthening system. Through numerical simulation, it has been shown that it is possible to predict accurately the flexural response of RC beams strengthened with FRPC laminates by selecting an appropriate material constitutive model. Comparisons are made between the available experimental results in literature and FE analysis results obtained by the present investigators using load-deflection and load-strain plots as well as ultimate load of the strengthened beams. Furthermore, evaluation of crack patterns from FE analysis and experimental failure modes are discussed at the end.

Cement/Slag/Fe(II) 시스템에 의한 클로로포름과 메틸렌클로라이드 함유 액상폐기물의 분해성 고형화/안정화 (Degradative Solidification/Stabilization of Liquid Waste Containing Chloroform and Methylene Chloride by Cement/Slag/Fe(II) Systems)

  • 성요셉;안철홍;최원호;박주양
    • 대한환경공학회지
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    • 제30권10호
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    • pp.1034-1038
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    • 2008
  • 분해성 고형화/안정화(DS/S, degradative solidification/stabilization)는 전통적인 고형화/안정화(S/S, Solidification/Stabilization)에 경제성과 유기 오염물질의 분해를 추가한 기술이다. 무기 오염물질은 고정되며 유기 오염물질은 DS/S시스템에 의해 분해된다. 본 연구에서는 액상폐기물 내의 클로로포름(CF)과 메틸렌클로라이드(MC) 분해를 위해 cement/slag/Fe(II)시스템을 바인더로 한 DS/S의 효율성을 평가 하였다. 초기 CF의 농도는 0.26 mM, 1.0 mM, 8.4 mM, 25 mM and 42 mM 그리고 Fe(II) 농도는 200 mM로 하였다. 실험결과 다양한 농도의 CF의 분해경향은 유사일차반응으로 표현할 수 있었으며 초기농도 0.26 mM에서 5일 이내에 95%가 분해되었다. MC의 분해를 촉진시키기 위하여 중금속 50 mg/L을 추가하였으나 분해는 거의 이루어지지 않았다. 따라서 MC의 분해를 위해서 추가적인 고찰이 필요하다고 판단되며 다른 반응 경로의 부산물에 대한 추가적인 고찰을 통해 cement/slag/Fe(II)에서 메탄 계열의 염소계유기화합물의 명확한 분해 경로와 메카니즘을 파악할 수 있을 것이다.

MICROSTRUCTURAL STUDY OF $Fe_{1-x}Ti_x$ ALLOYS FORMED BY ION BEAM MIXING

  • Jeon, Y.;Lee, Y.S.;Choi, B.S.;Woo, J.J.;Whang, C.N.
    • 한국진공학회지
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    • 제6권S1호
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    • pp.127-132
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    • 1997
  • Microstructure of the Fe-Ti system by ion beam mixing of multilayers at 300 K and 77 K has been studied in a wide composition range. The ion bombardment was carried out using $Ar^+$ ions at 80 keV. Using grazing angle x-ray diffraction we find that the lattice parameters of these bcc solid solutions are very close to that of $\alpha$-Fe. Extended x-ray absorption fine-structure spectroscopy have been performed to investgate the short-range order in the ion-beam-mixed state. The structure parameters, such as the interatomic distance and the coordination number are estmated from the Fe K-edge Fourier filtered EXAFS spectra. The interatomic distance is independent of the alloy concentration and it is almost constant. The study of x-ray absorption near-edge structure gives information on the individual $\rho$components of the partial densityof states of the conduction band of the Fe and Ti We also find that a charge transfer from Ti to Fe atoms takes place.

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3가철 함유 흡착제를 이용한 수용액상의 중금속 및 페놀제거연구 (Removal of Heavy Metal and Phenol from Aqueous Solution Using Fe(III) loaded Adsorbent)

  • 김석준;김원기;이승목;양재규;이남희
    • 대한환경공학회지
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    • 제31권7호
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    • pp.541-548
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    • 2009
  • 본 연구에서는 매립장 침출수 같은 중금속과 유기물을 함께 함유하고 있는 폐수를 처리하기위하여, Fe(III)을 활성탄, 모래, 불가사리와 같은 담체에 첨착 및 코팅시킨 흡착제를 사용하였다. 제조된 Iron Impregnated Activated Carbon(Fe-AC), Iron Coated Sand(ICS), Iron Coated Starfish(ICSF)는 EPA 3050B 방법을 통하여 각 매질에 함유된 철 함량을 분석하였으며, 회분식 반응조에서의 흡착실험을 통하여 각 흡착제의 Mn(II), Zn(II) 및 Cu(II)의 제거성능을 비교하였다. Fe-AC 및 ICS의 철 함유량은 각각 1,612 mg/kg 및 1,609 mg/kg으로서 매우 유사하였으며 ICSF의 철 함유량은 1,768 mg/kg으로 ICSF의 철 코팅함량이 다른 두 가지에 비해 150 mg/kg 정도 높게 나타났다. 회분식 실험에서의 Mn(II), Zn(II), Cu(II)의 제거효율은 ICSF, Fe-AC, ICS의 순으로 높은 제거율을 보였다. 각 흡착제를 단일 및 다중층으로 충전한 칼럼반응기에 의한 연속식 실험결과, 단일 흡착제에 비해 ICS, Fe-AC, ICSF의 순으로 충전한 시스템에서 높은 중금속 및 페놀제거효율을 나타내었으며, Cu(II)와 Zn(II)에 대해서는 뚜렷한 파과능을 보였으나 Mn(II) 제거율은 상대적으로 낮게 나타났다. 각 흡착제를 병합 충전한 다중층 칼럼반응시스템은 중금속 및 phenol제거에 효과적임을 알 수 있었다.

FATIGUE LIFE ASSESSMENT OF REACTOR COOLANT SYSTEM COMPONENTS BY USING TRANSFER FUNCTIONS OF INTEGRATED FE MODEL

  • Choi, Shin-Beom;Chang, Yoon-Suk;Choi, Jae-Boong;Kim, Young-Jin;Jhung, Myung-Jo;Choi, Young-Hwan
    • Nuclear Engineering and Technology
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    • 제42권5호
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    • pp.590-599
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    • 2010
  • Recently, efficient operation and practical management of power plants have become important issues in the nuclear industry. In particular, typical aging parameters such as stress and cumulative usage factor should be determined accurately for continued operation of a nuclear power plant beyond design life. However, most of the major components have been designed via conservative codes based on a 2-D concept, which do not take into account exact boundary conditions and asymmetric geometries. The present paper aims to suggest an effective fatigue evaluation methodology that uses a prototype of the integrated model and its transfer functions. The validity of the integrated 3-D Finite Element (FE) model was proven by comparing the analysis results of individual FE models. Also, mechanical and thermal transfer functions, known as Green's functions, were developed for the integrated model with the standard step input. Finally, the stresses estimated from the transfer functions were compared with those obtained from detailed 3-D FE analyses results at critical locations of the major components. The usefulness of the proposed fatigue evaluation methodology can be maximized by combining it with an on-line monitoring system, and this combination, will enhance the continued operations of old nuclear power plants.

Mössbauer Study of Two Discernable Fe Sites in CaFe2O4

  • Yoon, Sung-Hyun
    • Journal of Magnetics
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    • 제14권2호
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    • pp.86-89
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    • 2009
  • Structural and magnetic properties of polycrystalline $CaFe_2O_4$ prepared by the solid state reaction method were studied using powder X-ray diffraction (XRD) and $M{\ddot{o}}ssbauer$ spectroscopy. The structure of $CaFe_2O_4$ belongs to an orthorhombic system (space group: Pnma) with the lattice parameters $a=9.2373\;{\AA}$, $b=3.0237\;{\AA}$, and $c=10.7124\;{\AA}$. Results of structural refinement indicate, however, that there are two slightly different iron sites in the sample. The $M{\ddot{o}}ssbauer$ spectrum at 4.2 K shows a hyperfine sextet with a hyperfine magnetic field and an isomer shift of 47.3 T and 0.36 mm/s, respectively. An examination of the spectrum revealed that the line widths of the spectral lines were not uniform. The degree of asymmetric line broadening decreases with increasing temperature, suggesting that the difference in the degree of crystalline distortions between two $FeO_6$ octahedra is eliminated as the temperature rises.

산 촉매하에서 cis-$[Co(en)_2(N_3)_2]^+$ 와 Fe(II) 와의 산화-환원반응에 대한 반응속도와 메카니즘 (Kinetics and Mechanism for Redox Reaction of cis-$[Co(en)_2(N_3)_2]^+$ with Fe(II) in Acidic Solution)

  • 박병각;김광진;임주상
    • 대한화학회지
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    • 제33권3호
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    • pp.309-314
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    • 1989
  • 산 용액내에서 cis-$[Co(en)_2(N_3)_2]^+$와 Fe(II)간의 산화-환원 반응속도를 UV/vis-분광광도계로 측정하였다. 여기서 촉매 $H^+$가 관여한 반응속도상수와 각 반응물의 반응차수 그리고 활성화파라메타를 구하여 이들 자료를 바탕으로 타당한 반응메카니즘을 제안하였다. 본 연구의 실험결과를 보면, Co(III)와 Fe(II) 그리고 $H^+$에 대해서 각각 1차로 총괄반응이 3차 반응이다. 이때 반응속도상수 $K_H^+$$3.27{\times}10^{-2}l^2{\cdot}mol^{-2}{\cdot}sec^{-1}$이였다. 그리고 활성화에너지 $E_a$는 14.8Kcal/mol, 활성화엔탈피 ${\Delta}H^{\neq}$는 14.2Kcal/mol, 활성화엔트로피 ${\Delta}S^{\neq}$는 -16.7e.u.였다. 이러한 실험적 사실을 바탕으로, 본 반응계에서 $H^+$가 촉매로 작용하여 내부권(inner-sphere) 메카니즘으로 산화-환원반응이 진행되는 타당한 반응메카니즘을 제안하였다.

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입방정계 순 금속 Fe, Cu의 미끄럼 마멸 거동 (Sliding Wear Behavior of Pure Metal, Fe and Cu Having a Cubic Crystal System)

  • 이슬기;김용석
    • 소성∙가공
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    • 제19권6호
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    • pp.357-362
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    • 2010
  • Dry sliding wear behavior of pure Fe and Cu which have BCC and FCC crystal structure, respectively, was investigated. The wear characteristics of the pure metals with different crystal structure were compared. Dry sliding wear tests were carried out using a pin-on-disk wear tester at various loads under the constant sliding speed condition of 0.15 m/s against a silica ball at room temperature. Sliding distance was fixed as 600 m for all wear tests. Wear rate of a specimen was calculated by dividing the weight loss of the specimen after the test by the specific gravity and sliding distance. Worn surfaces and wear debris were analyzed by SEM. The wear of both pure Fe and Cu proceeded with surface deformation, resulting in similar wear rates despite of their structure difference under the current test conditions. Wear rates of both metals were low if the surface deformation due to wear forms thick surface-deformation layer that is strain hardened beneath the wearing surface. The pure Cu specimens showed a lot of oxides on the worn surface when tested at low loads less than 5 N, which resulted in very low wear rate.