• Title/Summary/Keyword: FE 실험

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A Study for Reductive Degradation and Surface Characteristics of Hexachloroethane by Iron Sulfide ($FeS,\;FeS_{2}$) (황화철($FeS,\;FeS_{2}$)을 이용한 헥사클로로에탄의 환원적 분해반응과 표면특성에 관한 연구)

  • Park Sang-Won;Kim Sung-Kuk;Heo Jae-Eun
    • Journal of Soil and Groundwater Environment
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    • v.11 no.5
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    • pp.35-42
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    • 2006
  • The following results were obtained in the reductive degradation of hexachloroethane (HCA), and surface characteristics by using iron sulfide ($FeS,\;FeS_{2}$) mediators. HCA was degraded to pentachloroethane (PCA), tetrachloroethylene(PCE), trichloroethylene(TCE) and cis-l,2-dichloroethylene (cis-1,2-DCE) by complicated pathways such as hydrogenolysis, dehaloelimination and dehydrohalogenation. FeS had more rapid degradation rates of organic solvent than $FeS_{2}$. In liquidsolid reaction, the reaction rates of organic solvents were investigated to explain surface characteristics of FeS and $FeS_{2}$.. To determine surface characteristics of FeS and $FeS_{2}$, the specific surface area and surface potential of each mineral was determined and the hydrophilic site ($N_{s}$) was calculated. The specific surface area ($107.0470m^{2}/g\;and\;92.6374m^{2}/g$) and the $pH_{ZPC}$ of minerals ($FeS\;PH_{ZPC}=7.42,\;FeS_{2},\;PH_{ZPC}=7.80$) were measured. The results showed that the Ns of FeS and $FeS_{2}$ were $0.053\;site/mm^{2}\;and\;0.205\;site/mm^{2}$, respectively. $FeS_{2}$ had more hydrophilic surface than FeS. In other words, FeS have more hydrophobic surface site than $FeS_{2}$.

System Identification of Real-Scale Structures Using Forced Vibration Test (실물크기 구조물의 강제진동 실험을 통한 시스템 식별)

  • Youn, Kyung-Jo;Lee, Sang-Hyun;Park, Eun-Churn;Yu, Eun-Jong;Min, Kyung-Won
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.11a
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    • pp.195-200
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    • 2007
  • System identification of real-scale structure is performed using forced vibration test. There exist various techniques available for identifying the dynamic characteristis of structures using dynamic and static measurements. In this study, The finite element(FE) model of the structure is analytically constructed using ANSYS and the model was updated using the results experimentally measured by the forced vibration test. forced vibration tests showed that Hybrid Mass Damper induced floor responses coincided with the earthquake induced ones which was numerically calculated based on the updated FE model.

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Electronic and Magnetic Structures of {Ca,Sr,Ba}$Fe_2As_2$ : Dynamical Mean Field Theory Approach ({Ca,Sr,Ba}$Fe_2As_2$의 전자 및 자성 구조: 동력학적 평균장 이론 접근)

  • Lee, Geun-Sik;Shim, Ji-Hoon
    • Progress in Superconductivity
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    • v.13 no.2
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    • pp.85-89
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    • 2011
  • Using the density functional theory and its combination to the dynamical mean field theory (DMFT), we have studied the electronic and magnetic structures of Fe-based superconductors, $AFe_2As_2$ (A=Ca, Sr, Ba). Our results for the electronic structure agree well with existing angle resolved photoemission spectroscopy (ARPES) data. The temperature dependent magnetization has been calculated using DMFT, and the magnetic transition temperatures are reasonably consistent with the experimentally observed trend for three compounds.

Holographic recording in doubly doped lithium niobate crystals (이중 첨가된 $LiNbO_3$ 결정을 이용한 홀로그램 기록)

  • 임기수
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.02a
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    • pp.52-53
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    • 2000
  • 광굴절 단결정을 이용한 홀로그램 저장은 일반적으로 Fe 흑은 Ce 과 같이 한 가지 종류의 이온이 첨가된 재료를 사용해왔다. 그러나 저장된 홀로그램 정보를 재생할때 지워지지 않도록 정착화를 위해 사용된 열이나 전기장 대신 자외선을 이용한 방법이 최근에 시도되고 있다$^{(1)}$ . 이 방법은 모든 것을 광으로 처리할 수 있는 장점이 있으나 2광자 기록방법$^{(2)}$ 과는 달리 두 가지 종류의 이온 첨가물이 필요하므로 전하의 이동이나 트랩과정이 더욱 복잡할 수밖에 없다. 특히 LiNbO$_3$ 재료는 photovoltaic 특성이 매우 강하여 다른 광굴절 재료와 구별된다. congruent Mn,Fe:LiNbO$_3$에 대한 실험 결과[1]와 stoichiometric LiNbO$_3$에서의 작은 polaron과 쌍 polaron에 의한 기록과 재생실험결과$^{(3)}$ 의 발표는 있으나 2중 첨가물의 LiNbO$_3$에 대한 이론적 접근은 아직 알려진 바 없다. 본 연구에서는 Mn,Ce:LiNbO$_3$와 Fe,W:LiNbO$_3$에서의 홀로그램 기록특성을 연구하였고 photovoltaic 효과를 고려한 홀로그램의 형성과 소멸과정에 대한 수치해석을 이용하여 결과의 설명을 시도하였다. (중략)

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브릴루앙 광산란을 이용한 열처리에 따른 CoFeB 박막의 Exchange Stiffness Constant 특성

  • Jeong, Jin-Yong;Kim, Ga-Eon;Jo, Jae-Hun;Yu, Cheon-Yeol
    • Proceedings of the Korean Magnestics Society Conference
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    • 2012.11a
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    • pp.57-58
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    • 2012
  • 이 연구는 BLS 실험을 이용하여 $Co_{40}Fe_{40}B_{20}$ 박막의 자성특성을 연구하였다. CoFeB의 열처리 온도에 따라서 $4{\pi}MS$는 일정하였고, $A_{ex}$$300^{\circ}C$ 이상에서 열처리한 시료의 경우 비슷한 값을 가짐을 확인하였다.

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FeCo 합금의 상전이를 전후한 표면 특성 연구

  • 김성민;한원근
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.158-158
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    • 2000
  • CsCl 구조의 합금의 상전이 현상 및 표면 특성을 Ising 모형 해밀토니안을 이용한 Monte Carlo 모의 실험 방법을 통하여 연구하였다. FeCo 합금 표면에 형성된 장이 없을 때는 합금이 상전이 온도에 접근함에 따라 표면의 원자 배열을 bulk에서 보다 더 빨리 무질서하게 하는 결과를 주었고 상전이 온도를 지나서는 표면과 bulk에서 모두 완전히 물질서 해지는 Surface-Induced Disorder 현상이 관측되었다. 표면에 장이 형성되고 그 세기가 점점 더 커짐에 따라 Surface-Induced Disorder와 surface-Induced Ofer가 서로 뒤섞여 있는 양상을 보였으며 장이 h=-0.0414eV/Atom 보다 더 강한 경우에는 상전이 온도 이후에도 표면의 질서가 잘 유지되는 Surface-Inducced Order 현상이 관측되었다. 이 결과를 최근에 발표된 FeCo 합금 표면에서의 Surface-Induced Order 현상과 비교하였다.

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A study on the Mossbauer effect and optical properties of $^{57}Fe$-doped-GaAs ($^{57}Fe$ 도프된 GaAs의 Mossbauer 효과 및 광학적 특성에 관한 연구)

  • 고정대;홍성락;김득영;강태원
    • Journal of the Korean Vacuum Society
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    • v.6 no.4
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    • pp.337-342
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    • 1997
  • We have investigated Mossbauer effect and emission properties of the Fe-doped GaAs grown by liquid phase epitaxy (LPE). The powder type of isotope $^{57}Fe$ was used as a dopant source in LPE-GaAs. From the analysis of Mossbauer effect the value of isomer shift, 0.303$\pm$0.018 mm/sec, is calculated at low temperature. This means that charge state of Fe ion in GaAs is 3+. The results of double crystal x-ray rocking curve (DCRC) and low temperature photoluminescence (PL) show the crystal quality of the epitaxial layers are good. Unusual luminescence peaks from the Fe-GaAs epitaxial layers appeared at emission energy of 0.99 eV and 1.15 eV. We attribute these emissions to Fe-acceptor related two deep radiative centers.

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The Electronic and Magnetic Properties of Fe Overlayers on W(110) (W(110)위에 성장한 Fe 웃층의 전자 및 자기적 성질)

  • ;;A. J. Freeman
    • Journal of the Korean Magnetics Society
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    • v.1 no.2
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    • pp.1-8
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    • 1991
  • The electronic and magnetic structure of Fe overlayers on W(110) is determined by means of the all-electron local spin density full potential linearized augmented plane wave (FLAPW) method with a single slab approach. Charge and spin densities, magnetic moments, contact hyperfine fields, and layer projected density of states (LDOS) are presented. For bilayer Fe coverage, we find magnetic moments to be 2.90 and 2.30 ${\mu}_B$ for the surface and subsurface Fe layers, respectively, corresponding to a 18% enhancement of the total magnetization compared with the calculated bulk value (2.22${\mu}_B$);For monolayer coverage the moment is 2.56 ${\mu}_B$ which is enhanced by 16% compared to bulk. Unusual changes in the magnetic hyperfine interaction are found in going from a monolayer to a bilayer coverage. Comparison of the results to the theoretical ones of the clean Fe(110) to discuss the hybridization and the negative pressure effects. We discuss our results by comparing them to experimental results.

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A Study on the exchange anisotropy and the giant magnetoresistance of Mn-Ir/Ni-Fe/buffer/Si with various buffer layers (Mn-Ir/Ni-Fe/buffer/Si 다층박막에서 하지층에 따른 교환이방성 및 거대자기저항에 대한 연구)

  • 윤성용;노재철;전동민;박준혁;서수정;이확주
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.5
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    • pp.486-492
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    • 1999
  • The purpose of this research was to find out what is the dominant factor determining the $H_{ex}$ and the $H_C$ of Mn-Ir/Ni-Fe multilayers with different buffer layers. Regardless of (111) texture of Mn-Ir layer, all samples showed over the $H_{ex}$ of 155 Oe. We found out the $H_{ex}$ and the $H_C$ of Mn-Ir/Ni-Fe multilayers depend on interface morphology and grain size of Mn-Ir layer at the interface between Mn-Ir and Ni-Fe layers. The dependence of magnetroesistance ratio and coupling field on the thickness of ferromagnetic layer, thickness of Cu layer and different buffer layers have been studied. Maximum magnetoresistance ratio appeared for the sample Ta(5 nm)/Mn-Ir(10 nm)/Ni-Fe(7.5 nm)/Cu(2 nm)/Ni-Fe(6 nm)/Ta(5 nm)/Si. Magnetoresistance ratio may be related to grain of ferromagnetic layer. Coupling field may be related to the roughness and the grain size of ferromagnetic layer in the spin-valve multilayers.

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