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Electrochemical properties of all solid state Li/LiPON/Sn-substituted LiMn2O4 thin film batteries

  • Kong, Woo-Yeon;Yim, Hae-Na;Yoon, Seok-Jin;Nahm, Sahn;Choi, Ji-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.409-409
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    • 2011
  • All solid-state thin film lithium batteries have many applications in miniaturized devices because of lightweight, long-life, low self-discharge and high energy density. The research of cathode materials for thin film lithium batteries that provide high energy density at fast discharge rates is important to meet the demands for high-power applications. Among cathode materials, lithium manganese oxide materials as spinel-based compounds have been reported to possess specific advantages of high electrochemical potential, high abundant, low cost, and low toxicity. However, the lithium manganese oxide has problem of capacity fade which caused by dissolution of Mn ions during intercalation reaction and phase instability. For this problem, many studies on effect of various transition metals have been reported. In the preliminary study, the Sn-substituted LiMn2O4 thin films prepared by pulsed laser deposition have shown the improvement in discharge capacity and cycleability. In this study, the thin films of LiMn2O4 and LiSn0.0125Mn1.975O4 prepared by RF magnetron sputtering were studied with effect of deposition parameters on the phase, surface morphology and electrochemical property. And, all solid-state thin film batteries comprised of a lithium anode, lithium phosphorus oxy-nitride (LiPON) solid electrolyte and LiMn2O4-based cathode were fabricated, and the electrochemical property was investigated.

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A Study on Braking Characteristics Control of Carbon Ceramic Composite for Brake Reliability Improvement of Luxury Car and Future Technology Evolution Trend Prediction (고급차의 제동 신뢰성 향상을 위한 카본 세라믹 복합재의 제동 특성 제어 및 향후 기술 진화 트랜드 예측에 관한 연구)

  • Shim, Jaehun;Jeon, Gabbae;Lee, Jounghee;Park, ByeongJoon;Im, Dongwon;Hyun, Eunjae;Jung, Kwangki;Kim, Kijeong;Kim, Hongki
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.6
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    • pp.684-693
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    • 2016
  • The luxury car industry has grown 10.5 % every year from 2010 to 2014. For this reason, it is very important for automotive companies to improve profitability and brand value. High-performance brake systems have become an absolute necessity because of the increase in engine power and customer preference among other factors. Also, competing automotive companies actively reinforce domestic production in order to maintain quality and infrastructure for luxury cars. In this regard, we demonstrated new carbon ceramic brakes to improve brake reliability for luxury cars and to improve the competitiveness of automotive companies. Finally, we propose the next-generation braking technology by predicting technological evolution trends.

Detection of Video Cut Using Autocorrelation Function and Edge Histogram (자기상관과 에지 히스토그램을 이용한 동영상 전환점 검출)

  • Noh, Jung-Jin;Moon, Young-Ho;Yoo, Ji-Sang
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.29 no.9C
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    • pp.1269-1278
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    • 2004
  • While the management of digital contents is getting more and more important, many researchers have studied about scene change detection algorithms to reduce similar scenes in the video contents and to efficiently summarize video data. The algorithms using histogram and pixel information are found out as being sensitive to light changes and motion. Therefore, visual rhythm gets used in recent work to solve this problem, which shows some characteristics of scenes and requires even less computational power. In this paper, a new scene detection algorithm using visual rhythm by direction is proposed. The proposed algorithm needs less computational power and is able to keep good performance even in the scenes with motion. Experimental results show the performance improvement of about 30% comparing with conventional methods with histogram. They also show that the proposed algorithm is able to keep the same performance even to music video contents with lots of motion.

Investigation of a Pseudo Capacitor with Polyacrylonitrile based Gel Polymer Electrolyte

  • Harankahawa, Neminda;Weerasinghe, Sandaranghe;Vidanapathirana, Kamal;Perera, Kumudu
    • Journal of Electrochemical Science and Technology
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    • v.8 no.2
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    • pp.107-114
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    • 2017
  • Pseudo capacitors belong to one group of super capacitors which are consisted with non carbon based electrodes. As such, conducting polymers and metal oxide materials have been employed for pseudo capacitors. Conducting polymer based pseudo capacitors have received a great attention due to their interesting features such as flexibility, low cost and ease of synthesis. Much work has been done using liquid electrolytes for those pseudo capacitors but has undergone various drawbacks. It has now been realized the use of solid polymer electrolytes as an alternative. Among them gel polymer electrolytes (GPEs) are in a key place due to their high ambient temperature conductivities as well as suitable mechanical properties. In this study, composition of a polyacrylonitrile (PAN) based GPE was optimized and it was employed as the electrolyte in a pseudo capacitor having polypyrrole (PPy) electrodes. GPE was prepared using ethylene carbonate (EC), propylene carbonate (PC), sodium thiocyanate (NaSCN) and PAN as starting materials. The maximum room temperature conductivity of the GPE was $1.92{\times}10^{-3}Scm^{-1}$ for the composition 202.5 PAN : 500 EC : 500 PC : 35 NaSCN (by weight). Performance of the pseudo capacitor was investigated using Cyclic Voltammetry technique, Electrochemical Impedance Spectroscopy (EIS) technique and Continuous Charge Discharge (GCD) test. The single electrode specific capacity (Cs) was found out to be 174.31 F/g using Cyclic Voltammetry technique at the scan rate of 10 mV/s and within the potential window -1.2 V to 1.2 V. The same value obtained using EIS was about 84 F/g. The discharge capacity ($C_d$) was 69.8 F/g. The capacity fade over 1000 cycles was rather a low value of 4%. The results proved the suitability of the pseudo capacitor for improving the performance further.

Protective Effect of Panax ginseng extract on Renal Functions Altered by Mercuric Chloride in Albino Rats

  • Saxena, Prabhu-N.;Mahour, K.;Kumar, Ashok
    • Journal of Ginseng Research
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    • v.30 no.3
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    • pp.100-105
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    • 2006
  • Liver and kidney are specific organs which play an active role in biotransformation and detoxification mechanisms. Ant adverse effect of chemicals or heavy metal can cause the delay or fade in these mechanisms. Present study was designed to find out the protective effect of Panax ginseng extract on renal functions altered by mercuric chloride (heavy metal) in albino rat. Fifty albino rats were divided into 10 groups. Five groups for acute study and five groups for sud-acute study viz. control group (Tween 20 and distilled water), mercuric chloride treated group (0.926 mg/kg body wt. for acute and 0.044 mg/kg body wt. for sub-acute group after calculated $LD_{50}$ (9.26 mg/kg body wt.) by probit analysis (Finney, 1971), Panax ginseng extract treated group (10 mg/kg body wt. for acute and sub-acute sets), mercuric chloride treated followed by Panax ginseng extract and Panax ginseng extract followed by mercuric chloride group. All doses were given orally by gavage tube. The result revealed that the serum urea and creatinine significantly increased in mercuric chloride treated group, while significantly decreased (p<0.01) in Panax ginseng extract group after acute and sub-acute treatment. The biochemical estimation is also confirmed by nephropathological aspect. However, the Panax ginseng extract treated followed by mercuric chloride group is more prominent than the mercuric chloride treated followed by Panax ginseng extract group. It can be concluded that Panax ginseng extract had a protective nature on renal functions against mercuric chloride toxicity in albino rats.

A case of Systemic Toxicity that Occurred in an Adult Who Intentionally Ingested Rhododendron Sclippenbashii (의도적으로 철쭉 섭취 후 발생된 성인 전신 중독 증상 1례)

  • Jeong, Sang-Min;Lee, Seung-Han;Lim, Jeong-Soo;Yoon, Sang-Yeol;Ryu, Seung;Lee, Jin-Woong;Kim, Seung-Whan;Yoo, In-Sool;You, Yeon-Ho
    • Journal of The Korean Society of Clinical Toxicology
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    • v.7 no.2
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    • pp.180-182
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    • 2009
  • It is well known that Rhododendron sclippenbashii contains the toxic material grayanotoxin. So, Koreans do not eat it, but they do eat azalea although it contains grayanotoxin. That is why there have been no reports about Rhododendron sclippenbashii intoxication after ingesting it intentionally, not accidentally. In this case, the patient was admitted to the emergency room with several toxic symptoms after intentionally consuming 50 blossoms of Rhododendron sclippenbashii to get rid of thirst. Treatment with saline infusion and atropine was successful and the outcome was favorable enough in this case to produce a complete cure without any sequelae at discharge. But toxic symptoms were seen for 24 hours, although the symptoms usually fade in 9 hours. Therefore, we should carefully treat and observe, for over 24 hours, the patient who intentionally ingests about 50 blossoms of Rhododendron sclippenbashii.

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Faded Color Correction using Classification Map in LCybCrg Color Space (LCybCrg 색 공간에서 분류맵을 이용한 바랜 색 보정)

  • Kyung, Wang-Jun;Kim, Dae-Chul;Lee, Cheol-Hee;Ha, Yeong-Ho
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.49 no.2
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    • pp.1-7
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    • 2012
  • Generally, correction methods for faded images use illuminant estimation algorithms, such as the gray world assumption and white patch Retinex methods, as the phenomenon of color fading is regarded as an illuminant effect. However, this induces inaccurate faded color correction, as images fade at different rates according to the ink property, temperature, humidity, and illuminant. Therefore, this paper presents a color correction method for faded images using classification in LCybCrg color space. The input faded image is first separated according to the chromaticity based on LCybCrg opponent color space. The faded color correction is then performed based on the gray world assumption in RGB color space. Thereafter, weights calculated from CybCrg values are applied to reduce contour artifacts. As a result, the proposed method provides better color correction for faded images than previous methods.

Collisionless Magnetic Reconnection and Dynamo Processes in a Spatially Rotating Magnetic Field

  • Lee, Junggi;Choe, G.S.;Song, Inhyeok
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.45.1-45.1
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    • 2016
  • Spatially rotating magnetic fields have been observed in the solar wind and in the Earth's magnetopause as well as in reversed field pinch (RFP) devices. Such field configurations have a similarity with extended current layers having a spatially varying plasma pressure instead of the spatially varying guide field. It is thus expected that magnetic reconnection may take place in a rotating magnetic field no less than in an extended current layer. We have investigated the spontaneous evolution of a collisionless plasma system embedding a rotating magnetic field with a two-and-a-half-dimensional electromagnetic particle-in-cell (PIC) simulation. In magnetohydrodynamics, magnetic flux can be decreased by diffusion in O-lines. In kinetic physics, however, an asymmetry of the velocity distribution function can generate new magnetic flux near O- and X-lines, hence a dynamo effect. We have found that a magnetic-flux-reducing diffusion phase and a magnetic-flux-increasing dynamo phase are alternating with a certain period. The temperature of the system also varies with the same period, showing a similarity to sawtooth oscillations in tokamaks. We have shown that a modified theory of sawtooth oscillations can explain the periodic behavior observed in the simulation. A strong guide field distorts the current layer as was observed in laboratory experiments. This distortion is smoothed out as magnetic islands fade away by the O-line diffusion, but is soon strengthened by the growth of magnetic islands. These processes are all repeating with a fixed period. Our results suggest that a rotating magnetic field configuration continuously undergoes deformation and relaxation in a short time-scale although it might look rather steady in a long-term view.

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Effect of Ti substitution on electrochemical properties $Li_{0.44}MnO_2$ synthesized by solid state reaction (고상반응법에 의해 제조된 $Li_{0.44}MnO_2$의 전기화학적 성질에 미치는 Ti 치환의 영향)

  • ;Marca M. Doeff;Abraham Anapolsky;Thomas J. Richardson
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.5
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    • pp.362-366
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    • 2000
  • $Li_{0.44}MnO_2$cathode material has high reversibility during lithium insertion processes and is not easily damaged through over-charging or over-discharging. $Mn_2O_3$is often present as an impurity phase, and reduce the electrochemical capacity of electrode because this phase is electrochemically inert. Adding of excess NaOH reduced the $Mn_2O_3$to the content under undetectable by X-ray diffraction. Because the capacity can be increased in the cathode materials with larger unit cell, some of the manganese was replaced with titanium having larger ion size, and powders with the formula $Li_{0.44}T_{iy}Mn_{1-y}O_2$(where y = 0.11, 0.22, 0.33, 0.44, and 0.55) was synthesized and characterized. A maximum reversible capacity of 150 mAh/g was obtained for $Li/P(EO)_8$LiTFSI/$Li_{0.44}Ti_{0.22}Mn_{0.78}O_2$cells in electrochemical potential spectroscopy (ECPS) experiments. Cells with the titanium-doped manganese oxides exhibited a fade rate of 0.12 % or less per cycle.

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Occupational Labor Market Activities by College Majors: On the Crisis of Science and Engineering Majors (대학졸업자의 전공계열별 직업노동시장 성과: 이공계 위기의 노동시장 원인론을 중심으로)

  • Kim, Chang-Hwan;Kim, Hyung-Seog
    • Korea journal of population studies
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    • v.29 no.3
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    • pp.1-27
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    • 2006
  • Labor market participation and occupational status for workers majoring in(natural) science and engineering are estimated and compared with workers of other majors at three levels: employment, prestigious occupations, and good occupations. For this, we utilized 2% Public Use Sample of 2000 Korea Census. The results of two-stage probit models, which adjust sample selection bias, do not support the argument that graduates of science and engineering majors are relatively disadvantaged. Workers of engineering majors are more likely to have 'good occupations' at their early job careers, but their advantages fade away quickly as they are aging. Especially at their 40s, their probability of having 'good occupations' start to be likely lower than workers of social science majors. This may be due to low human capital accumulation rates at work places along with quickly outdated skills which are acquired in colleges.