• 대한전기학회논문지
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• 제34권8호
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• pp.331-337
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• 1985

An inverter-excited induction generator is discussed in this paper. A brief review of the capacitor-excited induction generator is given and the steady state characteristics of the induction generator excited by an inverter are evaluated. It is shown that the output voltage of the system can be controlled by adjusting the slip, for given operating conditions. The introduction of feedback control makes it possible to control the output voltage stably over the wide range of speed and load. Experimental results are given. The output of the induction generator is then converted into a CVCF(Constant Voltage-Constant Frequency) power source using a PWM inverter with simple control circuit.

• 산업기술연구
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• 제23권A호
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• pp.29-33
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• 2003

This paper proposed methods of filament preheating to extend a fluorescent lamp life. The ballast for the fluorescent lamp can be classified into two main groups magnetics and electronics. The electronic ballast is lighter and smaller than the magnetic ballast and it can dim up and down. There are two ways to start the fluorescent lamp in the electronic ballast: rapid start and instant start. Also there are two methods of the driving inverter self excited oscillation and force excited oscillation. The rapid starting is different from the instant starting in that the rapid start is preheating the filament before the steady state. If there is a preheating process before the lamp ignition, the life of the fluorescent lamp can be increased. This paper presented the preheating methods for self excited oscillating system and force excited oscillating system.

• Bulletin of the Korean Chemical Society
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• 제32권10호
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• pp.3641-3643
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• 2011

Multiconfigurational wavefunctions were adopted to study structural isomers, their isomerization reactions and excited states of $HN_3$. In addition to the known linear isomer, two new structural isomers were found. The three isomers can be classified as sp, $sp^2$ and $sp^3$ hybridized species, respectively. The sp3 hybridized species turned out to be the second most stable. Large reaction barriers among these species prevent thermal isomerizations. A low-lying $^3A'$ exists with a relative energy of 13.5 kcal/mol. Dramatic re-hybridization and bond elongation was found in the first excited $^1A"$.

• 대한화학회지
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• 제20권3호
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• pp.212-220
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• 1976

1,1'-디시클로알케닐의 광고리화 반응을 형광 퀘ㄴ칭, 증감제등을 써서 연구하였다. 증감제를 쓰는 경우 이 디엔의 광고리화 반응은 비틀린 삼중상태나 평면구조의 트란스 삼중상태보다 높은 에너지 준위에 있는 평면구조의 s-시스 삼중상태에서 일어남을 알았다.

• 전기의세계
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• 제21권2호
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• pp.9-19
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• 1972

The transient characteristics of separately excited d-c motor driven by thyristor d-c chopper is studied in this paper. The armature controlled system is applied. As a result of theoretrical analysis the following conculsions were drawn: (1) For the transient analysis, it is recognized that the state transition analysis is a more general method and powerful tool than the state equation method or signal flow graph method, although it includes iterative matrix calculations. And the system is dealt with a finite width sampled-data system in the state transition analysis. (2) The transient characteristics of the motor angular velocity and its torque to the sampling duration variation are compared with those due to the amplitude variation of d-c chopper voltage as follows. The attenuation rate of the transient characteristics is equal in both cases, but the initial value of the transient characteristics in former case is greater than in latter case. (3) The roots of characteristics equation of the system lie inside the unit circle of the Z-plane. Therefor the system is stable. Further it is found that as the sampling duration is decreased the relative stability is lessened.

• Journal of Photoscience
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• 제6권2호
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• pp.61-65
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• 1999

The fluorescence properties and photoisomerization behavior of 1-(9-anthryl)-2-(n-quinolinyl)ethene (n-AQE, n=2-4) have been investigated in various solvents. t-3-AQE is strongly fluorescent, but does not accomplish photoisomerization, similar to parent hydrocarbon compound, t-1-(9-anthryl)-2-phenylethene (t-9-APE) or t-1-(9-anthryl)-2-(1-naphthyl)ethene (t-1-ANE). Fluorescence and photoisomerization oft-2-AQE and t-4-AQE are strongly affected by solvent polarity. Dependence of fluorescence quantum yield on the solvent polarity is moderate for t-2-AQE and large for t-4-AQE. In nonpolar solvent (in n-hexane), they exhibit relatively strong fluorescence, but do not isomerize to cis isomer on irradiation, even if inefficient isomerization is observed for t-4-AQE. However, as solvent polarity increases, their fluorescences become weak with efficient photoisomerization to corresponding cis isomer. Intramolecular charge-transfer excited state is presumed to contribute to photoisomerization. The S$_1$ decay parameters were found to be solvent-dependent due to the charge-transfer character of lowest S$_1$ state. In polar solvents, the activation barrier to twisting is reduced enhancing the isomerization of r-2-AQE and t-4-AQE in the singlet manifold.

• EDISON SW 활용 경진대회 논문집
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• 제3회(2014년)
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• pp.275-285
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• 2014

Dipyrene-based fluorescent chemosensor(분자 1)가 개발되었다. 분자 1은 여러 금속이온 중 $Cu^{2+}$와 $Hg^{2+}$의 fluorescent chemosensor로서 센싱할 수 있고, excimer-switch off mechanism에 따라 $Cu^{2+}$와 $Hg^{2+}$ 금속이온을 감지한다. Ground state와 excited state에 대한 DFT와 TD-DFT 방법을 통해 분자 1의 $Hg^{2+}$에 대한 형광 turn on/off을 확인하고, 구조변화에 따른 molecular orbital을 계산하였다. 계산결과 분자 1은 excited state에서 excimer를 형성할 수 있으나 $1+Hg^{2+}$는 excimer를 형성하지 못함을 알 수 있었다. 여기서 우리는 분자 1과 $Hg^{2+}$ 금속이온 결합에 대하여 실험값과 비교 분석하여 그 메커니즘 조사하였다.

• Bulletin of the Korean Chemical Society
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• 제28권8호
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• pp.1256-1260
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• 2007

Two β-diketone derivatives bearing triphenylene (1-naphthalene-2-yl-3-triphenylen-2-yl-propane-1,3-dione (NTPD)) and naphthalene (1,3-di-naphthalene-2-yl-propane-1,3-dione (DNPD)) and their Ln(III) complexes (Ln = Er or Gd) were synthesized and their photophysical properties were investigated. The sensitized emission of Er3+ ion in Er3+-[NTPD]3(terpy) and Er3+-[DNPD]3(terpy) was observed upon excitation at absorption maximum of ligands. Their photophysical studies indicate the sensitization of Er3+ luminescence by energy transfer through the excited triplet state of β-diketone ligand. The energy transfer rate through the excited triplet state of β-diketone ligand to Er3+ ion occurs faster than that of the oxygen quenching rate.

• Journal of Photoscience
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• 제2권1호
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• pp.13-18
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• 1995

The steady-state emission spectra of dicoumarol (DC) in ethanol and EPA have been examined at various temperatures (77-298 K). At room temperature, a fluorescence spectrum of DC in ethanol shows a emission maximum at 350 nm. In EPA a Stokes-shifted emission band appears around 470 nm in addition to the 350 nm emission, and its intensity is enhanced as temperature decreases. This emission is attributed to a zwitterionic tautomer of DC formed by a single excited-state intramolecular proton transfer (ESIPT) along the internal hydrogen-bonding. The fluorescence lifetimes have been measured at 350 and 450 nm as a function of temperature. The fluorescence decay at 350 nm is single exponential at any temperature, whereas the one at 450 nm becomes biexponential at temperatures below 250 K. These results are discussed in terms of a conformational change followed by the ESIPT. The activation energy barrier for the conformational change has been determined to be 3.7 $\pm$ 0.2 kJ/mole.

• Bulletin of the Korean Chemical Society
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• 제17권5호
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• pp.461-463
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• 1996

The laser-induced fluorescence excitation spectrum of 7-amino-4-(trifluoromethyl)coumarin in a supersonic jet has been recorded in the 340-352 nm region. The electronic band origin was observed at 28622.8 cm-1. Vibrational assignments for the three fundamental low-frequency modes and eight combination bands have been made for the S1 electronic excited state. The out-of-plane vibrations of this molecule have been characterized from the low-frequency assignments of the spectrum. The periodic potential energy function for the CF3 torsion, which satisfactorily fits the observed data, were also determined to be V(Φ)=95X(1-cos3Φ)-32X(1-cos6Φ) where Φ is the torsional angle. The relatively low torsional barrier of 99 cm-1 in S1 state could be explained by the small steric interactions between the functional groups attached to a bicyclic ring.