• Journal of the Korean Society of Safety
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• v.26 no.4
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• pp.59-64
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• 2011

Explosion limit and flash point are the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, in order to predict upper explosion limits(UELs), the upper flash point of n-alkanes and aromatic compounds were measured under the VLE(vapor-liquid equilibrium) state by using Setaflash closed cup tester(ASTM D3278). The UELs calculated by Antoine equation and chemical stoichiometric coefficient tusing the experimental upper flash point were compared with the several reported UELs. From the given results, using the proposed experimental and predicted method, it is possible to research the upper explosion limits of the other flammable substances.

• Fire Science and Engineering
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• v.19 no.4 s.60
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• pp.26-31
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• 2005

In order to evaluate the fire and explosion involved and to ensure the safe and optimized operation of chemical processes, it is necessary to know combustion properties. Explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, the explosion limits of alcohols were predicted by using the normal boiling points and the flash points based on a solution theory. The values calculated by the proposed equations agreed with literature data within a few percent. From the given results, using the proposed methodology; it is Possible to Predict the explosion limits of the other flammable substances.

• Journal of the Korean Institute of Gas
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• v.3 no.3 s.8
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• pp.51-57
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• 1999

A study on the vented gas explosion characteristics were carried out with the liquified petroleum gas(LPG) which is used in domestics and industries fuel. To evaluate a damage by gas explosion and to predict a explosion hazards, a series of experiment have been performed in the regular hexahedron vessel of 270${\iota}$. A side of the vessel was made to setting a polyester diaphragm which was ruptured by explosion to simulate an accidental explosion which ruptured the window by explosion. Experimental parameters were LPG concentration, ignition position, venting area, a strength of diaphragm which was ruptured and distances from venting, Experimental results showed that vented gas explosion pressure was more affected by the diaphragm strength than the gas concentration, and the vented gas explosion pressure and blast wave pressure was increased with decreasing the venting area and increasing the strength of diaphragm. In this research we can find that a damage by vented explosion at the outside can be larger than the inside by blast wave pressure near the venting.

• Fire Science and Engineering
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• v.22 no.3
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• pp.228-233
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• 2008

Detonation limit is one of the major physical properties used to determine the fire and explosion hazards of the flammable substances. In this study, the lower detonation limits (LDL) and the upper detonation limits (UDL) of the flammable substances predicted with the appropriate use of the heat of combustion and the stoichiometric coefficient. The values calculated by the proposed equations were a good agreement with literature data within a few percent. From a given results, It is to be hoped that this methodology will contribute to the estimation of the detonation limits of for other flammable substances.

• Fire Science and Engineering
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• v.27 no.3
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• pp.47-51
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• 2013

The explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. The explosion limit of organic acids have been shown to be correlated the heat of combustion and the chemical stoichiometric coefficients. In this study, the lower explosion and upper explosion limits of organic acids were predicted by using the heat of combustion and chemical stoichiometric coefficients. The values calculated by the proposed equations agreed with literature data within a few percent. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the other organic acids.

• Journal of the Korean Institute of Gas
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• v.19 no.2
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• pp.5-11
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• 2015

The explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. The explosion limit of aldehydes have been shown to be correlated the heat of combustion and the chemical stoichiometric coefficients. In this study, the lower explosion and upper explosion limits of aldehydes were predicted by using the heat of combustion and chemical stoichiometric coefficients. The values calculated by the proposed equations agreed with literature data above determination coefficient 0.99. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the aldehydes.

• Journal of the Korean Institute of Gas
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• v.25 no.1
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• pp.40-47
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• 2021

In this study, hazards of decomposition and explosion for tert-butylperoxymaleate(TBPM), an organic peroxide, were evaluated by using various equipment to determine the cause of a fire explosion accident. As a result of DSC analysis, the instantaneous power density of TBPM was 26,401 kW/ml, and the NFPA reactive index(Nr) was classified as 4. And the positive value of EP(explosive propagation) and SS(shock sensitivity) showed that the TBPM had a potential hazard of explosion. From the experimental results, the shock sensitivity and friction sensitivity was rated as class 4 and 5, respectively. In the pressure vessel test, TBPM was ranked USA-PVT No.4 and evaluated as a self-reactive substance. In the combustion rate test, TBPM had the combustion rate of 167 mm/sec and was evaluated as the flammable solid classification 2 in GHS.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.134-140
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• 2023

Activated carbon is a carbonaceous material mainly used as a gaseous or liquid adsorbent. As fire-related accidents occur consistently due to the accumulation of heat of adsorption and oxidation of volatile organic compounds, the explosive characteristics and thermal stability of powdered and granular activated carbon made from coal and coconut shells were evaluated. As a result of the particle size analysis, the powdered activated carbon was in the particle size range (0.4~3) ㎛, and thermal properties such as exothermic onset temperature and decomposition behavior were analyzed using a differential scanning calorimetry and a thermogravimetric analysis. As a result of the evaluation of the explosion hazards for dust, both coal-based and coconut-based powdered activated carbon are classified as St1 class with weak explosion, but this is a relative and does not mean that the explosion hazards is absolutely low. Therefore, it is necessary to establish countermeasures for reducing the damage.

• Journal of the Korean Institute of Gas
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• v.11 no.1 s.34
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• pp.13-17
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• 2007

It is very insecure to treat a butane can for cooking out of door. The human injury from the accidents of butane cans has been getting increased 1.5 times yearly since 2003. In this context, the Institute of Gas Technology Training in Korea Gas Safety Corporation carries out explosion experiment to make trainees to take all possible measures to ensure safe management of gas in the field by fully recognizing the hazards of gas explosion accidents. This study intends to examine the influence of such explosion experiments on the trainees witnessing nearby. The GEN exposed to the active students participating in the experiment away from 25 meters from the explosion site was 57.94 dB and the GEN to the passive students not participating away from 50 meters was 51.92 dB. According to Weber-Fechner's law for the lower value than 65 dB which is the environmental standard, it is safe from the place 15 meter far from the explosion place. The environmental standard of offices is 50 dB, and it is lower than the environmental standard if the office is 65 meter far from the explosion place.

• Fire Science and Engineering
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• v.23 no.5
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• pp.50-56
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• 2009

Explosion limit and autoignition temperature are the major properties used to determine the fire and explosion hazards of the flammable substances. Explosion limit and autoignition temperature for safe handling of ethylene were investigated. By using the literatures data, the lower and upper explosion limits of ethylene recommended 2.6vol% and 36vol%, respectively. Also autoignition temperatures of ethylene with ignition sources recommended $420^{\circ}C$ at the electrically heated crucible furnace (the whole surface heating) and recommended about $800^{\circ}C$ in the local hot surface. The new equations for predicting the temperature dependence and the pressure dependence of the lower explosion limits for ethylene are proposed. The values calculated by the proposed equations were a good agreement with the literature data.