• Title/Summary/Keyword: Exfoliation

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Structural Changes of Nylon 6/Clay Nanocomposite Film on Drawing Condition (Nylon 6/Clay 나노복합재 필름의 연신조건에 따른 구조적 변화)

  • 강영아;김경효;이양헌;조현혹
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.352-353
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    • 2003
  • Clay 분산 유/무기 나노복합재 제조기술은 실리케이트 층상구조의 점토광물을 나노 스케일의 시트상의 기본 단위로 박리(exfoliation)하여 고분자수지에 분산시킴으로써 범용 고분자의 낮은 기계적 물성의 한계를 엔지니어링 플라스틱 수준으로까지 올리고자 하는 것으로서, 기존의 무기 충진재 및 강화재의 입자크기(〉1 $\mu\textrm{m}$)를 나노 스케일까지 분산시켜 기존 무기물 충진 복합재의 단점을 한층 보완하는 것을 목표로 하고 있어 성능 및 원가 면에서 매우 유리한 방법으로 21세기의 복합재료 생산시장의 판도에 상당한 변화를 가져오게 할 수 있는 핵심기술이라 할 수 있다. (중략)

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The Esthetic management of pediatric patient with a hereditary disease (Schwachman-Diamond syndrome)

  • Kim, Kaayeong;Lee, Kwanhee;Kim, Minsoo
    • Journal of the Korean Academy of Esthetic Dentistry
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    • v.13 no.2
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    • pp.7-11
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    • 2004
  • The Schwachman-Diamond syndrome is an autosomal recessive syndrome(1/20,000 births), consisting of pancreatic insufficiency, neutopenia, which may be intermittent, neutrophil chemotaxis defects, metaphyseal dysostosis, failure to thrive and short stature. Patients present in infancy with poor growth and grease, foul-smelling stools that are characteristic of malabsorption. These children can be readily differentiated from those with cystic fibrosis by their normal sweat chloride levels, lack of the cystic fibrosis gene, and characteristic metaphyseal lesions. Pathologically, the pancreatic acini are replaced by fat with little fibrosis. The neutropenia may be cyclic. Recurrent pyogenic infections otitis media, pneumonia, dermatitis(fig 1), sepsis are common and a frequent cause of death. In dental examination, these patients had a poor oral hygine and moderate generalized marginal gingivitis, also show delayed primary tooth exfoliation and oral development. This report illustrates a case that pancreatic agenesis 6 yeas-old boy with various esthetic dental problems has been served the esthetic dental restoration of 6 years.

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A Study on the Non-Destructive Test of Concrete Tunnel Lining Using Infrared Thermography Technique (적외선 열화상기법을 이용한 콘크리트 터널 라이닝의 비파괴 시험에 관한 연구)

  • 김영근;장정범;김영진
    • Tunnel and Underground Space
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    • v.7 no.1
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    • pp.75-83
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    • 1997
  • The interest of diagnosis and maintenance of construction is increasing due to the collapse of infastructures. To obtain the complete, reliable and reproducible data ont he state of the entire structure, various non-destructive techniques are available, Especially, specific constructional characteristics of tunnels make the application of non-destructive tests more difficult. Despite of the complications of these conditions, non-destructive techniques should be capable of providing a description of the state of the tunnel lining, without the removal of the tunnel installations. In this paper, the infrared thermography technique using the difference of surface temperature was studied. The optimum equipment was selected and introduced, the principle, testing method and data anlaysis were investigated. Also, through the case study for inspection of concrete tunnel lining, this technique has proven to be a valuable non-destructive test for detecting the defects such as crack, leakage of water and exfoliation of concrete. The applicability and usefulness of this technique for estimation of concrete tunnel lining have been conformed.

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Acoustic Emission Characteristics of Plasma Sprayed Ceramic Coating Layer after Salt Spray (플라즈마용사 세라믹코팅 피막부식재의 음향방출 특성)

  • 김귀식;박경석;홍용의
    • Journal of Ocean Engineering and Technology
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    • v.15 no.3
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    • pp.69-74
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    • 2001
  • This paper was to investigate of a adhesiveness for the plasma sprayed coating materials did salt spray by acoustic emission method in tensile loadings. The powders used for the coating were nickel aluminum composite powder Ni-4.5wt.%Al and titanium dioxide powder $TiO_2$. These powders were coated on a carbon steel S45C by plasma spray method. The result solution was a 5% NaCl and the slat spray times were 2, 5 and 10 hours respectively. The salt solution penetrated into the surface of the substrate through pore of the coating layer built in the process of plasma spay. Corrosion productions formed on the surface of substrate. The adhesiveness between the substrate and the coating layer is weaken by corrosion and the exfoliation initiated chiefly at the corrosion surface of the substrate. The AE events and energy of the corroded coating specimens decreased as the salt spray times increased.

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Polyethylene terephthalate (PET) Nanocomposites filled with Fumed Silicas by Melt Compounding (Fumed silica가 충진된 Polyethylene terephthalate(PET) Nano복합재의 연구)

  • Hahm, Wan-Gyu;Im, Seung-Soon
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.309-312
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    • 2002
  • The polymer nanocomposites are attracting considerable attention on account of the characteristic properties of nanoparticles have extremely large surface area per a unit mass. Recentry, mica-type silicates like montmorillonite have received a good deal of attention as effective nano-reinforcemen(1), but actually some critical problems such as the difficulties of exfoliation and surface modification, the weak heat-resistance of modifier, and inferior processability due to the increase in melt viscosity have restricted the mass production and various applications of the nanocoposite. (omitted)

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ACCESSORY ROOT IN DECIDUOUS TEETH -case report- (유치의 부가치근)

  • Park, Kye-Ryun;Choi, Hyung-Jun;Sohn, Heung-Kyu;Lee, Jong-Gap
    • Journal of the korean academy of Pediatric Dentistry
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    • v.24 no.1
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    • pp.173-178
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    • 1997
  • As one of the developmental disturbances in shape of teeth, an accessory root may involve any teeth, but has very rare frequency in the deciduous teeth. Because it is possible to diagnose the accessory root only by use of the radiographs, it is important to detect this root early by carefully examining the radiographs. The accessory root produces several problems such as abnormal exfoliation of deciduous teeth, eruption abnormality of successive permanent teeth, infection due to residual root during tooth extraction, and incomplete pulp treatment, and therefore it is necessary to have a continuous follow check-up to prevent these problems.

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Conservation Treatment of Stairway-side Stone Panels Taken Out from West Pagoda of Gameunsa-site (감은사지(感恩寺址) 서탑출토(西塔出土) 보단측면석(步段側面石)의 보존처리(保存處理))

  • Kim, Jongwoo;Jeong, Taehwa;Jeong, Suyeon
    • Conservation Science in Museum
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    • v.9
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    • pp.59-66
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    • 2008
  • At platform-reinforcing side stone plate having been exhibited in outdoor exhibition space of Gyeongju National Museum, split and exfoliation were proceeding due to weathering at joined·restored parts. Accordingly we checked imbibitional minerals in the stone through observation and analysis with polarized microscope, and studied capillary water absorption rate using Schmidt Hammer rebound hardness measurement and Karsten Tube.

Layered Silicate-Polymer Nanocomposites

  • Jeong, Han-Mo
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.18-18
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    • 2003
  • Natural clays are composed of oxide layers whose thickness is about 1nm and cations existing between the layers. A number of these layers makes primary particles with a height of about 8∼10nm and these primary particles make aggregates with a size of about 0.1∼10$\mu\textrm{m}$. When layered silicate was made to be organophilic, by exchanging the interlayer cations with organic cationic molecules, the matrix polymer can penetrate between the layers to give a nanocomposite, where 1nm-scal clay layers exist separately in a continuous polymer matrix. These nanostructured hybrid organic-inorganic composites have attracted the great interest of researchers over the last 10 years. They exhibit improved performance properties compared with conventional composites, because their unique phase morphology by layer intercalation or exfoliation maximizes interfacial contact between the organic and inorganic phases and enhances interfacial properties. Since the advent of nylon-6/montmorillonite nanocomposite developed by Toyota Motor Co., the studies on layered silicate-polymer nanocomposites have been successfully extended to other polymer systems. They greatly improved the thermal, mechanical, barrier, and even the flame-retardant properties of the polymers.

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A Study on the Mechanism of Environmental Pollution in Caves (개방동굴의 환경오염 메카니즘에 관한 연구 - 고수동굴을 사례로 -)

  • Hong, Hyun-Cheol
    • Journal of the Speleological Society of Korea
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    • no.89
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    • pp.37-45
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    • 2008
  • If a cave is developed and opened to the public, the pollution in caves is inevitable. This kind of environmental pollution is caused by an environmental pollution system that is formed by the interaction among various pollution factors, not by a single factor. The main causes of the pollution are the development of passage, installation of lamps, tourists, oxidation of fixtures, temperature rise and littering, which in turn causes environmental pollution such as green and black mold growth, vatting, exfoliation and water pollution.

Preparation of Poly(methyl methacrylate)/Na-MMT Nanocomposites via in-Situ Polymerization with Macroazoinitiator

  • Jeong Han Mo;Ahn Young Tae
    • Macromolecular Research
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    • v.13 no.2
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    • pp.102-106
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    • 2005
  • Poly(methyl methacrylate) (PMMA)/sodium montmorillonite (Na-MMT) nanocomposites were prepared with a novel method utilizing a macroazoinitiator (MAI). To induce the intergallery polymerization of methyl methacrylate (MMA), the MAI containing a po1y(ethylene glycol) (PEG) segment was intercalated between the lamellae of Na-MMT and swelled with water to enhance the diffusion of MMA into the gallery. The structure of the nanocomposite was examined using X-ray diffraction and transmission electron microscopy, and the thermal properties were examined using differential scanning calorimetry and thermogravimetry. The PMMA/Na-MMT nanocomposite prepared by intergallery polymerization showed a distinct enhancement of its thermal properties; an approximately $30^{\circ}C$ increase in its glass transition temperature and an $80\sim100^{\circ}C$ increase in its thermal decomposition temperature for a $10\%$ weight loss.