• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.1
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• pp.32-44
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• 2002

Selective catalytic reduction of nitric oxide by methane in the presence of excess oxygen was investigated over copper and cobalt ion-exchanged ZSM-5 zeolites. Copper ion-exchanged ZSM-5(Cu-ZSM-5) has the limitations for commercial applications to lean-bum gasoline and diesel engines due to low thermal stability and resistance to water vapor and sulfur dioxide. But cobalt ion-exchanged ESM-5(Co-ZSM-5) is more active at high temperatures and also stable to water vapor and sulfur dioxide for catalytic reduction of nitric oxide by methane. The catalytic activity of Cu-ZSM-5 for NO reduction increases with increasing temperatures, reaches the maximum conversion of 23.0% at 350\"C. and then decreases with higher temperatures. In the meantime catalytic activities of Co-ZSM-5 show the maximum conversion of 25.8% at $500^{\circ}C$ Therefore Co-ZSM-5 catalysts have higher thermal stability at high temperatures. Catalytic activities of both zeolites were remarkably enhanced with the existence of oxygen in the exhaust. It is noted that the catalytic activity of Cu-ZSM-5 decreases with the increasing concentration of methane while the catalytic activity of Co-ZSM-5 decreases with increasing contents of methane in the exhaust. This may imply the existence of different paths of NO reduction by methane in the presence of excess oxygen fur Cu-ZSM-5 and Co-ZSM-5 catalysts. For binary metal ionexchanged ZSM-5, the primary ion-exchanged metal may be masked by secondary ion-exchanged component, which plays the important role for catalytic activities of binary metal ion-exchanged ZSM-5, Therefore CuCo-ZSM-5 catalysts show the similar volcano-shaped curves to Cu-ZSM-5 catalysts between the activity and temperature. It Is interesting that the activities of CoCu-ZSM-5 catalysts indicate almost no dependence on the concentration of methane in the exhaust.aust.

• Transactions of the Korean Society of Automotive Engineers
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• v.3 no.1
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• pp.76-88
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• 1995

The effects of exhaust gas recirculation(EGR) on the characteristics of NOx emissions and specific fuel consumption rate have been investigated using an eight-cylinder. four cycle. direct injection diesel engine operating at several loads and speeds. The theoretical NO formation concentration is calculated with the equivalence ratio as a parameter of flame temperature to study the effect of EGR on NOx emissions in the diesel combustion. The experiments in this study are conducted on the fixed fuel injection timing of $38^{\circ}$ BTDC regardless of experimental conditions. It is found that the specific fuel consumption rate is slightly increased with EGR rate. and NOx emissions are markedly reduced owing to the drop of the incoming oxygen concentratio and the increase of equivalence ratio as the EGR rate increases.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.2
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• pp.1-8
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• 2000

Recently, Our planet is faced with very serious problems related to the air pollution due to the exhaust emissions of the diesel engine. So, lots of researchers have studied to reduce the exhaust emissions of diesel engine that influenced the environment strong. But most researchers have mainly studied and suggested the solution of reduction on the total exhaust emissions of diesel engine. In this study, the quantities of the low and high hydrocarbon among the exhaust emissions in diesel engine have been investigated by the quantitative analysis of the hydrocarbon C1~C6 using the gas chromatography. This study carried out by comparing the chromatograms with diesel fuel and mixed fuel which are blended the diesel and DMC(dimethyl carbonate)that includes the oxygen of about 53%. The results of this study show that the hydrocarbon C1~C6 among the exhaust emissions of the mixed fuel are exhausted lower than those of the diesel fuel at the all load.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.6 s.261
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• pp.514-521
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• 2007

This study focused on the effects of the $CO_2$ gas concentration in fresh charge and induction air temperature on the combustion characteristics of homogeneous charge compression ignition with dimethyl ether (DME) fuel, which was injected at the intake port. Because of adding $CO_2$ in fresh charge, start of auto-ignition was retarded and bum duration became longer. Indicated combustion efficiency and exhaust gas emission were found to be worse due to the incomplete combustion. Partial burn was observed at the high concentration of $CO_2$ in fresh charge with low temperature of induction air. However, indicated thermal efficiency was improved due to increased expansion work by late ignition and prolonged bum duration. Start of auto-ignition timing was advanced with negligible change of burn duration, as induction air temperature increased. Burn duration was mainly affected by oxygen mole concentration in induction mixture. Bum duration was increased, as oxygen mole concentration was decreased.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.3
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• pp.359-364
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• 2004

For the development of high efficiency and low emission combustion systems, high temperature air combustion technology has been tested by utilizing preheated air over 1100 K and exhaust gas recirculation. In this system, combustion air is diluted with large amount of recirculated exhaust gases, such that the oxygen concentration is relatively low in the reaction zone, leading to low flame temperature. Since, the temperature fluctuations and sound emissions from the flame are small and flame luminosity is low, the combustion mode is expected to be flameless or mild combustion. Experiment was performed to investigate the turbulent flame structure and NO$_x$ emission characteristics in the high temperature air combustion focused on coflowing jet diffusion flames which has a fundamental structure of many practical combustion systems. The effect of turbulence has also been evaluated by installing perforated plate in the oxidizer inlet nozzle. LPG was used as a fuel. Results showed that even though NO$_x$ emission is sensitive to the combustion air temperature, the present high temperature air combustion system produce low NO$_x$ emission because it is operated in low oxygen concentration condition by the high exhaust gas recirculation.

• Journal of Navigation and Port Research
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• v.48 no.4
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• pp.274-283
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• 2024

Climate change is currently one of the most pressing environmental issues, primarily caused by carbon emissions from fossil fuel usage. As a result, alternative fuels that effectively reduce carbon emissions are garnering more attention. Among these alternatives, hydrogen has numerous advantages, such as its ability for large-scale storage and transport. However, it is crucial to prioritize safety measures, particularly in facilities that handle hydrogen, due to its highly flammable and fast-spreading nature. This study aims to compare and analyze the placement of supply and exhaust vents to efficiently release hydrogen in the event of a leak in an enclosed space. The experiments involved six different scenarios, each with various combinations of supply and exhaust vents. To ensure the experimental process's safety, helium, which shares similar physical properties with hydrogen, was used to analyze the internal oxygen concentration during ventilation system operations. The results revealed that among the six scenarios, Case 2, which employed a lower side supply vent and an upper side exhaust vent, exhibited the shortest ventilation time of 4 minutes and 30 seconds. Additionally, the decrease rate in oxygen concentration was examined in the upper, middle, and lower areas. Ventilation utilizing an upper surface supply vent and two exhaust vents on the upper surface and upper side (Case 6), showed lower oxygen concentration values in the upper area, while Case 2 yielded lower values in the middle and lower areas. Therefore, it is crucial to select an appropriate supply and exhaust vent configuration considering the space's characteristics and usage environment.

• International Journal of Automotive Technology
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• v.7 no.4
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• pp.385-390
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• 2006

A fast response $CO_2$ analyzer has been developed to study transient characteristics on an SI engine. The analyzer has the delay time of 4.5 ms and time constant of 2.8 ms, which is fast enough to measure $CO_2$ concentration on a transient condition. Wide range of A/F(Air/Fuel) ratio can be estimated using the analyzer with an additional switch type oxygen sensor. The results of measurement of $CO_2$ concentration and A/F ratio on a transient condition including rapid acceleration/deceleration and EGR(Ehxaust Gas Recirculation) on/off are presented and compared with a commercial exhaust gas analyzer and UEGO(Universial Exhaust Gas Oxyzen) sensor.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.1
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• pp.14-21
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• 2008

Synthetic gas is defined as reformed gas from hydrocarbon-based fuel and the major chemical species of the synthetic gas are $H_2$, CO and $N_2$. Among them, hydrogen from synthetic gas is very useful species in chemical process such as combustion. It is a main reason that many studies have been performed to develop an effective reforming device. Furthermore, other technologies have been studied for synthetic gas application, such as the ESGI(Exhaust Synthetic Gas Injection) technology. ESGI injects and burns synthetic gas in the exhaust pipe so that heat from hydrogen combustion helps fast warmup of the close-coupled catalyst and reduction of harmful emissions. However, it is very hard to understand combustion characteristic of hydrogen under low oxygen environment and complicated variation in chemical species in exhaust gas. This study focuses on the characteristics of hydrogen combustion under ESGI operating conditions using a CVC(Constant Volume Chamber). Measurements of pressure variation and flame speed have been performed for various oxygen and hydrogen concentrations. Results have been analyzed to understand ignition and combustion characteristics of hydrogen under lower oxygen conditions. The CVC experiments showed that under lower oxygen concentration, amount of active chemicals in the combustion chamber was a crucial factor to influence hydrogen combustion as well as hydrogen/oxygen ratio. It is also found that increase in volume fraction of oxygen is effective for the fast and stable burning of hydrogen by virtue of increase in flame speed.

• Journal of Hydrogen and New Energy
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• v.27 no.5
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• pp.581-588
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• 2016

To compare reduction reactivity of oxygen carrier particles, $CH_4$ combustion characteristics were measured and investigated in a bubbling fluidized bed reactor with increasing $CH_4$ concentration from 10 to 100 %. Among five oxygen carriers (OC-1, OC-2, SDN70, C14, C28), OC-1, OC-2, SDN70 particles were selected as better oxygen carriers from the viewpoints of fuel conversion and $CO_2$ selectivity. However, some oxygen carriers showed lower fuel conversion and $CO_2$ selectivity even though they have high oxygen transfer capacity. Therefore, we could conclude that not only TGA tests to measure the oxygen transfer capacity but also fluidized bed tests to analyze exhaust gas concentration should be performed to select better oxygen carrier without misunderstanding of carriers reactivity.

• Journal of Advanced Marine Engineering and Technology
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• v.33 no.6
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• pp.896-902
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• 2009

EGR is applied in order to lower temperature of combustion chamber by using the specific heat of carbon dioxide in engine exhaust gas. However, the problem of EGR system in diesel engine is high PM concentration. Combined EGR system can be reduced it by mixing exhaust gas of gas engine into the intake air of diesel engine. This experimental study was designed for EGR system for both engines use. The results of EGR experimental study by using diesel engine and gas engine are as follows. 1) The pressure of combustion and rate of heat release decreased. 2) The specific fuel consumption increased. But, up to middle load, it little increased. 3) NO concentration has decreased up to 50% in almost all combustion area. 4) The variation of the PM concentration at low load is not so seen. But at high load, PM increased rapidly when concentration of oxygen is decreased and most of it caused the increasing of Dry Soot.