• Title/Summary/Keyword: Expansion Coefficient

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Estimation of Critical Degree of Hydration and Thermal Expansion Coefficient of Early-Age Concrete from Measured Temperature, Strain and Stress (온도, 변형 및 응력 계측을 통한 초기재령 콘크리트의 임계수화도 및 열팽창계수 추정)

  • 오병환;최성철;신준호
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.809-814
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    • 2002
  • Recently, the properties of early-age concrete are increasingly important because these properties directly influence the behavior of early-age concrete structures including stress and cracking behavior. Nevertheless, the studies on early-age concrete are limited to strength and temperature development. The purpose of present study is to propose a simple and rational method which can predict the stress and strain behavior of young age concrete. A series of test have been done to measure the temperature development, strains and stresses in concrete members. The concept of equivalent age was used to define the degree of hydration and this degree of hydration was used to calculate the strength and elastic modulus. The critical degree of hydration and thermal expansion coefficient were calculated using experimental data. It is seen that the critical degree of hydration range from 0.05 to 0.11 based on the measuring method. The thermal expansion coefficient was calculated based on the measured non-mechanical strain and it is found that the coefficient decreases slightly with the increase of age. The consideration of critical degree of hydration in calculating stresses gives more accurate results. The present study provides useful method and data in evaluating early-age behavior of concrete structure.

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Expansion Valves Characteristics for Development of Control System on Air Conditioning and Refrigeration Systems (공조.냉동장치의 제어시스템 개발을 위한 팽창밸브 특성)

  • Kim, J.D.;Jang, J.E.;Yoon, J.I.
    • Journal of Power System Engineering
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    • v.2 no.3
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    • pp.34-40
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    • 1998
  • Performance characteristics of a refrigeration systems with various expansion valves and superheat changes were investigated experimentally. Experimental data have been taken utilizing three different devices; a thermostatic expansion valve, a linear type electronic expansion valve and a solenoid type electronic expansion valve. The data taken from tile three types of expansion valves were discussed with the temperature distribution of each zone in the evaporator and the superheat changes of the evaporator outlet In each zone temperature distribution fluctuated larger with the thermostatic expansion valve than with the electronic expansion valves. The optimum superheat ranged from $5^{\circ}C\;to\;15^{\circ}C$, and the superheat with the thermostatic expansion valve showed hunting phenomenon, which affected the evaporating and condensing temperature.

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DISTRIBUTIONS OF RESIDUAL STRESSES IN DIFFUSION BONDING OF DISSIMILAR MATERIALS TIAL TO STEEL 40CR

  • Peng, He;Jicai, Feng;Yiyu, Qian;Jiecai, Han
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.785-790
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    • 2002
  • Distributions of residual stress in diffusion bonding of dissimilar materials intermetallics TiAl to steel 40Cr were simulated by FEM calculation. Results showed that destructive residual stresses presented in the minute area adjacent to bond-line of the base material with smaller coefficient of thermal expansion. Reducing bonding temperature and diminishing bonding time are in favor of the mollification of interface tresses.

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The Effect of MgO Addition on Mullite (Mullite에 대한 MgO 첨가효과)

  • 조재우;김영호;이경희;이병하
    • Journal of the Korean Ceramic Society
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    • v.30 no.2
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    • pp.93-100
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    • 1993
  • The effects of MgO addition on thermal expansiion coefficient and dielectric constant of mullite were studied. Thermal coefficient and dielectric constant decrease with increasing MgO content and exhibit a minimum value at 1wt% MgO. However, above 3wt% MgO content both values increase. Result of X-ray diffraction analysis how that mullite compositions which include more than 0.1wt% MgO form cordierite. Spinel is also formed as well as cordierite in the composition containing more than 3wt% MgO. The results indicate that addition of MgO affect the thermal expansion coefficient and dielectric constant of mullite substrate because of the formation of new phases; cordierite and spinel. The thermal expansion coefficient and dielectric constant are affected mainly by cordierite and spinel in the regions containing less than more than 3wt% MgO, respectively.

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Study on the Coefficient of Thermal Expansion for Composites Containing 3-Dimensional Ellipsoidal Inclusions (3차원적 타원 형태의 충전제를 함유하는 복합체의 열팽창 계수 연구)

  • Lee, Kee-Yoon;Kim, Kyung-Hwan;Jeoung, Sun-Kyoung;Jeon, Hyoung-Jin;Joo, Sang-Il
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.206-214
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    • 2007
  • The theoretical study is developed for predicting the thermal expansion changes of composites which include complex inclusion, which is used three-dimensional ellipsoid model ($a_1>a_2>a_3$), which has two aspect ratios (the primary aspect ratio, $\rho_{\alpha}=a_1/a_3$ and the secondary aspect ratio, $\rho_{\beta}=a_1/a_2$). We can predict the feature of general thermal expansion factors by theoretical approach of matrix with aligned ellipsoidal inclusion using the Eshelby's equivalent tensor. The coefficients of longitudinal linear thermal expansion ${\alpha}_{11}$ decrease to those of inclusions, ${\alpha}_f$, as both aspect ratios increase. The coefficients of transverse linear thermal expansion of composites ${\alpha}_{33}$ initially increase and show the parabolic corves with maximum values, as the concentrations of filler increase. The coefficient of thermal expansion, ${\alpha}_{22}$ in the transverse direction decreases, as $\rho_{\alpha}$ increases, however, ${\alpha}_{22}$ increases as $\rho_{\beta}$ increases. The coefficient of linear thermal expansion of composites, ${\alpha}_{33}$ in the normal direction increases, as $\rho_{\alpha}$ increases, while ${\alpha}_{33}$ decreases as $\rho_{\beta}$ increases.

Thermal Expansion Behavior of Cordierite-SiC Whisker Ceramic Composites (코디어라이트-SiC위스커 복합재료의 열팽창 특성)

  • ;Weisskopf
    • Journal of the Korean Ceramic Society
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    • v.24 no.5
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    • pp.411-416
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    • 1987
  • Thermal expansions and thermal expansion coefficients of cordierite ceramics reinforced by SiC whiskers up to 40 vol. % were investigated. The composite specimens were hot pressed at 1523K for 30 min under 28.5 MPa pressing pressure in Ar atmosphere. Thermal expansions of the hot pressed composites were measured using a differential dilatometer up to 1262 K in air. Thermal expansions and thermal expansion coefficient of the composites increased with SiC whisker content. Thermal expansion behaviors of the composites were well explained by modelling parallel slabs randomly distributed on the whisker plane as the microstructural element of the composites.

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Analytical model of expansion for electric arc furnace oxidizing slag-containing concrete

  • Shu, Chun-Ya;Kuo, Wen-Ten;Juang, Chuen-Ul
    • Computers and Concrete
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    • v.18 no.5
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    • pp.937-950
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    • 2016
  • This study applied autoclave expansion and heat curing to accelerate the hydration of concrete and investigated how these methods affect the expansion rate, crack pattern, aggregate size effect, and expansion of electric arc furnace oxidizing slag (EOS)-containing concrete. An expansion prediction model was simulated to estimate the expansion behavior over a long period and to establish usage guidelines for EOS aggregates. The results showed that the EOS content in concrete should range between 20% and 30% depending on the construction conditions, and that coarse aggregates with a diameter of ${\geq}4.75-mm$ are not applicable to construction engineering. By comparison, aggregates with a size of 1.18-0.03 mm resulted in higher expansion rates; these aggregates can be used depending on the construction conditions. On Day 21, the prediction model attained a coefficient of determination ($R^2$) of at least 0.9.

The Linear Thermal Expansion Measurements and Estimations for UO2 and (U1-yCey)O2 Pellet (UO2 및 (U1-yCey)O2 소결체의 열팽창 측정 및 평가)

  • Kim, Dong-Joo;Kim, Yong-Soo;Lee, Young-Woo
    • Journal of the Korean Ceramic Society
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    • v.42 no.5 s.276
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    • pp.346-351
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    • 2005
  • The linear thermal expansions of $UO_2$ and $(U_{1-y}Ce_y)O_2$ pellet were measured from room temperature to $1400^{\circ}C$ as a function of Ce contents (0, 7.63, 14.84, and $21.68 mol\%$) by using the TMA(Thermo-Mechanical Analysis) method. From the measured data, the linear thermal expansion rate, the coefficient of linear thermal expansion and density variation with temperature were calculated, and the best-fitted temperature-dependent equations were recommended. It was shown that the rate and coefficient of $(U_{1-y}Ce_y)O_2$ thermal expansion increased and the density decreased with increasing Ce contents.

Influence of Li2O Addition on Physical Properties of Glass-Ceramics Fabricated Using a Coal Bottom Ash (석탄바닥재로 제조된 결정화 유리의 물리적 특성에 미치는 Li2O 첨가 영향)

  • Um, Noo-Li;Kang, Seung-Gu
    • Korean Journal of Materials Research
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    • v.20 no.2
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    • pp.72-77
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    • 2010
  • Glass-ceramics were fabricated by heat-treatment of glass obtained by melting a coal bottom ash with $Li_2O$ addition. The main crystal grown in the glass-ceramics, containing 10 wt% $Li_2O$, was $\beta$-spodumene solid solution, while in $Li_2O$ 20 wt% specimen was mullite, identified using XRD. The activation energy and Avrami constant for crystallization were calculated and showed that bulk crystallization behavior will be predominant, and this expectation agreed with the microstructural observations. The crystal phase grown in $Li_2O$ 10 wt% glass-ceramics had a dendrite-like shaped whereas the shape was flake-like in the 20 wt% case. The thermal expansion coefficient of the $Li_2O$ 10 wt% glass-ceramics was lower than that of the glass having the same composition, owing to the formation of a $\beta$-spodumene phase. For example, the thermal expansion coefficient of $Li_2O$ 10 wt% glass-ceramics was $20\times10^{-7}$, which is enough for application in various heat-resistance fields. But above 20 wt% $Li_2O$, the thermal coefficient expansion of glass-ceramics, on the contrary, was higher than that of the same composition glass, due to formation of mullite.

The Effects of a Filler with a High Coefficient of Thermal Expansion on a Sealant for High-Temperature (750 ~ 850℃) SOFCs (고온 (750 ~ 850℃) SOFC용 밀봉재의 특성에 미치는 고열팽창계수를 갖는 필러의 영향)

  • Kim, Bit Nam;Lee, Mi Jai;Hwang, Jong Hee;Lim, Tae Young;Kim, Jin Ho;Hwang, Hae Jin;Kim, Il Won;Chung, Woon Jin
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.470-475
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    • 2013
  • In this study, we report that effects of a filler with a high coefficient of thermal expansion on a sealant for high-temperature ($750{\sim}850^{\circ}C$) SOFC. We designed a $SiO_2-BaO-ZnO-B_2O_3-Al_2O_3$ glass system with a softening temperature higher than $750^{\circ}C$. The properties of the glass system show not only low volumetric shrinking but also low swelling. The glass system did not create a crystal phase during along-term heat treatment. We fabricated a seal gasket with 0, 10, 15, and 20 wt% cristobalite added as filler materials with glass powder. The coefficient of thermal expansion of the seal gasket increased according to cristobalite content. During along-term heat treatment, the leak rate decreased by about 5% after a heat treatment in an oxidizing atmosphere at $750^{\circ}C$ for 2000 h, also decreasing by about 6% after a heat treatment in a reducing atmosphere at $750^{\circ}C$ for 1000 h.