• Title/Summary/Keyword: External mixture

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Preparation of Pt Catalysts Supported on ACF with CNF via Catalytic Growth

  • Park, Sang-Sun;Rhee, Jun-Ki;Jeon, Yu-Kwon;Choi, Sung-Won;Shul, Yong-Gun
    • Carbon letters
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    • v.11 no.1
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    • pp.38-40
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    • 2010
  • Carbon supported electrocatalysts are commonly used as electrode materials for polymer electrolyte membrane fuel cells(PEMFCs). These kinds of electrocatalysts provide large surface area and sufficient electrical conductivity. The support of typical PEM fuel cell catalysts has been a traditional conductive type of carbon black. However, even though the carbon particles conduct electrons, there is still significant portion of Pt that is isolated from the external circuit and the PEM, resulting in a low Pt utilization. Herein, new types of carbon materials to effectively utilize the Pt catalyst are being evaluated. Carbon nanofiber/activated carbon fiber (CNF/ACF) composite with multifunctional surfaces were prepared through catalytic growth of CNFs on ACFs. Nickel nitrate was used as a precursor of the catalyst to synthesize carbon nanofibers(CNFs). CNFs were synthesized by pyrolysising $CH_4$ using catalysts dispersed in acetone and ACF(activated carbon fiber). The as-prepared samples were characterized with transmission electron microscopy(TEM), scanning electron microscopy(SEM). In TEM image, carbon nanofibers were synthesized on the ACF to form a three-dimensional network. Pt/CNF/ACF was employed as a catalyst for PEMFC. As the ratio of prepared catalyst to commercial catalyst was changed from 0 to 50%, the performance of the mixture of 30 wt% of Pt/CNF/ACF and 70wt% of Pt/C commercial catalyst showed better perfromance than that of 100% commercial catalyst. The unique structure of CNF can supply the significant site for the stabilization of Pt particles. CNF/ACF is expected to be promising support to improve the performance in PEMFC.

APOLLO2 YEAR 2010

  • Sanchez, Richard;Zmijarevi, Igor;Coste-Delclaux, M.;Masiello, Emiliano;Santandrea, Simone;Martinolli, Emanuele;Villate, Laurence;Schwartz, Nadine;Guler, Nathalie
    • Nuclear Engineering and Technology
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    • v.42 no.5
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    • pp.474-499
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    • 2010
  • This paper presents the mostortant developments implemented in the APOLLO2 spectral code since its last general presentation at the 1999 M&C conference in Madrid. APOLLO2 has been provided with new capabilities in the domain of cross section self-shielding, including mixture effects and transfer matrix self-shielding, new or improved flux solvers (CPM for RZ geometry, heterogeneous cells for short MOC and the linear-surface scheme for long MOC), improved acceleration techniques ($DP_1$), that are also applied to thermal and external iterations, and a number of sophisticated modules and tools to help user calculations. The method of characteristics, which took over the collision probability method as the main flux solver of the code, allows for whole core two-dimensional heterogeneous calculations. A flux reconstruction technique leads to fast albeit accurate solutions used for industrial applications. The APOLLO2 code has been integrated (APOLLO2-A) within the $ARCADIA^{(R)}$ reactor code system of AREVA as cross section generator for PWR and BWR fuel assemblies. APOLLO2 is also extensively used by Electricite de France within its reactor calculation chain. A number of numerical examples are presented to illustrate APOLLO2 accuracy by comparison to Monte Carlo reference calculations. Results of the validation program are compared to the measured values on power plants and critical experiments.

Effect of Emulsified Refine Cooking Oil and Expandable Microsphere on Durability of High-Volume Blast Furnace Slag Concrete (정제유지류 및 팽창성 인공 기포 조합이 고로슬래그 다량치환 콘크리트의 내구성 및 미시적 특성에 미치는 영향)

  • Han, Min-Cheol;Han, Dongyeop;Lee, Myung-Ho
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.2
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    • pp.201-207
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    • 2015
  • In this paper, a series of experiments was conducted to evaluate the resistibility of carbonation and freeze-thawing damage of the high-volume blast furnace slag concrete using expancel, the expandable microsphere, and ERCO, emulsified refine cooking oil. The concrete mixture of 0.45 water-to-binder ratio with 60% of blast furnace slag was evaluated for carbonation, freeze-thawing resistibility, SEM, and porosity. According to the previous research, replacing ERCO contributes on improving carbonation resistibility with capillary pore filling effect by soap foaming reaction of ERCO while significantly decreased freeze-thawing resistibility. To improve this decreased freeze-thawing resistibility, expancel was used, and thus freeze-thawing resistibility was improved as the replacement ratio of expancel was increased. It is considered that the selective volume shrunken effect of expancel due to the external pressure and decreased air void spacing factor due to expancel.

Performance of R502 Alternative Refrigerants for Low Temperature Applications (저온용 R502 대체냉매의 성능 평가)

  • Ha Jong-Chul;Hwang Ji-Hwan;Baek In-Chul;Jung Dongsoo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.10
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    • pp.883-890
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    • 2005
  • In this study, 2 pure hydrocarbon refrigerants of R1270 (Propylene) and R290 (Propane) and 3 binary mixtures composed of R1270, R29O and R152a were tested in a refrigerating bench tester with a scroll compressor in an attempt to substitute R502 used in most of the low temperature applications. The test bench provided 3\sim3.5$ kW capacity and water and water/glycol mixture were employed as the secondary heat transfer fluids. All tests were conducted under the same external conditions resulting in the average saturation temperatures of -28 and $45^{\circ}C$ in the evaporator and condenser, respectively. Test results showed that all refrigerants tested had $9.6\sim18.7\%$ higher capacity and $17.1\sim27.3\%$ higher COP than R502. The compressor discharge temperature of R1270 was similar to that of R502 while those of all other refrigerants were $23.7\sim27.9\%$ lower than that of R502. For all alternative refrigerants, the amount of charge was reduced up to $60\%$ as compared to R502. Overall, these alternative refrigerants offer better system performance and reliability than R502 and can be used as long term substitutes for R502 due to their excellent environmental properties.

The Occurrence and Formation Mode of Basaltic Rocks in the Tertiary Janggi Basin, Janggi Area (제 3기 장기분지에 나타나는 현무암질암의 산상과 형성기구)

  • Kim, Choon-Sik;Kim, Jin-Seop
    • The Journal of the Petrological Society of Korea
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    • v.16 no.2 s.48
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    • pp.73-81
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    • 2007
  • A basaltic tuff formation (Upper Basaltic Tuff of the Janggi Group) occurs in close association with basalt (Yeonil Basalt) at the Tertiary Janggi basin. The purpose of this paper is to describe the occurrence of the basaltic tuff and associated basalt and to determine their mode of formation. The basaltic rocks of the study area show few distinct lithofacies, all of which are originated from the interaction of basaltic magma with external water. The four lithofacies include (1) sideromelane shard hyaloclastite, (2) pillow breccia, (3) entablature-jointed basalt, and (4) in-situ breccia. The sideromelane shard hyaloclastite constitutes most of the Upper Basaltic Tuff and has a gradual contact with the pillow breccia. The pillow breccia consists of a poorly sorted mixture of isolated and broken pillows, and small basalt globules and fragments engulfed in a volcanic matrix of sideromelane shard hyaloclastite. The entablature-jointed basalt occurs as a small body within the hyaloclastite. It is characterized by irregularly-curved joints known as entablature. The in-situ breccia occurs as a marginal facies of entablature-jointed basalt, and its width varies from 10 to 30m. The result of this study indicates that the basaltic tuff and associated basalts of the study area were produced by the volcanic activity of same period and the basaltic tuff was formed by subaqueous eruption of basaltic lava followed by nonexplosive quench fragmentation.

Sustainable Slow Design in Contemporary Fashion Design (현대 패션에 표현된 지속가능한 느린 디자인)

  • Lee, Youn-Hee;Lee, Hyun-Ah;Park, Jae-Ok
    • Journal of the Korean Society of Clothing and Textiles
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    • v.31 no.1 s.160
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    • pp.21-32
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    • 2007
  • The purpose of this study is to establish the idea of sustainable slow design by analyzing literatures and preceding cases, based on the external elements of a design including forms, the methods of expression, materials and colors. This study reviewed the previous literature of books and pictures related to the research for case studies and content analysis. fashion books, magazines, and web-sites published from 2000 to 2005 were analyzed for this research. The sustainable slow design trends in fashion can be summarized as follow. The first is a timeless style which has sustain ability in design independently of the versatile fads and relies on functionality, serving the purpose of design. One of the examples is both clothes designed by Burberry and suits by Chanel. The second is a hand-touch style which the more time for outputs can be positively tolerated, in favor on eco-friendly design through the techniques of manual arts. The third is a renewable design which the combined values of design with reuse and renewal result in recreation of past ecology as shown in the technique of designs by mix & match. The forth is a transformable design which features the multi-purpose and multi-forms, eventually extending the lift cycle of products. As a result of analysis of the four designs above, it can be inferred that the representation of past styles, the mixture of old design with new design, the appropriate combination of conventional fabrics with advanced ones, the ecological trends of sports look was emerging.

Performance of R290 and R1270 as Alternative Refrigerants of R22 According to Temperature Variations of Evaporator and Condenser (증발기와 응축기 온도변화에 따른 R22 대체냉매 R290 및 R1270의 성능평가)

  • Baek In-Cheol;Park Ki-Jung;Shim Yun-Bo;Jung Dong-Soo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.10
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    • pp.761-767
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    • 2006
  • In this study, performance of 2 pure hydrocarbons R290 and R1270 was measured in an attempt to substitute R22 under 3 different temperature conditions. They were tested in a refrigerating bench tester with a hermetic rotary compressor. The test bench provided about 3.5 kW capacity and water and water/glycol mixture were employed as the secondary heat transfer fluids. All tests were conducted under the same external conditions resulting in the average saturation temperatures of $7/45^{\circ}C$ and $-7/41^{\circ}C$ and $-21/28^{\circ}C$ in the evaporator and condenser, respectively. Test results show that the coefficient of performance (COP) of these refrigerants is up to 11.54% higher than that of R22 in all temperature conditions. Compressor discharge temperatures were reduced by $14{\sim}31^{\circ}C$ with these fluids. There was no problem with mineral oil since the mixtures were mainly composed of hydrocarbons. The amount of charge was reduced up to 58% as compared to R22. Overall, these fluids provide good performance with reasonable energy savings without any environmental problem and thus can be used as long term alternatives for residential air-conditioning and heat pumping application.

Performance Evaluation of R22 Alternative Refrigerants According to Temperature Variations of Evaporator and Condenser (증발기와 응축기 온도변화에 따른 R22 대체냉매의 성능평가)

  • Baek, In-Cheol;Shim, Yun-Bo;Jung, Dong-Soo
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.58-63
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    • 2006
  • In this study, performance of 2 pure hydrocarbons and 3 mixtures was measured in an attempt to substitute R22 under 3 different temperature conditions. The mixtures were composed of R1270(propylene), R290(propane) and R152a. They were tested in a refrigerating bench tester with a hermetic rotary compressor The test bench provided about 3.5 kW capacity and water and water/glycol mixture were employed as the secondary heat transfer fluids. All tests were conducted under the same external conditions resulting in the average saturation temperatures of $7^{\circ}C/45^{\circ}C$ and $-7^{\circ}C/41^{\circ}C$ and $-21^{\circ}C/28^{\circ}C$ in the evaporator and condenser, respectively. Test results show that the coefficient of performance (COP) of these refrigerants is up to 11.54% higher than that of R22 in all temperature conditions. Compressor discharge temperatures were reduced by $14{\sim}31^{\circ}C$ with these fluids. There was no problem with mineral oil since the mixtures were mainly composed of hydrocarbons. The amount of charge was reduced up to 58% as compared to R22. Overall, these fluids provide good performance with reasonable energy savings without any environmental problem and thus can be used as long term alternatives for residential air-conditioning and heat pumping application.

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Hydrogen Sulfide Removal in Full-scale Landfill Gas Using Leachate and Chelated Iron (침출수 및 철킬레이트를 이용한 실규모 매립가스 내 황화수소 제거)

  • Park, Jong-Hun;Kim, Sang-Hyoun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.2
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    • pp.51-56
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    • 2019
  • $H_2S$ is a detrimental impurity that must be removed for upgrading biogas to biomethane. This study investigates an economic method to mitigate $H_2S$ content, combining scrubbing and aeration. The desulfurization experiments were performed in a laboratory apparatus using EDTA-Fe or landfill leachate as the catalyst and metered mixture of 50-52% (v/v) $CH_4$, 32-33% (v/v) $CO_2$ and 500-1,000 ppmv $H_2S$ balanced by $N_2$ using the C city landfill gas. Dissolved iron concentration in the liquid medium significantly affected the oxidation efficiency of sulfide. Iron components in landfill leachate, which would be available in a biogas/landfill gas utilization facility, was compatible with an external iron chelate. More than 70% of $H_2S$ was removed in a contact time of 9 seconds at iron levels at or over 28 mM. The scrubbing-aeration process would be a feasible and easy-to-operate technology for biogas purification.

Changes in Rheological Properties of O/W Emulsions according to the Type of Nonionic Surfactant and Emulsion Stabilizer (비이온 계면활성제, 유화안정제 종류에 따른 O/W 유화 제형의 유변학적 특성 변화)

  • Choi, Joong Seok;Jin, Byung Suk
    • Applied Chemistry for Engineering
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    • v.30 no.4
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    • pp.415-420
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    • 2019
  • To investigate the effect of nonionic surfactant and emulsion stabilizer on O/W emulsions, various emulsion formulations with different types of nonionic surfactants and emulsion stabilizers were prepared and their rheological properties were compared. In this study, polysorbate 60 (Tween 60), PEG-60 hydrogenated castor oil (HCO 60), octyldodeceth-16 (OD 16), and ceteareth-6 olivate (Olivem 800) were used as hydrophilic nonionic surfactants, whereas cetyl alcohol, glyceryl monostearate, and stearic acid as emulsion stabilizers. Phase separation occurred only in the emulsion formulation with octyldodeceth-16 and all other emulsion formulations maintained a stable phase. The viscosity, hardness, and creaminess of emulsion formulation using a mixture of ceteareth-6 olivate and cetyl alcohol were the highest, and the emulsified droplet size was also the largest. These results are due to the formation of a network structure texture with the development of a large amount of liquid crystal in the O/W emulsion. In this formulation, the value of elastic modulus was large and the thixotropic behavior, in which the viscosity varies with the history of external force, was observed.