• 한국염색가공학회지
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• 제31권4호
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• pp.233-240
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• 2019

Dyeing is an essential process for improving the value of textile products, but it is considered as one of industries causing pollution because of producing wastewater containing hazardous chemicals as well as using a large amount of water and energy. Global demand for greener technologies in textile field is getting much more attention and accordingly, the use of eco-friendly natural dyes is growing much larger. In textile printing, both dyes and pigments can be used. Pigment printing is more simple process and requires less water and less energy, compared to dye printing. In this study, the organic pigment was prepared from the marigold colorant. Samples were stencil printed, pressed(70℃, 3min) and then heat treated(150℃, 5min). The uptake of polyacrylic acid as a chemical binder was the lowest. In particular, marigold pigments were excellent in color and texture when Guar Gum and Sodium Alginate were used as binders. In addition, the light and washing fastness was rated very high as 4, 4/5 grades, and the rubbing fastness was also excellent as 3 and 4 grades.

• 한국의류학회지
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• 제25권1호
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• pp.3-12
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• 2001

The dyeing powder drawn out from Dryopteris crassirhizoma by water was concentrated. Using this powder, the silk and the cotton fabrics were dyed and they measured with the K/S value, surface color, mordant quantity in order to evaluate the dyeability, antimicrobial and deodorant properties. The colorant of Dryopteris crassirhizoma was proved flavonoids by FT-IR spectrum. The K/S values of silk were much higher than those of cotton, the color yield of the silk and cotton fabric were most efficient the postmordanting method. The surface colors on the dyed fabric depended heavily upon mordants used or mordanting methods. For all cases, the value of the dyed fabric was generally dark. The chroma produced clear for the Al-mordant of silk and the Cu-mordant of cotton in the 3% concentration of mordants, the color difference was distinct when using the Fe-mordant. The K/S values of cationized cotton were much higher than cotton. The color fastness was significantly improved when mordants were added, In the case of the light fastness, Fe and Cu-mordants improved more than 1 level. The Cu-mordant showed the greatest antimicrobial and deordarant activity on both of the silk and the cotton.

• 한국농촌생활과학회지
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• 제10권2호
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• pp.28-36
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• 1999

The purpose of this study was to examine the best condition for dyeing silk in green color used kudzu-vine leaves which were available everywhere in our country except winter. Dyeing experiments were done under various dyeing conditions according to extracting method of dyebath from kudsu-vine leaves, pH of dyebath, dyeing time, concentration of dyebath and mordants which were treated after dyeing. Color difference ($\Delta$E) and Munsell's HV/C and color fastness to drycleaning, washing, perspiration and light were measured. The main results were as follows : 1. The color difference of dyed silk increased in dyebath B & C which were extracted in alkali water comparing with dyebath A which was extracted in distilled water. In dyebath B & C, the color difference was the highest in case of dyebath pH 5.0. 2. The colors of fabrics dyed in dyebath A were mainly yellow and the colors in dyebath B & C were yellow green. 3. The color differences of dyed silk increased according to dyeing time and concentration of dyebath. 4. The color were changed with the treatment of mordants. The most strong green color could get in Cu mordant treatment in dyebath C, pH 5.0, and concentration 4. 5. The peak of reflectance within the visible light of the fabric dyed in the most strong green color could be seen in $\lambda$500-520nm. 6. On the whole, the colorfastness of experimental fabrics dyed in dyebath B, C and Cu mordant treatment was good except the colorfastness to the light.

• 한국염색가공학회지
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• 제35권3호
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• pp.151-158
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• 2023

In this study, we investigated the durability properties of the recycled leather using shaving scrap with antioxidant. Recycled leather sheets were manufactured by mixing shaving scrap and NB latex as a binder. HALS(Hindered Amine Light Stabilizer) and UVA(UV absorbers) were used as antioxidant. Mechanical properties such as hardness, tensile strength, elongation, tear strength and abrasion resistance were measured. Light aging resistance was evaluated using UV lamp and the degree of discoloration of the recycled leather sheets using a gray scale. In addition, to evaluate heat aging and UV aging, the degree of discoloration of the recycled leather sheets over time was measured using colorimeter. Washing fastness was evaluated on the degree of dyeing of recycled leather sheets for six type of multi-fiber woven fabrics (Acetate, Cotton, Nylon-66, Polyester, Acryl, Wool). To determine whether hazardous substances were detected in recycled leather sheets, the contents of arylamine and Cr 6⁺ were evaluated. As a result, when used in combination with antioxidant, the heat aging and light aging of recycled leather were improved and hazardous substance were not detected.

• 한국의류학회지
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• 제10권2호
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• pp.11-20
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• 1986

This study is to examine the colorfastness of leathers which has been tested for concentration of dyestuff and method of dyeing. This study Particularly attempts to solve some problems of colorfastness in wearing and treating leather goods. The finding of this study can summarized as follows: 1. In dyeing garment leathers classified by concentration, the colorfastness to light improves as concentration increases. 2. As the result the more concentration increases, the more the colorfastness to rubbing declines. 3. In colorfastness to dry cleaning, the grade of color fading has been to be high but that of staining to be bad as concentration increases. 4. In assessing change in colorfastness, grades to light and rubbing after coating have been found to be better than that before coating. 5. In colorfastness to dry cleaning after coating, both grades of color fading and staining have been found to be bad.

• 한국의류산업학회지
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• 제15권4호
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• pp.630-634
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• 2013

Cow leather coated with polyurethane film that contains various organic photosensitizers was investigated to demonstrate the antimicrobial properties in the application of the material to protective clothing and home appliances. To prepare the antimicrobial coating on leather surfaces with high potency against microbes, photoactive agents, such as benzophenone (BP), 4,4'-bis(dimethylamino) benzophenone (MK), 4,4'-dihydroxybenzophenone (DHBP) and methylene blue (MB), were incorporated into polyurethane-based coating solutions. The photoactive antimicrobial agent treated leather samples were characterized by SEM, color appearance, color fastness against abrasion, and antimicrobial tests. The optical properties of organic photosensitizers indicated that active UV absorbance ranges were different: BP (around 250 nm), MK (around 360 nm), DHBP (around 305 nm) and MB (around 295 nm &570 nm-685 nm). The intensity of the UV absorbance curve at the UVA light wavelength for the antimicrobial test showed the highest value with MK; subsequently, this was followed by MB, DHBP and BP in decreasing order. The treated-leather samples demonstrated excellent antibacterial activity under UVA light. The antimicrobial effects for the Staphylococcus aureus were superior to Escherichia coli. Moreover, the polyurethane finishing showed an effective durability to abrasion. The overall results indicated that DHBP is the most suitable PU coating additive to provide antimicrobial properties to leather as well as color and surface appearance than MK, MB, and BP.

• 한국의류학회지
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• 제23권6호
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• pp.788-799
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• 1999

This study was performed to investigate the effect of mordants on the dyeability colorfastness to light and to laundering and biological properties of mordanted and natural-dyed cotton and silk substrates. Natural red dyes were extracted from Caesalpinia Sappan L. (Sappan wood) and Rubia Akane Nakai (Madder) by boil water Five different compounds of Al, Cr, Cu, Fe and Sn were used as mordanting agents. The result of this study are sumarized as follows ; 1. In the of the fabrics mordanted and dyed with sappan wood K/S value increases and λmax shifts to the longer wavelength as mordant concentration increases. Color of the fabrics dyed with sappan wood and madder change to redder bluer and lighter after mordanting. 2. As the number of repetition of dyeing-mordnating process increase the color of the dyed fabrics tend to be redder bluer and darker. Mordanted dyes with Al and Sn make chroma increase. The quantity of mordant absorbed in the silk fabric increase as mordant concentration increase. More Fe is absorbed in silk than Cr is. 3. After being exposed to light the fabrics dyed with sappan wood and madder change to less red Fe and Cu mordanting yeild better colorfastness to light than others does. Natural-dyed fabrics exposed to light tend to be faded and whitened in CIELAB chromaticity co-ordinates. So we might trace back the original color of ancient faded fabrics by changes in color of natural dyes. 4. After washing the colors of natural dyes change to more blue, Fe and Cu mordanting give better colorfastness to wash than others do. 5. The soil-burial cotton is more susceptible to mildew and rot than the silk is. Antimicrobial activity of the natural-dyed cotton can be enhanced by Cu and silk can be enhanced by Cu and Cr mordanting respectively.

• 한국염색가공학회지
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• 제22권3호
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• pp.207-213
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• 2010

Natural dyeing of Sangju silk for graveclothes with mulberry extract solution was studied. The anthocyanidin dye in the extracted mulberry solution was markedly influenced by pH condition, which resulted in the changed maximum light absorption from a $\lambda$max of 525nm in acidic condition to 380nm in alkaline condition possibly due to the irreversible transformation of anthocyanidin to cyanidin form of the dye. The color fastness properties to both light and washing were good when the fabrics were dyed at $80^{\circ}C$ with the mulberry-extracted solution upto twice extraction.

• 한국생활과학회지
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• 제19권4호
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• pp.699-707
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• 2010

Catechu is widely used as in natural dyeing as well as in various medicines and tannage. This study investigated the dyeing properties and functionality of Catechu through a series of dyeing experiments using cotton fabric. It was shown that the absorbance of Catechu solution has two peaks at 220nm and 280nm. Thus, it can be concluded that the color constituent of Catechu is a catechol tannin and color tone is YR. The dyeability of Catechu increases as the concentration of the dye is increased. Its variation was shown to be similar to the isothermal absorption curve of the Freundlich. As dyeing time was increases, the dyeability did not change significantly after the 30 minute mark was passed. At high temperatures the dyeability was shown to increase. As the dyeing temperature was increased the color of dyeing fabrics changes from Y and YR to R. Experiments with pre-mordanting method showed that various colors can be obtained using Catechu. Cotton is effective in using K, Cu, Fe mordants, and the dyeability was shown to be improved with low pH. Both washing fastness and light fastness were shown to be low. However, the fabric color gradually changed to red was due to mailard reaction of catechol tannin causing by repeated washing and sunlight. The ultraviolet-cut ability was improved for cotton fabric dyed with Catechu. Also, dyed fabric with Catechu showed very good antimicrobial abilities at 99.9%.

• 한국염색가공학회지
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• 제14권1호
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• pp.1-10
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• 2002

The aim of study was to elucidate dyeability and antimicrobial and antifungal activity of silk fabrics dyed with Sophora Radix extracts according to different mordants. Dyes were extracted from Sophora Radix using ethanol. Then, silk fabrics were dyed with extracts two times by post-mordanting method in which the extract was 60%(owf), the mordant was 3%(owf), L.R was 1:20, the temperature was $60~60^\circ{C}$, the time of dyeing was 60min., and the time of mordanting was 60min. The dyeability was evaluated by surface color, K/S values and durability of dye. The skin microorganisms used in this study was S. sureus, B. subtilis, S. epidermidis, P. acnes, P. aeruginosa, E coli, A. niger, C. albicans and T. mentatrophytes. The results are as follows; 1. When mordants were added, K/S value of silk dyed was not improved much and surface color was 2.2Y to 8.8Y in H(hue) value which indicated greenish yellow to raddish yellow 2. The color fastness tests to light, perspiration, dry-cleaning, rubbing, and stain fabric washing show 4~5th degree which were valuated excellent. The color fastness to fade washing was improved to 3~4th degree by addition of $K_2CrO_7$ mordants. 3. Antibacterial activity of silk dyed using no-mordant as well as mordants was excellent on S. aureus, B. subtilis, S.epidermidis and P.acnes, but showed poor antibacterial activities on P.aeruginosa and E.coli such as gram negative baterials 4. Antifungal activity of silk dyed with ethanol extracts was good on A.niger, C.candida and T.mentagrophytes. Especially, on T. mentagrophytes there was no growth of fungus during 72 gous in silk dyed mordanting with $SnCl_2\cdot{2H}_2O$.