• Title/Summary/Keyword: Fe content

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Driving Forces for γ→ε Martensitic Transformation of Fe-Mn Alloys (Fe-Mn 합금의 γ→ε 마르텐사이트변태에 필요한 구동력)

  • Lee, Young-Kook;Choi, Chong-Sool
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.4
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    • pp.243-251
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    • 1996
  • Dilatometric experiment and thermodynamic calculation have been performed to determine $M_s$, $A_s$ and driving forces for ${\gamma}{\rightarrow}{\varepsilon}$ martensitic transformation of Fe-Mn alloys. The transformation temperatures($M_s$, $A_s$, $T_o) were decreased with increasing manganese content and were newly formulated as a function of manganese content. Driving force for ${\gamma}{\rightarrow}{\varepsilon}$ martensitic transformation was increased from -75J/mole to -105J/mole with increasing manganese content from 15wt.% to 25wt.%. Transformation temperature hysteresis($A_s-M_s$) was also increased from 50K to 80K with increasing mangenese content from 15wt.% to 25wt.%. The small driving force(-75J/mole~-105J/mole) and small ${\Delta}T$(50K~80K) for ${\gamma}{\rightarrow}{\varepsilon}$ martensitic transformation indicated that Fe-Mn alloys behave like thermoelastic martensitic alloys : We would like to call them semi-thermoelastic martensitic alloys.

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Sintering Behavior of the Injection Molded W-Ni-Fe Heavy Alloy by Addition of Metallic Stat (금속 염 첨가 방법을 이용하여 사출성형된 텅스텐 중합금의 소결거동)

  • 김대건;류성수;김은표;이정근;김영도;문인형
    • Journal of Powder Materials
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    • v.6 no.4
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    • pp.294-300
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    • 1999
  • This study was carried out to investigate the possibility whether Metal Injection Molding (MIM) process could be applied to 95wt.%W-3.5wt.%Ni-1.5wt.%Fe heavy alloy in order to obtain an intricate shape. Methylcellulose was used in the injection molding for binder. $FeCl_2-4H_2O$ was added in solvent substituting Fe powder and $FeCl_2$ was doped on W-Ni premixed powder. When $FeCl_2-4H_2O$ was added in solvent, the binder separation occurred for injection molding so that the matrix content was changed. Such problem was solved when $FeCl_2$ was doped. In this study. the debinding process did not affect residual carbon content. The sintered microsouctures as addition methods of Fe element and the sintering temperature from $1420^{\circ}C$ to $1470^{\circ}C$, which are around the temperature of liquid phase formation, were observed.

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A Study on the Electrodeposition of NiFe Alloy Thin Films Using Chronocoulometry and Electrochemical Quartz Crystal Microgravimetry

  • Myeong, No Seung
    • Bulletin of the Korean Chemical Society
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    • v.22 no.9
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    • pp.994-998
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    • 2001
  • Ni, Fe and NiFe alloy thin films were electrodeposited at a polycrystalline Au surface using a range of electrolytes and potentials. Coulometry and EQCM were used for real-time monitoring of electroplating efficiency of the Ni and Fe. The plating efficiency of NiFe alloy thin films was computed with the aid of ICP spectrometry. In general, plating efficiency increased to a steady value with deposition time. Plating efficiency of Fe was lower than that of Ni at -0.85 and -1.0 V but the efficiency approached to the similar plateau value to that of Ni at more negative potentials. The films with higher content of Fe showed different stripping behavior from the ones with higher content of Ni. Finally, compositional data and real-time plating efficiency are presented for films electrodeposited using a range of electrolytes and potentials.

Composition and magnetic ProPerties of CoFecu alloys according to electrolysis conditions (전해조건에 따른 CoFeCu 함금박막의 조성, 우선방위 및 자기적 특성)

  • 예길촌
    • Journal of the Korean institute of surface engineering
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    • v.30 no.1
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    • pp.3-12
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    • 1997
  • The composition, the preferred orientation and the magnetic properties of the CoFeCu alloys electrodepositen under various electrolysis conditions in sulfate baths ware investigated. As the D.C. current density increased, the Co content in alloy electrodeposits increased, while the Cu content decreased and Fe content remained content. The effect of magnetic field up to 300 Oe on the composition of alloys was negligible. The Cu content of the alloys deposited in pulse current increased noticeably with increasing off-time, while the Co and Fe content decreased. The coercivity of the alloys with 3.5 to 7.0wt.% Cu was 1.0 to 2.0 Oe, but increased noticeably above and below that composition. The application of magnetic field during deposition decreased the coercivity of alloys. The saturation flux density of the alloys with 3.5 to 5.0wt.% Cu was relatively high in the range from 16 to 20.7Gauss. The anisotropy field(HK) of the alloys deposited under the magnetic field(50∼300 Oe) ranged from 18 to 22 Oe. The alloys had fcc structure with (111) preferred orientation, whose distribution increased a little with increasing magnetic field.

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The Effect of Level and Period of Fe-methionine Chelate Supplementation on the Iron Content of Boiler Meat

  • Seo, S.H.;Lee, H.K.;Lee, W.S.;Shin, K.S.;Paik, I.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.21 no.10
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    • pp.1501-1505
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    • 2008
  • A broiler experiment was conducted to compare the effects of duration and level of iron-methionine chelate (Fe-Met) supplementation on the iron, copper (Cu) and zinc (Zn) content of broiler meat. Two hundred and fifty hatched Ross broiler chickens were randomly assigned to 5 dietary treatments. Each treatment had 5 replicates of 10 birds (5 males and 5 females) each. Birds were housed in raised floor batteries and fed traditional broiler diets ad libitum for 5 weeks. Dietary treatments were as follows: Control and two levels of Fe-Met (100 or 200 ppm in Fe) supplemented for either the whole period (0-5 wk) or grower period (4-5 wk). Production performance was not significantly affected by treatments. Iron content in the muscles (breast, leg and wing) and organs (liver and spleen) were significantly (p<0.05) increased as the level and duration of Fe-Met supplementation increased. The highest concentration of iron was shown in Fe-Met 200 fed for the whole period. Liver contained the highest amount of iron followed by spleen, leg muscle, wing muscle and breast muscle. Supplementation of Fe-Met 200 for the grower period resulted in higher iron concentration in liver and spleen than supplementation of Fe-Met 100 for the whole period. However, the same treatment resulted in lower iron concentration in muscles (breast, leg and wing) than the treatment of Fe-Met 100 for the whole period. In order to achieve the highest iron enrichment in the muscles, Fe-Met should be supplemented at 200 ppm in Fe for the whole period (5 wks). Fe-Met supplementation increased copper concentration in all muscles and organs except wing muscle. Zinc concentration decreased in breast and wing muscle but tended to increase in leg muscle, liver and spleen by Fe-Met 200 supplementation. Color of muscle was not significantly affected by Fe-Met treatments. However, redness of leg and breast muscle, and yellowness of leg and breast muscle tended to increase by supplementation of Fe-Met for the whole period. It was concluded that iron content of broiler meat can be effectively enriched by supplementation of 200 ppm of Fe as Fe-Met for 5 wks.

Variation of Magnetic Properties of Fe-Si Compressed Cores with Si Content (Si 함량에 따른 Fe-Si 압분코어의 자기적 특성)

  • Jang, Pyung-Woo;Lee, Bong-Han;Choi, Gwang-Bo
    • Journal of the Korean Magnetics Society
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    • v.20 no.1
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    • pp.13-17
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    • 2010
  • Fe-3, 4.2 and 6.8% Si compressed cores were fabricated, and then electrical resistivity, AC and DC magnetic properties, microhardness, and other properties were analyzed in order to know whether best soft magnetic properties could be also obtained in an Fe-Si compressed core with the well-known composition of Fe-6.5% Si. With increasing the silicon content, eddy current loss and hysteresis loss decreased and increased, respectively, so that a minimum total loss was not obtained in the well-known Fe-6.8 % Si cores, but obtained in the Fe-4.2 % Si cores. Also electrical resistivity of the cores and hardness of the particles increased monotonously with silicon content so that compaction ratio of the cores decreased. B2 and $DO_3$ ordered phase could be observed only in Fe-6.8% Si powder. A minimum loss and highest permeability of the Fe-4.2 % Si cores can be explained by the ratio of specific electrical resistivity of insulator to that of magnetic particles, micro-hardness, compaction ratio and demagnetization coefficient of the Fe-Si powder particles with silicon content.

The Effects of Fe and V on the Characteristics of $\beta$to$\alpha$ Transformation for Zr-0.8Sn Alloys (Fe와 V이 Zr-0.8Sn 합금의 $\beta{\rightarrow}\alpha$ 상변태 특성에 미치는 영향)

  • O, Yeong-Min;Kim, Seon-Jin
    • Korean Journal of Materials Research
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    • v.10 no.9
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    • pp.636-641
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    • 2000
  • The effects of Fe and V content on the characteristics of $\beta$ to $\alpha$ phase transformation for Zr-0.8Sn alloys were studied by optical and transmission electron microscopy. With increasing V content, $\beta{\rightarrow}\alpha+\beta$ transformation temperature decreased, thus allowing the width of $\alpha$-lath to be fine air-cooled Zr-0.8Sn-xV alloys. The width of $\alpha$-lath, however, was slightly increased with Fe content. While the $\beta$ to $\alpha$ transformed microstructures of water-quenched Zr-0.8Sn, Zr-0.8Sn-0.1Fe, Zr-0.8Sn-0.2Fe, Zr-0.8Sn-0.4Fe, Zr-0.8Sn-0.1V and Zr-0.8Sn-0.2V were mainly slipped martensite, that of water-quenched Zr-0.8Sn-0.4V was predominantly twinned martensite. The transition of slipped martensite to twinned martensite in Zr-0.8Sn-Xv was thought to be due to the decrease of $M_S$ temperature.

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Bioavailability of Iron-fortified Whey Protein Concentrate in Iron-deficient Rats

  • Nakano, Tomoki;Goto, Tomomi;Nakaji, Tarushige;Aoki, Takayoshi
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.7
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    • pp.1120-1126
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    • 2007
  • An iron-fortified whey protein concentrate (Fe-WPC) was prepared by addition of ferric chloride to concentrated whey. A large part of the iron in the Fe-WPC existed as complexes with proteins such as ${\beta}$-lactoglobulin. The bioavailability of iron from Fe-WPC was evaluated using iron-deficient rats, in comparison with heme iron. Rats were separated into a control group and an iron-deficiency group. Rats in the control group were given the standard diet containing ferrous sulfate as the source of iron throughout the experimental feeding period. Rats in the iron-deficiency group were made anemic by feeding on an Fe-deficient diet without any added iron for 3 wk. After the iron-deficiency period, the iron-deficiency group was separated into an Fe-WPC group and a heme iron group fed Fe-WPC and hemin as the sole source of iron, respectively. The hemoglobin content, iron content in liver, hemoglobin regeneration efficiency (HRE) and apparent iron absorption rate were examined when iron-deficient rats were fed either Fe-WPC or hemin as the sole source of iron for 20 d. Hemoglobin content was significantly higher in the rats fed the Fe-WPC diet than in rats fed the hemin diet. HRE in rats fed the Fe-WPC diet was significantly higher than in rats fed the hemin diet. The apparent iron absorption rate in rats fed the Fe-WPC diet tended to be higher than in rats fed the hemin diet (p = 0.054). The solubility of iron in the small intestine of rats at 2.5 h after ingestion of the Fe-WPC diet was approximately twice that of rats fed the hemin diet. These results indicated that the iron bioavailability of Fe-WPC was higher than that of hemin, which seemed due, in part, to the different iron solubility in the intestine.

The Characteristics of Distribution on the Heavy Metals in Soil of Kumho River Basin (금호강안의 토양중 중금속 분포특성)

  • 양성호;강선태;권오억
    • Journal of Environmental Health Sciences
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    • v.16 no.2
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    • pp.83-87
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    • 1990
  • This study was carried out to investigate the pollution of heavy metals in soil of seven stations from the upper spot (Yeungchun Dam) of Kumho River to the downstream(Gangchang Bridge). The results obtained were as follows: 1. The content of heavy metals in soil of Kumho River basin was highest at Gangchang Bridge [expresed in $\mu$g/g : Mn(246.0), Cd(1.90), Fe(551.2), Cu(108.2), Zn(86.4), Cr(80.2), respectively]. Whereas, the content of heavy metals expect for Mn, Cu was lowest at Yeungchun Dam [Cd(0.40), Fe(548.0), Zn(30.7), Cr(6.2), respectively] Also, the content of Cr, Zn was increased when the sampling areas are changed from upstream to downstream except for Hayang Bridge, and Hayang Bridge was the diverging point of the heavy metals content. 2. There were relatively correlated between Mn : FE, Cu, Zn, Cr, Fe : Cu, Zn, Cr(0.40 < $\left$\mid${r}\right$\mid$$ < 0.70), and were high correlated between Cd : Mn, Fe, Cu, Zn, Cu : Zn, Zn : Cr(0.70 < $\left$\mid${r}\right$\mid$$ < 0.90). Particularly, there was higest correlated between Cd : Cr, Cu : Cr(0.90< $\left$\mid${r}\right$\mid$$ < 1.0)

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Effect of ε Martensite Content and Strain Amplitude on Damping Capacity of Fe-17%Mn Alloy (Fe-17%Mn 합금의 진동감쇠능에 미치는 ε 마르텐사이트 함량과 진폭변형율의 영향)

  • Jun, Joong-Hwan;Lee, Young-Kook;Choi, Chong-Sool
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.2
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    • pp.112-120
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    • 1996
  • The effects of ${\varepsilon}$ martensite content and strain amplitude on damping capacity of an Fe-17%Mn alloy have been studied to establish damping mechanism of Fe-Mn system corresponding to the magnitude of strain amplitude. In a range of $1{\times}10^{-4}{\sim}3{\times}10^{-4}$ strain amplitude, the damping capacity is linearly proportional to the ${\varepsilon}$ martensite content, which suggests that stacking faults and ${\varepsilon}$ martensite variant boundaries are the principal damping sources. In the range of $4{\times}10^{-4}{\sim}6{\times}10^{-4}$ strain amplitude, however, a maximum damping capacity is observed around 68 vol.% ${\varepsilon}$. This behavior is very similar to dependence of relative area of ${\gamma}/{\varepsilon}$ interface on ${\varepsilon}$ martensite content. This means that in this strain range, ${\gamma}/{\varepsilon}$ interface acts as damping source in addition to the stacking faults and variant boundaries in Fe-17%Mn alloy.

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