• Title/Summary/Keyword: Exchange-Coupled

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Numerical Simulation of the Oscillating Flow Effect in the Channel of Polymer Electrolyte Membrane Fuel Cell (왕복 유동을 통한 확산증대 효과가 연료전지 성능에 미치는 영향에 대한 수치해석)

  • Kim, Jongmin;Kang, Kyung-Sik
    • Journal of the Korea Safety Management & Science
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    • v.20 no.4
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    • pp.7-13
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    • 2018
  • This study investigates the enhancement of the oxygen diffusion rate in the cathode channel of a proton exchange membrane fuel cell (PEMFC) by pure oscillating flow, which is the same as the mechanism of human breathe. Three-dimensional numerical simulation, which has the full model of the fuel cell including electrochemical reaction, ion and electronic conduction, mass transfer and thermal variation and so on, is performed to show the phenomena in the channel at the case of a steady state. This model could analysis the oscillating flow as a moving mesh calculation coupled with electrochemical reaction on the catalyst layer, however, it needs a lot of calculation time for each case. The two dimensional numerical simulation has carried on for the study of oscillating flow effect in the cathode channel of PEMFC in order to reduce the calculation time. This study shows the diffusion rate of the oxygen increased and the emission rate of the water vapor increased in the channel by oscillating flow without any forced flow.

Measurement of heavy metals in antarctic soil at the king sejong station: application of isotope dilution inductively coupled plasma mass spectrometry (동위원소희석 ICP-MS분석법에 의한 남극 세종기지 주변 토양의 중금속 측정)

  • Suh, Jung-Ki;Hwang, Euijin;Min, Hyung Sik
    • Analytical Science and Technology
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    • v.21 no.5
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    • pp.364-374
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    • 2008
  • Antarctic Environmental Monitoring Handbook' was published by COMNAP/SCAR in 2000. The standardized method described in this handbook is recommended for monitoring of antarctic environment. High pressure bomb technique in this guide was used to decompose soil samples. In compliance with this guide book, high pressure bomb technique was applied to decompose the antarctic soil sampled at the King Sejong Station. An Isotope Dilution-Inductively Coupled Plasma-Mass Spectrometry (ID-ICP-MS) was applied to determine mass concentrations of Pb, Cu and Zn in the soil. The accuracy in this method was verified by the analysis of certified reference materials (CRM) of NIST 2702 (marine sediment). The analytical results agreed with certified value within the range from 99.5~100.8%. Matrix separation was necessitated for the determination of Cu and Zn by Chelex 100 ion exchange resin. As a result, the average mass concentrations of Pb, Cu and Zn which are suspected to be caused by anthropogenic pollution were 332.9 mg/kg, 95.6 mg/kg and 115.3 mg/kg, respectively. Those for the metals sampled in the soils of the remote regions from the station were 28.1 mg/kg, 101.8 mg/kg and 115.6 mg/kg, respectively.

Study on Thermal Performance of Energy Textile in Tunnel (터널 지열 활용을 위한 에너지 텍스타일의 열교환 성능 연구)

  • Lee, Chulho;Park, Sangwoo;Sohn, Byonghu;Choi, Hangseok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.5
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    • pp.1907-1914
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    • 2013
  • Textile-type heat exchangers installed on the tunnel walls for facilitating ground source heat pump systems, so called "energy textile", was installed in an abandoned railroad tunnel around Seocheon, South Korea. To evaluate thermal performance of the energy textile, a series of long-term monitoring was performed by artificially applying daily intermittent cooling and heating loads on the energy textile. In the course of the experimental measurement, the inlet and outlet fluid temperatures of the energy textile, pumping rate, temperature distribution in the ground, and air temperature inside the tunnel were continuously measured. From the long-term monitoring, the heat exchange rate was recorded as in the range of 57.6~143.5 W per one unit of the energy textile during heating operation and 362.3~558.4 W per one unit during cooling operation. In addition, the heat exchange rate of energy textile was highly sensitive to a change in air temperature inside the tunnel. The field measurements were verified by a 3D computational fluid dynamics analysis (FLUENT) with the consideration of air temperature variation inside the tunnel. The verified numerical model was used to evaluate parametrically the effect of drainage layer in the energy textile.

The Clay Mineralogy of some Low Productive Paddy Soils In Kyonggi-Do (경기도(京畿道) 저위생산답(低位生産畓)의 점토광물(粘土鑛物)에 관(關)한 연구(硏究))

  • Shim, Sang Chil;Kim, Tai Soon;Lee, Hyung Koo;Song, Ki Joon;Valencia, I.G.
    • Korean Journal of Soil Science and Fertilizer
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    • v.7 no.3
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    • pp.127-135
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    • 1974
  • The samples were taken from the following localities previously classified as "Akiochi" area: Yangpyung, Puchun, and Pyungtaik, all of Kyonggi-do province. Five soil profiles were described in the field, and taken to the laboratory for physical and chemical analysis and mineralogical analysis by X-ray diffraction. The predominant clay minerals consist mainly of illite, vermiculite, chlorites and intergrade with vermiculite, and kaolinite. Illite or mica was found present in all samples and in all horizons. This was identified by the 9.83 to $10{\AA}$ (0.01) and $3.32{\AA}$ (003) basal reflections, Interhorizontal variations in mineral content and crystallinity are illustrated in their respective Xray diffractogram. Comparing the peak intensity, of the $14{\AA}$, $10{\AA}$ and $7{\AA}$ indicated the degree of weathering from the surface to the lower horizons. In general, the weathering of illite on the surface produced less pronounced $10{\AA}$ and $14{\AA}$ peak as compared to the lower horizons. The same may be said with kaolinite. On K-saturation, the $14{\AA}$ peak broadening on the low angle side was observed. This is interpreted to be due to chlorization. Heat treament from $100^{\circ}C$, $200^{\circ}C$, $400^{\circ}C$, $600^{\circ}C$, and $800^{\circ}C$. caused significant changes in the different diffractograms. Heating caused collasped of the $14{\AA}$ to $10{\AA}$ and the appearance of scattered peaks between $10-14{\AA}$. This is interpreted to the presence of vermiculite chlorite intergradient. The complete collapse of the $14{\AA}$ at $800^{\circ}C$ to $10{\AA}$ with increased intensity was attributed to the preservce of vermiculite. The principal difference among the clay minerals in each horizon is the concomitant increase and decrease in intensity with depth of the $14{\AA}$, $10{\AA}$ and $7{\AA}$ diffraction spacings. Apparently the weathering of illite ($10{\AA}$) is resulting in the formation of vermiculite ($14{\AA}$) and the interstratified material being an intermediate stage and the beginning of the formation of vermiculite. Some broadening- in the 17 to $18{\AA}$ was observed in Puchun-1 Pyungtaik-1 and Pyungtaik-2 specially so in the lower horizon in the Ca or Mg-saturated sample. Heated treatment tend to shift this peak to $14{\AA}$ indicating the presence of regular layering of the interstratified complex. The high amount of extractable aluminum and iron coupled with low exchange capacity indicate that iron and aluminum plays an important role in the weathering of these soils and is responsible to the low exchange capacity, high acidity and high phosphate absorptive capacity. The results presented substantiated the weathering sequence of Jackson in that mica ${\rightarrow}$ vermiculite ${\rightarrow}$ chloritezed vermiculite ${\rightarrow}$ kaolinite.

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A study on the evaluation of metal component in automatic transmission fluid by vehicle driving (차량 운행에 따른 자동변속기유(ATF) 금속분 분석평가 연구)

  • Lee, Joung-Min;Lim, Young-Kwan;Doe, Jin-Woo;Jung, Choong-Sub;Han, Kwan-Wook;Na, Byung-Ki
    • Journal of Energy Engineering
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    • v.23 no.2
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    • pp.28-34
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    • 2014
  • Automatic transmission fluid (ATF) is used for automatic transmissions in the vehicle as the characterized fluid. Recently, the vehicle manufacture usually guarantee for fluid change over 80000~100000 km mileage or no exchange, but most drivers usually change ATF below every 50000 km driving in Republic of Korea. It can cause to raise environmental contamination by used ATF and increase the cost of driving by frequently ATF change. In this study, we investigate the various physical properties such as flash point, fire point, pour point, kinematic viscosity, cold cranking simulator, total acid number, and metal component concentration for fresh and used ATF after driving (50000 km, 100000 km). The result showed that the total acid number, pour point, Fe, Al and Cu component had increased than fresh ATF, but 2 kind of used oil (50000 km and 100000km) had similar physical values and metal component concentration.

Impacts of Land Surface Boundary Conditions on the Short-range weather Forecast of UM During Summer Season Over East-Asia (지면경계조건이 UM을 이용한 동아시아 여름철 단기예보에 미치는 영향)

  • Kang, Jeon-Ho;Suh, Myoung-Seok
    • Atmosphere
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    • v.21 no.4
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    • pp.415-427
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    • 2011
  • In this study, the impacts of land surface conditions, land cover (LC) map and leaf area index (LAI), on the short-range weather forecast over the East-Asian region were examined using Unified Model (UM) coupled with the MOSES 2.2 (Met-Office Surface Exchange Scheme). Four types of experiments were performed at 12-km horizontal resolution with 38 vertical layers for two months, July and August 2009 through consecutive reruns of 72-hour every 12 hours, 00 and 12 UTC. The control experiment (CTRL) uses the original IGBP (International Geosphere-Biosphere Programme) LC map and old MODIS (MODerate resolution Imaging Spectroradiometer) LAI, the new LAI experiment (NLAI) uses improved monthly MODIS LAI. The new LC experiment (NLCE) uses KLC_v2 (Kongju National Univ. land cover), and the new land surface experiment (NLSE) uses KLC_v2 and new LAI. The reduced albedo and increased roughness length over southern part of China caused by the increased broadleaf fraction resulted in increase of land surface temperature (LST), air temperature, and sensible heat flux (SHF). Whereas, the LST and SHF over south-eastern part of Russia is decreased by the decreased needleleaf fraction and increased albedo. The changed wind speed induced by the LC and LAI changes also contribute the LST distribution through the change of vertical mixing and advection. The improvement of LC and LAI data clearly reduced the systematic underestimation of air temperature over South Korea. Whereas, the impacts of LC and LAI conditions on the simulation skills of precipitation are not systematic. In general, the impacts of LC changes on the short range forecast are more significant than that of LAI changes.

Modified Lorenz Chaos Synchronization Via Active Sliding Mode Controller (능동 슬라이딩 모드 제어기를 이용한 변형된 Lorenz 카오스 동기화)

  • Ryu, Ki-Tak;Lee, Yun-Hyung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.7
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    • pp.16-23
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    • 2018
  • Chaos is one of the most significant topics in nonlinear science, and has been intensively studied since the Lorenz system was introduced. One characteristic of a chaotic system is that the signals produced by it do not synchronize with any other system. It therefore seems impossible for two chaotic systems to synchronize with each other, but if the two systems exchange information in just the right way, they can synchronize. This paper addresses the problem of synchronization in a modified Lorenz chaotic system based on active control, sliding mode control, and the Lyapunov stability theory. The considered synchronization scheme consists of identical drive and response generalized systems coupled with linear state error variables. For this, a brief overview of the modified Lorenz chaotic system is given. Then, control rules are derived for chaos synchronization via active control and slide mode control theory, with a strategy for solving the chattering problem. The asymptotic stability of the overall feedback system is established using the Lyapunov stability theory. A set of computer simulation works is presented graphically to confirm the validity of the proposed method.

Quantitative Speciation of Selenium in Human Blood Serum and Urine with AE- RP- and AF-HPLC-ICP/MS

  • Jeong, Ji-Sun;Lee, Jonghae;Pak, Yong-Nam
    • Bulletin of the Korean Chemical Society
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    • v.34 no.12
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    • pp.3817-3824
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    • 2013
  • Various separation modes in HPLC, such as anion exchange (AE), reversed-phase (RP), and affinity (AF) chromatography were examined for the separation of selenium species in human blood serum and urine. While RP- and AE-HPLC were mainly used for the separation of small molecular selenium species, double column AF-HPLC achieved the separation of selenoproteins in blood serum efficiently. Further, the effluent of AF-HPLC was enzymatically hydrolyzed and then analyzed with RP HPLC for selenoamino acid study. The versatility of the hybrid technique makes the in-depth study of selenium species possible. For quantification, post column isotope dilution (ID) with $^{78}Se$ spike was performed. ORC ICP/MS (octapole reaction cell inductively coupled plasma/mass spectrometry) was used with 4 mL $min^{-1}$ Hydrogen as reaction gas. In urine sample, inorganic selenium and SeCys were identified. In blood serum, selenoproteins GPx, SelP and SeAlb were detected and quantified. The concentration for GPx, SelP and SeAlb was $22.8{\pm}3.4\;ng\;g^{-1}$, $45.2{\pm}1.7\;ng\;g^{-1}$, and $16.1{\pm}2.2\;ng\;g^{-1}$, respectively when $^{80}Se/^{78}Se$ was used. The sum of these selenoproteins ($84.1{\pm}4.4\;ng\;g^{-1}$) agrees well with the total selenium concentration measured with the ID method of $87.0{\pm}3.0\;ng\;g^{-1}$. Enzymatic hydrolysis of each selenium proteins revealed that SeCys is the major amino acid for all three proteins and SeMet is contained in SeAlb only.

PUF Logic Employing Dual Anti-fuse OTP Memory for High Reliability (신뢰성 향상을 위한 듀얼 안티퓨즈 OTP 메모리 채택 D-PUF 회로)

  • Kim, Seung Youl;Lee, Je Hoon
    • Convergence Security Journal
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    • v.15 no.3_1
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    • pp.99-105
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    • 2015
  • A typical SRAM-based PUF is used in random number generation and key exchange process. The generated out puts should be preserved, but the values are changed owing to the external environment. This paper presents a new D-PUF logic employing a dual anti-fuse OTP memory to the SRAM-based PUF. The proposed PUF can enhance the reliability of the logic since it can preserve the output values. First, we construct the OTP memory using an anti-fuse. After power up, a SRAM generates the random values owing to the mismatch of cross coupled inverter pair. The generated random values are programed in the proposed anti-fuse ROM. The values that were programed in the ROM at once will not be changed and returned. Thus, the outputs of the proposed D-PUF are not affected by the environment variable such as the operation voltage and temperature variation, etc. Consequently, the reliability of the proposed PUF will be enhanced owing to the proposed dual anti-fuse ROM. Therefore, the proposed D-PUF can be stably operated, in particular, without the powerful ECC in the external environment that are changed.

Generation of Protein Lineages with new Sequence Spaces by Functional Salvage Screen

  • Kim, Geun-Joong;Cheon, Young-Hoon;Park, Min-Soon;Park, Hee-Sung;Kim, Hak-Sung
    • Proceedings of the Korean Society for Applied Microbiology Conference
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    • 2001.06a
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    • pp.77-80
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    • 2001
  • A variety of different methods to generate diverse proteins, including random mutagenesis and recombination, are currently available, and most of them accumulate the mutations on the target gene of a protein, whose sequence space remains unchanged. On the other hand, a pool of diverse genes, which is generated by random insertions, deletions, and exchange of the homologous domains with different lengths in the target gene, would present the protein lineages resulting in new fitness landscapes. Here we report a method to generate a pool of protein variants with different sequence spaces by employing green fluorescent protein (GFP) as a model protein. This process, designated functional salvage screen (FSS), comprises the following procedures: a defective GFP template expressing no fluorescence is firstly constructed by genetically disrupting a predetermined region(s) of the protein, and a library of GFP variants is generated from the defective template by incorporating the randomly fragmented genomic DNA from E. coli into the defined region(s) of the target gene, followed by screening of the functionally salvaged, fluorescence-emitting GFPs. Two approaches, sequence-directed and PCR-coupled methods, were attempted to generate the library of GFP variants with new sequences derived from the genomic segments of E. coli. The functionally salvaged GFPs were selected and analyzed in terms of the sequence space and functional property. The results demonstrate that the functional salvage process not only can be a simple and effective method to create protein lineages with new sequence spaces, but also can be useful in elucidating the involvement of a specific region(s) or domain(s) in the structure and function of protein.

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