• Title/Summary/Keyword: F-가스

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Analysis of Flow Character and Gas Measurement from Final Cover Soil of sanitary Landfill (쓰레기 매립지 최종 복토층에서 가스 측정방법과 유출특성 해석)

  • 이해승
    • Journal of Korea Soil Environment Society
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    • v.3 no.3
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    • pp.75-86
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    • 1998
  • This paper is going to show the way we can sample the landfill gases flowing out to the air through final cover soil by using an closed chamber in the field for a short time. In addition, we came to the following results through the application of model with actual measurements. 1) Analyzing changes of concentration in the chamber(H: 10-30cm) every 5 minutes, considering analysis time of gas chromatograph for an half hour. 2) The proportion of $CE_4$to $CO_2$changes rapidly near the surface of final cover soil by the influence of methane oxidation reaction. 3) When flux of landfill gas is F=$10^{-5}$mol/$\textrm{m}^2$.s), methane oxidation reaction has an influence on composition of gases, however there is little influence when F=$10^{-6}$ mol/($\textrm{m}^2$.s).

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Characteristics of silicon etching related to $He-O_2,\; SiF_4$for trench formation (실리콘 트렌치 식각 특성에 미치는 $He-O_2,\; SiF_4$첨가 가스의 영향)

  • 김상기;이주욱;김종대;구진근;남기수
    • Journal of the Korean Vacuum Society
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    • v.6 no.4
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    • pp.364-371
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    • 1997
  • Silicon trench etching has been carried out using a magnetically enhanced reactive ion etching system in HBr plasma containing He-$O_2$, $CF_4$. The changes of etch rate and etch profile, the degree of residue formation, and the change of surface chemical state were investigated as a function of additive gas flow rate. A severe lateral etching was observed when pure HBr plasma was used to etch the silicon, resulted in a pot shaped trench. When He-$O_2$, $SiF_4$ additives were added to HBr plasma, the lateral etching was almost eliminated and a better trench etch profile was obtained. The surface etched in HBr/He-$O_2/SiF_4$ plasma showed relatively low contamination and residue elements compared to the surface etched in HBr/He-$O-2/CF_4$plasma. In addition, the etching characteristics including low residue formation and chemically clean etched surface were obtained by using HBr containing He-$O_2$ or $SiF_4$ additive gases instead of $CF_4$ gas, which were confirmed by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and atomic force microscopy (AFM).

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Re-determination of inelastic collision cross sections for $C_{3}F_{8}$ molecular gas in $C_{3}F_{8}-Ar$ mixture gases ($C_{3}F_{8}-Ar$혼합가스 상에서 $C_{3}F_{8}$분자가스의 비탄성단면적의 재결정)

  • Jeon, Byoung-Hoon
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.21-23
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    • 2005
  • The electron transport coefficients, the electron drift velocity W, the longitudinal diffusion coefficient $ND_L$ in $C_{3}F_{8}-Ar$ mixture gases were measured by Double shutter drift tube and calculated by multi-term approximation of the Boltzmann equation over the wide E/N range from 0.03 to 100 Td. And an inelastic collision cross sections for $C_{3}F_{8}$ molecular gas were redetermined for quantitative characteristic analysis.

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A Study on Greenhouse Gas Inventories for Regional Governments (A Case Study of Jeonbuk Province) (지자체 온실가스 인벤토리 구축연구 - 전라북도 사례)

  • Jang, Nam-Jung
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.7
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    • pp.565-572
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    • 2009
  • Greenhouse gas(GHG) inventories and basic strategies for Jeonbuk regional government were established to reduce greenhouse gas emissions. The method to construct GHG inventories of Jeonbuk followed the 'Revised IPCC 1996 Guidelines'which was used for the 'Third National Communication of the Republic of Korea under UNFCCC'. Korean government could use primary energy consumption for the energy industries section in the national GHG inventories. However, regional governments should use secondary energy consumption (included electricity consumption) for the energy industries section for their GHG inventories because they could not control the emission of energy transformation section. In the result of Jeonbuk GHG inventories in 2006, carbon dioxide($CO_2$) emissions from fuel combustion covered 87.1% of total emissions. Methane($CH_4$), carbon dioxide($CO_2$) from other sections, nitrous oxide($N_2O$) and F-gas(HFCs, PFCs, $SF_6$) accounted for 8.1, 2.2, 1.6 and 1.0% of total emissions, respectively. The sectional emission decreased in the order of the energy(88.0%), agriculture(7.6%), waste(2.3%) and industrial processes(2.1%) section. The energy industries section that contained electricity consumption was the most dominant emission source in the energy section. F-gas consumption, rice cultivation and waste incineration were main emission sources in the industrial processes, agriculture and waste section, respectively. In this study, basic directions of each section were established by the results of Jeonbuk GHG inventories in 2006.

Combustion Test and Performance Analysis of Fuel Rich Gas Generator (농후 연소 가스발생기의 연소실험과 성능해석)

  • Kwon, Sun-Tak;Lee, Chang-Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.33 no.2
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    • pp.92-97
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    • 2005
  • A series of combustion test was done to verify the optimization result of a gas generator for a 10 ton thrust liquid rocket engine. An injector element is F-O-F impinging type injector and the test was conducted with kerosene/LOX propellants. Test results of combustion temperature and pressure show a very good agreement with optimal design result and verify that the design method was properly established. And turbulence ring revealed its effectiveness in enhancing combustion gas mixing and temperature difference in the radial direction showed only less than 15K. Also turbulence ring induced only 3.2% pressure loss in the combustion chamber, which is far less than conventional level observed in a gas turbine engine. Axial temperature distribution also shows that turbulence ring could effectively reduce about 10% or more in gas generator length if its location is properly selected.

A Study on the Toxic Gases and Smoke Hazard of PASCON Trough (파스콘 트로프의 연기유독성에 관한 연구)

  • Lee, Chang-Woo;Hyun, Seong-Ho;Choi, Don-Mook
    • Fire Science and Engineering
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    • v.20 no.2 s.62
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    • pp.1-7
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    • 2006
  • The aim of the research is to estimate the effect of smoke and combustion gases on humane body indirectly through measuring the toxicity of those. For this purpose, the toxic index of smoke and combustion gases was investigated by smoke hazard test and analysis of smoke which were conducted by KS F 2271 and NES 713 method respectively. It i s proved by KS F 2271 method that PASCON trough is suitable to the testing standard of interior material and construction of building. In addition, it is identified by NES 713 method that combustion gases occurring in PASCON product were only carbon dioxide and carbon monoxide, and the smoke index of those was 0.944. This value means that the hazard effect of smoke gases on humane ! body can possibly happens when exposed to the smoke gases for more than 30 min. In aspect of the domestic situation that have not regulated the hazard estimation and the emissions of smoke when the flame retarding ability of the products have been requested, the toxic indexes of PASCON products are comparatively low.

Refractive index control of F-doped SiOC : H thin films by addition fluorine (Fluorine 첨가에 의한 F-doped SiOC : H 박막의 저 굴절률 특성)

  • Yoon, S.G.;Kang, S.M.;Jung, W.S.;Park, W.J.;Yoon, D.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.2
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    • pp.47-51
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    • 2007
  • F-doped SiOC : H thin films with low refractive index were deposited on Si wafer and glass substrate by plasma enhanced chemical vapor deposition (PECVD) as a function of rf powers, substrate temperatures, gas rates and their composition flow ratios ($SiH_4,\;CF_4$ and $N_2O$). The refractive index of the F-doped SiOC : H film continuously decreased with increasing deposition temperature and rf power. As $N_2O$ gas flow rate decreased, the refractive index of the deposited films decreased down to 1.3778, reaching a minimum value at rf power of 180W and $100^{\circ}C$ without $N_2O$ gas. The fluorine content of F-doped SiOC : H film increased from 1.9 at% to 2.4 at% as the rf power was increased from 60 W to 180 W, which results in the decrease of refractive index.

A study on combustion gas toxicity of polymeric materials using FTIR gas analysis (FTIR 가스분석에 의한 고분자재료의 연소가스독성 평가)

  • Lee, Doo-Hyung;Kong, Young-Kun
    • Journal of the Korean Society of Hazard Mitigation
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    • v.5 no.4 s.19
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    • pp.79-84
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    • 2005
  • When polymeric materials are exposed to fire condition, a lot of heat and toxic gases evolved and cause damage to property and human being. Especially toxic gases are major hazard to life safety. This study FTIR(Fourier Transform Infrared) spectrometer analysis was performaed to etermine the gas analysis and the concentration of gases evolved from PVC, FRP, SMC and Ureathane foam using ASTM E 1678 fire model. And FED toxicity index calculated from FTIR data also presented. By the comparison of animal test adopted in KS F 2271 and FTIR gas analysis method, FTIR gas analysis method can replace current animal toxicity test and produce precise and quantitative combustion gas data.

Characterization of thermal conduction for gas hydrate bearing in-situ sediments (울릉분지 현장 시료와 F110표준사를 이용한 GH함유토의 열전달 양상 분석)

  • Kim, Young Jin;Yun, T.S.
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.148.1-148.1
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    • 2011
  • 본 연구에서는 가스 하이드레이트의 미래 상업생산을 위한 연구활동으로 동해 울릉분지 현장시료를 채취하여 가스 하이드레이트 함유토의 열전도 현상에 관한 연구를 실시하였다. 두 종류의 현장시료를 이용하여 메탄 하이드레이트를 생성하여 공극비 및 포화도에 따라 조건을 달리하여 실험을 수행하였다. 열전도도 측정을 위하여 Transient Plane Source (TPS) 기법을 이용하였다. 현장시료의 사용에 앞서 예비실험으로써 F110표준사를 사용, 비교 분석 자료로써 활용하였다. 하이드레이트 생성 확률을 높이는 기법으로써 불포화시료를 동결, 해동 후 가스를 주입하였으며 동결된 불포화 시료의 열전달양상의 변화를 함께 고찰하였다. 실험결과, 하이드레이트의 포화도가 증가함에 따라 함유토의 열전도도의 증가함을 알 수 있어다. 거의 동일한 물과 GH의 열전도도에도 불구하고 하이드레이트 결정화 작용으로 동일한 포화도의 불포화 시료와 비교하여 약간의 상승을 보였다. 또한 공극비 및 흙을 구성하는 미네랄의 성분에 따라 열전도도의 발현 양상이 상이함을 관찰하였다. 이에 차후 하이드레이트 생산을 위한 현장 측정 및 전산 모사시 이에 관한 고려가 필요할 것으로 사료된다.

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Study on the Surface Reaction of Pt Thin Film with SF$_6$/Ar and Cl$_2$/Ar Plasma Gases (Pt 박막의 SF$_6$/Ar과 C1$_2$/Ar 플라즈마 가스와의 표면반응에 관한 연구)

  • 김상훈;주섭열;안진호
    • Journal of the Microelectronics and Packaging Society
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    • v.8 no.3
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    • pp.63-67
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    • 2001
  • Up to now, most studies about Pt-etching have been focused on physical sputtering mechanism with Cl-based plasma, while only a limited results are available for etching characteristics with fluorine-based plasma. In this study, etch characteristics of Pt thin film with $Cl_2$/Ar and $SF_{6}$/Ar Ar gas chemistries have been studied with ECR plasma etching system. It is confirmed that $SF_{6}$/Ar Ar plasma chemistry could make volatile etch-products through the reaction with Pt thin film. Also the improvement in etch rate, etch profile and surface roughness is obtained due to the formation of volatile platinum fluoride compounds.

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