• Mass Spectrometry Letters
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• v.12 no.4
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• pp.159-162
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• 2021

The fragmentation pattern of four hindered phenol antioxidants was investigated using ammonium and lithium ions as the additives for ionization. Due to different binding geometries and interactions, they underwent different characteristic fragmentation reactions providing useful complementary information for structural analysis of hindered phenol antioxidants. Ammonium ion adducts were fragmented successively until all t-butyl groups were lost in the form of isobutylene and allowed the estimation of the number of t-butyl groups present in the molecule. Lithium ion adducts produced fragment ions from major backbone cleavage, on the other hand, which provide more crucial information for the identification of detailed backbone structure.

• International Journal of Computer Science & Network Security
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• v.21 no.3
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• pp.1-10
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• 2021

In recent decades, the heterogeneous and dynamic behavior of Internet traffic has placed new demands on the adaptive resource allocation of the optical network infrastructure. However, the advent of multifiber elastic optical networks has led to a higher degree of spectrum fragmentation than conventional flexible grid networks due to the dynamic and random establishment and removal of optical connections. In this paper, we propose heuristic routing and dynamic slot allocation algorithms to minimize spectrum fragmentation and reduce the probability of blocking future connection requests by considering the power consumption in elastic multifiber elastic optical networks.

• Proceedings of the Materials Research Society of Korea Conference
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• 1996.05a
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• pp.125-125
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• 1996

• Proceedings of the Materials Research Society of Korea Conference
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• 1996.11a
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• pp.118-118
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• 1996

• Proceedings of the Materials Research Society of Korea Conference
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• 1996.11a
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• pp.120-120
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• 1996

• Tunnel and Underground Space
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• v.13 no.6
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• pp.444-454
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• 2003

Rock fragmentation technique by cutter penetration has widely been used in the mechanical tunnel excavation. Microcracks propagate and interact because of locally concentrated high stress induced by cutter penetration. which is caused by heterogeneity of rocks. In this study Weibull distribution function and degradation index are used to consider the strength heterogeneity of a rock and the degradation of rock properties after failure. Through the numerical analyses, it is shown that the lateral pressure has an important influence on the rock fragmentation. In the single cutter penetration, large chips are formed as lateral pressure increase. The cutter spacing is also an important factor that affects the rock fragmentation in the double cutter penetration. The fragmentation efficiency of the double cutter penetration is better when cutter spacing is 70 mm than 40 mm and 100 mm. From the results, it is expected that this study can be applied to a TBM tunnel design by understanding of chipping process and mechanism of rock due to cutter penetration.

• Mass Spectrometry Letters
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• v.4 no.2
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• pp.30-33
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• 2013

Chalcones are naturally occurring, biologically active molecules generating interest from a wide range of research applications including synthetic methodology development, biological activity investigation and studying fragmentation patterns. In this article, a series of chalcones has been synthesized and their fragmentation behavior was studied using modern ambient ionization technique Direct Analysis in Real Time (DART). DART ion source connected with an ion trap mass spectrometer was used for the fragmentation of various substituted chalcones. The chalcones were introduced to the DART source using a glass capillary without sample preparation step. All the chalcones showed prominent molecular ion peaks $[M]^{{\cdot}+}$ corresponding to the structures. Multistage mass spectral data $MS^n$ ($MS^2$ and $MS^3$) were collected for all the chalcones studied. The chalcones with substitutions at 3, 4 or 5 positions gave product ion peaks with the loss of a phenyl radical ($Ph^{\cdot}$) by radical initiated ${\alpha}$-cleavage, while substitution at 2 position of chalcone in the A-ring gave a product ion peak with the loss of substituted styryl radical (PhCH = $CH^{\cdot}$). In case of the chalcones with the substituent at 4 positions in A and B rings gave both types of fragmentation patterns. In conclusion, chalcones can be easily characterized using modern DART interface in very short time and efficiently without any cumbersome sample pretreatment.

• Explosives and Blasting
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• v.22 no.3
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• pp.1-12
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• 2004

In bench blasting, rock fragmentation is one of the most important factors determining productivity. Rock fragmentation could be affected by various conditions and these were hewn that rock joint conditions and in-situ block sizes were the biggest effect on it. This research is focused on what or how to influence on rock fragmentation according to relation between blasting conditions and the in-situ rock conditions such as rock joint conditions and in-situ block size. Field measurements were carried out in 3 open pit limestone mines, where in-situ rock conditions and blasting conditions were fully investigated. The results show that the parameters interact with blasting conditions complicatedly and especially in-situ block size has bigger effects. Dip direction of major joint set also can affect on fragmentation. Mean fragment size become smallest when dip direction of major joint set is about $30^{\circ}$ with the bench direction. The reason is considered to be come from difference of propagation paths of elastic wave.

• Clinical and Experimental Reproductive Medicine
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• v.22 no.3
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• pp.279-285
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• 1995

Despite the frequent incidence of embryo fragmentation in early human embryos, the reason of the embryo fragmentation has not been known yet. This study was conducted to investigate the histological difference(s) between fragmented (FR) and non-fragmented (NFR) human embryos focusing on comparison of mitochondrial distribution and protein synthesis. Multi-pronuclei zygotes (MPZ) such as three or more pronuclei containing in human in vitro fertilization and embryo transfer (IVF-ET) program were used for this study. MPZ were cultured in TCM-199 supplemented with 10% of human fetal cord serum (hFCS) in 5% $CO_2$ incubator at $37^{\circ}C$ for 24 hours. The cleaved embryos to 2-4 cells after 24 hours were grouped by their grade of fragmentation. Embryos were stained with Rhodamine123 (Rh123) and fluorescence was evaluated under the fluorescence microscope through PB 450-490 filter (Leitz). Regarding to protein synthesis during early human embryogenesis, there is no significant difference in the amount of synthetic proteins between FR and NFR embryos. Distribution of cytoplasmic organelles in embryos was evaluated by transmission electron microscope (TEM). The cytoplasmic distribution of mitochondria was different between FR and NFR embryos. The mitochondrial distribution was even in NFR, whereas severely aggregated in FR. It is not able to clarify in the present study whether this uneven mitochondrial distribution in FR embryo is the reason for embryo fragmentation or is the result from fragmentation. Physiological disparity related to the mitochondrial distribution may be one of the reasons for embryo fragmentation. Further studies should be addressed to investigate the physiological differences between FR and NFR embryos.

• Composites Research
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• v.12 no.2
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• pp.10-25
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• 1999

A new evaluation method for the interfacial properties of fibrous composites based on a fragmentation technique is proposed by using the gradual multi-fiber composite, in which the inter-fiber spacing is gradually changed. The results showed that as the inter-fiber distance increased, the aspect ratio of broken fibers decreased while the interfacial shear strength between the fiber and matrix increased. When the reciprocal of the inter-fiber destance was taken for the above relations, both the aspect ratio and interfacial shear strength showed a saturated value. This means that the gradual multi-fiber composite indicates an upper bound in aspect ratio and an upper bound in interfacial shear strength. It was concluded that this fragmentation test could be a new method for composite evaluation, since reducing a difference between these two bounds is effective for composite strengthening. In addition an elastoplastic finite element analysis was carried out to relate the above results with fiber stress a distribution around fiber breaks. It was proved that the bound obtained in the gradual multi-fiber composite test is closely related to stress concentrations caused by a group of multi-fiber breaks.