• Journal of the Korean Society of Safety
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• v.13 no.2
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• pp.116-121
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• 1998

Various flammable vapors as energy source and raw material have been stored, transported in the industries, and accidental leakage of these vapors occurs occasionally. Without an appropriate protection system, flammable vapors can be ignited and serious damage results from them. To reduce the risk caused by explosion, we should know the explosion limit and explosion characteristics. In this study, the maximum explosion pressure, the maximum explosion pressure rise, the effect of temperature and mixing with other vapor were measured in a cylindrical vessel. Experimental results showed that maximum explosion pressure of flammable vapor was about 3.1~$4.2 kg/cm^2$ and it was reached 3.4 times faster than that at explosion limit. The lower explosion limit was coincided well with Le Chateilier's equation, however, upper explosion limit was not.

• Fire Science and Engineering
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• v.29 no.6
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• pp.20-25
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• 2015

In order to examine the explosion risk of 2-ethylhexanoic acid, we experimentally studied the explosion limit, explosion pressure, and rate of increase of the explosion pressure at different oxygen concentrations. The lower explosion limit was 3.2% at a temperature of $100^{\circ}C$, and the oxygen concentration was 40 to 70%. The upper explosion limit was 4.5% and the lower explosion limit was 4.0% at an oxygen concentration of 21%.The maximum explosion pressure of 2-ethylhexanoic acid was 1.4161 MPa at an oxygen concentration of 70%, and the rate of increase of the explosion pressure was 62.692 MPa/s at this concentration.

• Fire Science and Engineering
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• v.26 no.4
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• pp.63-69
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• 2012

Explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, the lower explosion limit (LEL) and upper explosion limit (UEL) of organic halogenated hydrocarbons were predicted by using the heat of combustion and chemical stoichiometric coefficients. The calculated explosion limits by the proposed equations agreed with literature data within a few percent. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the other organic halogenated hydrocarbons.

• Journal of the Korean Society of Safety
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• v.24 no.5
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• pp.28-33
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• 2009

The thermochemical parameters for safe handling, storage, transport, operation and process design of flammable substances are explosion limit, flash point, autoignition temperatures(AITs), minimum oxygen concentration(MOC), heat of combustion etc.. Also it is necessary to know explosion limit at high temperature and pressure. For the safe handling of benzene, lower explosion limit(LEL) at $25^{\circ}C$, the temperature dependence of the explosion limits and flash point were investigated. And the AITs for benzene were experimented. By using the literatures data, the lower and upper explosion limits of benzene recommended 1.3 vol% and 8.0 vol%, respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for benzene, and the experimental AIT of benzene was $583^{\circ}C$. The new equations for predicting the temperature dependence of the explosion limits of benzene is proposed. The values calculated by the proposed equations were a good agreement with the literature data.

• Journal of the Korean Institute of Gas
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• v.15 no.4
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• pp.44-50
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• 2011

Explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, the lower explosion limit(LEL) and upper explosion limit(UEL) of ethers were predicted by using the heat of combustion and stoichiometric coefficients. The values calculated by the proposed equations agreed with literature data within a few percent. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the other flammable ethers.

• Journal of the Korean Society of Safety
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• v.16 no.4
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• pp.109-114
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• 2001

Explosive characteristics of the city gas were determined by using the gas explosion apparatues. The explosive range is determined between lower explosive limit of 5.0% and upper explosive limit of 15.3% at atmosphere and even though the oxygen concentration is decreased, lower explosive limit is not changed, but upper explosive limit is rapidly decreased. The minimum oxygen for combustion is determined 10%. The maximum explosion pressure is determined 5.72$\textrm{cm}^2$ and the maximum rate of explosion pressure rise is oxygen concentration of 12% to determined 160.12$\textrm{cm}^2{\cdot}$sec.

• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.618-622
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• 2017

Gasoline is a widely used product as a source for energy in homes, the automotive industry, and for industrial power generation, and it is also a product with a high risk of fire and explosion. In this study, to examine the risk for explosion for gasoline, PG, MG and RG, which are categorized according to octane number, were used as test specimens to measure their explosion limit according changes in oxygen concentration. The explosion limit for 21% oxygen concentration in air were confirmed to be 1.5~10.9%, 1.4~8.1%, and 1.3~7.6%, respectively, and the MOC for each of the test sample were confirmed to be 10.9%. The explosion limit measured in the test performed in this study confirmed between a 1.2%~7.6% wider explosion limit for the currently accepted MSDS for gasoline, and therefore it is considered that the results of this study can provide significant reference for preventing fires and explosions for process used gasoline.

• Journal of Industrial Technology
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• v.15
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• pp.5-13
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• 1995

Natural gas, which is getting more important as a fuel, should be liquefied and shipped in a special tank. During transportation, a spill of liquefied natural gas(LNG) could occur by a collision or even an accident. As a result, violent explosion called the superheat-limit explosion(SLE) can take place in some cases, unexpectedly. Such explosion may result from the formation of a superheated liquid which has attained the superheat-limit temperature when hot(water) and cold(LNG) liquids come into contact. Natural gas mixtures can be considered as discrete light components plus continuous heavy fractions where several continuous distribution function can be adopted. This work is aiming at prediction of the superheat-limit explosion condition by suing continuous thermodynamics development of algorithm to predict.

• Journal of the Korean Society of Safety
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• v.31 no.5
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• pp.42-48
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• 2016

The usage of the correct combustion properties of the treated substance for the safety of the process is critical. For the safe handling of n-nonane being used in various ways in the chemical industry, the flash point and the autoignition temperature(AIT) of n-nonane was experimented. And, the explosion limit of n-nonane was calculated by using the flash point obtained in the experiment. The flash points of n-nonane by using the Setaflash and Pensky-Martens closed-cup testers measured $31^{\circ}C$ and $34^{\circ}C$, respectively. The flash points of n-nonane by using the Tag and Cleveland open cup testers are measured $37^{\circ}C$ and $42^{\circ}C$. The AIT of n-nonane by ASTM 659E tester was measured as $210^{\circ}C$. The lower explosion limit by the measured flash point $31^{\circ}C$ was calculated as 0.87 vol%. And the upper explosion limit by the measured upper flash point $53^{\circ}C$ was calculated as 2.78 vol%. It was possible to predict lower explosion limit by using the experimental flash point or flash point in the literature.

• Special Issue of the Society of Naval Architects of Korea
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• 2015.09a
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• pp.69-73
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• 2015

An evaluation of the accidental limit state (ALS) for design of a semi-submersible drilling rig is one of the essential design requirements as well as ultimate limit state (ULS) and fatigue limit state (FLS). This paper describes the ALS evaluation on the explosion accident at shale shaker room of semi-submersible drilling rig. There are three steps for the ALS evaluation such as structural analysis at concept design, risk based safety design and structural analysis at detailed design. For the ALS evaluation at concept design, conceptual explosion overpressure from the Rule guided by the classification society was used in the structural analysis that was carried out using LS-DYNA. To set up the design accidental load (DAL), explosion analysis was carried out using FLACS taking safety barriers into consideration. Then, the structural analysis was carried out applying DAL for the ALS evaluation at detailed design. Through the ALS evaluation on the explosion at shale shaker room, the importance of the risk based safety design was described.