• Title/Summary/Keyword: Fe content

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Effects of Copper Addition on Damping Capacities, Atmospheric Corrosion and Mechanical Properties of Fe-17wt % Mn Alloy (Fe-17wt%Mn 합금의 진동감쇠능, 내후성 및 기계적 성질에 미치는 Cu 첨가의 영향)

  • Baik, S.H.;Kim, J.C.;Jee, K.K.;Choi, C.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.2
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    • pp.113-119
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    • 1995
  • We have reported that an Fe-17wt%Mn alloy exhibits the highest damping capacity in the Fe-Mn binary system. In the present work, the effects of copper content on the damping capacity, atmospheric corrosion and mechanical properties were studied. The damping capacities were measured at room temperature for the air cooled Fe-17wt%Mn alloy having copper content from 0.1wt% to 1.1wt%. The damping capacity of the Fe-17wt %Mn alloy was decreased with increasing copper content. However, the addition of Copper was found to improve mechanical properties and atmospheric corrosion resistance. These mechanical properties were attributed to the formation of stress-induced martensite during tensile test.

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Chemical Properties in the Soils of Reclaimed and Natural Tidelands of Southwest Coastal Area of Korea (II) - Distribution of Phosphorus Fractions - (우리나라 서남해안 간척지 및 간석지 토양의 화학적 특성 (II) - 인의 형태별 함량 분포 -)

  • Cho Jae-Young;Koo Ja-Woong;Son Jae-Gwon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.48 no.2
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    • pp.3-9
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    • 2006
  • The chemical fractions of phosphorus were investigated in the soils of reclaimed and natural tidelands of southwest coastal area of Korea. The content of total-P varied to ranged from 322 to 614 mg/kg dry weight with a mean value of 467 mg/kg. The order of different fractions of phosphorus in reclaimed tideland soils was as follows: 1) inorganic phosphorus: Ca-P > Fe-P > Al-P > reductant soluble Fe-P. 2) organic phosphorus: Inositol-P > nucleic acid-P > phospholipid-P. The content of Al-P showed negative correlation with organic matter content but showed positive correlation with pH. The content of Fe-P showed negative correlation with clay mineral content but showed positive correlation with organic matter content. Reductant soluble Fe-P and Ca-P were no correlation with soil properties. The content of inositol-P showed highly positive correlation with clay mineral, organic matter content, and CEC.

Effect of $CO_2$ Content on the Growth and Corrosion Characteristics of the Compound Layers in Gaseous Nitrocarburized Carbon Steels (가스 질화침탄처리한 탄소강의 화합물층 성장 및 부식특성에 미치는 $CO_2$함량의 영향)

  • Kim, Y.H.;Kim, S.D.;Yoon, H.J.
    • Journal of the Korean Society for Heat Treatment
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    • v.15 no.5
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    • pp.219-227
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    • 2002
  • This study has been performed to investigate the effect of $CO_2$ content on the growth characteristics of the compound layer, porous layer and corrosion characteristics of carbon steels after gaseous nitrocarburizing in $70%-NH_3-CO_2-N_2$ at $580^{\circ}C$ for 2.5 hrs. The results obtained from the experiment were the thickness of the compound and porous layers increased with increasing $CO_2$ contents. At the same fixed gas composition the thickness of the compound and porous layer increased with increasing carbon content of the specimens. X-ray diffraction analysis showed that compound layer was mainly consisted of ${\varepsilon}-Fe_{2-3}(N,C)$ and ${\gamma}^{\prime}-Fe_4N$ as the increased with $CO_2$ contents in atmosphere, compound layer was chiefly consisted of ${\varepsilon}-Fe_{2-3}(N,C)$ phase. With increasing $CO_2$ content and total flow rate in gaseous nitrocarburizing, the amount of ${\varepsilon}-Fe_{2-3}(N,C)$ phase in the compound layer was increased. The current density of passivity decreased with increasing $CO_2$ content due to the development of porous layer at the out most surface of ${\varepsilon}-Fe_{2-3}(N,C)$.

Anaysis of Fe in Seepage Water and Precipitates around a Hydrothermal Alteration Zone

  • Yun, Hyun-Seok;Moon, Seong-Woo;Lee, Jin-Kook;Jeong, Gyo-Cheol;Seo, Yong-Seok
    • The Journal of Engineering Geology
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    • v.27 no.3
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    • pp.345-351
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    • 2017
  • Acid drainage in civil engineering structures such as tunnels may lead to the deposition of precipitates that clog drainage channels and pipework. In evaluating acid drainage, the Fe content of water and precipitates, indicated by reddish brown coloration of rock surfaces, rivers, and soils, may be an important factor. In this study, acid drainage was evaluated by analyzing the Fe content of reddish brown seepage water that occurred in part of a tunnel. Geological investigations around the tunnel revealed a hydrothermal alteration zone cutting the bedrock, and cropping out in the upper parts of the tunnel. Analysis of drillcore revealed many fracture zones and veins. Inductively coupled plasma spectrophotometric analyses of water, precipitates, and soil samples, collected in the seepage water zone and around the tunnel, were conducted to evaluate acid drainage. The Fe content of seepage water in the tunnel was 0.030-0.333 mg/kg, which is 2-22 times higher than in local groundwater. The Fe content of precipitates in the tunnel was 165,403-301,051 mg/kg, similar to the 206,167-422,964 mg/kg content of drillcore from the hydrothermal alteration zone located above the tunnel. It is concluded that the seepage water is derived from Fe-containing acid drainage flowing in perforated tunnel drainpipes along the fracture zones and veins around the hydrothermal alteration zone.

Effect of Carbon on the Coefficient of Thermal Expansion of As-Cast Fe-3 0 wt.%Ni-12.5wt.% Co-xC Invar Alloys

  • 김봉서;유경재;김병걸;이희웅
    • Transactions of Materials Processing
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    • v.8 no.3
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    • pp.247-247
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    • 1999
  • The segregation (distribution) of nickel and the composition of its constituents influence the low thermal expansion characteristics (Invar effect) in Fe-30 wt.% Ni-12.5 wt.% Co-xC Invar alloy. The change of coefficient of the thermal expansion and magnetic properties were studied as an aspect of carbon addition causing the segregation of Ni in primary austenite of as-cast Fe-30 wt.% Ni-12.5 wt.% Co Invar alloy. The coefficient of thermal expansion of Fe-30 wt.% Ni-12.5 wt.% Co-xC Invar alloy showed its lowest value at 0.08 wt.% carbon, increased with increasing carbon content in the range of 0.08-1.0 wt.%C, kept constant at 1.0-2.0 wt.%C and decreased at carbon higher than 2.0 wt.%. The effective distribution of the coefficient of nickel in as-cast Fe-30 wt.% Ni-12.5 wt.% Co-xC Invar alloy increased with increasing carbon content. The volume fraction of they phase of Fe-30 wt.% Ni-12.5 wt.% Co-xC alloy increased with increasing carbon content. The microstructure of Fe-30 wt.% Ni-12.5 wt.% Co-xC alloy changed with the carbon content was independent of the coefficient of thermal expansion. The Curie temperature changed linearly with the carbon content and was similar to the change of the coefficient of thermal expansion. Moreover, the coefficient of thermal expansion decreased when the ratio of saturation magnetization to Curie temperature ($\sigma_s/T_c$) increased, decreasing the Curie temperature and showed a specific relationship with the magnetic properties of the Fe-30 wt.% Ni-12.5 wt.% Co-xCInvar alloy.

FTIR and M ssbauer Spectroscopic Studies on the Hydrothermal Epidote from the Bobae Clay Deposit, Pusan, Korea (보배광산에서 산출하는 열수변질 기원 녹염석의 분광학적 특성: 적외선 및 뫼스바우어 연구)

  • 추창오;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.9 no.2
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    • pp.55-63
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    • 1996
  • Epidote occurs as veinlets in the propylitic alteration zone of the Bobae clay deposit, Pusan, Korea. Its cell parameters apparently decrease with the contents of Al, Fe, and Ca. Fourier transform infrared (FTIR) spectra show one hydrosyl environment related to AlM2 at 3357-3358 cm-1. In the mid-infrared region, the peaks at 950 and 1030 cm-1 sharper with increasing Al shifting to higher energy region. The peak at 885 cm-1 shifts slightly to a lower energy region with a decreasing intensity as the Fe content increases. In the far-IR region, epidote exhibits absorption bands at 120 and 140 cm-1, which are related to the Ca-O bonds in A-sites.M ssbauer spectra of epidote show that the isomer shifts of Fe3+ range from 0.36-0.37 at the M3 site and from 0.35-0.44 at M1 site. Fe2+ shows the isomer shift ranging from 1.11 to 1.13. Quadrupole splitting is 2.04 for Fe3+M3, 0.52-0.70 for Fe3+M1, and 2.61-2.70 for Fe2+M3. Calculation shows Fe3+M386-90.7%, Fe3+M12.5-3.6%, and Fe2+M35.8-11.4% of total iron, showing preferential distribution of Fe3+ in the M3 site. The Fe3+M3 content is between 0.486 and 0.513 per formula unit. in the Fe-rich epidote, less Fe3+ and more Fe2+ are accommodated in the M1 and M3 sites. Hence, the overall disorder increases as total Fe content increase. The ordering parameter of the Bobae epidote is 0.93-0.95, suggesting a disequilibrium state below 200$^{\circ}C$. The constant temperature over a long period may be essential for the transition from disordered state to equilibrium state, despite the possible variation in flux and composition of the hydrothermal fluid.

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Studies on the Ouality of Boxthorn in Korea(Lycium chinense Miller) (한국 구기 품종의 품질에 관한 연구)

  • 이상래
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.28 no.2
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    • pp.267-271
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    • 1983
  • The southern parts varieties have shown higher content of Oleic acid, Linoleic acid, Vitamin A, Alcaloid, Ca, P and Fe than northern parts Varieties. The $N.\;P_2O_5\;and\;K_2O content of narrow leaf were higher than wide leaf, on the other hand the Ca, Mg, Fe and $SiO_2$ content of wide leaf were higher than narrow leaf. The content of $N, \;P_2O_5, \;K_2O$ have shown higher in first yellow leaf date, the content of Ca has shown higher in first falling leaf date and the content of Mn and Cu content have shown higher in second new leaf date.

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Effects of Iron, Silicon and Zinc Contained in Molten Aluminum on Aluminizing of Cast Iron (주철 소지상에 용융알루미늄 도금시 철 규소 및 아연의 영향)

  • Choi, Chong-Sool;Moon, Sung-Wuck
    • Journal of the Korean institute of surface engineering
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    • v.20 no.4
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    • pp.144-153
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    • 1987
  • In the case of dipping the Ni-Resist cast iron into molten aluminum with iron content, the thickness of intermetallic compound was remarkably increased with increasing iron content. The thickness was shown by following equation in the range of 1-3% iron content; $x=22.5t^{1/2}+4.47{\cdot}t{\cdot}(Fe%)$. where, x is thickness(${\mu}m$), t the time (minute), Fe% the iron w/o. When the Ni-Resist cast iron was dipped into the molten aluminum containing zinc content, the intermetallic compound thickness was also increased with increasing zinc contents. And thickness was represented by the following equation in the range of 2-10% zinc content; $x=3.46t^{1/2}+0.27{\cdot}t{\cdot}(Zn%)$. However, in the case of dipping the Ni-resist cast iron into molten aluminum with silicon content, the thickness of intermetallic compound was decreased with increasing silicon content, as shown in the following equation; $x=7.17t^{1/2}-0.15{\cdot}t{\cdot}(Si%)$. The intermetallic compound formed onto Ni-Resist cast iron was identified to be $FeAl_3\;and\;Fe_3Al$. As the result of hardness measurement, the peak hardness appeared in the intermetallic compound at near interface of the cast iron and the compound.

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Effects of CuEDTA and FeEDTA Foliar Spray on Antioxidant Activities of Apple (CuEDTA와 FeEDTA의 엽면살포가 사과의 항산화 활성에 미치는 영향)

  • Park, Ji-Young;Ryu, Ho-Ung;Shin, Hyun-Suk;Lim, Heon-Kyu;Son, In-Chang;Kim, Dae-Il;Jeong, Heon-Sang;Lee, Jun-Soo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.41 no.9
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    • pp.1305-1309
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    • 2012
  • For functional enhancement of apples, the effects of CuEDTA and FeEDTA foliar spray were investigated on the antioxidant contents and antioxidant activities in 'Hongro' fruit, which is a representative early season harvesting apple cultivar, at 30 days before harvest. The polyphenolic content of peel was significantly higher in the CuEDTA (1,228.6 mg/100 g) and FeEDTA (1,210.0 mg/100 g) spraying treatment groups compared to the control group (998.8 mg/100 g). The flavonoid content of peel showed the same trend as that of polyphenolic content. The ascorbic acid content of peel as also significantly increased in the CuEDTA and FeEDTA spraying treatment groups, but anthocyanin content was the highest in the control group (560.6 mg/100 g). The ABTS and DPPH radical scavenging activities were higher in the CuEDTA and FeEDTA spraying treatment groups than in the control group, but reducing power was not significantly different between the treatments. As a result of this study, 3% CuEDTA and FeEDTA spraying treatments at 30 days before harvest can be used to effectively enhance antioxidant contents in 'Hongro' apple.

Change in Properties of (Ba1-xLax)Fe3+1-tFe4+tO3-y System Depending on Heat Treatment Conditions

  • Lee, Eun-Seok;Lee, Seo-Jin
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.6
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    • pp.311-315
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    • 2017
  • The perovskite system $(Ba^{2+}{_{1-x}}La^{3+}{_x})Fe^{3+}{_{1-t}}Fe^{4+}{_t}O_{3-y}$ (y = (1 - x --t)/2) having a composition of x = 0.0, 0.1, 0.2, and 0.3 showedean increase in $Fe^{4+}$ mole ratios with an increase in oxygen partial pressure ($N_2{\rightarrow}air{\rightarrow}O_2$), and with an increasefin s, the $Fe^{3+}$ quantity decreased and oxygen content (3-y value) increased. For each N sampls heat-treated in $N_2$ gas, a considerable weight gain, i.e.g a steadynincrease if oxygen content, was observed in the TGA data on the cooling process. The conductivity values at a constant temperature were in the order of $N_2$$O_2$; the respective log ${\sigma}$ values (${\Omega}^{-1}{\cdot}cm^{-1}$) at 323 K of the BL0 sample were -5.75 (BL0-N), -3.39 (BL0-A), and -0.53 (BL0-O). The mixed valencies of $Fe^{3+}$ and $Fe^{4+}$ ions in each sample were also confirmed by both the oxidation curve above 350 mV and the cathodic reduction curve below 200 mV from cyclic voltammetry.