• Korean Chemical Engineering Research
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• 제54권4호
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• pp.487-493
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• 2016

양이온교환 고성능액체크로마토그래피에서 라이소자임을 분석하고, 실험결과인 크로마토그램을 통해 모멘트 분석을 수행하였다. 용리 인산완충용액은 1.0, 0.75, 0.5 M의 소금을 포함하였다. 실험변수는 유량, 용리 완충용액중 소금 농도, 시료의 농도로 하였다. General rate (GR) model을 도입하여 1차와 2차 모멘트를 해석하였다. 1차 모멘트 해석에서 평형상수 K를 구할 수 있으며, 이는 $L/u_0$ vs. $({\mu}_1-t_0)/(1-{\varepsilon}_e)(1-{\varepsilon}_i)$]를 도식화했을 때의 기울기이다. 2차 모멘트 해석에서 입자내 확산계수는 이론단수 실험자료에서 계산하였다. 모멘트 분석결과를 통해 여러 물질전달 현상이 이론단 상당높이(HETP)에 주는 영향을 알아보기 위해 van Deemter plot을 작성하고, 총괄 이론단 상당높이($H_{total}$)에 기여하는 $H_{ax}$, $H_f$, 그리고 $H_d$를 조사하였다. 그 중 입자내 확산계수를 나타내는 $H_d$가 가장 지배적이었고, 외부 물질전달 계수를 나타내는 $H_f$의 영향이 가장 미미했다.

• Macromolecular Research
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• 제17권7호
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• pp.528-532
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• 2009

The size and shape of free volume (FV) holes available in membrane materials control the rate of gas diffusion and its permeability. Based on this principle, a segmented, thermo-sensitive polyurethane (TSPU) membrane with functional gate, i.e., the ability to sense and respond to external thermo-stimuli, was synthesized. This smart membrane exhibited close-open characteristics to the size of the FV hole and water vapor permeation and thus can be used as smart food packaging materials. Differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), positron annihilation lifetimes (PAL) and water vapor permeability (WVP) were used to evaluate how the morphological structure of TSPU and the temperature influence the FV holes size. In DSC and DMA studies, TSPU with a crystalline transition reversible phase showed an obvious phase-separated structure and a phase transition temperature at $53^{\circ}C$ (defined as the switch temperature and used as a functional gate). Moreover, the switch temperature ($T_s$) and the thermal-sensitivity of TSPU remained available after two or three thermal cyclic processes. The PAL study indicated that the FV hole size of TSPU is closely related to the $T_s$. When the temperature varied cyclically from $T_s-10{\circ}C$ to $T_s+10^{\circ}C$, the average radius (R) of the FV holes of the TSPU membrane also shifted cyclically from 0.23 to 0.467 nm, exhibiting an "open-close" feature. As a result, the WVP of the TSPU membrane also shifted cyclically from 4.30 to $8.58\;kg/m^2{\cdot}d$, which produced an "increase-decrease" response to the thermo-stimuli. This phase transition accompanying significant changes in the FV hole size and WVP can be used to develop "smart materials" with functional gates and controllable water vapor permeation, which support the possible applications of TSPU for food packaging.

• 산업경영시스템학회지
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• 제43권1호
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• pp.132-142
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• 2020

Many countries around the world are pursuing various support policies to foster start-ups national widely in order to secure new economic growth engines in the era of the Fourth Industrial Revolution. The South Korean government announced the diffusion strategy for the 2'nd round Start-up Boom in March 2019 and is promoting the support policies for start-up incubating by various programs. Many incubators and startup accelerators operate various kinds of programs to foster start-ups using government financial supports. The purpose of this study is to investigate the effects of entrepreneurship and technical capability of entrepreneurs as the internal factors of the technology-based start-ups and the effects of programs supported by the government as an external factor on the corporate performance of a start-up company, and the mediating effects of core competence of start-ups were analyzed using SPSS and AMOS. The results show that the entrepreneurship, technical capability and the programs supported by incubators or accelerators had no direct effects on the corporate performance of a start-up, but the core competence of the company had complete mediating effects. In addition, the type of program supported by the comprehensive accelerator programs or the marketing supports had effects on the core competence rather than simple financial supports. Lastly, the policy proposals for incubating program support and future research directions along with the limitation are suggested.

• Bulletin of the Korean Chemical Society
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• 제29권2호
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• pp.422-426
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• 2008

Hemodialysis graft coated with paclitaxel prevents stenosis; however, large initial burst release of paclitaxel causes many negative effects such as drug toxicity and inefficient drug loss. Therefore we developed and tested a novel coating method, double dipping, to provide controlled and sustained release of paclitaxel locally. Expanded polytetrafluoroethylene (ePTFE) grafts were dipped twice into a solution of several different paclitaxel concentrations. In vitro release tests of the double dipping method showed that early burst release could be somewhat retarded and followed by sustained release for a long time. We observed the effect of paclitaxel coating by double dipping in porcine model of arterio-venous (AV) grafts between the common carotid artery and the external jugular vein. 12 weeks after constructing AV grafts, cross sections of the graft venous anastomosis were obtained and analyzed. Paclitaxel coated ePTFE grafts by double dipping were observed to prevent neointimal hyperplasia and therefore reduced stenosis of the arteriovenous hemodialysis grafts, especially at the graft venous anastomosis sites. Our results demonstrate that second dipping of ePTFE graft, which was already coated once with paclitaxel, washes off the drug on a surface of the graft and affects the ratio of paclitaxel on the surface to that of the inner space, possibly by diffusion: thus the early burst of drug can be somewhat reduced.

• 청정기술
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• 제20권1호
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• pp.51-56
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• 2014

본 연구에서는 폴리술폰(polysulfone, PSf)으로 알루미늄 수산화물(aluminum hydroxide, $Al(OH)_3$)을 고정화한 PSf-$Al(OH)_3$ 비드를 제조하였다. 제조한 PSf-$Al(OH)_3$ 비드에 의한 불소 이온 제거실험은 회분식으로 수행하였으며, pH, 초기농도, 공존이온과 같은 변수들의 영향을 살펴보았다. Langmuir 등온식으로 구한 불소 이온의 최대 제거량은 52.4 mg/g이었으며, 최적 pH 범위는 4~10이었다. PSf-$Al(OH)_3$ 비드에 의한 불소 이온의 제거과정은 전 단계에서 외부물질전달이 나중 단계에서 내부확산이 지배인 것을 알 수 있었다. 또한 PSf-$Al(OH)_3$에 의한 불소 이온의 제거에서 $HCO_3{^-}$, $SO{_4}^{2-}$, $NO_3{^-}$, $Cl^-$와 같은 공존 음이온들은 불소 이온의 제거에 방해를 하는 것으로 나타났다.

• 한국지반공학회지:지반
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• 제13권1호
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• pp.137-146
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• 1997

A Study on the 본 연구에서는 플라스틱드레인을 이용하여 진공수평배수에 의해 개량된 준설 점토 지반의 압밀거동을 파악하기 위하여 대형 압밀시험을 실시하였으며, 실험 결과가 포텐결중공원주의 압밀이론을 이용한 수치해석에 의해 비교 검토되었다. 본 연구 실험결과에 의하면 수평배수진공압밀시험은 점토층 내부의 함수비 및 간극수압과 드레인 배수 속도 등이 진공압밀 시간 경과에 따라 감소되어 압밀이 급속하게 진행되고 있음이 확인되었다. 점토층 중공원주의 방사류에 대한 선형포텐샬압밀이론을 이용하여 수치 압밀해석 결과 간극수압은 확산 형태보다 흙의 변형과 투수에 의해 크게 좌우되고 있으므로, 지표면 부근에서의 실측 침하량은 압밀응력증가율 a가 -0.5정도에서 수치해석과 일치하며 또한 드레인 설치 부근에서의 점토층 침하량은 Baryon 압밀이론과 유사한 거동을 나타내고 있다. 최종적으로 수평 배수에 대한 적당한 선택과정을 포함한 설계 및 시공관리가 시험결과에 의하여 설명 되었으며 포텐셜압밀이론은 진공배수시 수평드레인에 의한 압밀거동을 정확하게 예측할 수 있다.

• 한국분말재료학회지
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• 제26권5호
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• pp.389-394
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• 2019

In the present study, we have investigated the effect of sintering process conditions on the stability of the austenite phase in the nanocrystalline Fe-5wt.%Mn-0.2wt.%C alloy. The stability and volume fraction of the austenite phase are the key factors that determine the mechanical properties of FeMnC alloys, because strain-induced austenite-martensite transformation occurs under the application of an external stress at room temperature. Nanocrystalline Fe-5wt.%Mn-0.2wt.%C samples are fabricated using the spark plasma sintering method. The stability of the austenite phase in the sintered samples is evaluated by X-ray diffraction analysis and hardness test. The volume fraction of austenite at room temperature increases as the sample is held for 10 min at the sintering temperature, because of carbon diffusion in austenite. Moreover, water quenching effectively prevents the formation of cementite during cooling, resulting in a higher volume fraction of austenite. Furthermore, it is found that the hardness is influenced by both the austenite carbon content and volume fraction.

• Korean Chemical Engineering Research
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• 제57권2호
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• pp.172-176
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• 2019

저생 미생물 연료전지(BMFC)는 바다나 호수의 뻘 속에서 저생미생물이 유기물을 분해하면서 발생시키는 전기를 이용한 연료전지다. 본 연구에서는 BMFC 전극으로 카본 소재를 발수 처리한 고분자 전해질 연료전지(PEMFC)의 가스확산층(GDL)을 사용해서 성능이 높게 나오는 구동조건을 찾고자 하였다. 높은 저항 값을 갖는 외부저항을 사용했을 때 성능이 높았으며 바닷물에서 리드선의 부식에 의한 전극과 접촉저항 증가를 피해야 성능을 유지할 수 있었다. 기포 발생기를 사용해 최고출력밀도를 2배 이상 높일 수 있었고 최적 구동 온도는 $40^{\circ}C$였다.

• 한국도서관정보학회지
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• 제49권4호
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• pp.119-145
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• 2018

본 연구의 목적은 공공도서관이 지역콘텐츠 및 지역민의 요구에 부합한 특화주제를 선정하고 이를 기반으로 특화도서관을 운영함에 있어 필요한 실질적 가이드라인을 개발하는 것이다. 이를 위해 총 43개 국내 외 도서관을 선정하여 특화도서관 설립과정, 지역적 특성, 특화장서, 특화예산, 특화인력, 특화네트워크, 특화시설 및 환경, 특화프로그램, 홍보 등을 조사하여 시사점을 도출하였다. 도출된 시사점을 기반으로 운영 가이드라인을 4단계로 제안하였는데, 특화서비스 지원체계를 확립하고 지역밀착형 특화주제를 선정하는 준비단계, 선정된 특화주제를 서비스하기 위하여 도서관 환경을 조성하는 조성단계, 특화주제 관련 정보복합문화서비스를 기획하고 제공하는 운영단계, 서비스 고도화 및 확장을 위하여 도서관 외부기관과 소통하는 확산단계 등이다.

• Advances in materials Research
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• 제8권2호
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• pp.117-135
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• 2019

The lifetime of a gas turbine combustor is typically limited by the durability of its liner, the structure that encloses the high-temperature combustion products. The primary objective of the combustor thermal design process is to ensure that the liner temperatures do not exceed a maximum value set by material limits. Liner temperatures exceeding these limits hasten the onset of cracking which increase the frequency of unscheduled engine removals and cause the maintenance and repair costs of the engine to increase. Hot gas temperature prediction can be considered a preliminary step for combustor liner temperature prediction which can make a suitable view of combustion chamber conditions. In this study, the temperature distribution of ceramic panels for a V94.2 gas turbine combustor subjected to realistic operation conditions is presented using three-dimensional finite difference method. A simplified model of alumina ceramic is used to obtain the temperature distribution. The external thermal loads consist of convection and radiation heat transfers are considered that these loads are applied to flat segmented panel on hot side and forced convection cooling on the other side. First the temperatures of hot and cold sides of ceramic are calculated. Then, the thermal boundary conditions of all other ceramic sides are estimated by the field observations. Finally, the temperature distributions of ceramic panels for a V94.2 gas turbine combustor are computed by MATLAB software. The results show that the gas emissivity for diffusion mode is more than premix therefore the radiation heat flux and temperature will be more. The results of this work are validated by ANSYS and ABAQUS softwares. It is showed that there is a good agreement between all results.