KSCE Journal of Civil and Environmental Engineering Research
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v.38
no.4
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pp.555-565
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2018
Nowadays, the artificial ground freezing (AGF) method has been used in many geotechnical engineering applications such as temporary excavation support, underpinning, and groundwater cutoff. The AGF method conducts the freezing process by employing a refrigerant circulating through a set of embedded freezing pipes to form frozen walls serving as an excavation support and cutoff wall. Two refrigerants of brine with the freezing temperature of $-20{\sim}-40^{\circ}C$ and liquid nitrogen with the freezing (evaporating) temperature of $-196^{\circ}C$ are commonly being used in geotechnical applications. This paper performed a series of field experiments to evaluate the freezing rate of marine clay in application of the AGF method. The field experiments consisted of the single freezing-pipe test and the frozen-wall formation test by circulating liquid nitrogen, which is a cryogenic refrigerant, into freezing pipes constructed at a depth of 3.2 m in the ground. The temperature of discharged liquid nitrogen was maintained through the automatic valve, and the temperature change induced by AGF method was measured at the freezing pipes and in the ground with time. According to the experimental results, the single freezing-pipe test consumed about 11.9 tons of liquid nitrogen for 3.5 days to form a cylindrical frozen body with the volume of about $2.12m^3$. In addition, the frozen-wall formation test used about 18 tons of liquid nitrogen for 4.1 days to form a frozen wall with the volume of about $7.04m^3$. The radial freezing rate decreased with increasing the radius of frozen body because the frozen area at a certain depth is proportional to the square of the radius. The radial freezing rate was formulated as a simple equation.
According to own investigation conducted by Korea Gas Safety Corporation Gas Safety Research Institute in 2017, the length of underground pipes in domestic high-pressure gas pipelines is approximately 770km, of which 84% is buried in Ulsan and Yeosu industrial complexes. In particular, 56% of underground pipelines have been in operation for more than 20 years. This suggests urgent management of buried high pressure gas pipelines. PHMSA in US and EGIG in Europe, major causes of accidents in buried gas pipelines are reported as third party damage, external corrosion and loss of pipe wall thickness. Therefore, it is important to evaluate whether the defects affect the remaining life of the pipe when defects occur in the pipe. DNV and ASME have evaluated the residual strength of pipelines through the hydraulic rupture test using pipe specimens with artifact flaws. Once the operating pressure is known through the residual strength of the pipe, the wall thickness at the point at which the pipe ruptures is calculated. If we know the accurate rate of corrosion growth, we can predict the remaining life of pipe. In the study, we carried out experiments with A53 Grade.B and A106 Grade.B, which account for 80% of domestic buried pipes. In order to modify the existing model equation, specimens with a defect depth of 80% to 90% was tested, and a formula expressing the relationship between defect and residual strength was made.
The grouted splice steeve has been applied widely due to its superior construction efficiency, such as the unnecessity of post concrete and the large allowable limit to the arrangement of reinforcing bars. However, studies on grout-filled splice steeve still have not been sufficiently peformed. The purpose of this study is to investigate the confining effect of mortar grouted splice sleeve on reinforcing bar, known to strengthen the bond capacity between grout mortar and reinforcing bar. To accomplish this objective, totally 6 full-sized specimens were made and tested under monotonic loading. Each specimens were equipped with strain gauges at the 12 location of sleeve and reinforcing bar. The experimental variables adopted in this study are embedment length and size of reinforcing bars. Following conclusions are obtained; 1) Under ultimate strength condition, the confining pressure of grouted splice sleeve calculated from measured tangential and axial strain of the sleeve is over $200{\sim}300kgf/{cm}^2$ at any location of sleeve and improved with reduction in embedment length of reinforcing bar. 2) Untrauer and Henry's equation which describe bond strength of mortar as a function of its compressive strength and confining pressure, predicted the measured bond capacity of this test within the 5% limits.
The purpose of this study was to investigate the effect of dietary mushroom powder on blood glucose levels, seam lipid levels, glucose 6-phosphtase (G6Pase), thiobarbituric arid reactive substance (TBARS) and glutathione enzymes in diabetic rats treated with streptozotocin (STZ). Four groups of rats (Sprague-Dawley male rats, 180-200 g) were fed as follows: normal rats were fed a control diet (C), diabetic rats were file a control diet (CD), normal fats were fed a mushroom powder diet (M), and diabetic rals were find mushroom powder diet (MD). Diabetes was induced by single injection of streptozotocin (60 mg/kg B.W.). The animals were fed ad libium each of the experimental diets for five weeks. Food and water intake was determined every day. Blood glucose and serum total cholesterol levels were determined every week. After five weeks, the rats were sacrificed and blood glucose, serum total cholesterol, triglyceride levels and glutathione enzymes were measured. HDL-cholesterol levels were analyzed and LDL-cholesterol concentrations were calculated by equation. There was body weight loss in the diabetic rats, but the MD group showed less body weight loss than the CD group. Blood glucose and serum total cholesterol level of the MD group were lower than those of the CD group (p < 0.05). Also, serum total cholesterol of the M group was lower than that of the C group (p < 0.05). But the serum triglyceride level of the diabetic rats (CD and MD) was higher than that of the normal rats (C and M). However, there was no significant difference between the control diet group and the mushroom diet group. Serum HDL-cholesterol levels of the C group and CD group were higher than that of the M group (p < 0.05), and the MD group was not significantly different. But the serum LDL-cholesterol levels of the M group were lower than those of the C group (p < 0.05). Activity of hepatic microsomal G6Pase significantly increased in the CD and MD, reaching levels higher than those of the C and M groups. Hepateic gutathione S-transferase (GST, glutathione reductase (GR) and glutathione peroxidase (GPX) activity was not significant. But renal GST, GR and GPX activity in the MD group was lower than that of the CD group (p < 0.05). These results suggest that dietary mushroom reduces renal disorders such as oxidation and aging of tissue. In conclusion, dietary mushroom groups reduced blood glucose and cholesterol levels in STZ-induced diabetic rats and renal glutathione enzymes activity was averted in diabetic rats.
Lethal effect on Chinese radish Kimchi was investigated by using a pilot scale Kimchi pasteurizer. A simulation model was presented so as to predict the change in viable cell concentration of the Kimchi during pasteurization. D values of microorganisms in the Kimchi were found to be 2.21, 1.62, 0.73, 0.39 and 0.21min at 60, 64, 70, 75 and $80^{\circ}C$, correspondingly, and thereby z value was $19^{\circ}C$. One cycle time required was 0.99min at flow rate of 4 l/min. The ratio of lethality in preheating section to total lethality was 0.3 and the ratio of lethality in holding, precooling and cooling sections to total lethality was 0.7. The experimental data were in good agreement with the values simulated by two model equations to which linear and exponential temperature profiles were applied at $65^{\circ}C\;and\;70^{\circ}C$ in holding section.
Kim, Jeong-Han;Lee, Sung-Kyu;Kim, Yong-Hwa;Kim, Kyun
Applied Biological Chemistry
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v.40
no.1
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pp.71-75
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1997
Important physicochemical properties of captafol [N-(1,1,2,2-tetrachloro-ethylthio)cyclohex-4-ene-1,2-dicarboximide], water solubility, vapor pressure, hydrolysis and octanol/water partition coefficient(Kow) were measured based on the standard EPA and OECD methods. Water solubility of the chemical was 2.24 ppm at $25^{\circ}C$. Half-life by hydrolysis at $25^{\circ}C$ in the buffer solution of pH 3.0, pH 7.0, and pH 8.0 was 77.8 hr, 6.54 hr and 0.72 hr, respectively, demonstrating instability in alkaline solution. The half-life in acid condition was not significantly different by temperature change, however, that in neutral or alkaline solution became shorter at $40^{\circ}C$. Hydrolysis study with a reference compound, diazinon, proved that the experimental method of the present study is reliable. Vapor pressure of captafol, $8.27{\times}10^{-9}$ torr at $20^{\circ}C$, was calculated from the equation, log P=6.94-(4401.6/T) plotted on the experiment results under different temperature conditions, 40, 50, and $60^{\circ}C$. pressure of captafol, the contamination of captafol would not happen easily in environment by vaporization. High Kow value of 1,523 was observed and this might result in bioconcentration through food chain when captafol was exposed. However, affecting human health through aquatic bioaccumulation is not likely to occur due to its rapid hydrolysis in the environment.
In building construction, openings of the story-height deep beams are usually required for accessibility and service lines such as air conditioning ducts, drain pipes and electric units. It is known that the main parameters affecting the load bearing capacity of deep beams with web openings are size, shape, location and reinforcements of openings. However, there have been no pertinent theories and national design codes for predicting ultimate shear strength of reinforced concrete deep beams with web openings. In this study, the shear behavior of simply supported reinforced concrete deep beams with web openings subject to concentrated loads has been scrutinized experimentally. A total of 34 specimens, the geometry of openings, its reinforcements and shear span to depth ratio, being taken as the experimental variables, has been cast and tested in the laboratory. The effects of these structural parameters on the shear strength and crack initiation and propagation have been carefully checked and analyzed. From the tests, it has been observed that the failures of all specimens were due to shear mechanism and the ultimate strength of specimens varies according to the location of openings, by which the formation of compression struts between the loading points and supports are deterred. All of the test results of specimens have been compared with the formulas proposed by previous researchers. The results were closely coincident with the formulas given by Ray and Kong's equation except for some X series specimens having a larger dimension of openings beyond the geometric limits of proposed equations.
This paper shows the results of model tests on the lateral behavior of single rigid pile, which was constructed by driving, in homogeneous and non-homogeneous (two layered) NakDong River sands. The purpose of the present paper is to investigate the effect of ratio of lower layer thickness to embedded pile length, relative density of sand and pile construction conditions (Driven & Embedded piles) on the characteristics of lateral behavior of single pile. These effects can be quantified only by the results of model tests. As a model result, the lateral behavior depends upon the pile construction condition in loose-density soil more than in high-density soil. If the pile construction depends upon driving construction, the decrease of deflection remarkably increases for both loose homogeneous sand and non-homogeneous soil$(E_{h1}/E_{h2}/=0.18)$ with high thickness of upper layer but the decrease of maximum bending moment shows the opposite result to the decrease of deflection. And, with respect to deflection, it was found that the deflection ratio $(y_{Driven}y_{Embedded})$ of embedded to driven piles has the ranges of 0.65 - 0.88 $(D_r=90%)$0.38 - 0.65 $(D_r=61.8%)$ for each relative density of homogeneous soil and the range of 0.6 - 0.88 for non-homogeneous soil. Also, in this study, the experimental equation for the effects of drop height (DH) and H/L on the ratios of $y_D/y_E\; and MBM_D/MBM_ E$ is suggested from model tests.
Experimental transportations of the olive flounder (Paralichthys olivaceus) seedlings (body weight $2.1\pm0.39g$) with polyethylene vinyl bag were Performed to study the change of dissolved oxygen (DO) during transportation, survival rate and feeding activity of seedlings after transportation. The distance and time required for the transportations were 272 km and 11 hours, respectively. DO was rapidly decreased within 3 hours (P<0.05) during the transportation of seedlings of 40 fish in 10l of sea water at $15.6\~17.8^{\circ}C$ of initial water temperature with 5 ml/l of initial DO. The decreasing tendency of DO (Y) according to elapsed time (X) was expressed an equation of $Y\;=\;2.7444X^{-0.4780}$ (r=0.8071). Feeding activity of the seedlings after transportation supplemented with oxygen and icepack besides above transport conditions was significantly higher than that of fish supplemented with icepack only (P<0.05). It was desirable to starve the seedlings for 36 hours before transportation. Survival rate of seedlings was greatly reduced, when the dissolved oxygen concentration was lowered below the range of $0.7\~0.94ml/l$ just after transportation.
Kim, Gyeong Hwa;Park, Jong Gyu;Park, Hui Dong;Han, Jeong Hwa
Journal of the Korean Chemical Society
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v.45
no.6
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pp.570-576
/
2001
The europium doped yttrium oxybromide phosphors were synthesized by solid-state reaction method. The YOBr: $Eu^{3+}$ phosphor showed a strong and narrow red emission band at 621 nm and maximum emission intensity obtained when 0.05 mol Eu ions were doped. The red emission of $Eu^{3+}$ originated from $^5D_0$${\rightarrow}$$^7F_2$electric dipole transition. In order to investigate on photoluminescence behavior, several experimental skills and numerical fittings are conducted to the YOBr: $Eu^{3+}$ phosphor. The emission spectrum was measured in the UV range and then decay curve of $^5D_0$${\rightarrow}$$^7F_j$transitions was examined. The energy interaction type of YOBr: $Eu^{3+}$ phosphor was dipole-dipole interaction. In addition to the calculating by critical concentration, the critical distance ($R_0$) was calculated by decay curve fitting parameter from Inokuti-Hirayamas equation, and spectral overlap method. The critical distance was 17.03, 10.51 and 7.18$\AA$ for those methods, respectively. As considering systematic error of measurements, these values are within the same order, so that the above fitting methods are plausible and recommendable.
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