• 제목/요약/키워드: Exciplex 형광법

검색결과 24건 처리시간 0.023초

Excimer 형광법을 이용한 연료증기 농도측정법에 대한 연구 (Measurement of Fuel Vapor Concentration by Excimer Fluorescence Method)

  • 황승민
    • 한국환경과학회지
    • /
    • 제27권6호
    • /
    • pp.437-445
    • /
    • 2018
  • Laser induced-exciplex-fluorescence (EXCIPLEX) proposed by Melton is used to visualize fuel vapor in spray combustion. However, in the EXCIPLEX method based on TMPD/naphthalene system, the TMPD : naphthalene ratio is strictly restricted to 1 : 9. In addition, fluorescence intensity due to the vapor phase is extremely weak. To overcome these drawbacks, we propose a new laser-induced-excimer fluorescence (EXCIMER) method to visualize the liquid and vapor phases simultaneously. The spatial distributions of liquid and vapor in fuel spray suspended by ultrasonic waves are compared using the EXCIPLEX and EXCIMER methods. The correlation between fuel vapor concentration and fluorescence intensity is experimentally investigated by measuring the fluorescence intensity of saturated vapor formed over liquid fuel at a controlled temperature. These experimental results indicate that the EXCIMER method is effective for evaluating fuel vapor visualization in spray combustion. Furthermore, the quantitative distribution of fuel vapor concentration can be correctly estimated by the EXCIMER method.

증발 조건에서 직분식 가솔린 분무의 증기 농도의 분포 (Distribution of the Concentration of Fuel Vapor in DI Gasoline Sprays Under Evaporation Condition)

  • 황순철;최동석;차건종;김덕줄
    • 한국분무공학회지
    • /
    • 제4권4호
    • /
    • pp.1-8
    • /
    • 1999
  • The concentration and spatial distribution of vapor phases in DI (Direct Injection) gasoline spray were measured quantitatively by exciplex fluorescence method. Fluorobenzene and DEMA (diethylmethylamine) in a solution of hexane were used as the exciplex-forming dopants. The fluorescence intensity of vapor phase were obtained by ICCD camera with the appropriate filter The relationship between fluorescence intensity and vapor concentration was induced fer the purpose of a quantitative analysis. The 2-D vapor/liquid images of fuel spray were captured under the evaporation condition, and the spatial distribution of vapor concentration was obtained. The spatial distribution of liquid phase had hollow-cone shape. And the vapor phase was widely distributed in the whole spray. The behavior of vapor phase was significantly affected by second flow such as entrainment, vortex, while that of liquid phase was scarcely affected.

  • PDF

가시화 측정을 이용한 증발디젤분무의 기초 연구 (A Basic study on the Evaporative Diesel Spray with Visible Measurement)

  • 염정국
    • 동력기계공학회지
    • /
    • 제13권3호
    • /
    • pp.20-26
    • /
    • 2009
  • 디젤기관에서 배출되는 유해배출성분인 NOx(Nitrogen oxides)와 PM(Particulate matter)은 기관 실린더내의 혼합기 분포에 의해 그 생성이 지배된다. 이 때문에 그 유해배출물들을 저감하기 위해서는 연소의 전단계인 혼합기 분포 및 그 생성과정의 해석은 매우 중요하다. 디젤기관에서 노즐로부터 분사된 연료는 주위기체와 혼합기를 형성하는 과정에서 액체에서 기체로 상변화를 동반한다. 따라서 분무의 혼합기형성과정을 해석하기 위해서는 액상과 기상을 동시에 분리하여 계측하는 것이 필요하다. 그러므로 본 연구에서는 디젤분무를 대상으로 Melton 등이 제안한 엑시플렉스(Exciplex) 형광법을 이용하여, 분무의 액상과 기상을 동시에 2차원분리해서 가시화촬영을 행하였다. 그 엑시플렉스 형광법을 이용하여 획득한 이미지에 화상 응용해석을 실시하여 비정상증발디젤분무의 혼합기형성과정에 대한 정보를 얻고자 하였다. 엑시플렉스 형광법을 이용해서 증발분무의 거동측성을 해석한 결과 프랙틸해석을 이용한 분무 흐트러짐(Disturbance)의 평가에서 플랙틸차원은 분사압력의 변화에 관계없이 하나의 값, 약 1.1로 정리 할 수 있고, 그 결과 각 분사압력에 대한 분무 기상외곽곡선(외주)은 거의 동일한 정도의 요철형상을 갖는다.

  • PDF

GDI 분무의 기.액상 분포를 통한 분무의 성장 특성 (Characteristics of Spray Development from Vapor/Liquid Phase Distribution for GDI Spray)

  • 황순철;최동석;김덕줄
    • 한국자동차공학회논문집
    • /
    • 제9권2호
    • /
    • pp.50-58
    • /
    • 2001
  • The purpose of this research is to obtain the information of the development process of a vaporizing GDI spray using exciplex fluorecence method. Fluorobenzene/DEMA system was used as the exciplex-forming dopants. The 2-D spray images of liquid and vapor phases were acquired, and the behavior of both phases was analyzed by the image processing. The experiment was performed at the three different ambient perssures and the ambient temperature of 273K and 473K. As the result of this work, it was found that the development characteristics of GDI spray have stronger effect on the ambient pressure than on the ambient temperature. With an increase of ambient pressure, the distribution of vapor phase was decreased and the concentration of that was denser. Two regions, namely cone and mixing regions could be identified from those resulrs.

  • PDF

분무각이 다른 GDI인젝터에 대한 증발특성 (Vaporizing Characteristics of Spray from Two Different GDI Injectors)

  • 최동석;김덕줄
    • 대한기계학회논문집B
    • /
    • 제25권5호
    • /
    • pp.688-696
    • /
    • 2001
  • Vaporizing characteristics of two GDI injectors with different spray angles were investigated using exciplex fluorescence method. Injector I has narrower spray angle, while injector II has wider one. The exciplex system of fluorobenzene and DEMA in a non-fluorescing base fuel of hexane was employed. In quantifying concentration of fuel vapor, quenching of concentration and temperature was corrected. Droplet size and velocity were also measured by PDPA under non-vaporizing condition. From obtaining the images of liquid and vapor phases, vaporizing GDI sprays could be divided as two regions: cone and mixing regions. For injector I, vortex region was not developed. High concentration of fuel vapor due to vaporization of many fine droplets was distributed near the spray axis. For injector II, droplets with the diameter of about 10 $\mu$m were distributed in the vortex region. The vortex region had high concentration of fuel vapor due to vaporization of these droplets. Particularly, higher and lower concentrations of fuel vapor were balanced at 2ms after the start of injection for injector II.

엔진 유동장에서 분사시기에 따른 혼합기의 기ㆍ액상 농도 분포에 관한 연구 (Concentration Distribution of Liquid/vapor Phases under In-Cylinder Flow Field with Different Injection Timings)

  • 김한재;최동석;김덕줄
    • 한국자동차공학회논문집
    • /
    • 제9권5호
    • /
    • pp.96-104
    • /
    • 2001
  • The present study experimentally investigates the concentration distribution of liquid and vapor phase with different injection timings in the in-cylinder flow field of a optically accessible engine. The conventional MPI, DOHC engine was modified into DI gasoline engine. The images of liquid and vapor phases in the motoring engine were captured by using exciplex fluorescence method. Dopants used in this study were 2% fluorobenzene and 9% DEMA(diethyl-methyl-amino) in 89% solution of hexane by volume respectively. Two dimensional spray fluorescence images of liquid and vapor phases were acquired to analyze spray behaviors and fuel distribution in the in-cylinder flow field. Measurements were carried out fur four different injection timings, namely BTDC 270$^{\circ}$, 180$^{\circ}$, 90$^{\circ}$, and 50$^{\circ}$. Experimental results indicate that behaviors and distribution of vapor phase were largely affected by in-cylinder tumble flow, and mixture formation process was also greatly affected by in-cylinder flow at early injection mode and by ambient pressure at late injection mode.

  • PDF

중앙 분사방식의 직분식 가솔린 기관에서 연료 혼합기 형성에 미치는 분사시기와 캐비티 형상의 영향 (The Effect of Injection Timing and Cavity Geometry on Fuel Mixture Formation in a Central Injected DI Gasoline Engine)

  • 김태안;강정중;김덕줄
    • 한국자동차공학회논문집
    • /
    • 제12권2호
    • /
    • pp.32-38
    • /
    • 2004
  • This study was performed to investigate the behavior of liquid and vapor phase of fuel mixtures with different piston cavity diameters in a optically accessible engine. The conventional engine was modified as Central Injected DI gasoline engine with swirl motion. Two dimensional spray fluorescence images of liquid and vapor phase were acquired to analyze spray behavior and fuel distribution inside of cylinder using exciplex fluorescence method. Piston cavity geometries were set by Type S, M and L. The results obtained are as follows. In the spray formation after SOI, the cone angle and width of the spray were decreased at late injection timing. With a fuel injection timing of BTDC $180^{\circ}C$, fuel was not greatly affected in a piston cavity but generally distributed as homogeneous mixture in the cylinder. With a fuel injection timings of BTDC $90{\circ}C$ and $60^{\circ}C$, fuel mixture was widely distributed in near the cavity center. As a injection timing was late in the compression stroke, residual width of fuel mixture was narrow in proportion to piston cavity.

직분식 가솔린기관 내에서 피스톤 형상이 연료혼합기 거동에 미치는 영향 (The Effect of Piston Bowl Shape on Behavior of Vapor Phase in a GDI Engine)

  • 황필수;강정중;김덕줄
    • 대한기계학회논문집B
    • /
    • 제26권4호
    • /
    • pp.614-621
    • /
    • 2002
  • This study was performed to investigate the behavior of vapor phase of fuel mixtures with different piston bowl shapes(F, B and R-type) in a optically accessible engine. The images of liquid and vapor phases were captured in the motoring engine using exciplex fluorescence method. Fuel was injected into atmospheric nitrogen to prevent quenching phenomenon by oxygen. Injection pressure was 5.1MPa. Two dimensional spray fluorescence image of vapor phase was acquired to analyze spray behaviors and fuel distribution inside of cylinder. Four injection timings were set at BTDC 90$^{\circ}$, 80$^{\circ}$, 70$^{\circ}$, and 60$^{\circ}$. With a fuel injection timing of BTDC 90$^{\circ}$, fuel-rich mixture level in the center region was highest in a B-type piston. With a fuel injection timing of BTDC 60$^{\circ}$, R-type piston was best. R-type piston shape was suitable under enhanced swirl ratio and late injection condition and B-type piston shape was right in a weak swirl ratio. It was found that the piston bowl shape affected the mixture stratification inside of cylinder.

피스톤 형상에 따른 직분식 가솔린기관 내에서의 연료혼합기 거동특성 연구 (The Effect of Piston Bowl Shape on Behavior of Vapor Phases in a GDI Engine)

  • 황필수;강정중;김덕줄
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2001년도 추계학술대회논문집B
    • /
    • pp.915-920
    • /
    • 2001
  • This study was performed to investigate the behavior of vapor phase of fuel mixtures with different piston bowl shapes(F, B, and R-type) in a optically accessible engine. The images of liquid and vapor phases were captured in the motoring engine using exciplex fluorescence method. Fuel was injected into atmospheric nitrogen to prevent quenching phenomenon by oxygen. Injection pressure is 5.1MPa. Two dimensional spray fluorescence image of vapor phases was acquired to analyze spray behaviors and fuel distribution inside of cylinder. Four injection timings were set at BTDC $90^{\circ},\;80^{\circ},\;70^{\circ},\;and\;60^{\circ}$. With a fuel injection timing of BTDC $90^{\circ}$, fuel-rich mixture level in the center region was highest in a B-type piston. With a fuel injection timing of BTDC $60^{\circ}$, R-type piston was best. R-type piston shape was suitable under enhanced swirl ratio and late injection condition and B-type piston shape was right in a weak swirl ratio. It was found that the piston bowl shape affected the mixture stratification inside of cylinder.

  • PDF

직분식 가솔린 엔진에서 피스톤 캐비티 반경에 따른 연료 거동 분석 (A Study on the Fuel Behaivor with Cavity Diameter in a Gasoline Direct Injection Engine)

  • 김태안;강정중;김덕줄
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2003년도 추계학술대회
    • /
    • pp.472-477
    • /
    • 2003
  • This study was performed to investigate the behavior of vapor phase of fuel mixtures with different piston cavity diameters in a optically accessible engine. The images of vapor phases were measured in the motoring engine using exciplex fluorescence method. The conventional engine was modified as GDI engine with swirl flow. Fuel was injected into atmospheric nitrogen to prevent quenching phenomenon by oxygen. Injection pressure is 5.1MPa. Two dimensional spray fluorescence image of vapor phases was acquired to analyze spray behavior and fuel distribution inside of cylinder. Three injection timings were set at BTDC $180^{\circ}$, $60^{\circ}$and $60^{\circ}$. With a fuel injection timing of BTDC $60^{\circ}$, fuel-rich mixture was concentrated in near the cavity center. With a fuel injection timing of BTDC $60^{\circ}$, fuel-rich mixture level in the center region was highest in the S-type during the late compression stroke. With a fuel injection timing of BTDC $180^{\circ}$, fuel was not affected in a piston cavity and generally distributed as homogeneous mixture.

  • PDF