• Title/Summary/Keyword: Eyring model

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A Study of Two-Mode Failure Model for Crystalline Si Photovoltaic Module (실리콘 태양전지 모듈의 two-mode failure 모델의 연구)

  • Choi, Ki Young;Oh, Won Wook;Kang, Byung Jun;Kim, Young Do;Tark, Sung Ju;Kim, Donghwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.62.2-62.2
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    • 2011
  • To guarantee 20-25 years to the lifetime of the PV modules without failure, reliability test of the module is very important. Field-aged test of the outdoor environment is required. However, due to time constraints, accelerated testing is required to predict the lifetime of PV modules and find causes of failure. Failure is caused by many complex phenomena. In this study, we experimented two accelerated tests about corrosion and fatigue, respectively. First, temperature cycling test for fatigue were tested and Coffin-Manson equation was analyzed. Second, damp heat test for corrosion were tested and Eyring equation were analyzed. Finally, using two-mode failure model, we suggest a new lifetime model that analyze the phenomenon by combining two kinds of data.

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The Rheological and Mechanical Model for Relaxation Spectra of Polydisperse Polymers

  • Kim, Nam Jeong;Kim, Eung Ryul;Hahn Sang Joon
    • Bulletin of the Korean Chemical Society
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    • v.13 no.4
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    • pp.413-419
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    • 1992
  • The theoretical equation for the relaxation spectrum of nonlinear viscoelastic polymeric material was derived from the Ree-Eyring and Maxwell non-Newtonian model. This model consists of infinite number of hyperbolic sine law Maxwell elements coupled in parallel plus a spring without a dashpot. Infinite number of nonlinear viscoelastic Maxwell elements can be used by specifying distribution of relaxation times, hole volumes, molecular weights, crystallite size and conformational size, etc. The experimentals of stress relaxation were carried out using the tensile tester with the solvent chamber. The relaxation spectra of nylon 6 filament fibers in various electrolytic solutions were obtained by applying the experimental stress relaxation curves to the theoretical equation of relaxation spectrum. The determination of relaxation spectra was performed from computer calculation.

Solvent Effect on Stress Relaxation of PET Filament Fibers and Self Diffusion of Crystallites

  • Nam Jeong Kim;Eung Ryul Kim;Sang Joon Hahn
    • Bulletin of the Korean Chemical Society
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    • v.12 no.5
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    • pp.468-473
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    • 1991
  • Viscoelastic properties of PET filament fibers on stress relaxation were investigated in the solvents of $H_2$O, 0.05% NaOH and 50% DMF using an Instron (UTM4-100 Tensilon) with solvent chamber. The theoretical stress relaxation equation derived by applying the Ree-Eyring's hyperbolic sine law to dashpot of three element non-Newtonian model was applied to the experimental stress relaxation curves, and the model parameters $G_1,G_2$, ${\alpha}$ and ${\beta}$ were obtained. By analyzing temperature dependency of the relaxation time, the values of activation entropy, activation enthalpy and activation free energy for flow in PET filament fiber were evaluated, the activation free energy being about 25.7 kcal/mol. The self diffusion coefficient and hole distance were obtained from parameters ${\alpha}$, ${\beta}$ and crystallite size in order to study the self diffusion and the orientation of crystallites in amorphous region and the effect of solvent.

Investigation of the Acceleration Coefficient in Acceleration Models (가속모델의 가속계수 조사)

  • Hyunjong Park;Sungjun Kim;Beomsik Park;Somi Park;Siil Sung
    • Journal of Korean Society for Quality Management
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    • v.52 no.1
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    • pp.135-148
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    • 2024
  • Purpose: This study is to investigate the literature on accelerated tests based on the acceleration model and to provide a compilation of results on the parameters applied in the acceleration model and the test conditions. Methods: This research is conducts a literature review on accelerated tests using the acceleration model, with a focus on test targets, test conditions, and parameter values. The study is organizing the results of this literature review to facilitate their application in the design of reliability tests. Results: A literature review investigated a variety of test targets, test conditions, and parameter values. Conclusion: The results of the literature research conducted revealed various acceleration model parameter. Such literature research on accelerated tests can establish the foundation for reliability test design and contribute to future product development and quality improvement

The Study on the High Acceleration Life Test Method for the Automotive Electric and Electronic Parts (자동차 전장부품의 초 가속 실뇌성 수명시험 방법에 관한 연구)

  • Lee, Jong-Beom;Cho, Jai-Rip
    • Journal of Korean Society for Quality Management
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    • v.28 no.4
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    • pp.16-28
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    • 2000
  • Recently days, High Accelerated Life Test of electrical and electronic parts is increasing its importance. This study set the hypothesis to develop the method that was analysis and application of HALT for the automotive electrical and electronic parts, it used Arrhenius's Model and Eyring's Model, and ESS theory. Validity of application is proved by other test data. Especially, this study emphasis on utility of acceleration to temperature, humidity, voltage, mechanical stress and other stress. In this study set the pattem of practical application. Therefore, this study emphasis on the application of the HALT and the use of other parameter by acceleration reliability test data. The result of this study is as follows. 1) There is relationship between molar weight and material constant. 2) Characteristic of material is operating acceleration factor as well as parts failure factors. Of course, according to the characteristic of material, activation energy is often more important than molar weight. But it will be defined by more testing and improvements in practical application.

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Self Diffusions and Rheological Properties of Polyamide Polymer Materials in Various Solvents (용매 환경에서의 폴리아미드 고분자 재료의 자체확산과 유변학적인 특성)

  • Kim, Nam Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.4
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    • pp.1050-1059
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    • 2019
  • The self diffusion, hole volume, and flow thermodynamic parameters of polyamide fibers were calculated from rheological parameters and crystallite size in order to study of flow segments in amorphous region. The stress relaxation of polyamide filament fibers were carried out in air and various solvents at various temperatures using the tensile tester with the solvent chamber. The rheological parameters were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model. It was observed that the rheological parameters of these polyamide filament fibers are directly related to the relaxation spectra, self diffusion, viscosities, and activation energies of flow segments.

Reliability Assessment Methods for Electronic Component Removed Environmental Materials - focused on Printed Wiring Board without Pb and Br - (환경물질을 제외한 전자부품의 신뢰성평가 방법 연구 -Pb와 Br을 제거한 PWB를 중심으로-)

  • Lee Jong-Beom;Cho Jai-Rip
    • Journal of Applied Reliability
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    • v.5 no.2
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    • pp.241-259
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    • 2005
  • The environmental problem is a main subject of the 21C and an environment destruction phenomenon by various kinds of environmental materials is reaching serious level. Nations to be classified as the environmental developed country, are born again environmental rich country. And they earn a large income by trade Every kind environmental resource in an international commercial transaction. Especially, the study that a reliability assessment method to prevent to reliability problem to be happened when the solder lead(lead-free solder), non-cd component, non-bromide component(without the polybrominated biphenyls(PBB) and polybrominated diphenyl ethers(PBDE))and hexavalent chromium(Cr VI) clearance component and mercury-free applied to electronic equipment is progressed. As the result of the study for applying of a reliability assessment technique of lead-free solder that recognized the most of urgent problem at the company, combination accelerated life test could taken by adding and appling the part of a humidity acceleration part to Eyring Model which is proposed by R.E.Thomas. The reliability assessment methods study of PWB clean environmental materials is expected to respond to a reliability elevation and environmental material regulation policy spreading all over the world by beginning form Europe.

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Reliability Assessment Methods for Electronic Component Removed Environmental Materials - focused on Printed Wiring Board without Pb and Br - (환경물질을 제외한 전자부품의 신뢰성평가 방법 연구 -Pb와 Br을 제거한 PWB를 중심으로-)

  • Lee Jong-Beom;Cho Jai-Rip
    • Proceedings of the Korean Reliability Society Conference
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    • 2005.06a
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    • pp.393-404
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    • 2005
  • The environmental problem is a main subject of the 21C and an environment destruction phenomenon by various kinds of environmental materials is reaching serious level. Nations to be classified as the environmental developed country, are born again environmental rich country. And they earn a large income by trade Every kind environmental resource in an international commercial transaction. Especially, the study that a reliability assessment method to prevent to reliability problem to be happened when the solder lead(lead-free solder), non-cd component, non-bromide component(without the polybrominated biphenyls(PBB) and polybrominated diphenyl ethers(PBDE))and hexavalent chromium(Cr VI) clearance component and mercury-free applied to electronic equipment is progressed. As the result of the study for applying of a reliability assessment technique of lead-free solder that recognized the most of urgent problem at the company, combination accelerated life test could taken by adding and appling the part of a humidity acceleration part to Eyring Model which is proposed by R.E.Thomas. The reliability assessment methods study of PWB clean environmental materials is expected to respond to a reliability elevation and environmental material regulation policy spreading all over the world by beginning form Europe.

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Significant Structure of Liquid Water (물의 구조와 성질)

  • Pak, Hyung-Suk;Chang, Sei-Hun
    • Journal of the Korean Chemical Society
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    • v.8 no.2
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    • pp.68-74
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    • 1964
  • Water has the melting point, the boiling point, the heat of fusion, and the heat of vaporization all much higher than would be normally expected from the hydrogen compounds of the other members of the oxygen family. Another unique characteristic of ice-Ⅰ is its volume decrease which takes place in its melting. A number of significant efforts have been made in the past to explain these properties quantitatively. The authors, reasoning from the unusually great free surface energy of water and the characteristic volume change on melting, propose the structural model of liquid water as follows. On melting, fluidized vacancies of a molecular size are introduced. Thereupon, for the unusually great surface energy density, molecules surrounding the vacancies become to have close packed arrangement. But molecules not in direct contact with vacancies should still possess the original structure i. e., ice-Ⅰ. When a molecule adjacent to a vacancy jumps into the vacancy, the molecule attains the gaslike degree of freedom. Using the above model, the authors had developed the liquid partition function of water by applying the theory of significant structures in liquids. Molar volume, vapor pressure, entropy of fusion and entropy of vaporization were calculated over a wide temperature range. The results show good agreement with experimental observations.

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An experimental study on the characteristic times of viscoelastic fluids by falling ball viscometer (낙구식 점도계를 이용한 점탄성 유체의 특성시간에 관한 실험적 연구)

  • 전찬열;유상신
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.1
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    • pp.241-250
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    • 1990
  • Characteristic relaxation time and characteristic diffusion time of viscoelastic fluids are determined experimentally by measuring the zero-shear-rate viscosity by falling ball viscometer and the infinite-shear-rate viscosity by capillary tube viscometer. Fluids used in experiments are aqueous solutions of polyacrylamide Separan AP-273 and the polymer concentrations range from 300 to 2000 wppm. A newly designed laser beam and timer system is employed to overcome the difficulty in measuring terminal velocities of the low concentration solutions. Ball removal device is prepared to remove the dropped ball from the bottom of cylinder without disturbing the testing fluid. In order to measure the zero-shear-rate viscosity, densities of hollow aluminium balls are adjusted very close to the densities of testing fluids. Characteristic diffusion time, which is ball viscometer. However, terminal velocity of a needle by falling ball viscometer is not affected by the time interval of dropping needles and characteristic diffusion time is not measured with a dropping needle. Powell-Eyring model predicts the highest values of the characteristic relaxation times among models used for heat transfer experimental works for a given polymer solution. As degradation of a polymer solution continues, the zero-shear-rate viscosity decreases more seriously than the infinite-shear-rate viscosity. Characteristic relaxation times of polymer solutions decreases as degradation continues.