• Title/Summary/Keyword: Extraction system

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Extraction of Acetic Acid by Aliphatic Amino Extractants (지방족 아민 추출제에 의한 초산의 추출)

  • Lee, Han-Seob
    • Applied Chemistry for Engineering
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    • v.5 no.1
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    • pp.121-126
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    • 1994
  • To elucidate the effect on the reactive extraction of acetic acid, various carriers and modifiers were investigated. Carriers used were secondary and tertiary amines and solvation extractant. Diluent was n-butylacetate. Modifiers were 4-nonylphenol, TBP(Tti-n-butyl phospate) and isodecanol. Besides the effect of temperature and pH in aqueous phase were studied. The mixture of 50% tri-n-octyl/n-decylamine tertiary amine, gave higher degree of extraction and selectivity than other extractants in the extraction of acetic acid. It was found that 4-nonylphenol as modifier fairly good. The degree of extraction was higher with decreasing the pH in aquous phase and the temperature of extraction system.

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Back-Extraction Processes of C.C.Lipase with Mediated AOT Reverse Micellar System

  • Lee, Sung-Sik;Kim, Bong-Gyu;Sung, Nak-Chang;Lee, Jong-Pal
    • Bulletin of the Korean Chemical Society
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    • v.25 no.6
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    • pp.873-877
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    • 2004
  • The relationship between the behaviors of c.c.lipase back-extraction and their percolation phenomena by using AOT reverse micellar systems (RVMS) has been studied by the addition of a small amount of additives to organic phase such as thiols and nonionic-surfactants focusing on micelle-micelle interactions. The values of ${\beta}_t$ defined by the variation of percolation processes and back-extraction behaviors of c.c.lipase have a good linear correlation. The hydrophobicity of additive molecules suppressing the cluster formation of reverse micelles (high values of ${\beta}_t$) improved the back-extraction behavior of c.c.lipase. The back-extraction fraction and its rate of c.c.clipase are increased with decreasing of the value of hydrophilic lipophilic balance (HLB) and increasing of the hydrophobicity per additive molecules added to reverse micellar systems (RVSM) in the same additives concentration.

Extraction behavior of $\alpha$-lactalbumin using reverse micellar system

  • Noda, Kazuki;Konishi, Taiji;Naoe, Kazumitsu;Kawagoe, Mikio;Imai, Masanao
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.179-182
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    • 2004
  • This study reports the extraction behavior of $\alpha$-lactalbumin using bis(2-ethylhexyl) sulfosuccinate sodium (AOT) reverse micelles. Forward extraction of $\alpha$-lactalbumin in the reverse micellar organic phase from aqueous feed solutions was strongly dependent on the AOT concentration and the complete forward extraction of 0.03 mM $\alpha$-lactalbumin was successfully achieved at an AOT concentration of ca. 100 mM. A similar dependency of the forward extraction on the AOT concentration was obtained in isooctane, n-hexane, and n-octane systems. In the backward extraction from the micellar organic phase, the recovery of the protein as high as ca. 90% was obtained with pH control and/or salt addition.

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Effect of Alcohol Addition on Back-Extraction of BSA and Cytochrome c Using AOT Reverse Micellar System

  • Lee, Seong Sik;Lee, Bong Guk;Choe, Jin Seong;Lee, Jong Pal
    • Bulletin of the Korean Chemical Society
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    • v.22 no.8
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    • pp.897-902
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    • 2001
  • The protein back-extraction processes were discussed from the viewpoint of the micelle-micelle interaction. Bovine serum albumin (BSA) suppressing the cluster formation of reverse micelle (positive value of ${\beta}pr)$ has the high back-extra cted fraction (Eb), but cytochrome c enhancing the formation of reverse micelle (negative value of ${\beta}pr)$ has the low back-extracted fraction, relatively. We have also examined quantitatively the effects of alcohol addition and protein solubilization on the percolation process of reverse micelle. The alcohols suppressing the formation of micellar cluster (high values of ${\beta}t)$, remarkably improved the back-extraction rates of BSA and cytochrome c. The values of ${\beta}t$, defined by the variation of percolation process, and the back-extraction behavior of proteins have a good linear correlation. These results indicate that the micelle-micelle interaction or micellar clustering plays an important role in the back-extraction process of proteins.

Extraction Behavior of Uranyl Ion From Nitric Acid Medium by TBP Extractant in Ionic Liquid

  • Kim, Ik-Soo;Chung, Dong-Yong;Lee, Keun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.4
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    • pp.457-464
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    • 2020
  • In this study, extraction of uranium(VI) from an aqueous nitric acid solution was investigated using tri-n-butyl phosphate (TBP) as an extractant in an ionic liquid, 1-alkyl-3-methylimidazolium bis (trifluoromethylsulfonyl)imide ([Cnmim][Tf2N]). The distribution ratio of U(VI) in 1.1 M TBP/[Cnmim][Tf2N] was significantly high when the concentration of nitric acid was low. The value of the distribution ratio decreased as the concentration of the nitric acid increased at lower acidities, and then increased with a nitric acid concentration of up to 8 M. This can be attributed to the different extraction mechanisms of U(VI) based on nitric acid concentrations. Thus, a cation exchange at low acidity levels and an ion-pair extraction at high acidity levels were suggested as the extraction mechanism of U(VI) in the TBP/[Cnmim][Tf2N] system.

Calculation of Radius of Influence and Evaluation of Applicability of Air Sparging/Soil Vapor Extraction system for the Remediation of Petroleum Contaminated Rail Site (유류로 오염된 철로지역의 지중정화를 위한 영향반경 산정과 공기주입법/토양증기추출법의 적용성 평가)

  • Cho, Chang-Hwan;Park, Joung-Ku;Kim, Yong-Deok;Seo, Chang-Il;Jin, Hai-Jin;Choi, Sang-Il
    • Journal of Soil and Groundwater Environment
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    • v.20 no.1
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    • pp.1-6
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    • 2015
  • The objectives of this study were to calculate the radius of influence (ROI) of well for an air-sparging (AS)/soil vapor extraction (SVE) system and to evaluate the applicability of the system applied for the remediation of the petroleum contaminated rail site. For air permeability test, three monitoring wells were installed at a location of 1.3 m, 2.3 m, 3.0 m from the extraction well. And the pressure of each monitoring well was measured by extracting air from the extraction well with the pressure and flow of $(-)2,600mmH_2O$ and $1.58m^3/min$. The ROI for an extraction well was calculated as 4.31 m. Air was injected into the injection well with the pressure and flow of $3,500mmH_2O$ and $0.6m^3/min$ to estimate the radius of influence for oxygen transfer. Oxygen concentrations of air from three monitoring wells were measured. The ROI of an injection well for oxygen transfer was calculated as 3.46 m. The 28 extraction wells and 19 injection wells were installed according to the ROI calculated. The AS/SVE system was operated eight hours a day for five months. The rail site was contaminated with the petroleum and concentrations of benzene, toluene, and xylene were over the 'Worrisome Standard' of the 'Soil Environment Conservation Act'. The contaminated area was estimated as $732m^2$ and contaminants were dispersed up to (-)3 m from the ground. During the operation period, soil samples were collected from 5 points and analyzed periodically. With the AS/SVE system operation, concentrations of benzene, toluene, and xylene were decreased from 7.5 mg/kg to 2.0 mg/kg, from 32.0 mg/kg to 23.0 mg/kg, from 35.5 mg/kg to 23.0 mg/kg, respectively. The combined AS/SVE system applied to the rail site contaminated with volatile organic compounds (VOCs) exhibited a high applicability. But the concentration of contaminants in soil were fluctuated due to the heterogeneous of soil condition. Also the effect of the remediation mechanisms was not clearly identified.

All-optical Data Extraction Based on Optical Logic Gates (반도체 광 증폭기를 이용한 전광 데이터 추출)

  • Lee, Ji Sok;Jung, Mi;Lee, Hyuk Jae;Lee, Taek Jin;Jhon, Young Min;Lee, Seok;Woo, Deok Ha;Lee, Ju Han;Kim, Jae Hun
    • Korean Journal of Optics and Photonics
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    • v.23 no.4
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    • pp.143-146
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    • 2012
  • All-optical data extraction, one of the key technologies for all-optical computing and optical communication to perform add-drop, packet switching, and data reset, etc., is experimentally demonstrated by using cross-gain modulation (XGM) of semiconductor optical amplifiers (SOAs). Also, all-optical data extraction based on numerical simulation is performed by using the VPI simulation tool. In this paper, the suggested optical system based on SOAs shows the potential for high speed, and highly integrable and low power optical data computing.

Pulse Diagnosis Algorithm and Digital Filter Design for Development of Digital Biomedical System (전자 맥진기 시스템 개발을 위한 맥파분석 알고리즘과 디지털 필터 설계)

  • Kim, Sang-Ho;Lim, Duk-Gyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.11
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    • pp.4473-4482
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    • 2010
  • The examination of pulse, which is a typical palpation technique in the oriental medicine, has been used conventional analog system for discrimination of 28 pulses. However, the clipping phenomenon in the pulses, which used same feature extraction technique with ECG signals, has been occurred in analog system due to feature extraction method and over amplification from the input signals. It caused inaccurate to analyze the pulse signals. In this paper, we propose a digital filter design technique based on Prony's method for signal modeling and C-spline interpolation for feature extraction from pulse signal to compensate analog pulse detection system. In addition, we suggest a compensated electronic pulse detection system comprising new pulse analyzing algorithm and shape analysis technique for pulses, which were difficult to use in analog system. The feasibility for new proposed system has been confirmed comparing output signals between electronic pulse detection system having proposed filter design techniques with pulse analyzing algorithm and conventional analog system.

Development of the Sample Pretreatment Technique using Microwave for Analysis of Insecticide Imidacloprid Residues (마이크로파를 이용한 잔류 살충제 Imidacloprid 분석용 시료전처리 기술개발)

  • Ahn, S.Y.;Cho, H.K.;Lee, E.Y.
    • Journal of Biosystems Engineering
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    • v.32 no.2 s.121
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    • pp.121-129
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    • 2007
  • This study was conducted to elucidate extraction efficiency by microwave technique in comparison with sonication technique for extraction of insecticide residue in pear. In the analysis of the extraction efficiency of microwave for a pear spiked with imidacloprid, the extraction efficiency by microwave power of 300 W with extraction temperature of $80^{\circ}C$, heating time of 1 to 3 minute was shown to be similar with the extraction time 20 minutes by sonication. The optimal condition. in consideration of economical condition and treatment time, for microwave extraction of imidacloprid in the pear were 300 watts of power supply, $100^{\circ}C$ of extraction temperature, 1 minute of heating time and 10 mL of acetone volume. A new microwave vessel was developed to rapidly process the sample of the insecticide imidacloprid residues in the pear. This vessel was designed to include a reaction chamber and a filtration equipment, and a gathering chamber. The system could curtail a pretreatment time to 21 minutes than sonication and 7.9 minutes than the previous microwave vessel.

A Study on Extracting News Contents from News Web Pages (뉴스 웹 페이지에서 기사 본문 추출에 관한 연구)

  • Lee, Yong-Gu
    • Journal of the Korean Society for information Management
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    • v.26 no.1
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    • pp.305-320
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    • 2009
  • The news pages provided through the web contain unnecessary information. This causes low performance and inefficiency of the news processing system. In this study, news content extraction methods, which are based on sentence identification and block-level tags news web pages, was suggested. To obtain optimal performance, combinations of these methods were applied. The results showed good performance when using an extraction method which applied the sentence identification and eliminated hyperlink text from web pages. Moreover, this method showed better results when combined with the extraction method which used block-level. Extraction methods, which used sentence identification, were effective for raising the extraction recall ratio.