• Title/Summary/Keyword: Exchange times

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Fabrication of electro-optical modulator of directional coupler $2{\times}2$ ($2{\times}2$ 방향성 결합형 광 변조기의 제작 연구)

  • Kang, Ki-Sung;Chae, Kee-Byung;Soh, Dae-Wha
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1993.05a
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    • pp.113-116
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    • 1993
  • A guided - wave electro - optical modulatored directional coupler $2{\times}2$ was fabricated on X-cut $LiNbO_3$ by proton exchange wi th self-aligned method. The Electode pattern was formed by the four extra gap electrode separtion within self-aligned electrode mask. Initial cross over state turned that by controlling the anneal ing process and self-aligned electrodes are used in fabricating the electro-optical modulatored directional coupler $2{\times}2$. The modulatored directional coupler $2{\times}2$ has very good figures of merits: the measured crosstalk was -28.2 dB and the modulating valtage of 3.2[V].

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A Kinetic Study of Phosphate Absorption by Rice Roots (벼에 의한 인산흡수의 기작에 관한 연구)

  • 장남기
    • Journal of Plant Biology
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    • v.21 no.1_4
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    • pp.33-38
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    • 1978
  • Phosphate absorption from a Na2H32PO4 solution by Oryza sativa L. was studied in order to elucidate kinetic mechanisms of ion transport. The rates of phosphate absorption from different concentraitons indicated the presence of dual mechanisms in root tips, one in the low (1$\times$10-6 to 8$\times$10-5M) and the other in the high (1$\times$10-4 to 8$\times$10-3M). A phosphate compensation point of phosphate transport was revealed with a 1$\times$10-6M solution of Na2H32PO4. The kinetic model that ion transport involves an exchange reaction of absorption and desorptin is prosposed as follows: where C represents an ionic-specific organic carrier in the membrane; M, Mo and Mi are the mineral ions, M-outside and M-inside; MC is a carrier-ion complex; and the K's represent rate constants. In this model, the Mi velocity, v, is given by: {{{{v= {dMi} over {dt}= {(K1K3Mo-K2K4Mi) Ct} over {(K2+K3)+K1Mo+K4Mi} }} where Ct is equal to C+MC, and t is time.

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The Anion Exchange Chromatographic Studies on the Polymerization Equilibria of Molybdate and Tungstate and the Production of APT (음이온 교환크로마토그래피에 의한 몰리브덴산과 텅스텐산의 중합, 평형 및 APT 제조에 관한 연구)

  • Cha Ki Won;Park Kee Chae
    • Journal of the Korean Chemical Society
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    • v.19 no.4
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    • pp.225-232
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    • 1975
  • The elution behaviour of molybdate and tungstate through anion exchange column has been studied at the various pH. A discussion is made to evaluate the equilibrium constants of the polymerization of these acids comparing with the behaviour of chromate ion and dichromate ion. The eqailibrium constants found at $20^{\circ}$ are $K = 4{\times}10^{53} for 7MoO_4^{2-} + 8H^+ {\longleftrightarrow} Mo7O_{24}^{6- }+ 4H_2O$$ K = 3{\times}10^{54} for 6WO_4^{2-} + 7H^+ {\longleftrightarrow} HW6O_{21}^{5-} + 7H_2O$ referring to this results the conditions of separation of tungstate and molybdate are obtained. iThe quantitative separations of carbonate, molybdate and tungstate from the pregnant solution have been established by anion exchange chromatography, using the $22 cm{\times}44.27 cm^2$ column of Rexyn 201. The optimum eluents for the quantitative separation of those ions are as follows; 0.2M solution of sodium chloride at pH 8 for carbonate, the mixture of 0.5 M ammonium chloride and 0.05 M sodium sulfate at pH 5 for molybdate and 0.5 M solution of ammonium chloride at pH 10 for tungstate. Tungstate is directly recovered from the pregnant solution as a form of ammonium paratungstate, by eluting with ammonium chloride solution.

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Detection of Magnetic Bacteria Using PHR Sensors with Trilayer Structure (삼층박막 구조의 PHR 센서를 이용한 자기 박테리아 감지)

  • Yoo, Sang Yeob;Lim, Byeong Hwa;Song, In Cheol;Kim, Cheol Gi;Oh, Sun Jong
    • Journal of the Korean Magnetics Society
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    • v.23 no.6
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    • pp.200-204
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    • 2013
  • In this study, we have fabricated magnetoresistive sensors of $50{\mu}m{\times}50{\mu}m$ cross type by trilayer structure of antiferromagnetic/nonmagnetic/ferromagnetic. The magnetic signal and magnetic domain of this sensor is measured. The sensor hysteresis loop is not in symmetrical at 0 Oe. This is may be due to the exchange coupling between ferromagnetic layer and anti ferromagnetic layer. This exchange bias value is 20 Oe. The sensor signal is measured at between the applied magnetic field and current. The sensor signal is measured between the applied magnetic field and current at $20^{\circ}$ and $90^{\circ}$ angles. The sensitivity of sensor signals is $20{\mu}V/Oe$ and $7{\mu}V/Oe$ at $20^{\circ}$ and $90^{\circ}$ angles, respectively. In addition, this sensor is also applied for the detection of magnetic bacteria at $20^{\circ}$ angle. From these results, we calculate the stray field of single bacteria is to be $5{\times}10^{-5}$Oe.

A Study on Sensitivity Analysis and Uncertainty Analysis for Continuous Stirred Tank Reactors (연속교반탱크 반응기에 대한 민감도 및 불확실성 분석에 관한 연구)

  • Kim In-Won;Jin Sang-Hwa;Kim In-Tea;Song Hee-Oeul;Yeo Yeong-Koo
    • Journal of the Korean Institute of Gas
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    • v.5 no.4 s.16
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    • pp.70-78
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    • 2001
  • In order to find out which equipment failures were mostly contributed to the rupture of a continuous stirred tank reactor, the sensitivity analysis was carried out. The uncertainty of likelihood of the rupture of reactor was studied by the uncertainty analysis. And the cost effectiveness analysis resulted in the recommendation of the exchange with a better reliable unit if you want to maintain the process efficiently from the view point of cost. The uncertainty analysis showed that the likelihood of catastrophic rupture of the reactor was distributed from $8.09{\times}10^{-04}$ to $5.50{\times}10^{-02}/year$. As a result of cost-effectiveness analysis, it was proposed to exchange the voting logic unit for a better safer system.

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Continuous dialysis of selected salts of sulphuric acid

  • Bendova, Helena;Snejdrla, Pavel;Palaty, Zdenek
    • Membrane and Water Treatment
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    • v.1 no.3
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    • pp.171-179
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    • 2010
  • The transport of selected salts of sulphuric acid (cobalt, copper, iron(II), manganese, nickel and zinc sulphate) through an anion-exchange membrane Neosepta-AFN was investigated in a counter-current continuous dialyzer at various salt concentrations and volumetric liquid flow rates. The basic transport characteristics - the rejection coefficient of salt and the permeability of the membrane - were calculated from measurements at steady state. The salt concentration in model mixtures was changed in the limits from 0.1 to 1.0 kmol $m^{-3}$ and the volumetric liquid flow rate of the inlet streams was in the limits from $8{\times}10^{-9}$ to $24{\times}10^{-9}m^3\;s^{-1}$. Under the experimental conditions given, the rejection coefficient of salts tested was in the range from 65% to 94%. The lowest values were obtained for iron(II) sulphate, while the highest for copper sulphate. The maximum rejection of salt was reached at the highest volumetric liquid flow rate and the highest salt concentration in the feed. The permeability ($P_A$) of the Neosepta-AFN membrane for the individual salts was in the range from $0.49{\times}10^{-7}m\;s^{-1}$ to $1.8{\times}10^{-7}m\;s^{-1}$ and it can be described by the following series: $P_{FeSO_4}$ < $P_{NiSO_4}$ < $P_{ZnSO_4}$ < $P_{CoSO_4}$ < $P_{MnSO_4}$ < $P_{CuSO_4}$. The permeability of the membrane was strongly affected by the salt concentration in the feed - it decreased with an increasing salt concentration.

An Analysis on Mutual Shock Spillover Effects among Interest Rates, Foreign Exchange Rates, and Stock Market Returns in Korea (한국에서의 금리, 환율, 주가의 상호 충격전이 효과 분석)

  • Kim, Byoung Joon
    • International Area Studies Review
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    • v.20 no.1
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    • pp.3-22
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    • 2016
  • In this study, I examine mutual shock spillover effects among interest rate differences, won-dollar foreign exchange change rates, and stock market returns in Korea during the daily sample period from the beginning of 1995 to the October 16, 2015, using the multivariate GARCH (generalized autoregressive conditional heteroscedasticity) BEKK (Baba-Engle-Kraft-Kroner) model framework. Major findings are as follows. Throughout the 6 model estimation results of variance equations determining return spillovers covered from symmetric and asymmetric models of total sample period and two crisis sub-sample periods composed of Korean FX Crisis Times and Global Financial Crisis Times, shock spillovers are shown to exist mainly from stock market return shocks. Stock market shocks including down-shocks from the asymmetric models are shown to transfer to those other two markets most successfully. Therefore it is most important to maintain stable financial markets that a policy design for stock market stabilization such as mitigating stock market volatility.

Purification and Characterization of Extracellular Inulinase from Bacillus sp. (Bacillus sp.가 세포외로 생산하는 Inulinase의 정제 및 특성)

  • 김경남;최용진
    • Microbiology and Biotechnology Letters
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    • v.18 no.5
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    • pp.490-495
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    • 1990
  • The extracellular inulinase from Bacillus spp. was purified to a single protein through a sequence of operations including ammonium sulfate fractionation, heat treatment, DEAE Sepharose C1-6B ion exchange chromatography, Sephadex 6-100 and Sephadex 6-150 gel filtration. The purified enzyme was confirmed to be a $\beta$ -D-fructofuranosidase(EC 3.2.1.26) which was much more active on sucrose than on inulin(I/S = 0.2). The maximal inulinase activity was observed at pH 6.0 and at the temperature of $50^{\circ}C$. The mo1ecular weight of the enzyme was about 56, 000. Tryptophan and histidine residues of the enzyme molecule were found to be essential for its catalytic activity.

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Effect of the Molecular Weight of Poly(vinyl alcohol) Blended with Sulfonated Polysulfone Membranes for Fuel Cell Applications

  • Chang, Sung-Hyuk;Chung, Sung-Il;Rhim, Ji-Won
    • Korean Membrane Journal
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    • v.5 no.1
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    • pp.18-24
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    • 2003
  • In order to improve the mechanical properties of the sulfonated polysulfone (SPSf) membranes previously synthesized in our laboratory, poly(vinyl alcohol) (PVA) was blended which is well known as the excellent physical and chemical properties. The resulting membranes blended with several molecular weight of PVA varying from 13,000 to 124,000 have been characterized to investigate the effect of PVA molecular weight in terms of ion conductivities, methanol permeabilities, water contents and ion exchange capacities for both heat treated and untreated membranes at 150$^{\circ}C$. The proton conductivity is decreased as the molecular weight of PVA increases. The plain SPSf-6.0 showed the proton conductivity of 0.078 S/cm whereas the blended membrane with M.W. 31,000 PVA indicated 0.04 S/cm. For methanol permeabilities, when PVA is added to SPAf-6.0, methanol crossover is increased because of the gain of the hydrophilicity from 3.4 to 6.5${\times}$10$\^$-6/ $\textrm{cm}^2$/s. For the annealed blended membranes (with M.W. 31,000 PVA), both the methanol corssover and proton conductivity showed very consistent values, about 2.3${\times}$10$\^$-6/ $\textrm{cm}^2$/s and 0.036 S/cm, respectively.

Study on the Recovery and Determination of Scandium from Tin Slag (주석슬러그에서 스칸듐원소의 정량 및 회수에 관한 연구)

  • Cha, Gi Won;Jeong, Ui Sik;Kim, Gyeong Hwan
    • Journal of the Korean Chemical Society
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    • v.34 no.1
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    • pp.98-101
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    • 1990
  • A new spectrophotometric determination method of scandium in the tin slag solution has been investigated using methyl thymol blue as a colorimetric reagent. Scandium is recovered by the anion exchange resin, Amberlite IRA 400, using the mixture solution of ammonium sulfate and sulfuric acid and an eluent. The mole ratio of complex of scandium and MTB at pH 6 is 1 to 1 and the wave length of the maximum absorbance is 585 nm and the molar absorptivity at this wave length is $2.0 {\times} 10^4\;\iota{\cdot}mol^{-1}{\cdot}cm^{-1}$. When tin slag solution is loaded into anion exchange resin and eluted, ions in the solution except scandium ion are eluted rapidly and scandium is eluted lately. So scandium is recovered easily.

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