• Journal of the Korean Society of Industry Convergence
• /
• v.23 no.6_2
• /
• pp.927-934
• /
• 2020

Magnesium powder has been widely used in various industries because it is light weight and extremely high mechanical strength including aeronautics and chemicals. However, magnesium, as a combustible metal, poses serious safety issues such as fires and explosions if it is not managed properly. Especially, magnesium's max adiabatic flame temperature is 3,340℃ and it is impossible to extinguish it by using water, CO2 and Halonagents. The aim of this study is to identify the combustion characteristics of magnesium powder. We carried out a combustion experiment, using 1 kg of magnesium (purity > 99 %, particle < 150 ㎛). The features of the magnesium burning process were scrutinized using infrared thermal image analysis. Also, a field-emission scanning electron microscope (FE-SEM) were used employed to analyze particulate composites and properties. It concludes the significant tendency of magnesium fire and light, combustion carbide's particle characteristics. This study contributes to make better prevention and response manners to magnesium fires, as well as fire investigation measures.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2003.06a
• /
• pp.1865-1868
• /
• 2003

This paper provides a new method for hybrid machining, particularly suited to micro fabrication applications such as micro point, micro line, micro structure, micro partition and so on. Developed micro fabrication process by electrical discharge machining (EDM) and electrical discharge deposition (EDD) with metal powder (Ti, Fe) has been studied to build TiC or FeC structure. Titanium powder or iron powder is supplied from working fluid (kerosene or de-ionized water with powder) and adheres on a workpiece by the heat and electric power caused by the electrical discharge. The use of a tool electrode is expected to keep powder concentration high in the gap between a workpiece and a tool electrode and to accrete powder material on the workpiece. The deposition is tried under various electrical conditions (workpiece. tool electrode, working fluid, discharge current, voltage and powder etc.). On the other hand. using electrical discharge machining (EDM) with the same tool electrode, it can be used as a removal process (cutting) by electro erosion at the same time. Therefore. this new method can do a hybrid machining to build up and down a structure with the workpiece.

• Journal of Environmental Health Sciences
• /
• v.30 no.5 s.81
• /
• pp.358-365
• /
• 2004

The photocatalytic oxidation of Rhodamine B(RhB) was studied using photocatalytic reactor filled with module of quartz tube. Module of quartz tube consisted of small quartz tube (inner diameter, 1.5 mm; outer diameter, 3 mm) bundle coated with powder $TiO_2$ and uncoated large quartz tube (inner diameter, 20 mm; outer diameter, 22 mm). Two 30 W germicidal lamp was used as the light source and the reactor volume was 0.5 l. The effects of parameters such as the coating materials and numbers, initial concentration, $H_{2}O_2$ dose and metal deposition (Ag, Pt and Fe) and simultaneous application of $H_{2}O_2$ and metal deposition. The results showed that the initial reaction constant of quartz module coated with powder $TiO_2$ was higher 1.4 time than that of the $TiO_2$ sol and optimum coating number is twice. In order to increase reaction rate, simultaneous application of photocatalytic and photo-fenton reaction using Fe coating and dose $H_{2}O_2$ dose increased reaction rate largely.

• Journal of Powder Materials
• /
• v.20 no.4
• /
• pp.280-284
• /
• 2013

Stress-strain curves are fundamental properties to study characteristics of materials. Flow stress curves of the powder materials are obtained by indirect testing methods, such as tensile test with the bulk materials and powder compaction test, because it is hard to measure the stress-strain curves of the powder materials using conventional uniaxial tensile test due to the limitation of the size and shape of the specimen. Instrumented nanoindentation can measure mechanical properties of very small region from several nanometers to several micrometers, so nanoindentation technique is suitable to obtain the stress-strain curve of the powder materials. In this study, a novel technique to obtain the stress-strain curves using the combination of instrumented nanoindentation and finite element method was introduced and the flow stress curves of Fe powder were measured. Then obtained stress-strain curves were verified by the comparison of the experimental results and the FEA results for powder compaction test.

• Journal of Powder Materials
• /
• v.25 no.5
• /
• pp.375-378
• /
• 2018

Conductive and dielectric SiC are fabricated using electroless plating of Ni-Fe films on SiC chopped fibers to obtain lightweight and high-strength microwave absorbers. The electroless plating of Ni-Fe films is achieved using a two-step process of surface sensitizing and metal plating. The complex permeability and permittivity are measured for the composite specimens with the metalized SiC chopped fibers dispersed in a silicone rubber matrix. The original non-coated SiC fibers exhibit considerable dielectric losses. The complex permeability spectrum does not change significantly with the Ni-Fe coating. Moreover, dielectric constant is sensitively increased with Ni-Fe coating, owing to the increase of the space charge polarization. The improvements in absorption capability (lower reflection loss and small matching thickness) are evident with Ni-Fe coating on SiC fibers. For the composite SiC fibers coated with Ni-Fe thin films, a -35 dB reflection loss is predicted at 7.6 GHz with a matching thickness of 4 mm.

• Journal of Powder Materials
• /
• v.30 no.1
• /
• pp.1-6
• /
• 2023

High-entropy alloys (HEAs) are attracting attention because of their excellent properties and functions; however, they are relatively expensive compared with commercial alloys. Therefore, various efforts have been made to reduce the cost of raw materials. In this study, MIM is attempted using coarse equiatomic CoCrFeMnNi HEA powders. The mixing ratio (powder:binder) for HEA feedstock preparation is explored using torque rheometer. The block-shaped green parts are fabricated through a metal injection molding process using feedstock. The thermal debinding conditions are explored by thermogravimetric analysis, and solvent and thermal debinding are performed. It is densified under various sintering conditions considering the melting point of the HEA. The final product, which contains a small amount of non-FCC phase, is manufactured at a sintering temperature of 1250℃.

• Journal of the Korean Society for Heat Treatment
• /
• v.34 no.1
• /
• pp.17-24
• /
• 2021

In this study, Ti-X (X=Mn, Fe, Mo) powder alloys were designed and manufactured by both powder metallurgy (PM) and metal powder injection molding (MIM) process to improve strength and formability compared to CP-Ti powder materials. It was found that the lamellar microstructure consisted of α and β phases was formed in PM-processed alloys. However, MIM-processed alloys showed not the lamellar microstucture but the equiaxed α + β microstructure. It was also revealed that the contents of X component and feedstock were not affected to microstructure evolution. The reason why different microstructure was appeared between PM-processed and MIM-processed alloys is not clear yet, but supposed to be the effect of intersticial elements such as C, H and N derived from feedstock during debinding process of MIM.

• Journal of Powder Materials
• /
• v.12 no.6 s.53
• /
• pp.399-405
• /
• 2005

Nanopowders of titanium dioxide $(TiO_2)$ incorporating the transition metal element(s) were synthesized by flame synthesis method. Single element among Fe(III), Cr(III), and Zn(II) was doped into the interior of $TiO_2$ crystal; bimetal doping of Fe and Zn was also made. The characteristics of transition-metal-doped $TiO_2$ nanopowders in the particle feature, crystallography and electronic structures were determined with various analytical tools. The chemical bond of Fe-O-Zn was confirmed to exist in the bimetal-doped $TiO_2$ nanopowders incorporating Fe-Zn. The transition element incorporated in the $TiO_2$ was attributed to affect both Ti 3d orbital and O 2p orbital by NEXAFS measurement. The bimetal-doped $TiO_2$ nanopowder showed light absorption over more wide wavelength range than the single-doped $TiO_2$ nanopowders.

• Proceedings of the Korean Powder Metallurgy Institute Conference
• /
• 2006.09a
• /
• pp.383-384
• /
• 2006

Fe-4Ni-0.5Mo-1Cu powder was selected as raw material, pressed and sinter-hardened at $1135\;^{\circ}C$ for 30 min with rapid cooling. The density varies in the range of $7.24-7.29\;g/cm^3$. Its fatigue properties have been tested in axial loading of alternating tensile/compressive stress at R=-1 with a servo-pulse pump. The fatigue endurance limit was measured to be 260 MPa. The microstructure showed more homogeneous bainite and martensite. Fractography displayed the fatigue cracks initiated from the pore areas near the surface. A non-typical ductile fatigue striation was found. More dimples occurred on fracture surface due to the plastic deformation, which can prohibit cracking propagation and improve its fatigue properties.

• Proceedings of the Korean Powder Metallurgy Institute Conference
• /
• 2000.11a
• /
• pp.11-12
• /
• 2000

Non-stoichiometric ceramics of $Ni_{x}ZnO_{1-x}Fe_{2}O_{4}$ were prepared by self-propagating high temperature synthesis reaction with various processing conditions and their stoichometric numbers were determined by neutron diffraction. The neutron diffraction patterns were measured at room temperature using monochromatic neutrons with a wave length of 0.18339 nm from a Ge(331) mocochromator at a 90 degree take off angle. The Rietveld refinement of each pattern converged to good agreement (x2=1.88-2.24). The neutron diffraction analysis revealed the final stoichiometries of the ferrites were $Ni_{0.38}Zn_{0.62}Fe_{2}O_{4}$ and $Ni_{0.33}Zn_{0.67}Fe_{2}O_{4]$, respectively. This supports that final stoichiometric number of the self-propagating high temperature synthesis product can be controlled by the processing parameters during the combustion reaction.