• Title/Summary/Keyword: Fe 과잉첨가

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The Effect of Ba and Fe Concentration on Soft Magnetic Properties of Z-Type Barium Ferrite (Z-Type 바리움 페라이트 분말의 연자성 특성에 미치는 Ba 및 Fe 농도의 영향)

  • Cho, Kwang-Muk;Nam, In-Tak
    • Journal of the Korean Magnetics Society
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    • v.19 no.1
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    • pp.12-16
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    • 2009
  • Z-type barium ferrite [($Ba_{3}Co_{0.8}Zn_{1.2}Fe_{24}O_{41}$, $Ba_{3+{\delta}}Co_{0.8}Zn_{1.2}Fe_{24}O_{41}$ ${\delta}$ = 3, 5, 7, 13 wt%. $Ba_{3}Co_{0.8}Zn_{1.2}Fe_{24+{\delta}}O_{41}$ ${\delta}$ = 5, 7, 10 wt% )] were synthesized using co-precipitation method. The microstructure and magnetic properties of synthesized particles were investigated. In all prepared particles M-type Ba ferrite is identified with Z-type Ba ferrite together. It is found that particles having 7 wt% for Ba and 5 wt% for Fe excess addition revealed high saturation magnetization, respectively. All synthesized particles showed relatively high coercivity for device application. This result may be attributed to the contribution of M-type Ba ferrite. Ba and Fe excess addition was not affected to the structural change of CoZnZ Ba ferrite. The certain amount of excess additions of Ba and Fe and the 2 step heat-treatment may be beneficial to the improvement of soft magnetic properties of Z-type barium hexa-ferrite

Dielectric and Field-induced Strain Behaviors due to Excess PbO in Lead Yttrium Zirconate Stannate Titanate Ceramics (과잉 PbO에 의한 (Pb,Y) $(Zr,Sn,Ti)O_3$세라믹스의 유전 및 전기장유기변형 특성)

  • Yun, Gi-Hyeon;Kim, Jeong-Hui;Gang, Dong-Heon
    • Korean Journal of Materials Research
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    • v.10 no.1
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    • pp.34-40
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    • 2000
  • The $Pb_{0.94}Y_{0.04}[(Zr_{0.6}Sn_{0.4})_{0.915}Ti_{0.085}]O_3$ ceramics which corresponded to the antiferroelectric-ferroelectric phase boundary composition were prepared for digital-type-piezoelectric/electrostrictive device application. Their dielectric, field-induced polarization (P) and strain (X) behaviors were studied with variations in sintering condition and excess PbO content. The orthorhombic structure of specimens was hardly affected either by excess PbO addition or sintering temperature. With increasing excess PbO content, grains tended to be smaller and rounded ones, and the optimum sintering temperature was lowered. Excess PbO addition stabilized the antiferroelectric phase of the specimen effectively, which was confirmed by P-E and X-E analyses. Also the digital-type-strain character was found to be enhanced despite of slight increase in phase transition (AFE-FE) field and electrical resistivity, and decrease in maximum strain. These results were explained in terms of possible lattice defects and domain wall motion.

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A study on the toxicity of photosensitizer-coated magnetic fluids for photodynamic therapy (광감제가 코팅된 자성유체의 독성에 관한 연구)

  • 박상임;김종오;김종희;임종환;윤효인
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.145-145
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    • 2003
  • 자성유체는 암 치료와 질병진단 등과 같은 다양한 분야에서 유용한 응용의 가능성을 갖는다 [1]. 생리적 염도인 중성 pH에서 생체조직과 잘 교합하고, 높은 안정성을 가지는 자성유체는 자성 나노입자 표면에 화학적으로 흡착된 계면활성제 종류에 따라 달라진다 [2]. 본 실험에서는 화학적 공침법을 이용하여 Fe$^{2+}$와 Fe$^{3+}$ 의 몰비가 1:2인 수용액에 pH 12 이상의 과잉 알칼리(NH$_4$OH 12ml)를 첨가시켜 마그네타이트 콜로이드 용액을 제조하였다. 광감제로는 hematoporphyin을 사용하였으며 투입량은 1$\times$$10^{-3}$mol/l 였다. 또한 1차 및 2차 계면활성제로는 decanoic acid와 starch, citric acid, oleic acid 등이 각각 사용되었다. 각 계면활성제가 코팅된 자성미립자의 특성을 조사하기 위해 동결 건조 후 VSM, FT-IR 및 TEM 분석을 수행하여 자기적 특성과 코팅표면의 결합구조 및 미시적 구조를 분석하였다. 그리고, 각각의 계면활성제가 코팅된 자성유체의 독성을 조사하기 위해 rat를 이용한 생체실험이 병행되었다.

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Studies on the Preparation and Utilization of Sea Mustard Extracts with the Treatment Conditions (처리조건별 미역농축물의 제조 및 이용에 관한 연구)

  • LEE Kang-Ho;LEE Dong-Ho;CHO Ho-Sung;JUNG Woo-Jin
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.26 no.5
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    • pp.409-415
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    • 1993
  • For the use of sea mustard in snack food as the supplement of minerals and nutrients, three types of product like sweet jelly, jam and candy were prepared adding fresh sea mustard homogenates, dried sea mustard powder and sea mustard extract, respectively. That were prepared by four different ways, cold water extract, hot water extract, $1\%$ NaOH extract and $95\%$ ethanol extract. The extract contains plenty of particulary iodine and calcium in hot water extract and other nutrients. Judging by sensory evaluation, color, flavor and taste of jam, sweet jelly and candy added with sea mustard, products were satisfactory to attractive snack food for children and these could be useful as the source of minerals and nutrients.

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Studies on Nutrio-physiological Response of Rice Plant to Root Environment (근부환경(根部環境)에 따른 수도(水稻)의 영양생리적(營養生理的) 반응(反應)에 관(關)한 연구(硏究))

  • Park, J.K.;Kim, Y.S.;Oh, W.K.;Park, H.;Yazawa, F.
    • Korean Journal of Soil Science and Fertilizer
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    • v.2 no.1
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    • pp.53-68
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    • 1969
  • The nutriophysiological response of rice plant to root environment was investigated with eye observation of root development and rhizosphere in situation. The results may be summarized as follows: 1) The quick decomposition of organic matter, added in low yield soil, caused that the origainal organic matter content was reached very quickly, in spite of it low value. In high yield soil the reverse was seen. 2) In low yield soil root development, root activity and T/R value were very low, whereas addition of organic matter lowered them still wore. This might be contributed to gas bubbles around the root by the decomposition of organic matter. 3) Varietal difference in the response to root environment was clear. Suwon 82 was more susceptible to growth-inhibitine conditions on low-yield soil than Norin 25. 4) Potassium uptake was mostly hindered by organic matter, while some factors in soil hindered mostly posphorus uptake. When the organic matter was added to such soil, the effect of them resulted in multiple interaction. 5) The root activity showed a correlation coeffieient of 0.839, 0.834 and 0.948 at 1% level with the number of root, yield of aerial part and root yield, respectively. At 5% level the root-activity showed correlation-coefficient of 0.751, 0.670 and 0.769 with the uptake of the aerial part of respectively. N, P and K and a correlation-coefficient of 0.729, 0.742 and 0.815 with the uptake of the root of respectively N.P. and K. So especially for K-uptake a high correlation with the root-activity was found. 6) The nitrogen content of the roots in low-yield soil was higher than in high-yield soil, while the content in the upper part showed the reverse. It may suggest ammonium toxicity in the root. In low-yield soil Potassium and Phosphorus content was low in both the root and aerial part, and in the latter particularly in the culm and leaf sheath. 7) The content of reducing sugar, non-recuding sugar, starh and eugar, total carbohydrates in the aerial part of plants in low yield soil was higher than in high yield soil. The content of them, especially of reducing sugar in the roots was lower. It may be caused by abnormal metabolic consumption of sugar in the root. 8) Sulfur content was very high in the aerial part, especially in leaf blade of plants on low yield soil and $P_2O_5/S$ value of the leaf blade was one fifth of that in high yield soil. It suggests a possible toxic effect of sulfate ion on photophosphorization. 9) The high value of $Fe/P_2O_5$ of the aerial part of plants in low yield soil suggests the possible formation of solid $Fe/PO_4$ as a mechanical hindrance for the translocation of nutrients. 10) Translocation of nutrients in the plant was very poor and most nutrients were accumulated in the root in low yield soil. That might contributed to the lack of energy sources and mechanical hindrance. 11) The amount of roots in high yield soil, was greater than that in low yield soil. The in high-yield soil was deep, distribution of the roots whereas in the low-yield soil the root-distribution was mainly in the top-layer. Without application of Nitrogen fertilizer the roots were mainly distributed in the upper 7cm. of topsoil. With 120 kg N/ha. root were more concentrated in the layer between 7cm. and 14cm. depth. The amount of roots increased with the amount of fertilizer applied.

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A Study on the Mineral Content of Calcium-fortified Foods in Korea (우리나라의 칼슘강화식품의 무기질 함량에 관한 연구)

  • 김욱희;김을상
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.1
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    • pp.96-101
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    • 2003
  • This study was done to analyze the contents of minerals, to compare the measured values of calcium and the labeled values in food labeling and to analyze the ratio of calcium to other minerals in 43 calcium-fortified Food products sold in markets in Seoul, Korea. Content of minerals such as Ca, P, Mg, Na, K, Fe, Cu, Zn was measured by atomic absorption or colorimetric method after dry-ashing or wet-ashing. The measured values of calcium were ranged 65.5~343.9% of the labeled values in 43 calcium-fortified products. In 21 calcium-fortified food products, the measured calcium values were ranged 120~160% of the labeled values, and in three drinks those were less than 80% of the labeled, which is not acceptable to the food regulation. The ratios of Ca:P were 2.63$\pm$1.99 (mean$\pm$SD) in grain Products, 1.79$\pm$0.39 in Ramyuns, 2.80$\pm$0.53 in retort pouch food products and 8.35$\pm$12.87 in drinks. The Ca:Fe ratios were 126.33$\pm$44.36 in grain products, 130.65$\pm$34.67 in Ramyuns, 120.31$\pm$71.15 in retort pouch food products and 700.25$\pm$553.70 in drinks. The ratios of Ca:Mg were 11.86$\pm$5.40 in grain products, 9.29$\pm$1.34 in Ramyuns, 9.09$\pm$2.09 in retort pouch food products and 32.50$\pm$41.35 in drinks. The P:Mg ratios were 4.11$\pm$1.54 in grain products, 4.17$\pm$0.67 in Ramyuns, 2.58$\pm$0.45 in retort pouch food Products and 2.59$\pm$2.50 in drinks. These results suggest calcium contents and the ratio of calcium contents to other minerals in calcium-fortified food products should be strictly controlled.

The Strategy for the Environmental Education through the Practical Arts(TechnologyㆍHome economics) Subject in a viewpoint of the Clothing & Textiles resources (의생활자원 관점에서의 실과(기술ㆍ가정) 환경교육방안에 관한 연구)

  • Chung Mee-Kyung
    • Journal of Korean Home Economics Education Association
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    • v.16 no.3
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    • pp.131-146
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    • 2004
  • The Purpose of this study is to suggest strategies for environmental education through the Practical Arts(TechnologyㆍHome economics) Subject in a viewpoint of the clothing & textiles resources to resolve problems in the clothing life area. For this, this study was carried out through review of literature which is related with the consumption, the environmental problems, the environmental policies, and regulations of the government and new environmental technologies, of clothing & textiles industries and environmental education. The major findings of the study were as follows; 1) The environmental education system model in a viewpoint of the Clothing & Textiles resources was developed. This model system is consisted with interactions on school, government, industry, home and non-government organizations. Thus, the fact that Practical Arts(TechnologyㆍHome economics) Subject were the most effective subject to teaching the environmental education viewpoint of the Clothing & Textiles resources was confirmed. 2) The standards were analysed out to analyse the contents in the clothing area of the Practical Arts(TechnologyㆍHome economics) Subject. It were consist of 4 factors and 12 elements under the factors: Awareness of clothing & textile resources(clothing consumption, production of clothing & textile and environmental problems). Planning and buying of clothing(planning, buying), Management of clothing(understand of textile. human body & environment, laundering and Environmental pollution, arrangement & conservation) Recycling & exhaust of clothing(contribution, redesign, recycling, exhaust) 3) Analysing the current Practical Arts (TechnologyㆍHome economics) subject from the Environmental education in the clothing section, the environmental education related with clothing were taught the most in the middle school course, and environmental contents were concentrated in the recycling factors. but not so much on other factors. 4) After analysing the Practical Arts (TechnologyㆍHome economics) subject, the strategies were suggested for reinforcing the environmental education in the clothing of the Practical Arts(TechnologyㆍHome economics) subject.

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