• Journal of the Korean Institute of Gas
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• v.23 no.1
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• pp.27-35
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• 2019

In order to solve the global warming and reduce greenhouse gas emissions, $CO_2$ capture technology was developed by applying oxy-fuel combustion. But there has been such a problem that its economic efficiency is low due to the high price of oxygen gases. ASU is known to be most suitable method to produce large quantity of oxygen, to reduce the oxygen production cost, the efficiency of ASU need to be improved. To improve the efficiency of ASU, exergy analysis can be used. The exergy analysis provides the information of used energy in the process, the location and size of exergy destruction. In this study, the exergy analysis was used for process developing and optimization of large scale ASU. The process simulation of ASU was conducted, the results were used to calculate the exergy. As a result, to reduce the exergy loss in the cold box of ASU, a lower operating pressure process was suggested. It was confirmed the importance of heat leak and heat loss reduction of cold box. Also, the unit process of ASU which requires thermal integration was confirmed.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.5
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• pp.515-524
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• 2022

In this study, the on-site hydrogen production process for refueling stations that were not energy-optimized was improved through exergy analysis and heat exchange network synthesis. Furthermore, the process was scaled up from 30 Nm3/h to 150 Nm3/h to improve hydrogen production capacity. Exergy analysis results show that exergy destruction in the SMR reactor and the heat exchanger accounts for 58.1 and 19.8%, respectively. Thus, the process is improved by modifying the heat exchange network to reduce the exergy loss in these units. As a result of the process simulation analysis, thermal and exergy efficiency is improved from 75.7 to 78.6% and 68.1 to 70.4%, respectively. In conclusion, it is expected to improve the process efficiency when installing on-site hydrogen refueling stations.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.49-51
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• 2012

In this paper, the integration issue, such as an air-side integration design between the gas turbine and air separation unit, is described and analyzed by the exergy and energy balance of the combined-cycle power block in an IGCC power plant. The results showed that the net power of the system was almost same, but that of the gas turbine was decreased as the integration degree increased. The highest exergy loss was occurred in the combustor of gas turbine, which was affected by the chemical reaction, heat conduction, mass diffusion, and viscous dissipation.

• Journal of Advanced Marine Engineering and Technology
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• v.36 no.5
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• pp.574-579
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• 2012

This paper presents the new cascade liquefaction cycles using $CO_2-C_2H_6-N_2$ and $CO_2-N_2$. The performance and exergy of cascade liquefaction cycles are analyzed using HYSYS software and then confirmed the possibility of these cycles for LNG-FPSO ship. From the comparison of performance and exergy loss of these cycles, the cascade liquefaction cycles using $CO_2-C_2H_6-N_2$ showed higher performance and the cycle using $CO_2-N_2$ presented higher exergy loss. The cascade liquefaction cycle using $CO_2-N_2$ is lower efficiency and higher compressor work compared to the optimized cascade liquefaction cycle using $C_3H_8-C_2H_4-C_1H_4$. But, if the efficiency of $N_2$ cycle in these liquefaction cycles is improved, it is possible to apply the cascade liquefaction cycle using $CO_2-C_2H_6-N_2$ and $CO_2-N_2$ to LNG-FPSO ship due to the simple composition device of these cycles.

• Journal of Power System Engineering
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• v.16 no.2
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• pp.24-29
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• 2012

In this paper, an analysis on performance and exergy of R404A refrigeration system using R744 secondary refrigerant was performed numerically to optimize the design for the operating parameters. The operating parameters considered in this study include subcooling and superheating degree, internal heat exchanger and compression efficiency, evaporation and condensation temperature in the R404A refrigeration cycle and temperature difference of cascade heat exchanger. The main results are summarized as follows : The COP(coefficient of performance) of R404A refrigeration system increases with increasing evaporation temperature. The evaporation capacity of R744 as secondary refrigerant increases with the increase in evaporation pressure of R744 secondary refrigeration. And the enthalpy in the evaporator outlet of R744 increases with the increasing evaporation pressure of R744 secondary refrigeration. Therefore, it is important to analysis for the relationship between COP of R404A refrigeration system and refrigeration capacity of R744. As cascade evaporation temperature increase, the exergy loss of condenser and compressor using R404A is the largest among all components. Therefore, the exergy loss in the condenser and compressor using R404A must be decreased to enhance the COP of R404A refrigeration system with R744 secondary refrigerant.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.9
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• pp.937-944
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• 2012

The thermodynamic characteristics of a trilateral cycle with water as a working fluid have been theoretically investigated for an electric generation system to recover the waste heat of the exhaust gas from a diesel engine used for the propulsion of a large ship. As a result, when a heat source was given, the efficiencies of energy and exergy were maximized by the specific conditions of the pressure and mass flow rate for the working fluid at the turbine(expander) inlet. In this case, as the condensation temperature increased, the volume expansion ratio of the turbine could be reduced properly; however, the exergy loss of the heat source and exergy destruction of the condenser increased. Therefore, in order to recover the waste exergy from the topping cycle, the combined cycle with a bottoming cycle such as an organic Rankine cycle, which is utilized at relatively low temperatures, was found to be useful.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.41 no.2
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• pp.87-95
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• 2017

The concept of entransy has been proposed recently as a potential heat transfer mechanism and could be useful in analyzing and optimizing the heat-work conversion systems. This work presents an entransy analysis for the irreversible Carnot cycle by systematic balance formulations of the entransy loss, work entransy, and entransy dissipations, which are consistent with exergy balances. Additionally, several forms of system efficiency are introduced based on entransy for the appreciation of the optimal system performance. The effects of the source temperature and irreversible efficiencies on the optimal conditions for system efficiencies are systematically investigated for both dumping and non-dumping cases of used source fluid. The results show different trends in entransy efficiencies when compared to the conventional efficiencies of energy and exergy, and represent another method to assess the effective use of heat source in power generation systems.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.20 no.9
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• pp.624-630
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• 2008

When various kinds of outputs are produced from a single energy system, the methodology which allocates the common cost to each output cost is very important because it is directly related with the profit and loss of producers and purchasers. In the cost allocation methodology of the heat and the electricity on a cogeneration, there are energy method, work method, proportional method, benefit distribution method, exergetic methods, and so on. On the other hand, we have proposed a worth method which can be applied to any system. The definition of this methodology is that the unit cost of a product is proportion to the worth. Where, worth is a certain evaluating basis that can equalize the worth of products. In this study, we applied worth method to a steam-turbine cogeneration which produces 22.2 MW of electricity and 44.4 Gcal/h of heat, and then we allocated 2,578 $/h of common cost to electricity cost and heat cost. Also, we compared with various cost allocation methods. As the result, we conclude that exergy of various kinds of worth basis evaluates the worth of heat and electricity most reasonably on this system.

• Proceedings of the SAREK Conference
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• 2008.11a
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• pp.351-356
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• 2008

When various kinds of outputs are produced from a single energy system, the methodology which allocates the common cost to each output cost is very important because it is directly related with the profit and loss of producers and purchasers. In the cost allocation methodology of the heat and the electricity on a cogeneration, there are energy method, work method, proportional method, benefit distribution method, various exergetic methods, and so on. On the other hand, we have proposed a worth evaluation method which can be applied to any system. The definition of this methodology is that the unit cost of a product is proportion to the worth. Where, worth is a certain evaluating basis that can equalize the worth of products. In this study, we applied this methodology to a gas-turbine cogeneration which produces 119.2 GJ/h of electricity and 134.7 GJ/h of heat, and then we allocated 3,150 $/h of fuel cost to electricity cost and heat cost. Also, we compared with various cost allocation methods. As the result, we conclude that exergy of various kinds of worth basis evaluates the worth of heat and electricity most reasonably on this system.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.16 no.3
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• pp.305-314
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• 1987

Thermodynamic analysis of a mixed refrigerant refrigeration cycle has been performed by computing thermodynamic properties of various refrigerants. The analyses are carried cut to identify the sources and distribution of the energy degradation by irreversible processes. Heat exchange process with the surroundings produces the entropy and the irreversible loss can be reduced by the mixed refrigerant whose phase change temperature varies during the phase change processes in the evaporator and the condenser. The concept has been applied to find the minimum compression work and thus the minimum energy loss in the overall system, specifically in the case of the mixed refrigerant of R12 and R114. Parametric studies have been added to recognize the various factors affecting the system performance.