• 제목/요약/키워드: Fe oxide

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Electrical Conductivity Change of Manganese oxide with Addition of Transition Metal (천이금속 첨가에 따른 이산화망간의 전기전도도 변화)

  • Kim, Bong-Seo;Lee, Dong-Yoon;Lee, Hee-Woong;Chung, Won-Sub
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2028-2030
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    • 2005
  • The electrical conductivity of manganese oxide and complex manganese oxide produced by anodic deposition method was measured. The additive transition metal is Cu, Co and Fe. The transition metals like as Cu, Co and Fe improved electrical conductivity of complex manganese oxide compared with manganese oxide. This is coincide with the results of molecular orbital calculation by DV-Xa.

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Corrosion characterization of Fe-aluminide alloys with various sulphuric acid solution ($H_2SO_4$ 수용액 변화에 따른 철 알루미나이드 합금의 부식특성)

  • Lee, B.W.;Choi, H.L.
    • Journal of Power System Engineering
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    • v.10 no.2
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    • pp.83-88
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    • 2006
  • Corrosion characterization of Fe-XAl-0.3Y(X=5, 10, 14 wt%) alloys in $0.1{\sim}1N$ sulphuric acid at room temperature was studied using potentiodynamic techniques. The morphology and components of corrosion products on surface of Fe-aluminide alloys were investigated using SEM/EDX, XRD. The potentiodynamic polarization curve of alloys exhibited typical active, passive, transpassive behaviour. Corrosion potential($E_{corr}$) and corrosion current density($I_{corr}$) values of Fe-XAl-0.3Y alloys followed linear rate law. $E_{corr}$ of 10Al alloy and 14Al alloy was ten times lower than 5Al alloy. Icorr of 14Al alloy was five times lower than 5Al alloy. The passive film on the surface of Fe-5Al-0.3Y alloy was formed iron oxide. Fe-10Al-0.3Y and Fe-14Al-0.3Y alloys passive films were aluminium oxide. especially, Fe-14Al-0.3Y alloy showed good corrosion resistance in $0.1{\sim}1N$ sulphuric acid. This is attributed to the forming of protective $Al_2O_3$ oxide on the surface of Fe-14Al-0.3Y alloy.

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Measurements of fractional exhaled nitric oxide in pediatric asthma

  • Hahn, Youn-Soo
    • Clinical and Experimental Pediatrics
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    • v.56 no.10
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    • pp.424-430
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    • 2013
  • Exhaled nitric oxide (NO) has been extensively investigated as a noninvasive marker of airway inflammation in asthma. The increased NO expression induced by inflammatory mediators in airways can be monitored easily in exhaled air from asthmatic children. Based on the relationship between the increased NO expression and eosinophilic airway inflammation, fractional exhaled nitric oxide (FeNO) measurements become an important adjunct for the evaluation of asthma. In addition, the availability of portable devices makes it possible to measure FeNO more easily and frequently in the routine pediatric practice. Despite various confounding factors affecting its levels, FeNO can be applicable in diagnosing asthma, monitoring treatment response, evaluating asthma control, and predicting asthma exacerbations. Thus, although pulmonary function tests are the standard tools for objective measurements of asthmatic control, FeNO can broaden the way of asthma monitoring and supplement standard clinical asthma care guidelines.

Metal nano-wire fabrication and properties (금속 나노와이어의 제조와 특성)

  • Hamrakulov, B.;Kim, In-Soo
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.432-434
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    • 2009
  • Metal nano-wire arrays on Cu-coated seed layers were fabricated by aqueous solution method using sulfate bath at room temperature. The seed layers were coated on Anodic aluminum oxide (AAO) bottom substrates by electrochemical deposition technique, length and diameter of metal nano-wires were dominated by controlling the deposition parameters, such as deposition potential and time, electrolyte temperature. Anodic aluminum oxide (AAO) was used as a template to prepare highly ordered Ni, Fe, Co and Cu multilayer magnetic nano-wire arrays. This template was fabricated with two-step anodizing method, using dissimilar solutions for Al anodizing. The pore of anodic aluminum oxide templates were perfectly hexagonal arranged pore domains. The ordered Ni, Fe, Co and Cu systems nano-wire arrays were characterized by Field Emission Scanning Electron Microscopy (FE-SEM) and Vibrating Sample Magnetometer (VSM). The ordered Ni, Fe, Co and Cu systems nano-wires had different preferred orientation. In addition, these nano-wires showed different magnetization properties under the electrodepositing conditions.

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Water Splitting Capacity Improvement of Mn-Fe Oxide Prepared by Ball Milling with $ZrO_2$

  • Kang, Kyoung-Soo;Cho, Mi-Sun;Kim, Chang-Hee;Park, Chu-Sik
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1122-1123
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    • 2006
  • Mn-Fe oxide and Mn-Fe oxide/$ZrO_2$(50wt%/50wt%) were prepared by ball milling method. XRD data of the prepared samples revealed that hematite and ferrite phase coexisted. Water splitting at 1273K, after thermal reduction at 1573K, was performed 4 times for the samples. Hydrogen production amount was analyzed by GC with TCD detector. Water splitting capacity of Mn-Fe oxide was improved by ball milling with $ZrO_2$.

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A Surface Study of 304 and 316 Stainless Steel Oxidized between $300^{\circ}C$ and $500^{\circ}C$ ($300^{\circ}C$$500^{\circ}C$사이에서 산회된 304, 316 스테인리스강의 표면특성)

  • 김경록;이경구;강창석;최답천;이도재
    • Journal of the Korean institute of surface engineering
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    • v.32 no.1
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    • pp.43-48
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    • 1999
  • Oxidation behavior of 304 and 316 stainless steels was studied. After solution heat treatment, specimens were polished up to 1$mu \textrm{m}$ using $Al_2O_3$ powder and then subjected to oxidation between $300^{\circ}C$ and 50$0^{\circ}C$ in dry air. TEM and EDS were used for analyzing the components and structure of oxide film. TEM analysis of oxide film revealed that thin amorphous Fe oxide ($Fe_2O_3$) was formed on the top of surface while polycrystalline (Cr, $Fe_2O_3$ was formed below the amorphous Fe oxide layer. The specimens oxidized at $500^{\circ}C$ showed that 316 stainless steel had higher oxidation resistance than 304 stainless steel. These results suggest that Mo component of 316 stainless steel suppresses the formation of Cr carbide which may result in a local Cr depleted area.

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High-Temperature Corrosion Characteristics of T22 and T92 Steel in SO2-Containing Gas at 650 ℃ (650 ℃의 SO2 가스 환경 하에서 T22와 T92 강의 고온 부식특성)

  • Jung, Kwang-Hu;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.18 no.6
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    • pp.285-291
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    • 2019
  • In this study, the corrosion characteristics of T22 and T92 steel were investigated in 6O2 + 16CO2 + 2SO2 gas environment at 650 ℃. Corrosion characteristics were characterized by weight gain, oxide layer thickness, scanning electron microscope, optical microscope, energy dispersive X-ray spectroscopy, and X-ray diffraction. T22 and T92 steel tended to stagnate oxide layer growth over time. Oxidation kinetics were analyzed using the data of oxide layer thickness, and a regression model was presented. The regression model was significantly acceptable. The corrosion rate between the two steels through the regression model showed significant difference. The T92 steel was approximately twice as large as the time exponent and showed very good corrosion resistance compared to the T22 steel. In both steels, the oxide layer mainly formed a Fe-rich oxide layer composed of hematite (Fe2O3), magnetite (Fe3O4), and spinel (FeCr2O4). Sulfide segregation occurred in the oxide layer due to SO2 gas. However, the locations of segregation for the T22 and T92 steel were different.

A study on the nature of needle-like inclusions in corundum crystals (커런덤의 침상내포물 본질에 관한 연구)

  • 배상덕;김상기;최종건;김판채
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.3
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    • pp.101-104
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    • 2004
  • It was realized that MC-XRD is useful for phase analyzing of inclusions in crystals because it can focus the X-Ray beam to the small particles sized dozens of $\mu\textrm{m}$ with high S/N ratio. By using this MC-XRD, needle-like inclusions which are seen generally in corundum crystals known as rutile was found to be the iron titanium oxide and iron oxide which has the chemical composition of $Fe_2TiO_4,\; Fe_2TiO_5,\; Fe_2O_3$respectively

An Oxidation Behavior with Heat-treatment in STS 304 and 316 (STS 304, 316강의 열처리에 따른 산화거동)

  • Lee, Kyung-Ku;Yoon, Dong-Ju;Ghi, Whe-Bong;Kang, Chang-Sug;Lee, Doh-Jae
    • Journal of the Korean Society for Heat Treatment
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    • v.11 no.3
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    • pp.186-191
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    • 1998
  • An oxidation behavior of 304 and 316 stainless steels were studied in dry air. After solution treatment, specimens were polished up to $1{\mu}m$ $A1_2O_3$ grade and then subjected to oxidation treatment in dry air at $800^{\circ}C{\sim}1200^{\circ}C$. The oxidation behavior between matrix and oxide scale was analyzed with SEM, EDS and XRD. When oxidation treatment was conducted at $1200^{\circ}C$, large thickness of Fe oxide scale was formed on top of surface and fine $(Cr,Fe)_2O_3$ oxide film was formed below it. Cr rich zone existed at interface between metal and $(Cr,Fe)_2O_3$ oxide layer, and it was believed that this zone acted as obstacle to oxidation. Most of Ni was detected at the interface between metal and $(Cr,Fe)_2O_3$ and also detected at the interface between $Fe_2O_3$ and $(Cr,Fe)_2O_3$.

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A Study on the Oxide Scale of the Long Term Serviced 12%Cr Boiler Tube Steel (장기간 사용한 12%Cr강 보일러 튜브의 산화스케일에 관한 연구)

  • Kim, Beom-Soo;Min, Taek-Ki
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.24 no.3
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    • pp.281-287
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    • 2012
  • The internal oxide scale of twelve superheater and reheater tubes were tested which were serviced for 30,000~120,000 hours in thermal power plants. The oxide scale was formed in three layers. The Cr-rich area was observed beneath the original metal surface. The hematite ($Fe_2O_3$) phase was formed on the outer surface. The intermediate layer was magnetite ($Fe_3O_4$). The thickness of Cr-rich layer was about half of the total scale. All layers grew during the operation hour of the plant. The thickness of thickest scale was 0.2mm in superheater tubes. This can increase the tube metal temperature about $7^{\circ}C$ more than initial state. $7^{\circ}C$ tube metal temperature can reduce tube life about 30%, but the boiler tube's design margin is big enough therefore it has been analyzed that it would not effect on the life span.